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A11103 0bbM03
NATL INST OF STANDARDS & TECH R.I.C.
A1 11 03066403
NIST
PUBLICATIONS
.,;^, -^^ gss siiMi wapfc ,- EC H N I C AL N OT E 1 325
U.S. DEPARTMENT OF COMMERCE / National Institute of Standards and Technology
QC
100
.U5753
E1325
1989
C.2
rhe National Institute of Standards and Technology^ was established by an act of Congress on March 3,
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Tables for the
Thermophysical Properties of
Methane
Daniel G. Friend
James F. Ely
Hepburn Ingham
Thermophysics Division
Center for Chemical Engineering
National Engineering Laboratory
National Institute of Standards and Technology
Boulder, Colorado 80303-3328
^^^^^°^^o.
^^ATES O^ ^
U.S. DEPARTMENT OF COMMERCE, Robert A. Mosbacher, Secretary
NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY, Raymond G. Kammer, Acting Director
Issued April 1989
National Institute of Standards and Technology Technical Note 1325
Natl. Inst. Stand. Technol., Tech. Note 1325, 490 pages (Apr. 1989)
CODEN:NTNOEF
U.S. GOVERNMENT PRINTING OFFICE
WASHINGTON: 1989
CONTENTS
ABSTRACT ix
1 , INTRODUCTION 1
2. THERMODYNAMIC PROPERTIES AND THEIR ALGEBRAIC REPRESENTATION 2
2 . 1 Fixed Point Constants 2
2 . 2 Liquid-Vapor Saturation Boundary 4
2 . 3 Ideal Gas Equation 5
2.4 Residual Helmholtz Energy 6
2 . 5 Derived Property Equations 8
3. TRANSPORT PROPERTIES AND THEIR ALGEBRAIC REPRESENTATION 12
3 . 1 Dilute Gas Correlations 12
3 . 2 Excess Property Correlations 14
3 . 3 Critical Enhancement Correlation 15
4. SUMMARY OF UNCERTAINTIES ASSOCIATED WITH THE CORRELATIONS 18
4 . 1 Two - Phase Boundary 18
4 . 2 Thermodynamic Properties 19
4 . 3 Transport Properties 22
5 . ACKNOWLEDGMENTS 24
6 . REFERENCES 25
APPENDIX A: TABLES FOR THE COMPARISON OF EXPERIMENTAL
DATA AND THE CORRELATIONS 31
APPENDIX B: TABLES FOR THE THERMO PHYSICAL PROPERTIES
OF METHANE 287
APPENDIX C: LISTING OF A FORTRAN 77 PROGRAM TO CALCULATE
THE THERMO PHYSICAL PROPERTIES OF METHANE 443
111
LIST OF TABLES
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
Al.
A2.
A3.
A4.
A5.
A6.
A7.
A8.
A9.
AlO.
All.
A12.
A13.
A14.
Bl.
B2.
B3.
B4.
FIXED POINT CONSTANTS AND OTHER PARAMETERS USED IN THE CORRELATIONS 3
COEFFICIENTS FOR LIQUID-VAPOR BOUNDARY CORRELATIONS 5
COEFFICIENTS FOR IDEAL GAS FREE ENERGY, EQ (5) 6
EXPONENTS AND COEFFICIENTS FOR THE RESIDUAL FREE ENERGY (j)^ (EQ (6)) 7
IDEAL GAS FREE ENERGY AND ITS DERIVATIVES 9
RESIDUAL FREE ENERGY AND ITS DERIVATIVES 10
THERMODYNAMIC PROPERTY EQUATIONS 11
COEFFICIENTS FOR DILUTE GAS TRANSPORT PROPERTIES 13
COEFFICIENTS FOR EXCESS TRANSPORT PROPERTY CORRELATIONS 15
CONSTANTS FOR A 17
cr
COMPARISONS FOR SATURATED VAPOR PRESSURES 33
COMPARISONS FOR SATURATED LIQUID DENSITIES 40
COMPARISONS FOR SATURATED VAPOR DENSITIES 52
COMPARISONS OF EXPERIMENTAL AND CALCULATED PVT DATA 58
COMPARISONS FOR SECOND VIRIAL COEFFICIENTS 143
COMPARISONS FOR ISOCHORIC SPECIFIC HEAT CAPACITY 145
COMPARISONS FOR ISOBARIC SPECIFIC HEAT CAPACITY 156
COMPARISONS FOR SPECIFIC HEAT CAPACITY OF THE SATURATED LIQUID 170
COMPARISONS FOR SOUND SPEED 173
COMPARISONS FOR COLLISION INTEGRAL 196
COMPARISONS FOR ZERO DENSITY VISCOSITY 198
COMPARISONS FOR ZERO DENSITY THERMAL CONDUCTIVITY 204
COMPARISONS FOR VISCOSITY AT ELEVATED PRESSURES 211
COMPARISONS FOR THERMAL CONDUCTIVITY AT ELEVATED PRESSURES 229
PROPERTIES OF IDEAL GAS AT . 1 MPA AND DILUTE GAS
TRANSPORT PROPERTIES 288
PROPERTIES ALONG SATURATION BOUNDARY 298
PROPERTIES IN THE SINGLE- PHASE REGION ALONG ISOBARS 301
PROPERTIES IN THE SINGLE- PHASE REGION ALONG ISOTHERMS 412
LIST OF SYMBOLS AND UNITS
Symbol
Description
SI Units
(used in text)
REFERENCE
Roman
A
a,b
B
C.
1
E
F
G.
1
H
H.
1
k
M
n,
1
P
Q
R
R
Molar Helmholtz energy
Exponents in scaled equation
Second virial coefficient
(2 2)*
Coefficients in '
Isobaric specific heat capacity
Isochoric specific heat capacity
Constant in scaled equation
Crossover function in X
cr
Coefficients in F
Contribution from internal modes
J»mol
-1 +
Molar Gibbs energy
Coefficients in p
oL
ex
aV
Coefficients in r/
Molar enthalpy
Coefficients in P
c
Coefficients in p
Coefficients in A
ex
Boltzmann constant
Relative molecular mass
Avogadro constant
Coefficients in ^
Pressure
Constant in scaled equation
Coefficients in <f)
Molar gas constant
Constant in scaled equation
A 3 n-1
dm 'mol
T 1-1 1.-1
J«mol 'K
J«mol 'K
J»mol
J»mol
J'K
mol
MPa
T 1-1 V-1
J»mol 'K
eq (4)
eq (21), table (10)
table (7)
eq (10), table (8)
table (7)
table (7)
eq (22), table (10)
eq (17)
eq (17), table (10)
eqs (11,12).
table (8)
table (7)
eq (2) , table (2)
eq (13), table (9)
tables (1,7)
eq (1), table (2)
eq (3), table (2)
eq (15), table (9)
table (1)
table (1)
table (1)
eq (6), table (4)
eq (21), table (10)
eq (5) , table (3)
table (1)
eq (21), table (10)
VI
LIST OF SYMBOLS AND UNITS (CONT'D)
Symbol
r.
1
s.
1
t
T
T
U
u
W
w
Z
Description
Exponent of 5
Molar entropy
Constant in scaled equation
SI Units
(used in text)
J»mol 'K
SWEOS Schmidt -Wagner Equation of State
Exponent of t
Reduced temperature, kT/e
Temperature, IPTS-68
Reduced temperature, (T -T)/T
Molar internal energy
Unified atomic mass unit
Constant in scaled equation
Speed of sound
Compressibility factor, P/RTp
REFERENCE
eqs (6,13,15).
tables (4,9)
table (7)
eq (22), table (10)
-
eqs (6,13,15).
tables (4.9)
-
eqs (9,10)
K
-
-
eq (18)
,-1
•mol
table (7)
kg
table (1)
-
eq (23), table (10)
-1
m»s
table (7)
-
eq (3)
Greek
fi Scaling exponent in p ,p
r Constant in scaled equation
S Reduced density, p/p
5 Reduced density variable
e Scaling exponent in P
€ Energy parameter potential
e/k Energy parameter potential
rj Shear viscosity
6 Variable in scaled equation
A Thermal conductivity
p Molar density
eqs (2,3),
table (2)
eq (24), table (10)
-
eq (14)
-
eq (1), table (2)
J
See e/k, below
K
table (1)
/iPa»s
eq (7)
-
eqs (21.22)
mW»m 'K
■1
eq (8)
mol 'dm
Vll
LIST OF SYMBOLS AND UNITS (CONT'D)
Symbol
Description
SI Units
REFERENCE
*
n
A.rrt
n
(2,2)*
Reduced density, (/? -p)/p
Distance parameter in potential
Reduced inverse temperature,! /T
Reduced Helmholtz energy, A/RT
Reduced compressibility
Variable in scaled equation
Reduced collision integral
nm
eq (19)
table (1)
eq (4)
eqs (20,21,24)
eqs (21,23)
eqs (9,10)
Superscripts
id Ideal gas contribution
r Residual contribution
Subscripts
c Value at critical point
cr Critical contribution
ex Excess contribution
t Value at triple point
tL.tV Value at triple point in liquid, vapor
a Value at saturation boundary
CTL,aV Value in saturated liquid, vapor
8 Partial derivative with respect to 5
T Partial derivative with respect to t
Value at zero density
eq (4) , table (1)
eq (4)
table (1)
eqs (8,16)
eqs (7,8,13,15)
table (1)
table (1)
eq (1)
eqs (2,3)
tables (5,6)
tables (5,6)
eqs (7-9,11)
Throughout this paper, the mole (mol) quantifies the amount of substance
whose elementary entities are the molecular constituents (CH, ) of the
methane fluid.
Vlll
TABLES FOR THE THERMOPHYSICAL PROPERTIES OF METHANE
Daniel G. Friend, James F. Ely and Hepburn Ingham
Thermophysics Division
National Engineering Laboratory
National Institute of Standards and Technology
(formerly National Bureau of Standards)
Boulder, Colorado 80303
The thermophysical properties of methane are tabulated for a large
range of fluid states based on recently formulated correlations.
For the thermodynamic properties, temperatures from 91 to 600 K at
pressures less than 100 MPa are included. For the viscosity, the
corresponding range is 91 - 400 K with pressures to 55 MPa, while
for the thermal conductivity the range is 91 - 600 K with
pressures to 100 MPa. In addition to the tables of properties,
algebraic expressions and associated tables of coefficients are
given to allow additional property calculations. Tables of
comparisons between experimental property determinations and the
correlations are also given both for primary data used in the
formulation of the correlations and for additional data. A
listing of a FORTRAN program for the evaluation of methane
thermophysical properties using the Schmidt-Wagner equation of
state is included.
Key words: correlation; density; equation of state; heat capacity;
methane; phase boundary; pressure; speed of sound; thermal
conductivity; thermophysical properties; transport properties;
virial coefficients; viscosity.
IX
1. INTRODUCTION
We have recently developed correlations for several of the
thermophysical properties of methane [1] , including an equation of state
analogous to that proposed by Schmidt and Wagner [2], equations for the
liquid-vapor phase boundary, and correlations for the fluid viscosity and
thermal conductivity. Details of the development and error analysis of
the formulations have been presented elsewhere [1]. In this paper, we
summarize our equations and present extensive tabular comparisons of the
correlations with experimental data and tables of properties based on these
correlations. We have also included the listing of a FORTRAN program
which can be used interactively to calculate properties of methane.
The rationale for these new correlations and the present set of tables
was discussed in Ref.[l]. Briefly summarized, since the extensive works of
Goodwin [3], Angus et al . [4], and Sychev et al. [5], for example, there
have been many new experimental measurements, including accurate phase
boundary measurements [6], critical region PVT experiments [7], and
extensive thermal conductivity [8] and viscosity measurements [9]. In
addition, the form of the residual Helmholtz energy correlation, first
proposed by Schmidt and Wagner [2], gives an excellent description of the
thermodynamic surface and describes the critical region extremely well for
a classical equation of state. The new ancillary equations for the phase
boundary incorporate the results of lowest order scaling theory, and both
viscosity and thermal conductivity correlations improve the description of
the fluid properties when compared to previous correlations. The economic
importance of methane, as the major constituent of natural gas, makes the
use of improved thermophysical properties correlations especially
desirable. Also, the present correlations should prove useful as reference
equations for corresponding states models for mixtures and other pure
fluids .
The next two sections give, for thermodynamic and transport
properties, the algebraic forms for the fluid property correlations with
very brief narrative. The List of Symbols and Units given above is a
-1-
useful adjunct to the equations, and tables of necessary coefficients and
constants are interspersed throughout the text. Extensive discussion of
the development of the equations and evaluation of fitted coefficients was
given in Ref.[l]. Tables which follow, in Appendix A, give the comparisons
between the correlations and experimental data; these include both primary
data, used in the determination of the coefficients in the equation, and
secondary data, not explicitly used for any of a number of
reasons as discussed in Ref.[l]. The next set of tables, in Appendix B,
gives values of the thermophysical properties for convenient values of the
temperature, density, or pressure. Finally, this report concludes with a
listing in Appendix C, of a FORTRAN 77 program which allows interactive
evaluation of many thermophysical properties for any state point within the
range of the correlations.
2. THERMODYNAMIC PROPERTIES
AND THEIR AIjGEBRAIC REPRESENTATION
2.1 Fixed Point Constants
Values for the critical and triple -point constants, intermolecular
potential parameters (for transport properties using the 11-6-8, 7=3
potential), reference values for ideal gas properties, and miscellaneous
constants are given in table 1. Details of the selection process and
quoted uncertainties are given in Ref.[l]. The values of the critical
constants, including all the quoted digits and disregarding the associated
uncertainties, are needed for evaluating the correlating equations below.
The fundamental constants in table 1 agree with the values most recently
recommended by CODATA [10].
-2-
TABLE 1
FIXED POINT CONSTANTS AND OTHER PARAMETERS USED IN THE CORRELATIONS
Triple Point:
T = 90.6854 ± 0.0003 K
P^ = 11.696 ± 0.002 kPa
p = 28.145 ± 0.005 mol.dm'^
p = 15.66 ± 0.05 mol.m'^
tv
Critical Point:
T = 190.551 ± 0.01 K
c
P = 4.5992 ± 0.003 MPa
c
p = 10.139 ± 0.01 mol.dm'^
c
Z = 0.28631 ± 0.0005
c
Intermolecular
Potential
Parameters :
6/k = 174 K a = 0.36652 nm
Ideal Gas
Reference Point
Values :
(at 298.15 K and 0.101 325 MPa)
S^^ = 186.266 J.K'-'-.mol'"'"
H^^ = 10.0177 kJ.mol'-^
Miscellaneous :
Relative molecular mass...M = 16.043
r
Universal gas constant. . .R = 8.314 510 J«mol 'K
-23 -1
Boltzmann constant... k = 1.380 658 x 10 J»K
23 -1
Avogadro constant. . .N = 6.022 136 7 x 10 mol
-27
Unified atomic mass unit...u = 1.660 540 2 x 10 kg
-3-
2.2 Liquid-Vapor Saturation Boundary
The three equations for the pressure, liquid density, and vapor
density along the two -phase boundary are described in this section.
Although the full equation of state can be used with the Maxwell
construction method to evaluate these quantities, these equations include
theoretically inspired scaling terms and are more accurate in the critical
region. The measurements of Kleinrahm and Wagner [6] were the primary data
used to establish these correlations.
For the saturated vapor pressure P , the equation
P (T) = P EXP [ H,T*/(1-T*) + H„T* + H.T*^ + H, T*^ + H^T*^ ], (1)
a c 1' 2 3 4 5
*
where T =(T -T)/T , is used. The necessary constants and critical exponent
are given in table 2
The densities of the saturated liquid p and saturated vapor
p are given by
av ^ ■'
'olP^ = ^c
1 +
*B *2 *3
G T ^+ G T + G T
1 + G,T
4
(l-yS)
(2)
and
p (T)r z -1
p (T)= -^— ^+P (T)r° -^—
R T ^ P
1+
J T ^ + J T '^ + J (T +T ) + J^T
*2 ^^-l
(3)
1 + J.T
4
respectively. In eq (3), Z - P /(RT p ) is the critical compressibility
factor given in table 1, t = T /T, and P (T) must be evaluated from eq (1)
The constants are again found in table 2. Tables Al , A2 , and A3 in
Appendix A give comparisons between experimental phase boundary
measurements and the quantities calculated by eqs (1-3).
4-
TABLE 2
COEFFICIENTS FOR LIQUID-VAPOR BOUNDARY CORRELATIONS
Saturated Vapor
Saturated Liquid
Saturated Vapor Density
Pressure eq (1)
Density eq (2)
eq
(3)
e = 1.90
^ = 0.355
^ =
0.355
H = -6.589 879
H^ = 0.635 517 5
G = 1.838 982
G^ = -0.772 745 2
r-
-0.737 748 3
-1.241 532
H = 11.310 28
H^ = -10.387 20
H^ = 3.393 075
G = 0.559 244 6
G; = -0.380 779 3
4
|:
-1.649 972
2.281 949
1.439 570
2.3 Ideal Gas Equation
The thermodynamic surface is described by an equation for the molar
Helmholtz energy, A. Thus, the important derived properties can be
obtained by simple, analytical differentiation. The Helmholtz energy is
divided into ideal gas and residual constituents according to
A(p,T) = A^^ + A^ = RT^ = RT(^^^ + (f>^)
(4)
All the derived thermodynamic properties can similarly be divided into
ideal and residual contributions as discussed below.
Our ideal gas correlation is based on Goodwin's fit [11] of the
spectroscopically derived data of McDowell and Kruse [12]. With the
definitions S = p/p and r = T /T, the dimensionless ideal gas contribution
to the Helmholtz energy is written as
1,^^(8, t) = A^^ / RT
= Qi
Q4 ^"^/^ + Qs
+ In 5 + Q2 In r + Q3 r'^/^ +
r-1 + Qg In (1 - e^^'-)
(5)
5-
with the coefficients Q. given in table 3. Equation (5) must be evaluated
at the experimental density and temperature, although for many
thermodynamic properties, there is no density (or pressure) dependence in
the required derivatives, as discussed below. The constants in table 3
incorporate integration constants necessary to give the standard values
of the entropy and enthalpy reported in table 1. Reference [11] gives
a table of comparisons between the spectroscopic data and the correlations;
these comparisons are not repeated in this paper.
TABLE 3
COEFFICIENTS FOR IDEAL GAS FREE ENERGY, eq (5)
r-
r-
-15.479 844
|i
1.690 097 9
-10.413 865
-0.391 154 1
2.599 832 4
4.720 671 5
-3.385 408 3
-10.543 907
2.4 Residual Helmholtz Energy
The residual term in eq (5) for the Helmholtz energy was correlated
by a 32-term function introduced by Schmidt and Wagner [2]. The resulting
equation of state has been called the SWEOS and the coefficients for
methane were obtained by multiproperty least- squares fitting as described
in Ref.[l]. Explicitly, we write
13
r . s .
5 " r " +
i=l
24
r. s .
5 " r ^ +
i=14
32
-S
\ r. s.
Z n. 5 ^ r ^
i=25
(6)
with 8 = p/p and r = T /T as before. The coefficients n. and the
' c c' 1
exponents r. and s. are given in table 4.
TABLE 4
EXPONENTS AND COEFFICIENTS FOR THE RESIDUAL FREE ENERGY (t> (eq (6))
i r . s . n.
11 1
,r. s.
1 r 1
110 0.384 436 099 66
2 1 1.5 -0.179 692 598 80 x 10
3 1 2.5 0.329 444 947 37
4 2 -0.5 0.226 312 728 44 x lO'j
5 2 1.5 0.759 236 768 80 x 10
6 2 2 0.693 758 447 26 x lO'}
7 3 0.241 163 263 95 x lO'
8 3 1 0.107 009 920 85 x lO':
9 3 2.5 -0.380 933 275 16 x lO'^
10 6 0.471 537 561 14 x 10
11 7 2 0.556 607 678 81 x lO'^
12 7 5 0.548 759 346 53 x lO'^
13 8 2 -0.999 632 699 97 x 10
,2
e 5 1 r 1
14 1 5 -0.128 087 979 28
15 1 6 0.380 198 873 38 x 10
16 2 3.5 0.139 226 650 55
17 2 5.5 -0.874 996 348 86 x lO'^
18 3 3 -0.334 894 165 76 x lO'^
19 3 7 -0.517 576 297 12 x lO"
20 5 6 0.252 835 179 12 x 10
21 6 8.5 0.518 703 205 95 x lO'^
22 7 4 -0.166 770 594 52 x lO'^
23 8 6.5 -0.607 401 927 39 x lO'^
24 10 5.5 -0.972 915 359 99 x 10
^4
e 5 1 r 1
25 2 22 -0.298 844 010 46 x lO"^
26 3 11 -0.130 940 111 24 x lO'?"
27 3 18 0.198 175 833 80 x lO'
28 4 11 0.208 465 762 33 x.lO'
29 4 23 -0.358 025 052 63 x 10
30 5 17 -0.203 486 851 74
31 5 18 0.215 964 755 09
32 5 23 -0.429 340 628 25 x 10
-7-
2.5 Derived Property Equations
One can evaluate many of the thermodynamic properties of methane by
taking the appropriate derivatives of the Helmholtz energy as given In
eqs (4-6). In tables 5 and 6 we have collected the coefficients necessary
to calculate the six lowest order derivatives for the Ideal gas and
residual contributions to the free energy. In our notation, the first
isothermal (reduced) density derivative of the (reduced) residual free
energy is denoted
S
d(f>^(5,T)
88
RT
3A^(P,T)
dp
and similarly for other derivatives
To calculate derivatives of the ideal gas contribution to the free
energy, one is guided by the form of eq (5). The left-most column of table
5 lists the factors necessary for the various derivatives, and the
remaining columns give the coefficients of these factors directly beneath
the heading which indicates the quantity to be calculated. The resulting
terms are to be added as in eq (7) . The values of the Q. parameters are
obtained from table 4.
TABLE 5
IDEAL GAS FREE ENERGY AND ITS DERIVATIVES
eq (5)
( =1 )
( =-1 )
2^ id
f: A id
( =0 )
1
■^l
1
^2
-1
-^2
In 5
1
In r
«2
^-1/3
«3
-Q3/3
4Q3/9
^-2/3
«4
-2Q4/3
lOQ^/9
-1
r
•^s
-Q5
2Q5
In (1 - e*^7^)
%
(e-V-l)-l
-^'^l'
e'^y' (eV -l)-2
2 2
For derivatives of the residual free energy, eq (2) and tables 4 and 6
can be used. As in eq (6) , the derivatives are obtained by summing 32
terms of three general types. Each of the terms has factors consisting
of powers of the reduced density and temperature with the explicit
exponents r. and s. and coefficients n. given for each value of i in table
11 1 '^
4. The additional exponential factor, with its argument either the second
or fourth power of the density, is indicated in the column heading of table
6 where appropriate. The remaining coefficients relevant to the derivative
being calculated are given in the appropriate row in that table.
9-
TABLE 6
RESIDUAL FREE ENERGY AND ITS DERIVATIVES
(i = 1 to 13)
-52 r- s.
(i = 14 to 24)
-5^ r. s.
e n^ 5 ^r ^
(i = 25 to 32)
/
1
1
1
<
r .
1
r. - 2«2
1
r. - 45^
1
<
s .
1
s .
1
s .
1
^'*\s
r.(r.-l)
[r (r -1)
-2(2r..l)i
+45 ]
[r (r -1)
-4(2r.+3)5^
Vl65^]
TT
s,(s.-l)
s.(s.-l)
s.(s.-l)
«'*L
r . s .
1 1
s.(r.-252)
s^(r^-45^)
In table 7, the most common thermodynamic quantities of interest have
been expressed in terms of the reduced derivatives of the Helmholtz energy
as discussed above. All nominally extensive quantities (that is, the
various thermodynamic potentials and heat capacities) are given on a per-
mole basis. It is straightforward to use these tables to calculate the
most useful thermodynamic properties of methane. In tables A4-A9 of
Appendix A, we give comparisons of experimental data and correlated values
for the PVT surface, second virial coefficient, isochoric specific heat
capacity, isobaric specific heat capacity, specific heat capacity of the
liquid along the saturation boundary, and speed of sound.
-10-
TABLE 7
THERMODYNAMIC PROPERTY EQUATIONS
Pressure :
P(p,T) = pRT (1 + 5<^J)
Internal Energy:
U(p,T) = RT (r.jij:'^ + r4>^^)
Enthalpy :
H(p,T) = RT (1 + r<^^^ + T<f>^ + S4>^,)
T TO
Glbbs Energy:
G(p,T) = RT (1 + <f>^'^ + 4>' + 54>])
Helmholtz Energy:
A(p,T) = RT {4>^^ + <t>'^)
Entropy:
S(p,T) = -R {4>^^ + 4>'^ - 74,"^ - r^^)
Isochoric Specific
Heat Capacity:
C (p,T) = -R (r^^^f + t'^4>1 )
V T T TT
Isobaric Specific
Heat Capacity:
(1 + S4>'^ - Stc^":)^
C(p,T) = C(p,T) + R '— ^
1 . 2S,l . S^l^
Saturated Liquid
Specific Heat Capacity:
- R (1 . 5*^ - Sr^l) / ^f
crL
Speed of Sound:
RT C (p,T)
A r V '
Second Virial
Coefficient:
1
B(T) = — lim <f>^^
' 6-^0 ^
c
11
3. TRANSPORT PROPERTIES
AND THEIR ALGEBRAIC REPRESENTATION
The viscosity and thermal conductivity are correlated as the sums of
terras representing the temperature dependent dilute gas contributions, the
temperature and density dependent excess contributions and, for the thermal
conductivity, a contribution from the critical enhancement. The viscosity
is given by
77(p,T) - r?Q(T) + ri^^(p,T)
(7)
and the expression for thermal conductivity is
A(p,T) = Aq(T) + A^^(p,T) + A^^(p,T)
(8)
These terms are described in this section.
3.1 Dilute Gas Correlations
Our expression for the dilute gas viscosity is from the Chapman- Enskog
theory [13]. Using the appropriate constants from table 1, we find
r?Q(T) = 10.50 Jt / a^'^'^^'^it) /iPa.s
where the reduced temperature t = kT/e . The collision integral Q '
has been approximated for the 11-6-8, 7=3 intermolecular potential
function [14] ,
(9)
,(2,2)^-v
i=l
C. t
1
[(i-l)/3-l]
(10)
with coefficients C. listed in table 8. The collision integrals tabulated
12
in Ref.[14] are compared to eq (10) in table AlO of Appendix A;
experimental values of ry. are compared to values calculated from eq (9) in
table All.
TABLE 8
COEFFICIENTS FOR DILUTE GAS TRANSPORT PROPERTIES
Q
' '^ , eq (10)
f
Lnt • ^'i (12)
-3.032 813 828 1
16.918 880 086
^1
1.458 850
-37.189 364 917
41.288 861 858
^2
-0.437 716 2
-24.615 921 140
1
8.948 843 095 9
-1.873 924 504 2
0.209 661 013 90
-9.657 043 707 4 x 10
For the thermal conductivity A^ of the dilute gas, we have chosen a
modified Eucken model [15] with resulting equation
A^(T) = 0.51826 ryQ(T)[ 3.75 - f. (r^<?i^^ + 1.5) ] mW-m'"^.K'"^
(11)
In eq (11), f. ^ is the dimensionless function defined by
mt -^
^int = ^1 ^ (V^)
(12)
with the fitted coefficients f also given in table 8, and the viscosity
should be expressed in /iPa«s, as in eq (9). The quantity t 4> in eq (12)
can be evaluated from tables 3 and 5. Table A12 of Appendix A gives
comparisons between experimental values for the dilute gas thermal
conductivity and values calculated from eq (11).
13-
3.2 Excess Property Correlations
For the excess viscosity, we use the rational polynomial
11
r,,^(p,T)
12.149
r . s .
5 r
i=l
..)
r . s .
5 r
1=10
-1
fj.'Pa.' s
(13)
where the exponents r. and s. and the dimensionless fitted coefficients,
g. , are given in table 9. Comparisons between experimental viscosities and
viscosities calculated using eq (7) with eqs (9) and (13) are given in
table A13 of Appendix A.
The excess thermal conductivity X has been correlated to a
ex ,, ^
polynomial in 5 and r with a factor in the final term of (5 ) , defined
o
by
«. (T) =
p (T) / p , if T < T and p < p ,
avc c c
1 , otherwise,
(14)
in the final term. In eq (14) , p is the density of the saturated vapor
av
and can be calculated from eq (3). The quantity 5 (T) differs from 1 only
in the vapor phase below the critical temperature. Thus we write
A (p,T) = 6.2963^
ex
i=l
r. s. - ,
11 2 *
j . 5 r + j^5 /S
mW»m 'K
(15)
The exponents and dimensionless fitting coefficients for eq (15) are
included in table 9.
14
TABLE 9
COEFFICIENTS FOR EXCESS TRANSPORT PROPERTY CORRELATIONS
T) , eq
ex ^
(13)
A
ex
, eq (15)
i
r.
1
s .
1
Si
r.
1
s .
1
h
1
1
0.412 501
37
1
2.414 920 7
2
1
1
-0.143 909
12
3
0.551 663 31
3
2
0.103 669
93
4
-0.528 377 34
4
2
1
0.402 874
64
4
1
0.073 809 553
5
2
1.5
-0.249 035
24
5
0.244 655 07
6
3
-0.129 531
31
5
1
-0.047 613 626
7
3
2
0.065 757
76
* 2
1.555 461 2
8
4
0.025 666
28
^»-
9
4
1
-0.037 165
26
Term divided by 5 2
10
1
-0.387 983
41
U
11
1
1
0.035 338
15
3.3 Critical Enhancement Correlation
The remaining term in eq (8) is the critical enhancement of the
thermal conductivity; it is easily observed in a broad region around the
critical point. We have correlated this using a function very similar to
that developed by Sengers et al . [16]. After evaluating the universal,
fluid dependent, and correlated constants, we write
A (p,T)
cr
91.855 ^ ,^ ^ ... , , mW
r r 2 "'0 4681 * ■*
7?(p,T) T
(16)
m«K
where the viscosity is expressed in /iPa«s in eq (16). The empirical
dimensionless crossover or damping function F is defined by
1 ■*-|l/2 *2 ■*
F(T ,p ) = e T' ' p A
(17)
where F F and F are constants in table 10 and T and p" measure
i A p ^
deviations from the critical point according to
-15
T = (T^ - T)/T^ ( = 1 - 1/r ) (18)
and
/ = (p. - P)/P. ( = 1 - 5 ). (19)
The final factor in eq (16) is the reduced and symmetrized
compressibility Xr,. • Throughout most of the phase diagram, this
can be evaluated classically using
xt = 0.28631 St [1 + 2S4>^ + 8^<f>^ ]'^ , (20)
^ 6 SS
where the derivatives in eq (20) are found from tables 4 and 6. However,
the classical quantity in eq (20) is not very accurate in the region very
close to the critical point, so in the small region defined by 185 K < T <
-3 -3
196 K and 7.6 mol»dm < p < 12.7 mol»dm , we recommend evaluating the
compressibility using the MLSG [17] scaled equation of state. In this
region, then,
x^*(p,T) = Q |p*r^ e^ [0 + n(^+R)]"^. (21)
where the variables 6 and Q are defined as
fl + E (1 + ST* |p*r^/^2/3, if T*< -|p"|l/^S
9 = i (22)
I 1 , if T > -|p l^/^/S
and
* . *,
1//S
n = W T |p I '"^ (23)
and the remaining constants in eq (21) can be found in table 10. Finally,
along the critical isochore, if 185 K < T < 196 K, we can use
xt*(p=Pc'T) = r |T*|-^ (24)
-16-
to avoid spurious singularities in eq (21) . This completes the description
of the thermal conductivity enhancement and the correlation for the methane
fluid transport properties. Table A14 of Appendix A gives tabular compar-
isons between experimental values of the thermal conductivity coefficient
and those calculated from eq (8) using eqs (11, 12, 15-17).
TABLE 10
CONSTANTS FOR A
cr
Fitted coefficients:
^T =
2.646
F =
2.678
P
^A =
-0.637
Critical exponent:
/? -
0.355
Universal constants:
a =
3.352
b =
0.732
E =
0.287
R =
0.535
Fluid dependent constants
derived from Ref.[16] :
Q =
0.113 3
s =
-6.098
w =
-1.401
r =
0.080 1
17
4. SUMMARY OF UNCERTAINTIES
ASSOCIATED WITH THE CORRELATIONS
We have judged the uncertainties associated with the correlations in
various regions of the phase diagram. These judgements are based on an
examination of the deviations of our correlations from experimental data
using tables such as included in Appendix A and deviation plots as in
Ref.[l], an assessment of the experiments themselves and their reported
accuracies, and comparisons of these correlations with previously published
equations. In this section, we will summarize the results of our assesment
so that the equations and the tables in Appendix B can be used
appropriately; details concerning the establishment of these uncertainties
are given in Ref.[l]. In this section, the terms "uncertainty", "error",
and "accuracy" are used interchangeably; the deviations from the true
value, of quantities calculated from the correlations, will not exceed the
stated uncertainty.
4.1 Two -Phase Boundary
First, for the pressure along the liquid- vapor saturation boundary, we
have considered the uncertainties of both the triple-point and critical
point pressures (table 1), the quality of the measurements of Ref.[6], and
the disconcerting disagreement between the earlier benchmark data. We make
the subjective judgment that either the ancillary eq (1) or the SWEOS will
provide values of the saturation pressures accurate within 0.06 percent
above T = 120 K and accurate within 0.3 percent below this temperature.
For the density of the saturated liquid, again, either the ancillary
equation or the value of the density from the SWEOS can be used with an
estimated accuracy well under 0.2 percent throughout the range from the
triple point to just below the critical point. We estimate that between
190.5 K and T the uncertainty in the saturated liquid density associated
with these equations may exceed 1 percent.
We have considered the data and conclusions of Refs.[3, 4, 6], and
estimate that the error associated with either eq (3) or the SWEOS for the
density of the saturated vapor does not exceed 1 percent from the triple
point temperature to 91 K, 2 percent above T = 190.5 K, and is well under
0.5 percent for the remainder of the two -phase boundary.
4.2 Thermodynamic Properties
In this section, we discuss the uncertainties associated with the full
equation of state. The PVT surface is considered first, and both the
calculation of pressure with temperature and density as independent
variables, and the calculation of density with temperature and pressure as
independent variables are discussed. For this discussion, the
thermodynamic space is divided into temperature regions: T - 185 K, 185 -
195 K, 195 - 300 K, and 300 - 600 K. Following the treatment of the PVT
surface, uncertainties associated with the calculation of the second virial
coefficient, isochoric specific heat capacity, isobaric specific heat
capacity, specific heat capacity of the saturated liquid, and speed of
sound are discussed in turn.
We offer the following guidelines when calculating pressures from the
SWEOS when given densities and temperatures between the triple point and
185 K. For the vapor phase, the errors should not exceed 0.2 percent. For
the liquid below 150 K and below 1 MPa, the percentage uncertainty is
extremely large, but the actual pressure should not be in error by more
than 0.1 MPa. Most of the remaining data indicate that the error should be
less than 5 percent. An exception occurs below 120 K or very close to the
saturation line, where the uncertainty approaches 10 percent. Most of the
primary PVT data (from Goodwin [38]) in this temperature region and below
.3
about 30 MPa and 28.5 mol'dm exhibit deviations from the correlation well
below 1 percent. Calculation of an accurate density from a given
temperature and pressure is a much easier task in the region below 185 K.
The general uncertainty is well below 1 percent. In the vapor phase, all
points at temperatures below 180 K or pressures below 3.5 MPa show absolute
-19-
deviations below 0.5 percent. A few vapor points closer to the critical
point in both temperature and pressure show higher deviations. We estimate
that for the liquid in this range, a 0.2 percent accuracy in the
determination of the density from the SWEOS is expected.
Our comparisons suggest that in calculating the pressure using the
SWEOS in the temperature range 185 - 195 K, accuracies of better than 0.1
percent are expected at up to 6 MPa. The accuracy is expected to
deteriorate to about 2 percent at higher pressures. Our study suggests
that in this temperature range the SWEOS should return a density well
within 0.5 percent accuracy. The exception is quite close to the critical
point, 190.4 K < T < 190.6 K and 4.4 MPa < P < 4.8 MPa, where errors of
nearly 5 percent are possible.
In the temperature range 195 to 300 K, we find the largest quantity of
PVT data with a very large range in pressures. In predicting pressures
from the present SWEOS in this temperature region and below 10 MPa (or 15
-3
mol'dm ) an accuracy of 0.5 percent is expected; above these pressures, 5
percent errors are possible. For prediction of densities, in our judgment,
0.2 percent is the general uncertainty associated with the SWEOS for most
-3
of this region, except for a deterioration to 0.5 percent above 20 mol»dm
and below 210 K. The correlation can be extrapolated to pressures above
100 MPa in this temperature range (to about 600 MPa) , but the estimated
uncertainty becomes closer to 8 percent in pressure and 1 percent in
density.
We summarize our observations of the data and the SWEOS for predicting
pressures at temperatures above 300 K as follows. For pressures below 40
MPa and temperatures to 600 K, the expected accuracy is 0.2 percent. In
the pressure range 40 - 200 MPa the accuracy is near 1 percent, but for
higher pressures the uncertainty increases with increasing pressure and may
reach 20 percent at 1000 MPa. In the highest pressure range, above 800
MPa, it is also prudent to restrict the temperature to 450 K because there
are no data at significantly higher temperatures. We have extended the
correlation above the 100 MPa cutoff in this temperature range , but the
quality of the equation clearly deteriorates at high pressures; pressures
-20-
above 100 MPa are not included in the tables of Appendix B. For the
calculation of densities for temperatures below 350 K and densities below
-3
15 mol'dm , an accuracy of 0.2 percent should be associated with the
-3
SWEOS . For temperatures up to 600 K or densities to 20 mol»dm , the error
increases to 0,5 percent. The error increases to 1 percent up to 25
-3
mol'dm and 5 percent at higher densities. Extrapolation of the SWEOS to
-3
state points above 450 K for the density range above 20 mol»dm is not
advised.
We estimate an uncertainty in the correlation for the second virial
coefficient of about 1 percent throughout the range, from the triple point
to 625 K.
In our judgment, a 2 percent uncertainty should be expected when
calculating the isochoric specific heat capacity from the SWEOS outside the
critical region, and the accuracy approaches 5 percent for temperatures
-3
between 180 K and 200 K for densities up to 14 mol»dm . The
asymptotically critical behavior of C is not well described by this (or
any) classical equation of state.
We estimate that the SWEOS will give isobaric heat specific capacities
within about 2 percent for the liquid and supercritical fluid from 115 K to
about 300 K for pressures to about 15 MPa. The uncertainty is assumed to
be worse outside these ranges, and in the general critical region, 20
percent errors may be possible. Very close to the critical point, the
behavior of this classical SWEOS will not describe the heat capacities
accurately.
The accuracy of the SWEOS in predicting saturated liquid specific heat
capacities is 2 percent from the triple point to 186 K and 5 percent for
temperatures approaching the critical point.
For predicting the speed of sound in methane, we can summarize our
observations by the following subjective guidelines for the use of the
SWEOS. Below 180 K or above 195 K, with pressures below about 20 MPa, for
the saturated liquid, compressed liquid, vapor phase, and supercritical
-21-
fluid, accuracies of 0.6 percent can be anticipated. Between 180 K and 188
K, or above 20 MPa (to about 35 MPa) , the accuracy decreases to 1.5
percent. In the general region of the critical point, 188 K to 195 K and
4.5 MPa to 4.7 MPa, the uncertainties can exceed 5 percent. Our classical
equation of state cannot give accurate results for derivative properties at
the critical point or for state points extremely close to the critical
point (approximately 190 to 191 K and 4.55 to 4.65 MPa). In particular,
theory indicates that the speed of sound should vanish at the critical
point; in our formulation this speed is about 231 m's This discrepancy
between theory and our correlation occurs principally because the very
small divergence of the isochoric specific heat capacity ( ~|T-T | where
a is about 0.1) is not predicted by a classical equation of state; in our
formulation the value of C at the critical point is about 45 J»mol 'K
V '^
In addition, because of truncation error, the nominally zero value of
- 8 - 1
3P/3p I is equal to about 10 J»mol and the related C which should
13 -1 -1
diverge strongly, is found to be about 10 J«mol -K at the critical
point.
The comparisons with experimental data (and the process of determining
the coefficients of the SWEOS) probe only four derivatives of the
r r r r
dimensionless, residual Helmholtz energy, namely 4>s , <f>66, <i>TT , and <i>ST -
While this should describe the actual surface quite well, additional
uncertainties will enter any calculation which requires other derivatives
or integrals of these directly accessible functions. We hesitate to make
any quantitative predictions of the errors involved in calculating any
thermodynamic quantities not explicitly discussed in this section, but we
do conjecture that these errors will be comparable to those found with any
other precise equation of state for methane.
4.3 Transport Properties
From the dispersion of the data and correlations, the quoted
experimental accuracies associated with the data, and a study of the use of
the 11-6-8 intermolecular potential in the Chapman- Ens kog dilute gas
-22-
theory, we estimate that the correlation of eqs (9) and (10) will give
dilute gas viscosities for methane with associated accuracies of 0.5
percent from the 270 K to 600 K and 1 percent above that range. For lower
temperatures, and especially below the critical point, the data are
extremely sparse or nonexistent. We anticipate that, with this potential
function, the theory will extrapolate well, but we increase our error
estimate to 2 percent for temperatures from the triple point to 270 K.
We next examine the viscosity of methane at elevated pressures. For
the vapor phase, below the critical temperature, we estimate that the error
varies from 2 percent, as above, to more than 5 percent as the saturated
vapor line is approached. For the liquid below the critical temperature,
the data indicate an accuracy of about 3 percent from the phase boundary to
the compressed liquid at pressures to 30 MPa. Above the critical
temperature, in the temperature range from T to 270 K, the data indicate
^ -3
an accuracy of about 5 percent for densities up to 10 mol«dm . In the
same temperature range, but for higher densities and for pressures up to
about 30 MPa, the viscosity increases and the estimated uncertainty drops
-3
to about 2 percent. For the low density region, to 10 mol»dm , we
estimate that the uncertainty associated with the correlation is 1 percent
in the higher temperature range, to 450 K. For pressures up to 55 MPa and
temperatures to 450 K, the error is about 2 percent. The correlation
attempts to describe the rapidly rising excess viscosity as the melting
line is approached. It has a zero in the denominator, corresponding to a
singularity in the correlation within the fluid region; this occurs well
outside the range of any data. In addition to the usual warnings
concerning extrapolation beyond the range of the correlating equation, any
user is cautioned about this singularity, which can be a problem only at
pressures exceeding 200 MPa.
For the thermal conductivity of the dilute methane gas, we estimate
that the accuracy of the correlation is about 2.5 percent for temperatures
between 130 and 625 K. For temperatures below 130 K, where the vapor
pressure is about 0.37 MPa, the current correlation could give errors in
excess of 10 percent for the thermal conductivity of dilute methane.
23
We estimate that the accuracy of the correlation for the total thermal
conductivity of methane is about 2 percent for most of the range between
110 K and 725 K and for pressures to 70 MPa (or densities to about 29
-3
mol'dm ). The exceptions occur around the critical point and near both
saturation boundaries, where 5 percent errors are typical, and greater
errors could occur in the very close to the critical point. For the vapor
at lower temperatures and the dense liquid near the triple point, an
uncertainty of nearly 10 percent is possible.
5. ACKNOWLEDGMENTS
We thank R.D. McCarty for helpful discussions and W. Wagner for
providing a copy of his experimental tables prior to publication. We also
thank R.T Jacobsen and M.W. Chase for their careful reviews of parts of
the manuscript.
-24
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25-
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26
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29
APPENDIX A
TABLES FOR THE COMPARISON OF EXPERIMENTAL DATA
AND THE CORRELATIONS
Al . COMPARISONS FOR SATURATED VAPOR PRESSURES 33
A2 . COMPARISONS FOR SATURATED LIQUID DENSITIES 40
A3 . COMPARISONS FOR SATURATED VAPOR DENSITIES 52
A4. COMPARISONS OF EXPERIMENTAL AND CALCULATED PVT DATA 58
A5 . COMPARISONS FOR SECOND VIRIAL COEFFICIENTS 143
A6. COMPARISONS FOR ISOCHORIC SPECIFIC HEAT CAPACITY 145
A7. COMPARISONS FOR ISOBARIC SPECIFIC HEAT CAPACITY 156
A8. COMPARISONS FOR SPECIFIC HEAT CAPACITY OF THE SATURATED LIQUID... 170
A9 . COMPARISONS FOR SOUND SPEED 173
AlO . COMPARISONS FOR COLLISION INTEGRAL 196
All. COMPARISONS FOR ZERO DENSITY VISCOSITY 198
A12 . COMPARISONS FOR ZERO DENSITY THERMAL CONDUCTIVITY 204
A13 . COMPARISONS FOR VISCOSITY AT ELEVATED PRESSURES 211
A14. COMPARISONS FOR THERMAL CONDUCTIVITY AT ELEVATED PRESSURES. ...... 229
31
We make several prefatory notes to the fourteen tables in this Appendix.
Additional specific notes can be found at the beginning of most of the tables.
In several instances, only first authors are given; complete citations can be
found in the numbered references. Deviations are given on a percentage basis
according to Dev = 100 (Cal - Exp)/Exp. The weights (Wt) refer to weighting of
individual data points in the least squares algorithms for the determination of
the coefficients of the correlating equations as discussed in detail in Ref.[l].
The summary statistics given for each reference and for the cumulative
experimental data are defined as follows,
AAD = ly ICali-Expil , (Al)
BIAS = ly(Cali-Expi),
(A2)
RMS =
i y (Call -Expi)2- BIAS'
1/2
(A3)
The quantity N above represents the number of points in the data set, and the
summation over the index i is over all N points. These statistics give
dimensioned quantities; the analogously defined dimensionless statistics are
based on percentage deviations. Thus, AAD-%, BIAS-%, and RMS-% are defined as
above, but with the quantity (Cal^ - Exp^ ) replaced by 100(Cal^ - Exp^ ) . Some
of the entries in the tables have digits beyond the range of significance,
including trailing zeroes; these serve only to maintain uniform appearance of
the columns and the quantities can be truncated according to the error estimates
in the original experimental publications, the discussion in Ref.[l], or the
uncertainties quoted in Sec. 4 above.
32
TABLE Al
COMPARISONS FOR SATURATED VAPOR PRESSURES
Notes for Table Al. The numeral 1 associated with quantities refers to comparisons
with eq (1); the numeral 2 refers to conparisons with the SWEOS. Similarly, Wtl
refers to weighting for the development of eq (1) , and Wt2 refers to weighting of
the Gibbs condition for the development of the SWEOS. For the points generated from
eq (1), in the last part of the table, statistics relative to eq (1) have no
meaning; these points are therefore excluded from the totals.
Data from Kleinrahm and Wagner [6]
T Pff, exp ?fj, eq (1) Devi P^, SWEOS Dev2 Wtl Wt2
K MPa MPa % MPa %
90.685
0.117
OOE-01
0.116
93E-01
-0.060
0.116
93E-01
-0.061
1.0
0.0
91.000
0.121
70E-01
0.121
75E-01
0.043
0.121
75E-01
0.040
1.0
0.0
95.000
0.198
30E-01
0.198
34E-01
0.019
0.198
32E-01
0.011
1.0
0.0
100.000
0.344
OOE-01
0.344
08E-01
0.022
0.344
08E-01
0.024
1.0
0.0
105.000
0.564
30E-01
0.564
26E-01
-0.007
0.564
33E-01
0.006
1.0
0.0
110.000
0.882
20E-01
0.882
03E-01
-0.019
0.882
19E-01
-0.001
1.0
0.0
111.631
0.101
lOE+00
0.101
llE+00
0.006
0.101
13E-fO0
0.025
1.0
0.0
115.000
0.132
34E+00
0.132
32E+00
-0.015
0.132
34E+00
0.003
1.0
0.0
120.000
0.191
56E+O0
0.191
58E+00
0.010
0.191
61E-+00
0.024
1.0
0.0
125.000
0.268
98E+00
0.268
96E+00
-0.006
0.268
99E+00
0.002
1.0
0.0
130.000
0.367
62E+00
0.367
60E+00
-0.006
0.367
60E+00
-0.005
1.0
0.0
135.000
0.490
70E+00
0.490
71E+00
0.003
0.490
68E+00
-0.003
1.0
0.0
140.000
0.641
62E+00
0.641
65E+00
0.004
0.641
56E+00
-0.010
1.0
0.0
145.000
0.823
73E+00
0.823
79E+00
0.008
0.823
69E-tO0
-0.005
1.0
0.0
150.000
0.104
06E+01
0.104
06E+01
0.007
0.104
05E+01
-0.007
1.0
0.0
155.000
0.129
57E+01
0.129
58E+01
0.008
0.129
56E+01
-0.005
1.0
0.0
160.000
0.159
29E+01
0.159
30E+01
0.004
0.159
28E-K)1
-0.007
1.0
0.0
165.000
0.193
62E+01
0.193
61E+01
-0.007
0.193
59E-K)1
-0.014
1.0
0.0
170.000
0.232
96E+01
0.232
94E+01
-0.011
0.232
93E-+01
-0.015
1.0
0.0
175.000
0.277
79E+01
0.277
76E+01
-0.010
0.277
76E-K)1
-0.011
1.0
0.0
180.000
0.328
68E+01
0.328
65E+01
-0.009
0.328
63E+01
-0.017
1.0
0.0
182.000
0.350
89E+01
0.350
87E+01
-0.005
0.350
84E-f01
-0.014
1.0
0.0
184.000
0.374
23E+01
0.374
23E+01
0.000
0.374
19E-K)1
-0.011
1.0
0.0
186.000
0.398
78E+01
0.398
81E+01
0.007
0.398
76E-K)1
-0.006
1.0
0.0
187.000
0.411
54E+01
0.411
59E+01
0.010
0.411
53E401
-0.003
1.0
0.0
33
Data from Klelnrahm and Wagner [6] (continued)
T
Pa.
exp
Pa.
eq (1)
Devi
Pa.
SWEOS
Dev2
Wtl
Wt2
K
MPa
MPa
%
MPa
%
188.000
0.424
66E+01
0.424
71E+01
0.013
0.424
65E-K)1
0.000
1.0
0.0
189.000
0.438
14E+01
0.438
20E+01
0.014
0.438
15E-K)1
0.003
1.0
0.0
189.500
0.445
03E+01
0.445
09E+01
0.013
0.445
05E-K)1
0.004
1.0
0.0
189.800
0.449
22E+01
0.449
27E+01
0.011
0.449
24E-K)1
0.004
1.0
0.0
190.000
0.452
04E+01
0.452
08E+01
0.010
0.452
05E-K)1
0.003
1.0
0.0
190.100
0.453
45E+01
0.453
49E+01
0.009
0.453
47E+01
0.003
1.0
0.0
190.200
0.454
88E+01
0.454
91E+01
0.007
0.454
89E-K)1
0.003
1.0
0.0
190.300
0.456
30E+01
0.456
33E+01
0.006
0.456
31E-K)1
0.002
1.0
0.0
190.400
0.457
74E+01
0.457
76E+01
0.004
0.457
75E-HD1
0.002
1.0
0.0
190.450
0.458
46E+01
0.458
47E+01
0.003
0.458
46E-K)1
0.001
1.0
0.0
190.500
0.459
18E+01
0.459
19E+01
0.002
0.459
18E401
0.001
1.0
0.0
190.530
0.459
61E+01
0.459
62E+01
0.001
0.459
62E+01
0.000
1.0
0.0
190.551
0.459
92E+01
0.459
92E+01
0.000
0.459
92E-K)1
0.000
1.0
0.0
Number of Points (Ref . 6)
38
AADl-% 0.011, BIASl-% 0.002, RMSl-% 0.015
AADl 0.171, BIASl 0.105, RMSl 0.233 kPa
AAD2-% 0.009, BIAS2-% -0.001, RMS2-% 0.015
AAD2 0.118, BIAS2 -0.050, RMS2 0.177 kPa
Data from Prydz and Goodwin [18]
T
Pa. exp
Pa. eq (1)
Devi
P^, SWEOS
Dev2
Wtl
Wt2
K
MPa
MPa
%
MPa
%
91.000
0.122 30E-01
0.121 75E-01
-0.448
0.121 75E-01
-0.451
0.0
0.0
92.000
0.138 80E-01
0.138 14E-01
-0.473
0.138 14E-01
-0.477
0.0
0.0
93.000
0.157 OOE-01
0.156 28E-01
-0.458
0.156 27E-01
-0.465
0.0
0.0
94.000
0.177 OOE-01
0.176 30E-01
-0.396
0.176 29E-01
-0.404
0.0
0.0
95.000
0.199 lOE-01
0.198 34E-01
-0.383
0.198 32E-01
-0.391
0.0
0.0
34
Data from Prydz and Goodwin [18] (continued)
T
Pa.
exp
Pa.
eq (1)
Devi
Pa.
SWEOS
Dev2
Wtl
Wt2
K
MPa
MPa
%
MPa
%
96.000
0.223
40E-01
0.222
54E-01
-0.385
0.222
52E-01
-0.392
0.0
0.0
97.000
0.250
OOE-01
0.249
06E-01
-0.377
0.249
04E-01
-0.382
0.0
0.0
98.000
0.279
OOE-01
0.278
04E-01
-0.343
0.278
04E-01
-0.346
0.0
0.0
99.000
0.310
70E-01
0.309
66E-01
-0.334
0.309
66E-01
-0.335
0.0
0.0
100.000
0.345
lOE-01
0.344
08E-01
-0.297
0.344
08E-01
-0.295
0.0
0.0
101.000
0.382
60E-01
0.381
46E-01
-0.298
0.381
47E-01
-0.294
0.0
0.0
102.000
0.423
20E-01
0.421
99E-01
-0.287
0.422
OlE-01
-0.280
0.0
0.0
103.000
0.467
lOE-01
0.465
84E-01
-0.270
0.465
88E-01
-0.262
0.0
0.0
104.000
0.514
40E-01
0.513
20E-01
-0.233
0.513
25E-01
-0.223
0.0
0.0
105.000
0.565
60E-01
0.564
26E-01
-0.237
0.564
33E-01
-0.224
0.0
0.0
106.000
0.620
60E-01
0.619
22E-01
-0.223
0.619
31E-01
-0.208
0.0
0.0
107.000
0.679
90E-01
0.678
27E-01
-0.240
0.678
38E-01
-0.224
0.0
0.0
108.000
0.743
20E-01
0.741
62E-01
-0.213
0.741
74E-01
-0.196
0.0
0.0
109.000
0.811
30E-01
0.809
47E-01
-0.226
0.809
61E-01
-0.208
0.0
0.0
110.000
0.883
90E-01
0.882
03E-01
-0.211
0.882
19E-01
-0.193
0.0
0.0
111.000
0.961
50E-01
0.959
52E-01
-0.205
0.959
71E-01
-0.187
0.0
0.0
111.000
0.961
60E-01
0.959
52E-01
-0.216
0.959
71E-01
-0.197
0.0
0.0
112.000
0.104
48E+00
0.104
22E+00
-0.252
0.104
24E-K)0
-0.233
0.0
0.0
113.000
0.113
28E+00
0.113
02E+00
-0.232
0.113
04E-K)0
-0.213
0.0
0.0
114.000
0.122
65E+00
0.122
38E+00
-0.222
0.122
40E-K)0
-0.203
0.0
0.0
115.000
0.132
55E+00
0.132
32E+00
-0.174
0.132
34E-K)0
-0.155
0.0
0.0
115.000
0.132
62E+00
0.132
32E+00
-0.227
0.132
34E-K)0
-0.208
0.0
0.0
116.000
0.143
llE+00
0.142
87E+00
-0.170
0.142
89E-K)0
-0.152
0.0
0.0
116.000
0.143
17E+00
0.142
87E+00
-0.212
0.142
89E+00
-0.194
0.0
0.0
117.000
0.154
34E+00
0.154
04E+00
-0.193
0.154
07E-K)0
-0.175
0.0
0.0
118.000
0.166
16E+00
0.165
87E+00
-0.174
0.165
90E-K)0
-0.158
0.0
0.0
119.000
0.178
71E+00
0.178
37E+00
-0.188
0.178
40E-K)0
-0.172
0.0
0.0
120.000
0.191
91E+00
0.191
58E+00
-0.173
0.191
61E+00
-0.158
0.0
0.0
121.000
0.205
81E+00
0.205
51E+00
-0.147
0.205
54E-K)0
-0.134
0.0
0.0
122.000
0.220
52E+00
0.220
18E+00
-0.152
0.220
21E-K)0
-0.140
0.0
0.0
123.000
0.235
98E+00
0.235
64E+00
-0.145
0.235
66E-K)0
-0.134
0.0
0.0
124.000
0.252
28E+00
0.251
89E+00
-0.155
0.251
91E-K)0
-0.146
0.0
0.0
125.000
0.269
33E+00
0.268
96E+00
-0.136
0.268
99E+00
-0.128
0.0
0.0
126.000
0.287
31E+00
0.286
89E+00
-0.147
0.286
91E-K)0
-0.140
0.0
0.0
127.000
0.306
08E+00
0.305
69E+00
-0.128
0.305
70E-K)0
-0.123
0.0
0.0
35
Data from Prydz and Goodwin [18] (continued)
T
Pa.
exp
Pa.
eq (1)
Devi
Pa.
SWEOS
Dev2
Wtl
Wt2
K
MPa
MPa
%
MPa
%
128.000
0.325
80E+00
0.325
39E+00
-0.126
0.325
40E-K)0
-0.122
0.0
0.0
129.000
0.346
44E+00
0.346
02E+00
-0.122
0.346
02E+00
-0.120
0.0
0.0
130.000
0.368
02E+00
0.367
60E+00
-0.115
0.367
60E+00
-0.114
0.0
0.0
131.000
0.390
61E+00
0.390
16E-K)0
-0.116
0.390
16E-K)0
-0.117
0.0
0.0
132.000
0.414
18E+00
0.413
72E+O0
-0.111
0.413
71E-K)0
-0.113
0.0
0.0
133.000
0.438
80E+00
0.438
32E+O0
-0.110
0.438
30E-K)0
-0.113
0.0
0.0
134.000
0.464
47E+00
0.463
97E+00
-0.107
0.463
95E+O0
-0.111
0.0
0.0
135.000
0.491
26E+00
0.490
71E400
-0.111
0.490
68E+00
-0.117
0.0
0.0
136.000
0.519
08E+00
0.518
57E+00
-0.099
0.518
53E+00
-0.106
0.0
0.0
137.000
0.548
lOE+00
0.547
56E+00
-0.098
0.547
51E-K)0
-0.108
0.0
0.0
138.000
0.578
34E+00
0.577
72E+00
-0.107
0.577
66E-K)0
-0.118
0.0
0.0
139.000
0.609
64E+00
0.609
07E+00
-0.093
0.609
OOE400
-0.105
0.0
0.0
140.000
0.642
19E+00
0.641
65E+00
-0.085
0.641
56E-K)0
-0.099
0.0
0.0
141.000
0.676
06E+00
0.675
47E+00
-0.088
0.675
36E+00
-0.103
0.0
0.0
142.000
0.711
16E+00
0.710
56E+00
-0.084
0.710
44E-K)0
-0.101
0.0
0.0
143.000
0.747
58E+00
0.746
97E+00
-0.082
0.746
82E4O0
-0.101
0.0
0.0
144.000
0.785
25E+00
0.784
70E+00
-0.070
0.784
60E+00
-0.082
0.0
0.0
145.000
0.824
39E+00
0.823
79E+00
-0.072
0.823
69E-K)0
-0.085
0.0
0.0
146.000
0.864
91E+00
0.864
27E+00
-0.073
0.864
16E-K)0
-0.087
0.0
0.0
147.000
0.906
79E+00
0.906
17E+O0
-0.068
0.906
05E-K)0
-0.082
0.0
0.0
148.000
0.950
21E+00
0.949
51E-K)0
-0.073
0.949
38E-K)0
-0.087
0.0
0.0
149.000
0.995
OlE+00
0.994
33E+00
-0.068
0.994
19E-K)0
-0.082
0.0
0.0
150.000
0.104
14E+01
0.104
06E+01
-0.074
0.104
05E401
-0.088
0.0
0.0
151.000
0.108
92E+01
0.108
85E+01
-0.065
0.108
83E-K)1
-0.080
0.0
0.0
152.000
0.113
86E+01
0.113
79E+01
-0.064
0.113
77E-K)1
-0.078
0.0
0.0
153.000
0.118
98E+01
0.118
89E+01
-0.072
0.118
87E+01
-0.086
0.0
0.0
154.000
0.124
24E+01
0.124
15E+01
-0.068
0.124
14E+01
-0.082
0.0
0.0
155.000
0.129
67E+01
0.129
58E+01
-0.068
0.129
56E-K)1
-0.082
0.0
0.0
156.000
0.135
26E-K)1
0.135
17E+01
-0.064
0.135
16E-K)1
-0.077
0.0
0.0
157.000
0.141
04E+01
0.140
94E+01
-0.068
0.140
92E-f01
-0.080
0.0
0.0
158.000
0.146
98E+01
0.146
88E401
-0.070
0.146
86E-K)1
-0.082
0.0
0.0
159.000
0.153
lOE+01
0.153
OOE+01
-0.070
0.152
98E401
-0.081
0.0
0.0
160.000
0.159
41E+01
0.159
30E+01
-0.069
0.159
28E-K)1
-0.080
0.0
0.0
161.000
0.165
88E+01
0.165
78E+01
-0.064
0.165
76E-K)1
-0.074
0.0
0.0
162.000
0.172
57E+01
0.172
45E+01
-0.073
0.172
43E401
-0.083
0.0
0.0
36
Data from Prydz and Goodwin [18] (continued)
T
Pa.
exp
Pa.
eq (1)
Devi
Pa.
SWEOS
Dev2
Wtl
Wt2
K
MPa
MPa
%
MPa
%
163.000
0.179
42E+01
0.179
30E+01
-0.063
0.179
29E+01
-0.072
0.0
0.0
164.000
0.186
49E+01
0.186
36E+01
-0.069
0.186
34E-K)1
-0.077
0.0
0.0
165.000
0.193
73E+01
0.193
61E+01
-0.062
0.193
59E401
-0.069
0.0
0.0
166.000
0.201
20E+01
0.201
06E+01
-0.070
0.201
04E+01
-0.076
0.0
0.0
167.000
0.208
83E+01
0.208
71E+01
-0.057
0.208
70E+01
-0.062
0.0
0.0
168.000
0.216
74E+01
0.216
57E+01
-0.079
0.216
56E-K)1
-0.083
0.0
0.0
169.000
0.224
81E+01
0.224
65E+01
-0.072
0.224
64E-K)1
-0.075
0.0
0.0
170.000
0.233
lOE+01
0.232
94E+01
-0.071
0.232
93E-K)1
-0.074
0.0
0.0
171.000
0.241
60E+01
0.241
45E+01
-0.064
0.241
44E+01
-0.066
0.0
0.0
172.000
0.250
33E+01
0.250
18E+01
-0.059
0.250
17E-K)1
-0.061
0.0
0.0
173.000
0.259
30E+01
0.259
14E+01
-0.060
0.259
13E-K)1
-0.062
0.0
0.0
174.000
0.268
49E+01
0.268
33E+01
-0.058
0.268
33E-f01
-0.060
0.0
0.0
175.000
0.277
91E+01
0.277
76E+01
-0.053
0.277
76E401
-0.054
0.0
0.0
176.000
0.287
61E+01
0.287
44E+01
-0.060
0.287
43E+01
-0.062
0.0
0.0
177.000
0.297
50E+01
0.297
36E+01
-0.049
0.297
35E401
-0.051
0.0
0.0
178.000
0.307
70E+01
0.307
53E+01
-0.054
0.307
52E+01
-0.057
0.0
0.0
179.000
0.318
09E+01
0.317
96E+01
-0.041
0.317
95E-K)1
-0.044
0.0
0.0
180.000
0.328
82E+01
0.328
65E+01
-0.052
0.328
63E-K)1
-0.059
0.0
0.0
180.000
0.328
84E+01
0.328
65E+01
-0.058
0.328
63E-K)1
-0.065
0.0
0.0
181.000
0.339
77E+01
0.339
62E+01
-0.042
0.339
59E-K)1
-0.051
0.0
0.0
182.000
0.350
98E+01
0.350
87E+01
-0.032
0.350
84E-K)1
-0.041
0.0
0.0
182.000
0.351
OOE+01
0.350
87E+01
-0.038
0.350
84E-K)1
-0.047
0.0
0.0
183.000
0.362
56E+01
0.362
40E+01
-0.045
0.362
36E+01
-0.055
0.0
0.0
184.000
0.374
35E+01
0.374
23E+01
-0.032
0.374
19E-K)1
-0.044
0.0
0.0
185.000
0.386
47E+01
0.386
36E+01
-0.029
0.386
31E-K)1
-0.041
0.0
0.0
186.000
0.398
89E+01
0.398
81E+01
-0.020
0.398
76E-K)1
-0.033
0.0
0.0
187.000
0.411
66E+01
0.411
59E+01
-0.018
0.411
53E-K)1
-0.031
0.0
0.0
188.000
0.424
74E+01
0.424
71E-K)1
-0.008
0.424
65E+01
-0.021
0.0
0.0
189.000
0.438
24E+01
0.438
20E+01
-0.009
0.438
15E-K)1
-0.020
0.0
0.0
190.000
0.452
lOE+01
0.452
08E+01
-0.003
0.452
05E-K)1
-0.010
0.0
0.0
Number of Points (Ref.l8) 105
AADl-%
AADl
AAD2-%
AAD2
0.137,
0.679,
0.139,
0.771,
BIASl-%
BIASl
BIAS2-%
BIAS2
-0.137,
-0.679,
-0.139,
-0.771,
RMSl-% 0.108
RMSl 0.514 kPa
RMS2-% 0.103
RMS2 0.587 kPa
37
Data from
Haynes [19]
T
Pa, exp
Pa, eq (1)
Devi
Pa, SWEOS
Dev2
Wtl
Wt2
K
MPa
MPa
%
MPa
%
95.000
0.198 70E-01
0.198 34E-01
-0.182
0.198 32E-01
-0.190
0.0
0.0
100.000
0.344 80E-01
0.344 08E-01
-0.210
0.344 08E-01
-0.208
0.0
0.0
105.000
0.565 lOE-01
0.564 26E-01
-0.148
0.564 33E-01
-0.136
0.0
0.0
110.000
0.883 40E-01
0.882 03E-01
-0.155
0.882 19E-01
-0.137
0.0
0.0
115.000
0.132 48E+00
0.132 32E+00
-0.121
0.132 34E-K)0
-0.103
0.0
0.0
120.000
0.191 67E+00
0.191 58E+00
-0.048
0.191 61E400
-0.033
0.0
0.0
125.000
0.269 08E+00
0.268 96E+00
-0.044
0.268 99E-K)0
-0.035
0.0
0.0
130.000
0.367 60E+00
0.367 60E+00
-0.001
0.367 60E-K)0
0.000
0.0
0.0
135.000
0.490 69E+00
0.490 71E+00
0.005
0.490 68E-K)0
-0.001
0.0
0.0
140.000
0.641 55E+00
0.641 65E+00
0.015
0.641 56E-K)0
0.001
0.0
0.0
Number of Points (Ref . 19) 10
AADl-%
AADl
AAD2-%
AAD2
0.093,
0.082,
0.084,
0.061,
BIASl-%
BIASl
BIAS2-%
BIAS2
-0.089,
-0.058,
-0.084,
-0.060,
RMSl-% 0.080
RMSl 0.075 kPa
RMS2-% 0.077
RMS2 0.048 kPa
Data from eq (1)
T
?(j, exp
Pa. eq (1)
Devi
?tj, SWEOS
Dev2
Wtl
Wt2
K
MPa
MPa
%
MPa
%
91.0
1.217 52E-02
1.217 52E-02
_
1.217 49E-02
-0.003
.
46595.385
96.0
2.225 40E-02
2.225 40E-02
-
2.225 25E-02
-0.007
-
25531.209
101.0
3.814 59E-02
3.814 59E-02
-
3.814 75E-02
0.004
-
14913.515
106.0
6.192 18E-02
6.192 18E-02
-
6.193 06E-02
0.014
-
9199.929
111.0
9.595 25E-02
9.595 25E-02
-
9.597 06E-02
0.019
-
5947.908
116.0
1.428 67E-01
1.428 67E-01
_
1.428 93E-01
0.018
.
4004.906
121.0
2.055 07E-01
2.055 07E-01
-
2.055 35E-01
0.013
-
2793.881
126.0
2.868 87E-01
2.868 87E-01
-
2.869 07E-01
0.007
-
2010.580
131.0
3.901 56E-01
3.901 56E-01
-
3.901 55E-01
0.000
-
1487.113
136.0
5.185 69E-01
5.185 69E-01
-
5.185 28E-01
-0.008
-
1127.035
38
Data from eq (1) (continued)
T Pa. exp
K MPa
P^, eq (1) Devi P^, SWEOS
MPa % MPa
Dev2
Wtl
Wt2
141.0
6.754 67E-01
6.754 67E-01
6.753 61E-01
-0.016
1500.000
146.0
8.642 75E-01
8.642 75E-01
8.641 59E-01
-0.013
1500.000
151.0
1.088 50E-K)0
1.088 50E-K)0
1.088 34E+00
-0.014
1500.000
156.0
1.351 74E-K)0
1.351 74E-K)0
1.351 57E+00
-0.013
1500.000
161.0
1.657 78E-K)0
1.657 78E-K)0
1.657 60E+00
-0.010
1500.000
166.0
2.010 57E-K)0
2.010 57E-K)0
2.010 44E+00
-0.006
3750.000
171.0
2.414 45E-K)0
2.414 45E-K)0
2.414 39E+00
-0.002
3750.000
176.0
2.874 35E-K)0
2.874 35E-K)0
2.874 31E+00
-0.001
3750.000
181.0
3.396 22E-K)0
3.396 22E-K)0
3.395 94E+00
-0.008
3750.000
186.0
3.988 lOE+00
3.988 10E-+00
3.987 57E+00
-0.013
3750.000
Number of Points (eq (1)) 20
AADl-% - ,
AADl - ,
AAD2-% 0.010,
AAD2 0.096,
BIASl-%
BIASl
BIAS2-%
BIAS2
-0.002,
-0.086,
RMSl-%
RMSl
RMS2-% 0.011
RMS2 0.132 kPa
Total Points 153 for Ancillary Equation
AADl-% 0.103,
AADl 0.514,
BIASl-% -0.099, RMSl-% 0.109
BIASl -0.444, RMSl 0.563 kPa
Total Points 173 for Equation of State
AAD2-% 0.092,
AAD2 0.508,
BIAS2-% -0.090,
BIAS2 -0.492,
RMS2-% 0.104
RMS2 0.581 kPa
39
TABLE A2
COMPARISONS FOR SATURATED LIQUID DENSITIES
Note: The numeral 1 associated with quantities refers to comparisons with eq (2);
the numeral 2 refers to comparisons with the SWEOS. Similarly, Wtl refers to
weighting for the development of eq (2) , and Wt2 refers to weighting of the
Gibbs condition for the development of the SWEOS. For the points generated
from eq (2), in the last part of the table, statistics relative to eq (2)
have no meaning; these points are therefore excluded from the totals.
Data from Kleinrahm and Wagner [6]
T
Pah' exp
Pc-L' eq(2)
Devi
p^L. SWEOS
Dev2
Wtl
Wt2
K
mol'dm'-'
mol'dm"^
%
mol'dm""'
%
90.685
28.1411
28.1474
0.022
28.1452
0.015
1.0
0.0
91.000
28.1144
28.1208
0.023
28.1192
0.017
1.0
0.0
95.000
27.7811
27.7811
0.000
27.7860
0.018
1.0
0.0
100.000
27.3571
27.3518
-0.019
27.3624
0.019
1.0
0.0
105.000
26.9223
26.9157
-0.025
26.9295
0.027
1.0
0.0
110.000
26.4772
26.4709
-0.024
26.4858
0.032
1.0
0.0
111.631
26.3286
26.3236
-0.019
26.3384
0.037
1.0
0.0
115.000
26.0197
26.0154
-0.016
26.0298
0.039
1.0
0.0
120.000
25.5490
25.5473
-0.007
25.5600
0.043
1.0
0.0
125.000
25.0629
25.0641
0.005
25.0744
0.046
1.0
0.0
130.000
24.5594
24.5632
0.015
24.5708
0.046
1.0
0.0
135.000
24.0353
24.0415
0.026
24.0466
0.047
1.0
0.0
140.000
23.4889
23.4956
0.028
23.4984
0.040
1.0
0.0
145.000
22.9145
22.9210
0.028
22.9221
0.033
1.0
0.0
150.000
22.3071
22.3123
0.023
22.3124
0.024
1.0
0.0
155.000
21.6599
21.6624
0.012
21.6622
0.011
1.0
0.0
160.000
20.9618
20.9618
0.000
20.9617
-0.001
1.0
0.0
165.000
20.2000
20.1966
-0.017
20.1966
-0.017
1.0
0.0
170.000
19.3516
19.3457
-0.030
19.3451
-0.034
1.0
0.0
175.000
18.3815
18.3730
-0.046
18.3706
-0.059
1.0
0.0
180.000
17.2151
17.2070
-0.047
17.2044
-0.062
1.0
0.0
182.000
16.6600
16.6537
-0.038
16.6536
-0.039
1.0
0.0
184.000
16.0238
16.0205
-0.020
16.0263
0.016
1.0
0.0
186.000
15.2610
15.2622
0.008
15.2793
0.120
1.0
0.0
187.000
14.8040
14.8072
0.021
14.8325
0.193
1.0
0.0
40
Data from Kleinrahm and Wagner [6] continued
T
PcL ' exp
Pat> eq(2)
Devi
p^L . SWEOS
Dev2
Wtl
Wt2
K
mol'dm"^
mol'dm'^
%
mol»dm"^
%
188.000
14.2617
14.2672
0.039
14.3028
0.288
1.0
0.0
189.000
13.5704
13.5766
0.046
13.6234
0.391
1.0
0.0
189.500
13.1152
13.1218
0.050
13.1727
0.439
1.0
0.0
189.800
12.7744
12.7795
0.040
12.8303
0.438
1.0
0.0
190.000
12.4960
12.5000
0.032
12.5476
0.413
1.0
0.0
190.100
12.3325
12.3356
0.025
12.3796
0.382
1.0
0.0
190.200
12.1436
12.1463
0.022
12.1838
0.331
1.0
0.0
190.300
11.9180
11.9187
0.006
11.9449
0.226
1.0
0.0
190.400
11.6225
11.6228
0.002
11.6265
0.034
1.0
0.0
190.450
11.4243
11.4242
-0.001
11.4071
-0.150
1.0
0.0
190.500
11.1494
11.1463
-0.027
11.0923
-0.513
1.0
0.0
190.530
10.8882
10.8736
-0.135
10.7796
-0.997
1.0
0.0
190.551
10.1390
10.1390
0.000
10.1390
0.000
1.0
0.0
Number of Points (Ref . 6) 38
AADl-% 0.025, BIASl-% 0.000, RMSl-% 0.034
AADl 0.004, BIASl 0.000, RMSl 0.005 mol-dm"^
AAD2-% 0.148, BIAS2-% 0.050, RMS2-% 0.249
AAD2 0.020, BIAS2 0.009, RMS2 0.030 mol-dm"^
Data from Orrit and Laupretre [20]
T
Pcf exp
PaL' eq(2)
Devi
p^L. SWEOS
Dev2
Wtl
Wt2
K
mol'dm"^
mol«dm"^
%
rool'dm"^
%
99.447
27.4263
27.3996
-0.097
27.4097
-0.061
0.0
0.0
104.630
26.9731
26.9482
-0.092
26.9618
-0.042
0.0
0.0
109.832
26.5081
26.4860
-0.083
26.5009
-0.027
0.0
0.0
115.147
26.0219
26.0019
-0.077
26.0162
-0.022
0.0
0.0
117.812
25.7545
25.7539
-0.002
25.7674
0.050
0.0
0.0
41
Data from Orrit and Laupretre [20] continued
T
Pah . exp
PaL' eq(2)
Devi
p^L . SWEOS
Dev2
Wtl
Wt2
K
mol'dm"^
mol'dm"^
%
mol«dm"^
%
120.577
25.5183
25.4924
-0.102
25.5048
-0.053
0.0
0.0
123.300
25.2303
25.2302
0.000
25.2414
0.044
0.0
0.0
126.026
24.9872
24.9628
-0.097
24.9726
-0.059
0.0
0.0
128.614
24.7142
24.7040
-0.041
24.7123
-0.008
0.0
0.0
131.494
24.4343
24.4096
-0.101
24.4165
-0.073
0.0
0.0
134.235
24.1376
24.1228
-0.061
24.1282
-0.039
0.0
0.0
137.004
23.8590
23.8259
-0.139
23.8299
-0.122
0.0
0.0
139.730
23.5405
23.5258
-0.063
23.5287
-0.050
0.0
0.0
142.412
23.2494
23.2223
-0.117
23.2242
-0.108
0.0
0.0
145.146
22.9265
22.9037
-0.099
22.9048
-0.095
0.0
0.0
147.933
22.5955
22.5685
-0.120
22.5689
-0.118
0.0
0.0
153.472
21.9111
21.8659
-0.206
21.8657
-0.207
0.0
0.0
150.627
22.2515
22.2332
-0.082
22.2333
-0.082
0.0
0.0
155.955
21.5415
21.5329
-0.040
21.5327
-0.041
0.0
0.0
159.051
21.1301
21.0992
-0.146
21.0991
-0.147
0.0
0.0
Number of Points (Ref . 20) 20
AADl-%
AADl
AAD2-%
AAD2
0.088,
0.021,
0.072,
0.017,
BIASl-%
BIASl
BIAS2-%
BIAS2
-0.088.
-0.021,
-0.063,
-0.015,
RMSl-%
RMSl
RMS2-%
RMS2
0.047
0.011
0.059
0.013
mol • dm" ^
mol'dm
-3
Data from Haynes and Hiza [21]
T
PaL . exp
PaL. eq(2)
Devi
p^L. SWEOS
Dev2
Wtl
Wt2
K
mol* dm" ^
mol* dm" ^
%
mol* dm""'
%
105.000
26.9458
26.9157
-0.112
26.9295
-0.061
0.0
0.0
110.000
26.4985
26.4709
-0.104
26.4858
-0.048
0.0
0.0
115.000
26.0443
26.0154
-0.111
26.0298
-0.056
0.0
0.0
120.000
25.5721
25.5473
-0.097
25.5600
-0.047
0.0
0.0
125.000
25.0845
25.0641
-0.081
25.0744
-0.040
0.0
0.0
42
Data from Haynes and Hiza [21] continued
T
PaL. exp
PaL. eq(2)
Devi
p^L. SWEOS
Dev2
Wtl
Wt2
K
mol'dm""'
mol'dra""'
%
mol'dm"^
%
130.000
24.5775
24.5632
-0.058
24.5708
-0.027
0.0
0.0
135.000
24.0540
24.0415
-0.052
24.0466
-0.031
0.0
0.0
140.000
23.5067
23.4956
-0.047
23.4984
-0.035
0.0
0.0
145.000
22.9312
22.9210
-0.045
22.9221
-0.040
0.0
0.0
150.000
22.3218
22.3123
-0.043
22.3124
-0.042
0.0
0.0
160.000
20.9876
20.9618
-0.123
20.9617
■0.124 0.0 0.0
Number of Points (Ref . 21) 11
AADl-% 0.079,
BIASl-%
-0.079,
RMSl-% 0.030
AADl 0.020,
BIASl
-0.020,
RMSl 0.008
mol • dm" ^
AAD2-% 0.050,
BIAS2-%
-0.050,
RMS2-% 0.025
AAD2 0.012,
BIAS2
-0.012,
RMS2 0.005
mol • dm" ^
Data from McClune [22]
T
PcL' exp
PaL . eq(2)
Devi
p^L. S\VEOS
Dev2
Wtl
Wt2
K
mol'dm""'
mol • dm" ^
%
mol'dm"^
%
93.150
27.9493
27.9385
-0.039
27.9407
-0.031
0.0
0.0
93.150
27.9493
27.9385
-0.039
27.9407
-0.031
0.0
0.0
98.150
27.5267
27.5113
-0.056
27.5201
-0.024
0.0
0.0
103.150
27.0978
27.0779
-0.073
27.0908
-0.026
0.0
0.0
108.150
26.6521
26.6366
-0.058
26.6513
-0.003
0.0
0.0
113.150
26.1977
26.1853
-0.047
26.2000
0.009
0.0
0.0
118.150
25,7340
25.7221
-0.046
25.7355
0.006
0.0
0.0
123.150
25.2615
25.2448
-0.066
25.2560
-0.022
0.0
0.0
Number of Points (Ref. 22)
AADl-%
AADl
AAD2-%
AAD2
0.055,
0.015,
0.017,
0.005,
BIASl- %
BIASl
BIAS2-%
BIAS2
-0.055,
-0.015,
-0.013,
-0.004,
-3
RMSl-% 0.011
RMSl 0.003 mol -dm'
RMS2-% 0.015
RMS2 0.004 mol-dm"3
43
Data from Terry et al. [23]
T
P„L ' exp
PaL. eq(2)
Devi
p^L. SWEOS
Dev2
Wtl
Wt2
K
mol'dm"^
mol'dnf^
%
mol'dm"^
%
92.029
28.0346
28.0336
-0.003
28.0339
-0.003
0.0
0.0
93.090
27.9519
27.9436
-0.030
27.9457
-0.022
0.0
0.0
93.654
27.8975
27.8957
-0.006
27.8986
0.004
0.0
0.0
95.743
27.7233
27.7177
-0.020
27.7236
0.001
0.0
0.0
95.905
27.7225
27.7038
-0.067
27.7099
-0.045
0.0
0.0
100.939
27.2831
27.2705
-0.046
27.2818
-0.005
0.0
0.0
102.616
27.1502
27.1246
-0.094
27.1371
-0.048
0.0
0.0
107.338
26.7229
26.7089
-0.053
26.7234
0.002
0.0
0.0
108.806
26.6082
26.5780
-0.114
26.5928
-0.058
0.0
0.0
112.156
26.2882
26.2759
-0.047
26.2907
0.010
0.0
0.0
114.003
26.1369
26.1072
-0.114
26.1218
-0.058
0.0
0.0
117.523
25.7883
25.7810
-0.028
25.7946
0.024
0.0
0.0
119.319
25.6420
25.6119
-0.117
25.6248
-0.067
0.0
0.0
123.040
25.2307
25.2555
0.098
25.2667
0.143
0.0
0.0
125.765
25.0206
24.9887
-0.128
24.9986
-0.088
0.0
0.0
127.426
24.8201
24.8234
0.013
24.8324
0.050
0.0
0.0
130.078
24.5872
24.5552
-0.130
24.5628
-0.099
0.0
0.0
132.228
24.3426
24.3335
-0.037
24.3399
-0.011
0.0
0.0
136.122
23.9493
23.9213
-0.117
23.9258
-0.098
0.0
0.0
137.671
23.8061
23.7532
-0.222
23.7569
-0.207
0.0
0.0
140.482
23.4704
23.4415
-0.123
23.4441
-0.112
0.0
0.0
142.092
23.2555
23.2589
0.015
23.2610
0.023
0.0
0.0
145.195
22.9151
22.8979
-0.075
22.8990
-0.070
0.0
0.0
147.541
22.6171
22.6163
-0.004
22.6168
-0.001
0.0
0.0
151.369
22.1523
22.1388
-0.061
22.1388
-0.061
0.0
0.0
Number of Points (Ref . 23) 25
AADl-% 0.070, BIASl-% -0.060, RMSl-% 0.064
AADl 0.018, BIASl -0.015, RMSl 0.016 mol'dra"'
AAD2-% 0.052, BIAS2-% -0.032, RMS2-% 0.065
AAD2 0.013, BIAS2 -0.008, RMS2 0.016 mol'dm"^
44
Data from Klosek and McKinley [24]
T
PaL. exp
PaL. eq(2)
Devi
p^L. SWEOS
Dev2
Wtl
Wt2
K
mol»dm"^
mol'dm"^
%
mol'dra'^
%
94.261
27.8437
27.8441
0.001
27.8479
0.015
0.0
0,0
99.817
27.3539
27.3676
0.050
27.3780
0.088
0.0
0.0
105.372
26.8631
26.8829
0.074
26.8968
0.126
0.0
0.0
110.928
26.3635
26.3872
0.090
26.4021
0.146
0.0
0.0
116.483
25.8654
25.8780
0.049
25.8920
0.103
0.0
0.0
122.039
25.3377
25.3522
0.057
25.3640
0.104
0.0
0.0
127.594
24.7887
24.8066
0.072
24.8155
0.108
0.0
0.0
133.150
24.2373
24.2372
0.000
24.2431
0.024
0.0
0.0
Number of Points (Ref . 24) 8
AADl-%
AADl
AAD2-%
AAD
0.049,
0.013,
0.089,
0.023,
BIASl-
BIASl
BIAS2-
BIAS2
0.049,
0.013,
0.089,
0.023.
RMSl-% 0.031
RMSl 0.008 mol.dm"^
RMS2-% 0.043
RMS2 0.011 mol«dm"3
Data from Rodosevich and Miller [25]
T
PaL. exP
PaL' eq(2)
Devi
p^L. SWEOS
Dev2
Wtl
Wt2
K
mol'dm"^
mol'dm"''
%
mol'dm"^
%
91.000
28.1175
28.1208
0.012
28.1192
0.006
0.0
0.0
100.150
27.3545
27.3388
-0.057
27.3495
-0.018
0.0
0.0
108.050
26.6638
26.6455
-0.069
26.6602
-0.014
0.0
0.0
114.940
26.0396
26.0210
-0.071
26.0354
-0.016
0.0
0.0
Number of Points (Ref. 25) 4
AADl-% 0.052,
BIASl -%
-0.046,
AADl 0.014,
BIASl
-0.012,
AAD2-% 0.014,
BIAS2-%
-0.011,
AAD2 0.004,
BIAS2
-0.003,
RMSl-% 0.034
RMSl 0.009 mol»dra"3
RMS2-% 0.010
RMS2 0.003 mol«dra"3
45
Data from Verbeke [26]
T
PaL ' exp
PaL' eq(2)
Devi
p^L . SWEOS
Dev2
Wtl
Wt2
K
mol'dm"''
mol'dni"'^
%
mol'dm"^
%
190.050
12.4400
12.4204
-0.158
12.4664
0.212
0.0
0.0
190.150
12.2700
12.2447
-0.206
12.2859
0.129
0.0
0.0
190.250
12.0700
12.0385
-0.261
12.0712
0.010
0.0
0.0
190.350
11.7900
11.7826
-0.063
11.7997
0.082
0.0
0.0
190.450
11.4100
11.4242
0.125
11.4071
-0.025
0.0
0.0
Number of Points (Ref . 26) 5
AADl-%
AADl
AAD2-%
AAD2
0.163,
0.020,
0.092,
0.011,
BIASl-%
BIASl
BIAS2-%
BIAS2
-0.113,
-0.014,
0.082,
0.010,
.-3
RMSl-% 0.135
RMSl 0.016 mol.dm
RMS2-% 0.085
RMS2 0.010 mol'dm"3
Data from Vennix et al. [27]
T
PaL . ^^P
PaL. eq(2)
Devi
p^L. SWEOS
Dev2
Wtl
Wt2
K
mol'dm""'
mol • dm" ^
%
mol* dm"''
%
138.951
23.6246
23.6124
-0.052
23.6155
-0.038
0.0
0.0
158.829
21.2348
21.1311
-0.488
21.1309
-0.489
0.0
0.0
166.766
20.0075
19.9073
-0.501
19.9072
-0.501
0.0
0.0
174.773
18.5009
18.4206
-0.434
18.4183
-0.446
0.0
0.0
178.726
17.5690
17.5291
-0.227
17.5260
-0.245
0.0
0.0
182.608
16.5275
16.4711
-0.341
16.4723
-0.334
0.0
0.0
186.771
14.9754
14.9175
-0.387
14.9408
-0.231
0.0
0.0
188.852
13.7549
13.6933
-0.448
13.7385
-0.119
0.0
0.0
189.882
12.6809
12.6713
-0.076
12.7213
0.319
0.0
0.0
Number of Points (Ref. 27) 9
AADl-%
AADl
AAD2-%
AAD2
0.328,
0.058,
0.302,
0.054,
BIASl- %
BIASl
BIAS2-%
BIAS2
-0.328,
-0.058,
-0.232,
-0.045,
,-3
RMSl-% 0.161
RMSl 0.032 mol 'dm
RMS2-% 0.247
RMS2 0.044 raol'dm"^
46
Data from
Goodwin [28]
T
Pah ' exp
PctL. eq(2)
Devi
p^L, SWEOS
Dev2
Wtl
Wt2
K
mol'cin""'
mol'dm""'
%
mol'dm'^
%
130.000
24.5580
24.5632
0.021
24.5708
0.052
0.0
0.0
135.000
24.0410
24.0415
0.002
24.0466
0.023
0.0
0.0
140.000
23.5000
23.4956
-0.019
23.4984
-0.007
0.0
0.0
145.000
22.9320
22.9210
-0.048
22.9221
-0.043
0.0
0.0
150.000
22.3290
22.3123
-0.075
22.3124
-0.074
0.0
0.0
155.000
21.6860
21.6624
-0.109
21.6622
-0.110
0.0
0.0
160.000
20.9910
20.9618
-0.139
20.9617
-0.140
0.0
0.0
165.000
20.2340
20.1966
-0.185
20.1966
-0.185
0.0
0.0
170.000
19.3870
19.3457
-0.213
19 . 3451
-0.216
0.0
0.0
175.000
18.4170
18.3730
-0.239
18.3706
-0.252
0.0
0.0
180.000
17.2490
17.2070
-0.243
17.2044
-0.258
0.0
0.0
184.000
16.0540
16.0205
-0.209
16.0263
-0.172
0.0
0.0
186.000
15.2860
15.2622
-0.156
15.2793
-0.044
0.0
0.0
188.000
14.2840
14.2672
-0.118
14.3028
0.131
0.0
0.0
Number of Points (Ref . 28) 14
AADl-%
AAD
AAD2-%
AAD
0.127,
0.024,
0.122,
0.023,
BIASl-%
BIASl
BIAS2-%
BIAS 2
-0.124,
-0.023,
-0.093,
-0.018,
RMSl-% 0.086
RMSl 0.016 mol'dm'3
RMS2-% 0.114
RMS2 0.021 mol'dm'3
Data from Ricci and Scafe [29]
T
PaL' exp
P<ri' eq(2)
Devi
p^L. SWEOS
Dev2
Wtl
Wt2
K
mol'dm"^
mol'dm"^
%
mol'dm"'^
%
185.030
15.7100
15.6501
-0.381
15.6609
-0.313
0.0
0.0
186.030
15.3020
15.2495
-0.343
15.2668
-0.230
0.0
0.0
187.031
14.8360
14.7919
-0.297
14.8176
-0.124
0.0
0.0
188.031
14.2850
14.2486
-0.255
14.2845
-0.004
0.0
0.0
189.032
13.5780
13.5505
-0.202
13.5976
0.145
0.0
0.0
190.032
12.4740
12.4496
-0.196
12.4963
0.178 0.0
0.0
47
Data from Ricci and Scafe [29] continued
Number of Points (Ref . 29) 6
AADl-%
AADl
AAD2-%
AAD2
0.279,
0.041,
0.166,
0.024,
BIASl-%
BIASl
BIAS2-%
BIAS2
-0.279,
-0.041,
-0.058,
-0.010,
,-3
RMSl-% 0.069
RMSl 0.013 mol.dm"
RMS2-% 0.182
RMS2 0.027 mol.dm"3
Data from Goodwin [30]
T
Pel. > exp
PaL. eq(2)
Devi
p^L . SWEOS
Dev2
Wtl
Wt2
K
mol'dm"^
mol«dm"^
%
mol'dm"^
%
150.000
22.3320
22.3123
-0.088
22.3124
-0.088
0.0
0.0
175.000
18.4200
18.3730
-0.255
18.3706
-0.268
0.0
0.0
180.000
17.2540
17.2070
-0.272
17.2044
-0.287
0.0
0.0
184.000
16.0600
16.0205
-0.246
16.0263
-0.210
0.0
0.0
Number of Points (Ref. 30) 4
AADl-% 0.215,
BIASl- %
-0.215,
AADl 0.038,
BIASl
-0.038,
AAD2-% 0.213,
BIAS2-%
-0.213,
AAD2 0.038,
BIAS2
-0.038,
,-3
RMSl-% 0.074
RMSl 0.011 mol.dm
RMS2-% 0.078
RMS2 0.012 mol.dm" 3
Data from Goodwin [31]
T
Pel . exp
PaL> eq(2)
Devi
PaL> SWEOS
Dev2
Wtl
Wt2
K
mol.dm"-*
mol.dm"^
%
mol'dra"^
%
93.512
27.9100
27.9078
-0.008
27.9105
0.002
0.0
0.0
97.173
27.6050
27.5952
-0.035
27.6029
-0.007
0.0
0.0
101.434
27.2430
27.2275
-0.057
27.2392
-0.014
0.0
0.0
105.165
26.9160
26.9011
-0.055
26.9150
-0.004
0.0
0.0
109.611
26.5270
26.5058
-0.080
26.5207
-0.024
0.0
0.0
48
Data from Goodwin [31] (continued)
T
PaL' exp
PaL. eq(2)
Devi
p^L. SWEOS
Dev2
Wtl
Wt2
K
mol«dm"^
mol'dm"''
%
mol'dm""'
%
113.772
26.1460
26.1284
-0.067
26.1430
-0.011
0.0
0.0
117.746
25.7820
25.7601
-0.085
25.7736
-0.033
0.0
0.0
121.893
25.3880
25.3663
-0.086
25.3781
-0.039
0.0
0.0
125.825
24.9990
24.9827
-0.065
24.9926
-0.026
0.0
0.0
129.657
24.6110
24.5982
-0.052
24.6060
-0.020
0.0
0.0
133.773
24.1860
24.1717
-0.059
24.1773
-0.036
0.0
0.0
133.878
24.1760
24.1606
-0.064
24.1661
-0.041
0.0
0.0
139.352
23.5780
23.5679
-0.043
23.5709
-0.030
0.0
0.0
145.448
22.8800
22.8679
-0.053
22.8689
-0.048
0.0
0.0
151.553
22.1300
22.1152
-0.067
22.1152
-0.067
0.0
0.0
157.199
21.3790
21.3612
-0.083
21.3610
-0.084
0.0
0.0
163.659
20.4280
20.4092
-0.092
20.4092
-0.092
0.0
0.0
169.326
19.4920
19.4665
-0.131
19.4660
-0.133
0.0
0.0
175.053
18.3900
18.3618
-0.153
18.3594
-0.166
0.0
0.0
Number of Points (Ref . 31) 19
AADl-% 0.070,
BIASl-%
-0.070,
RMSl-% 0.031
AADl 0.016,
BIASl
-0.016,
RMSl 0.006
mol'dm""'
AAD2-% 0.046,
BIAS2-%
-0.046,
RMS2-% 0.044
AAD2 0.010,
BIAS2
-0.010,
RMS2 0.008
mol«dm'^
Data from Jansoone et al. [32]
T p^L . exp p^L . eq(2) Devi
K mol'dra"^ mol«dm"''
187.469 14.5820 14.5672
189.311 13.3000 13.3068
189.707 12.8790 12.8935
190.048 12.3970 12.4237
190.316 11.8240 11.8772
190.442 11.3670 11.4597
190.515 10.7960 11.0288
Devi
PoL> SWEOS
Dev2
Wtl
Wt2
%
mol'dm"^
%
0.102
14.5971
0.103
0.0
0.0
0.051
13.3566
0.425
0.0
0.0
0.112
12.9448
0.511
0.0
0.0
0.215
12.4698
0.587
0.0
0.0
0.450
11.9008
0.650
0.0
0.0
0.815
11.4466
0.701
0.0
0.0
2.157
10.9573
1.494
0.0
0.0
49
Data from Jansoone et al. [32] (continued)
Number of Points (Ref . 32) 7
AADl-% 0.557,
AADl 0.063,
AAD2-% 0.639,
BIASl-% 0.528,
BIASl 0.059,
BIAS2-% 0.639,
AAD2 0.076, BIAS2
0.076,
,-3
RMSl-% 0.721
RMSl 0.078 mol'dm
RMS2-% 0.394
RMS2 0.041 raol»c3m"3
Data from eq (2)
T
Pch ' exp
p^L. eq(2) E
>evl p^L > SWEOS
Dev2
Wtl Wt2
K
mol'dra"'^
mol'dm"^
% mol'dm''^
%
91.0
28.12075
28.12075
28.11919
-0.006
17.390
96.0
27.69569
27.69569
27.70194
0.023
10.963
101.0
27.26517
27.26517
27.27660
0.042
7.354
106.0
26.82746
26.82746
26.84162
0.053
5.201
111.0
26.38069
26.38069
26.39559
0.056
3.850
116.0
25.92291
25.92291
25.93700
0.054
2.964
121.0
25.45195
25.45195
25.46417
0.048
2.362
126.0
24.96542
24.96542
24.97517
0.039
1.941
131.0
24.46062
24.46062
24.46769
0.029
1.639
136.0
23.93442
23.93442
23.93895
0.019
49.669
141.0
23.38312
23.38312
23.38551
0.010
44.004
146.0
22.80217
22.80217
22.80303
0.004
- 199.223
151.0
22.18586
22.18586
22.18588
0.000
- 184.268
156.0
21.52672
21.52672
21.52651
-0.001
- 174.141
161.0
20.81447
20.81447
20.81438
0.000
- 168.363
166.0
20.03418
20.03418
20.03409
0.000
- 167.007
171.0
19.16248
19.16248
19.16155
-0.005
- 170.897
176.0
18.15860
18.15860
18.15590
-0.015
- 182.282
181.0
16.93856
16.93856
16.93686
-0.010
- 206.862
186.0
15.26221
15.26221
15.27930
0.112
- 260.343
Number of Points (eq. (2)) 20
AADl-% - ,
AADl - ,
AAD2-% 0.026,
AAD2 0.006,
BIASl-%
BIASl
BIAS2-%
BIAS2
0.023,
0.005,
RMSl-%
RMSl
RMS2-% 0.031
RMS2 0.006 mol'dm"^
50
Total Points 177 for Ancillary Equation
AADl-% 0.111, BIASl-% -0.055, RMSl-% 0.214
AADl 0.020, BIASl -0.013, RMSl 0.029 mol'dm'
-3
Total Points 197 for Equation of State
AAD2-% 0.114, BIAS2-% -0.001, RMS2-% 0.211
AAD2 0.019, BIAS2 -0.003, RMS2 0.033 mol-drn'^
Total Points 76 from Refs, 6, 20-22 for Ancillary Equation
AADl-% 0.052, BIASl-% -0.040, RMSl-% 0.054
AADl 0.012, BIASl -0.010, RMSl 0.012 mol'din"^
Total Points 76 from Refs. 6, 20-22 for Equation of State
AADl-% 0.102, BIASl-% 0.000, RMSl-% 0.186
AADl 0.017, BIASl -0.002, RMSl 0.025 mol.dm"^
51
TABLE A3
COMPARISONS FOR SATURATED VAPOR DENSITIES
Notes for Table A3. The numeral 1 associated with quantities refers to comparisons
with eq (3); the numeral 2 refers to con^)arisons with the SWEOS. Similarly, Wtl
refers to weighting for the development of eq (3) , and Wt2 refers to weighting of
the saturated vapor densities in the development of the SWEOS. For the points
generated from eq (3), in the last part of the table, statistics relative to eq (3)
have no meaning; these points are therefore excluded from the totals.
Data from Kleinrahm and Wagner [6]
T p^v . exp p^v , eq(3)
K mol'dm'^ mol«dm"^
90.685
91.000
95.000
100.000
105.000
0.015 63
0.016 23
0.025 43
0.042 16
0.066 28
0.015 64
0.016 23
0.025 42
0.042 14
0.066 30
Devi
0.034
■0.012
•0.041
■0.047
0.028
p^v . SWEOS
mol»dm~
0.015 65
0.016 25
0.025 43
0.042 15
0.066 30
Dev2
%
0.155
0.104
0.018
-0.025
0.035
Wtl
1.0
1.0
1.0
1.0
1.0
Wt2
0.0
0.0
0.0
0.0
0.0
110.000
111.631
115.000
120.000
125.000
130.000
135.000
140.000
145.000
150.000
0.099 77
0.113 10
0.144 75
0.203 49
0.278 63
0.373 02
0.490 01
0.633 24
0.807 50
1.018 33
0.099 81
0.113 12
0.144 79
0.203 54
0.278 62
0.372 91
0.489 71
0.632 89
0.807 15
1.018 30
0.045
0.017
0.029
0.026
■0.003
■0.030
■0.062
•0.055
■0.043
■0.003
0.099 82
0.113 13
0.144 83
0.203 63
0.278 81
0.373 22
0.490 14
0.633 43
0.807 71
1.018 76
0.053
0.028
0.052
0.070
0.063
0.052
0.027
0.030
0.025
0.042
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
155.000
160.000
165.000
170.000
175.000
180.000
182.000
184.000
186.000
187.000
1.273 35
1.582 93
1.961 49
2.430 79
3.028 90
3.828 69
4.238 42
4.729 87
5.347 68
5.732 94
1.273 83
1.583 83
1.962 64
2.432 20
3.029 52
3.827 39
4.236 04
4.726 28
5.343 67
5.729 03
0.037
0.057
0.059
0.058
0.020
-0.034
-0.056
■0.076
-0.075
-0.068
1.274 06
1.583 75
1.962 28
2.431 73
3.029 25
3.827 36
4.235 79
4.725 28
5.340 76
5.724 44
0.056
0.052
0.040
0.039
0.012
-0.035
-0.062
-0.097
-0.129
-0.148
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
52
Data from Kleinrahm and Wagner [6] (continued)
T p^v. exp p^v. eq(3) Devi p^^ , SWEOS
K
mol'dm"^
mol'dm
,-3
%
mol*dm
,-3
Dev2
Wtl
Wt2
188.000
6.202 44
6.199
74
-0,044
6.192
76
-0.156
1.0
0.0
189.000
6.820 73
6.821
13
0.006
6.811
37
-0.137
1.0
0.0
189.500
7.237 74
7.241
06
0.046
7.230
89
-0.095
1.0
0.0
189.800
7.556 57
7.562
03
0.072
7.553
44
-0.041
1.0
0.0
190.000
7.820 23
7.826
92
0.085
7.821
73
0.019
1.0
0.0
190.100
7.976 69
7.983
80
0.089
7.981
91
0.065
1.0
0.0
190.200
8.156 83
8.165
49
0.106
8.168
94
0.148
1.0
0.0
190.300
8.375 62
8.385
08
0.113
8.397
75
0.264
1.0
0.0
190.400
8.660 47
8.672
58
0.140
8.703
06
0.492
1.0
0.0
190.450
8.854 95
8.866
51
0.131
8.913
33
0.659
1.0
0.0
190.500
9.129 22
9.139
30
0.110
9.214
75
0.937
1.0
0.0
190.530
9.396 00
9.408
46
0.133
9.514
12
1.257
1.0
0.0
190.551
10.139 00
10.139
00
0.000
10.139
00
0.000
1.0
0.0
Number of Points (Ref . 6) 38
AADl-%
0.055,
BIASl-%
0.021,
RMSl-% 0.063
AADl
0.003,
BIASl
0.002,
RMSl 0.004
mol'dm"^
AAD2-%
0.150.
BIAS2-%
0.102,
RMS2-% 0.282
AAD2
0.011,
BIAS2
0.008,
RMS2 0.026
mol«dm"^
Data from Goodwin [3]
T
Pav. exp
Pav. eq(3)
Devi
p^v. SWEOS
Dev2
Wtl
Wt2
K
mol'dm"^
mol'dm""*
%
mol'dm"^
%
94.000
0.022 90
0.022 81
-0.384
0.022 83
-0.313
0.0
0.0
100.000
0.042 20
0.042 14
-0.141
0.042 15
-0.120
0.0
0.0
106.000
0.072 20
0.072 19
-0.016
0.072 19
-0.010
0.0
0.0
112.000
0.116 20
0.116 31
0.091
0.116 32
0.104
0.0
0.0
118.000
0.178 10
0.178 23
0.074
0.178 29
0.109
0.0
0.0
124.000
0.262 10
0.262 17
0.026
0.262 33
0.087
0.0
0.0
130.000
0.373 00
0.372 91
-0.024
0.373 22
0.058
0.0
0.0
136.000
0.516 40
0.516 10
-0.059
0.516 56
0.030
0.0
0.0
142.000
0.699 20
0.698 57
-0.090
0.699 13
-0.011
0.0
0.0
148.000
0.930 10
0.928 98
-0.121
0.929 49
-0.065
0.0
0.0
53
Data from Goodwin [3] (continued)
K mol'dm"^ mol»dm"^
154.000
160.000
169.067
169.270
169.417
169.601
169.794
173.088
173.290
173.489
173.473
173.675
173.857
177.094
177.328
1.220 90
1.585 20
2.344 10
2.364 00
2.381 00
2.400 60
2.418 80
2.791 60
2.814 70
2.840 00
2.842 30
2.864 30
2.887 70
3.343 40
3.379 50
1.218 73
1.583 83
2.336 30
2.356 81
2.371 78
2.390 67
2.410 66
2.782 59
2.807 49
2.832 28
2.830 28
2.855 69
2.878 83
3.332 77
3.369 12
Devi
%
-0.178
-0.087
-0.333
-0.304
-0.387
-0.414
-0.336
-0.323
■0.256
-0.272
-0.423
-0.301
■0.307
■0.318
■0.307
/j^v. SWEOS
mol'dm"
1.219 02
1.583 75
2.335 83
2.356 34
2.371 31
2.390 20
2.410 19
2.782 21
2.807 12
2.831 92
2.829 92
2.855 34
2.878 49
3.332 64
3.369 01
Dev2
%
-0.154
-0.091
-0.353
-0.324
-0.407
-0.433
-0.356
-0.336
-0.269
-0.284
■0.436
■0.313
-0.319
■0.322
■0.310
Wtl
0.0
0.0
0.0
0.0
0,0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Wt2
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
181.389
181.768
183.514
184.285
184.510
186.319
188.545
4.126 90
4.204 20
4.618 90
4.826 30
4.887 60
5.479 50
6.527 80
4.103 90
4.185 03
4.597 76
4.804 97
4.868 98
5.459 46
6.512 37
■0.557
■0.456
-0.458
■0.442
■0.381
-0.366
■0.236
4.103 76
4.184 83
4.597 02
4.803 78
4.867 63
5.456 09
6.503 83
-0.561
■0.461
-0.474
■0.467
■0.409
■0.427
-0.367
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Number of Points (Ref . 3) 32
AADl-%
AADl
AAD2-%
AAD2
0.265,
0.008,
0.274,
0.009,
BIASl-%
BIASl
BIAS2-%
BIAS2
-0.253.
-0.008,
-0.250,
-0.009,
RMSl-% 0.168
RMSl 0.007 mol'dm'3
RMS2-% 0.194
RMS2 0.008 mol.dm'3
54
Data from Ricci and Scafe [29]
T p^v. exp p^v, eq(3)
K mol'dm'^ mol»dm"^
185.030
186.030
187.031
188.031
189.032
190.032
,038 00
,384 00
,786 00
,275 00
,918 00
7.960 00
5.023 89
5.354 31
5.742 13
6.216 23
6.845 03
7.874 93
Devi
%
■0.280
■0.552
■0.758
■0.937
■1.055
■1.069
p^v. SWEOS
mol'dm"^
5.022 10
5.351 36
5.737 48
6.209 16
6.835 19
7.870 63
Dev2
%
-0.316
-0.606
-0.839
-1.049
-1.197
-1.123
Wtl
0.0
0.0
0.0
0.0
0.0
0.0
Wt2
0.0
0.0
0.0
0.0
0.0
0.0
Number of Points (Ref . 29) 6
AADl-%
AADl
AAD2-%
AAD2
0.775,
0.051,
0.855,
0.055,
BIASl-%
BIASl
BIAS2-%
BIAS2
-0.775,
-0.051,
-0.855,
-0.055,
-3
RMSl-% 0.285
RMSl 0.024 mol.dm
RMS2-% 0.311
RMS2 0.026 mol.dm' 3
Data from Jansoone et al. [32]
T p^v . exp p^v . eq(3)
K mol'dm"^ mol»dm'^
189.785
190.066
190.299
190.500
190.524
7.551 00
7.935 00
8.392 00
9.161 00
9.686 00
7.544 14
7.928 11
8.382 63
9.139 30
9.340 56
Devi
%
■0.091
■0.087
■0.112
■0.237
■3.566
p^v , SWEOS
mol'dra"^
7.535 40
7.924 93
8.395 17
9.214 75
9.439 01
Dev2
%
-0.207
-0.127
0.038
0.587
-2.550
Wtl
0.0
0.0
0.0
0.0
0.0
Wt2
0.0
0.0
0.0
0.0
0.0
Number of Points (Ref. 32) 5
AADl-%
AADl
AAD2-%
AAD2
0.819,
0.078,
0.702,
0.066,
BIASl -%
BIASl
BIAS2-%
BIAS2
-0.819,
-0.078,
-0.452,
-0.043,
r3
RMSl-% 1.375
RMSl 0.134 mol.dm
RMS2-% 1.085
RMS2 0.105 mol.dm' 3
55
Data from Verbeke [26]
T p^v. exp p^v, eq(3)
K mol'dm""' mol»dm"^
190.070
190.170
190.270
190.370
190.470
8.000 00
8.170 00
8.360 00
8.620 00
9.000 00
7.934 53
8.107 78
8.313 99
8.575 86
8.961 86
Devi
%
■0.818
-0.762
-0.550
-0.512
■0.424
p^v , SWEOS
mol'dm"^
7.931 48
8.109 33
8.323 30
8.599 53
9.018 02
Dev2
%
-0.856
-0.743
-0.439
-0.237
0.200
Wtl
0.0
0.0
0.0
0.0
0.0
Wt2
0.0
0.0
0.0
0.0
0.0
Number of Points (Ref . 26) 5
AADl-%
0.613,
BIASl-%
-0.613,
RMSl-% 0.151
AADl
0.051,
BIASl
-0.051.
RMSl 0.011
mol'dm"'
AAD2-%
0.495,
BIAS2-%
-0.415,
RMS2-% 0.378
AAD2
0.041,
BIAS2
-0.034,
RMS2 0.031
mol'dm"^
Data from eq (3)
T
P^v. exp
Pcv> eq(3)
Devi p^v . SWEOS
Dev2 Wtl Wt2
K
mol'dra"^
mol'dm""'
% mol'dm"^
%
91.0
1.622 81E-02
1.622 81E-02
1.624 68E-02
0.115
46595.385
96.0
2.825 47E-02
2.825 47E-02
2.826 86E-02
0.049
25531.209
101.0
4.631 83E-02
4.631 83E-02
4.632 59E-02
0.017
14913.515
106.0
7.218 88E-02
7.218 88E-02
7.219 25E-02
0.005
9199.929
111.0
1.078 22E-01
1.078 22E-01
1.078 33E-01
0.010
5947.908
116.0
1.553 63E-01
1.553 63E-01
1.554 04E-01
0.027
4004.906
121.0
2.171 65E-01
2.171 65E-01
2.172 70E-01
0.048
2793.881
126.0
2.958 44E-01
2.958 44E-01
2.960 50E-01
0.070
2010.580
131.0
3.943 53E-01
3.943 53E-01
3.946 86E-01
0.084
1487.113
136.0
5.160 96E-01
5.160 96E-01
5.165 55E-01
0.089
1127.035
141.0
6.650 93E-01
6.650 93E-01
6.656 38E-01
0.082
1500.000
146.0
8.462 19E-01
8.462 19E-01
8.467 63E-01
0.064
1500.000
151.0
1.065 57E+00
1.065 57E+00
1.066 OOE400
0.040
1500.000
156.0
1.331 08E+00
1.331 08E+00
1.331 27E-K)0
0.014
1500.000
161.0
1.653 52E+00
1.653 52E+00
1.653 39E-K)0
-0.008
1500.000
56
Data from eq. (3) (continued)
T p^v. exp p^v. eq(3) Devi p^^ , SWEOS
K
mol'dm"
mol'dm
,-3
%
mol'dm'
.-3
Dev2
Wtl
Wt2
166.0
2.048 40E+00
2.048 40E+00
2.048 OOE400
-0.020
-
3750.000
171.0
2.539 84E+00
2.539 84E+00
2.539 39E-K)0
-0.018
-
3750.000
176.0
3.169 62E+00
3.169 62E+00
3.169 42E-K)0
-0.006
.
3750.000
181.0
4.023 30E+00
4.023 30E+00
4.023 21E+00
-0.002
-
3750.000
186.0
5.343 67E+O0
5.343 67E+00
5.340 76E4O0
-0.054
-
3750.000
Number of Points (eq (3)) 20
AADl-% - ,
AADl - ,
AAD2-% 0.041,
AAD2 0.354,
BIASl-%
BIASl
BIAS2-%
BIAS2
0.030,
■0.064,
RMSl-% -
RMSl
RMS2-% 0.043
RMS2 0.707 mol«dra'3
Total Points 86 for Ancillary Equation
AADl-% 0.260, BIASl-% -0.222,
AADl 0.015, BIASl -0.013,
RMSl-% 0.454
RMSl 0.041 mol.dm'3
Total Points 106 for Equation of State
AAD2-% 0.250, BIAS2-% -0.123,
AAD2 0.012, BIAS2 -0.011,
RMS2-% 0.418
RMS2 0.037 mol.dm'3
57
TABLE A4
COMPARISONS OF EXPERIMENTAL AND CALCULATED PVT DATA
Notes for Table A4. The first column marked Dev in the tables refers to
deviations between the experimental pressure and the pressure calculated
using the SWEOS and the experimental temperature and density. The
statistics for these deviations are given under the Pressure heading.
The second Dev column refers to deviations between the experimental
density and the density calculated using the SWEOS and the experimental
temperature and pressure. The statistics for these deviations are given
under the Density heading. The weights in the tables are for the least
squares determination of the coefficients in the equation of state. Some
of the tabulated densities in Ref . [37] (and included in this table) were
near the two -phase boundary and are based on alternative correlations
rather than being direct experimental determinations. This also applies
to the data Ref. [44] at temperatures above 250 K.
Data from Achtermann et al. [33]
T
P.exp
P.cal
Dev
/?,exp
p.cal
Dev
Wt
K
MPa
MPa
%
mol • dm" ^
mol • dm" ^
%
323
15
1.070
1.069
-0.011
0.4035
0.4036
0.011
0.2263
323
15
1.550
1.550
-0.017
0.5882
0.5883
0.017
0.1566
323
15
2.021
2.021
-0.019
0.7716
0.7717
0.019
0.1204
323
15
2.467
2.467
-0.026
0.9471
0.9474
0.027
0.0989
323
15
3.047
3.046
-0.033
1.1779
1.1783
0.034
0.0803
323
15
3.559
3.558
-0.038
1.3844
1.3849
0.040
0.0690
323
15
4.026
4.024
-0.047
1.5746
1.5753
0.049
0.0611
323
15
4.512
4.509
-0.049
1.7746
1.7755
0.052
0.0546
323
15
5.026
5.023
-0.058
1.9886
1.9898
0.062
0.0492
323
15
5.528
5.524
-0.061
2.1993
2.2007
0.065
0.0448
323
15
6.000
5.996
-0.064
2.3996
2.4013
0.068
0.0413
323
15
6.546
6.541
-0.066
2.6329
2.6348
0.071
0.0379
323
15
7.037
7.032
-0.068
2.8448
2.8469
0.073
0.0353
323
15
8.049
8.043
-0.069
3.2863
3.2888
0.075
0.0309
323
15
9.027
9.021
-0.066
3.7180
3.7206
0.072
0.0276
323
15
10.067
10.062
-0.056
4.1816
4.1841
0.060
0.0247
323
15
11.072
11.068
-0.042
4.6321
4.6341
0.045
0.0224
323
15
12.070
12.067
-0.027
5.0801
5.0816
0.029
0.0205
323
15
13.054
13.052
-0.011
5.5210
5.5216
0.011
0.0189
323
15
14.079
14.080
0.006
5.9777
5.9774
-0.006
0.0174
58
lata
from
Achtermann et al.
[33] (continued)
T
P,exp
P.cal
Dev
p,exp
P.cal
Dev
Wt
K
MPa
MPa
%
mol • dm" ^
mol • dm" ^
%
323
15
15.092
15.095
0.022
6.4243
6.4229
-0.022
0161
323
15
16.068
16.073
0.029
6.8484
6.8464
-0.029
0150
323
15
17.081
17.088
0.042
7.2813
7.2783
-0.042
0140
323
15
18.084
18.093
0.050
7.7011
7.6973
-0.049
0131
323
15
18.988
18.999
0.055
8.0706
8.0664
-0.052
0123
323
15
20.142
20.154
0.060
8.5292
8.5245
-0.055
0114
323
15
21.125
21.138
0.063
8.9078
8.9028
-0.056
0108
323
15
22.103
22.116
0.061
9.2728
9.2679
-0.053
0101
323
15
23.109
23.123
0.058
9.6360
9.6312
-0.050
0095
323
15
24.101
24.113
0.054
9.9816
9.9771
-0.045
0090
323
15
25.107
25.118
0.046
10.3196
10.3158
-0.037
0085
323
15
26.126
26.136
0.040
10.6497
10.6464
-0.031
0080
323.
15
27.139
27.148
0.033
10.9656
10.9628
-0.025
0076
323.
15
28.112
28.120
0.028
11.2581
11.2557
-0.021
0072
323.
15
28.668
28.675
0.024
11.4203
11.4183
-0.017
0070
Number of Points (Ref. 33) 35
PRESSURE:
AAD-%
0.043
BIAS-%
-0.004
RMS-%
0.046
AAD
0.006
BIAS
0.003
RMS
0.007
MPa
DENSITY :
AAD-%
0.042
BIAS-%
0.008
RMS-%
0.046
AAD
0.002
BIAS
-0.001
RMS
0.003
mol • dm" "^
Data
from
Achtermann et al.
[34]
T
P.exp
P.cal
Dev
p.exp
p.cal
Dev
Wt
K
MPa
MPa
%
mol • dm" ^
mol • dm" "^
%
273
15
0.102
0.102
-0.072
0.0449
0.0449
0.072
0000
273
15
0.625
0.625
-0.010
0.2794
0.2794
0.010
0000
273
15
1.086
1.086
0.004
0.4909
0.4909
-0.004
0000
273
15
1.590
1.589
-0.010
0.7273
0.7274
0.010
0000
273
15
2.102
2.102
-0.014
0.9739
0.9740
0.015
0000
59
Data from Achtermann et al. [34] (continued)
T
P.exp
P.cal
Dev
p.exp
p.cal
Dev
Wt
K
MPa
MPa
%
mol • dm" ^
mol • dm" ^
%
273
15
2.568
2.567
-0.018
1.2038
1.2040
0.019
0.0000
273
15
3.061
3.060
-0.029
1.4527
1.4532
0.032
0.0000
273
15
3.542
3.541
-0.024
1.7018
1.7022
0.026
0.0000
273
15
4.046
4.045
-0.026
1.9691
1.9697
0.029
0.0000
273
15
4.466
4.465
-0.033
2.1968
2.1976
0.036
0.0000
273
15
5.026
5.024
-0.044
2.5074
2.5086
0.049
0.0000
273
15
5.492
5.490
-0.047
2.7729
2.7744
0.053
0.0000
273
15
6.013
6.008
-0.077
3.0748
3.0775
0.088
0.0000
273
15
6.544
6.539
-0.086
3.3911
3.3945
0.100
0.0000
273
15
6.967
6.961
-0.088
3.6477
3.6515
0.103
0.0000
273
15
7.191
7.184
-0.096
3.7853
3.7896
0.113
0.0000
273
15
8.586
8.585
-0.007
4.6745
4.6749
0.008
0.0000
273
15
7.297
7.294
-0.050
3.8534
3.8556
0.058
0.0000
273
15
6.185
6.180
-0.077
3.1764
3.1792
0.089
0.0000
273
15
5.224
5.220
-0.088
2.6184
2.6210
0.100
0.0000
273
15
4.398
4.394
-0.089
2.1584
2.1605
0.100
0.0000
273
15
3.692
3.688
-0.087
1.7792
1.7809
0.096
0.0000
273
15
3.090
3.087
-0.079
1.4667
1.4680
0.085
0.0000
273
15
2.580
2.578
-0.069
1.2090
1.2099
0.074
0.0000
273
15
2.149
2.148
-0.066
0.9966
0.9973
0.070
0.0000
273
15
1.788
1.787
-0.060
0.8215
0.8220
0.062
0.0000
273
15
1.485
1.484
-0.050
0.6772
0.6776
0.052
0.0000
273
15
1.231
1.231
-0.049
0.5582
0.5585
0.050
0.0000
273
15
1.020
1.020
-0.053
0.4601
0.4603
0.054
0.0000
273
15
0.844
0.844
-0.035
0.3793
0.3794
0.035
0.0000
273
15
0.699
0.698
-0.053
0.3126
0.3128
0.054
0.0000
273
15
0.577
0.577
-0.045
0.2577
0.2578
0.045
0.0000
273
15
0.477
0.477
-0.038
0.2124
0.2125
0.039
0.0000
273
15
0.394
0.394
-0.036
0.1751
0.1752
0.037
0.0000
273
15
0.325
0.325
-0.048
0.1443
0.1444
0.048
0.0000
273
15
0.269
0.269
0.027
0.1190
0.1190
-0.027
0.0000
273
15
0.221
0.222
0.052
0.0981
0.0980
-0.052
0.0000
273
15
0.183
0.183
-0.027
0.0808
0.0808
0.027
0.0000
283
15
0.236
0.236
-0.027
0.1008
0.1008
0.027
0.0000
283
15
0.331
0.331
0.006
0.1418
0.1418
-0.006
0.0000
60
Data from Achtermann et al. [34] (continued)
T
P.exp
P.cal
Dev
P.exp
p.cal
Dev
Wt
K
MPa
MPa
%
mol • dm" ^
rool • dm' ^
%
283
.15
0.426
0.426
-0.010
0.1826
0.1826
0.010
0.0000
283
.15
0.526
0.526
-0.029
0.2258
0.2259
0.030
0.0000
283
15
0.623
0.623
-0.035
0.2682
0.2683
0.035
0.0000
283
15
0.718
0.718
-0.023
0.3096
0.3097
0.023
0.0000
283
15
0.913
0.913
-0.032
0.3954
0.3955
0.033
0.0000
283
15
1.109
1.109
-0.037
0.4821
0.4823
0.038
0.0000
283
15
1.280
1.279
-0.052
0.5582
0.5585
0.053
0.0000
283
15
1.611
1.610
-0.047
0.7078
0.7081
0.049
0.0000
283
15
1.638
1.637
-0.054
0.7198
0.7202
0.056
0.0000
283
15
2.100
2.098
-0.060
0.9320
0.9326
0.063
0.0000
283
15
2.156
2.155
-0.056
0.9582
0.9588
0.058
0.0000
283
15
2.591
2.590
-0.062
1.1626
1.1634
0.066
0.0000
283
15
3.070
3.067
-0.074
1.3914
1.3925
0.079
0.0000
283
15
3.154
3.152
-0.063
1.4324
1.4334
0.067
0.0000
283
15
3.555
3.552
-0.075
1.6284
1.6297
0.081
0.0000
283
15
4.043
4.040
-0.074
1.8717
1.8732
0.081
0.0000
283
15
4.105
4.103
-0.065
1.9034
1.9048
0.071
0.0000
283
15
4.541
4.538
-0.069
2.1255
2.1271
0.075
0.0000
283
15
5.014
5.010
-0.069
2.3707
2.3725
0.076
0.0000
283
15
5.515
5.512
-0.064
2.6359
2.6378
0.072
0.0000
283
15
5.884
5.880
-0.066
2.8343
2.8364
0.074
0.0000
283
15
5.999
5.995
-0.069
2.8965
2.8987
0.077
0.0000
283
15
6.509
6.504
-0.068
3.1761
3.1786
0.077
0.0000
283
15
6.722
6.718
-0.059
3.2951
3.2973
0.067
0.0000
283
15
6.991
6.988
-0.052
3.4461
3.4482
0.060
0.0000
283
15
7.477
7.473
-0.046
3.7216
3.7236
0.053
0.0000
283
15
7.531
7.528
-0.036
3.7529
3.7544
0.041
0.0000
283
15
8.466
8.467
0.009
4.2973
4.2969
-0.010
0.0000
283
15
7.160
7.158
-0.021
3.5425
3.5434
0.024
0.0000
283
15
6.041
6.038
-0.037
2.9201
2.9213
0.042
0.0000
283
15
5.082
5.080
-0.038
2.4072
2.4082
0.042
0.0000
283
15
4.264
4.262
-0.035
1.9843
1.9851
0.039
0.0000
283
15
3.568
3.567
-0.030
1.6357
1.6362
0.032
0.0000
283
15
2.979
2.978
-0.023
1.3483
1.3486
0.025
0.0000
283
15
2.482
2.482
-0.021
1.1114
1.1116
0.022
0.0000
61
Data from Achtermann et al. [34] (continued)
T
P.exp
P.cal
Dev
p.exp
p.cal
Dev
Wt
K
MPa
MPa
%
mol • dm' ^
mol • dm" ^
%
283
15
2.064
2.064
-0.005
0.9162
0.9162
0.005
0.0000
283
15
1.714
1.714
-0.005
0.7552
0.7552
0.005
0.0000
283
15
1.422
1.422
-0.004
0.6225
0.6225
0.004
0.0000
283
15
1.178
1.178
0.012
0.5132
0.5131
-0.012
0.0000
283
15
0.976
0.975
-0.001
0.4230
0.4230
0.001
0.0000
283
15
0.807
0.807
0.023
0.3487
0.3486
-0.024
0.0000
283
15
0.667
0.667
-0.013
0.2874
0.2874
0.013
0.0000
283
15
0.551
0.551
-0.007
0.2369
0.2369
0.007
0.0000
283
15
0.455
0.455
0.012
0.1953
0.1953
-0.013
0.0000
283
15
0.376
0.376
0.025
0.1610
0.1610
-0.025
0.0000
283
15
0.310
0.310
-0.019
0.1327
0.1327
0.019
0.0000
283
15
0.256
0.256
0.018
0.1094
0.1094
-0.018
0.0000
283
15
0.211
0.211
0.031
0.0902
0.0902
-0.031
0.0000
283
15
0.174
0.174
-0.050
0.0743
0.0743
0.050
0.0000
283
15
0.144
0.144
0.084
0.0613
0.0612
-0.085
0.0000
293
15
0.098
0.098
0.035
0.0405
0.0405
-0.035
0.0000
293
15
0.243
0.243
-0.029
0.1002
0.1002
0.029
0.0000
293
15
0.353
0.353
-0.013
0.1458
0.1458
0.013
0.0000
293
15
0.433
0.433
0.006
0.1793
0.1793
-0.006
0.0000
293
15
0.524
0.524
-0.012
0.2171
0.2171
0.012
0.0000
293
15
0.637
0.637
-0.020
0.2644
0.2645
0.020
0.0000
293
15
0.734
0.734
-0.016
0.3051
0.3051
0.016
0.0000
293
15
0.931
0.931
-0.019
0.3886
0.3887
0.020
0.0000
293
15
1.137
1.137
-0.024
0.4763
0.4764
0.024
0.0000
293
15
1.312
1.312
-0.032
0.5515
0.5517
0.033
0.0000
293
15
1.621
1.621
-0.036
0.6853
0.6856
0.037
0.0000
293
15
1.908
1.908
-0.038
0.8110
0.8113
0.040
0.0000
293
15
2.313
2.312
-0.035
0.9903
0.9907
0.037
0.0000
293
15
2.642
2.641
-0.042
1.1384
1.1389
0.044
0.0000
293
15
3.080
3.079
-0.037
1.3380
1.3385
0.039
0.0000
293
15
3.565
3.564
-0.038
1.5629
1.5635
0.041
0.0000
293
15
4.064
4.063
-0.038
1.7983
1.7990
0.040
0.0000
293
15
4.265
4.263
-0.049
1.8940
1.8950
0.053
0.0000
293
15
4.540
4.538
-0.048
2.0267
2.0278
0.052
0.0000
293
15
5.024
5.022
-0.050
2.2625
2.2637
0.055
0.0000
62
Data from Achtermann et al
K
P.exp
MPa
P.cal
MPa
[34] (continued)
Dev P.exp p.cal
% mol • dm" ^ mol • dm" ^
Dev
Wt
293
.15
5
.514
5.511
-0.042
2
5052
2.5063
0.046
0.0000
293
15
6
005
6.002
-0.049
2
7521
2.7536
0.054
0.0000
293
15
6
493
6.490
-0.039
3
0016
3.0029
0.043
0.0000
293
15
6
979
6.977
-0.036
3
2536
3.2549
0.040
0.0000
293
15
7
466
7.463
-0.036
3
5087
3.5101
0.041
0.0000
293
15
7
705
7.702
-0.037
3
6353
3.6368
0.042
0.0000
293
15
8
409
8.406
-0.036
4
0120
4.0136
0.040
0.0000
293
15
7
083
7.079
-0.055
3
3073
3.3094
0.062
0.0000
293
15
5
954
5.951
-0.061
2
7263
2.7281
0.068
0.0000
293
15
4
994
4.991
-0.061
2
2474
2.2489
0.066
0.0000
293
15
4
179
4.176
-0.054
1
8526
1.8537
0.058
0.0000
293
15
3
489
3.487
-0.046
1
5271
1.5278
0.049
0.0000
293
15
2
907
2.906
-0.044
1
2588
1.2594
0.046
0.0000
293
15
2
419
2.418
-0.059
1
0377
1.0383
0.062
0.0000
293
15
2
009
2.008
-0.051
8554
0.8559
0.053
0.0000
293
15
1
667
1.666
-0.047
7051
0.7054
0.048
0.0000
293
15
1
381
1.381
-0.040
5812
0.5814
0.041
0.0000
293
15
1
144
1.143
-0.031
4791
0.4793
0.032
0.0000
293
15
946
0.946
-0.022
3949
0.3950
0.023
0.0000
293
15
782
0.782
-0.023
3255
0.3256
0.023
0.0000
293
15
646
0.646
-0.035
2683
0.2684
0.035
0.0000
293
15
534
0.534
-0.011
2212
0.2212
0.012
0.0000
293
15
441
0.441
-0.027
1823
0.1823
0.027
0.0000
293
15
364
0.364
-0.009
1503
0.1503
0.009
0.0000
293
15
300
0.300
-0.034
1239
0.1239
0.034
0.0000
293
15
248
0.248
-0.016
1021
0.1021
0.017
0.0000
293
15
204
0.205
0.026
0842
0.0842
-0.026
0.0000
293
15
169
0.169
0.017
0694
0.0694
-0.017
0.0000
293
15
139
0.139
0.001
0572
0.0572
-0.001
0.0000
Number of Points (Ref. 34) 139
PRESSURE: AAD-% 0.040 BIAS-% -0.034 RMS-%
AAD 0.001 BIAS -0.001 RMS
DENSITY : AAD-% 0.043 BIAS-% 0.037 RMS-%
AAD . 001 BIAS . 001 RMS
0.030
0.002 MPa
0.033
0.001 mol -dm" 3
63
Data from Cheng [35]
T P.exp P.cal
K MPa MPa
Dev p , exp p , cal
% mol • dm" ^ mol • dm" ^
Dev
Wt
111
23
28
.700
33
440
16
514
27
9096
27
7278
-0
651
0136
111
23
40
200
44
534
10
780
28
3046
28
1549
-0
529
2020
111
23
51
900
57
667
11
113
28
7274
28
5470
-0
628
.1794
111
23
72
.600
79
897
10
052
29
3600
29
1621
-0
674
1516
121
19
21
.800
22
251
2
068
26
7237
26
7019
-0
081
.0183
121
.19
33
.500
34
321
2
452
27
.2628
27
2285
-0
126
0155
121
19
74
.600
75
071
631
28
.6780
28
6640
-0
049
.1730
121
.19
94
.200
94
341
150
29
.2141
29
2104
-0
013
1506
121
.19
114
.400
113
820
-0
507
29
7000
29
7138
046
1336
131
79
46
500
48
655
4
634
27
1518
27
0645
-0
322
2489
131
79
60
700
63
311
4
301
27
7008
27
6082
-0
335
2133
131
79
74
800
77
646
3
805
28
1770
28
0865
-0
321
1877
131
79
89
200
91
881
3
006
28
6041
28
5267
-0
271
.1680
131
79
104
800
107
675
2
743
29
0360
28
9603
-0
261
1507
143
82
48
300
49
093
1
642
26
4131
26
3774
-0
135
2861
143
82
70
500
70
968
664
27
2926
27
2756
-0
062
2236
143
82
96
800
96
598
-0
208
28
1373
28
1434
022
1792
156
96
49
500
48
046
-2
937
25
5297
25
6039
291
3400
156
96
61
700
61
235
-0
754
26
1575
26
1780
078
2839
156
96
76
900
75
511
-1
806
26
7451
26
7982
199
2417
156
96
95
100
93
085
-2
119
27
3748
27
4417
244
2049
167
61
41
500
41
589
214
24
4618
24
4562
-0
023
4340
167
61
56
000
55
754
-0
439
25
2653
25
2779
050
3423
167
61
75
100
74
609
-0
654
26
1370
26
1575
078
2687
167
61
93
600
92
773
-0
883
26
8384
26
8679
110
2234
179
29
48
800
49
037
486
24
1604
24
1455
-0
062
4358
179
29
75
800
75
419
-0
503
25
5493
25
5664
067
2951
179
29
100
300
99
289
-1
008
26
5111
26
5477
138
2296
192
87
33
400
34
083
2
045
22
0605
21
9933
-0
304
0015
192
87
52
900
53
319
792
23
5849
23
5573
-0
117
0009
192
87
71
400
71
610
294
24
6427
24
6319
-0
044
0007
192
87
97
900
97
370
-0
542
25
7998
25
8208
081
0.
0005
212
00
40
100
39
993
-0
268
21
2404
21
2514
052
0.
4820
212
00
58
600
58
230
-0
632
22
7739
22
7998
0.
114
0.
3094
212
00
74
600
73
651
-1
273
23
7417
23
7949
0.
224
0.
2378
64
Data from Cheng [35] (continued)
T P.exp P,cal Dev ^,exp p.cal
K MPa MPa % mol-dm'^ mol-dm'^
Dev
Wt
212
.00
95
.000
93
.595
-1
.479
24
.7464
24
8095
255
1832
225
.07
42
.800
42
.659
-0
.330
20
.6101
20
6252
073
5187
225
.07
62
.500
61
.376
-1
.799
22
.2519
22
3331
365
3269
225
.07
82
.300
80
.755
-1
877
23
.4797
23
5647
362
2362
225
.07
108
.700
106
.345
-2
.167
24
7219
24
8216
403
1728
237
57
30
.200
30
.295
.314
17
9437
17
9260
-0
098
0034
237
.57
60
.600
60
.209
-0
645
21
4638
21
4951
146
3722
237
57
94
600
93
635
-1
021
23
5793
23
6283
208
2156
249
43
41
100
41
437
820
18
8076
18
7619
-0
243
7017
249
43
58
100
57
853
-0
425
20
6016
20
6238
108
4320
249
43
74
400
73
885
-0
692
21
8579
21
8932
161
3118
249
43
94
200
93
131
-1
135
23
0256
23
0828
249
2327
261
55
40
700
40
850
369
17
9147
17
8923
-0
125
8045
261
55
53
300
53
246
-0
102
19
4666
19
4724
030
5348
261
55
68
000
67
150
-1
250
20
7512
20
8194
329
3842
261
55
82
600
81
065
-1
858
21
7628
21
8625
458
2981
261
55
100
100
97
875
-2
222
22
7583
22
8763
518
2337
278
71
34
800
35
181
1
093
15
7754
15
6977
-0
492
0040
278
71
50
000
50
473
945
18
1752
18
1163
-0
324
4391
278
71
62
400
62
920
834
19
5160
19
4667
-0
253
3145
278
71
77
400
77
392
-0
Oil
20
7211
20
7217
003
2339
278
71
99
900
99
329
-0
571
22
1288
22
1607
144
1668
293
41
46
500
46
390
-0
236
16
7983
16
8144
096
5525
293
41
64
000
63
485
-0
805
18
8466
18
8972
269
3379
293
41
79
100
78
868
-0
293
20
1776
20
1952
087
2462
293
41
94
700
93
829
-0
920
21
2089
21
2631
256
1930
309
29
36
900
36
877
-0
061
14
2227
14
2275
033
8834
309
29
51
600
51
431
-0
327
16
6694
16
6923
137
5110
309
29
66
700
67
047
521
18
4570
18
4231
-0.
184
3384
309
29
84
700
84
449
-0
297
19
9283
19
9468
093
2406
309
29
105
800
105
101
-0
661
21
2721
21
3122
189
1769
Number of Points (Ref . 35)
66
PRESSURE:
AAD-%
1.803
BIAS-%
0.721
RMS-%
3.315
AAD
1.080
BIAS
0.205
RMS
1.739
MPa
DENSITY :
AAD-%
0.204
BIAS-%
0.001
RMS-%
0.261
AAD
0.049
BIAS
-0.002
RMS
0.065
mol'dm"^
65
Data from Douslin et al. [36]
T P.exp P.cal Dev p.exp p.cal
K MPa MPa % mol-dm'^ mol-dra'^
Dev
Wt
273
.15
1
.638
1.637
-0.029
0.7500
0.7502
0.030
0.0150
298
.14
1
.802
1.801
-0.028
0.7500
0.7502
0.029
0.0135
303
.14
1
.835
1.834
-0.021
0.7500
0.7502
0.021
0.0133
323
.14
1
.966
1.965
-0.008
0.7500
0.7501
0.008
0.0124
348
.14
2
.129
2.129
-0.005
0.7500
0.7500
0.006
0.0114
373
.15
2
.293
2.293
-0.002
0.7500
0.7500
0.002
0.0106
398
.16
2
456
2.456
-0.003
0.7500
0.7500
0.003
0.0098
273
.15
2
156
2.155
-0.040
1.0000
1.0004
0.042
0.0114
298
.14
2
379
2.378
-0.033
1.0000
1.0003
0.034
0.0103
303
14
2
423
2.422
-0.036
1.0000
1.0004
0.037
0.0101
323
14
2
601
2.600
-0.023
1.0000
1.0002
0.024
0.0094
348
14
2
822
2.822
-0.018
1.0000
1.0002
0.018
0.0086
373
15
3
043
3.043
-0.012
1.0000
1.0001
0.012
0.0080
398
16
3
264
3.263
-0.007
1.0000
1.0001
0.007
0.0074
273
15
3
154
3.152
-0.052
1.5000
1.5008
0.056
0.0079
298
14
3
499
3.498
-0.046
1.5000
1.5007
0.048
0.0071
303
14
3
569
3.567
-0.053
1.5000
1.5008
0.056
0.0069
323
14
3
843
3.842
-0.029
1.5000
1.5005
0.031
0.0064
348
14
4
185
4.184
-0.024
1 . 5000
1.5004
0.025
0.0058
373
15
4
527
4.526
-0.020
1.5000
1.5003
0.020
0.0054
398
16
4
868
4.867
-0.021
1.5000
1.5003
0.021
0.0050
273
15
4
105
4.102
-0.068
2.0000
2.0015
0.076
0.0061
298
14
4
580
4.578
-0.057
2.0000
2.0012
0.062
0.0054
303
14
4
675
4.672
-0.059
2.0000
2.0013
0.064
0.0053
323
14
5
053
5.050
-0.052
2.0000
2.0011
0.055
0.0049
348
14
5
522
5.521
-0.025
2.0000
2.0005
0.026
0.0044
373
15
5
992
5.990
-0.041
2.0000
2.0008
0.042
0.0041
398
16
6
458
6.457
-0.021
2.0000
2.0004
0.022
0.0038
273
15
5
014
5.010
-0.069
2.5000
2.5019
0.077
0.0051
298
14
5
626
5.623
-0.061
2.5000
2.5017
0.067
0.0045
303
14
5
748
5.745
-0.064
2.5000
2.5017
0.069
0.0044
323
14
6
234
6.231
-0.050
2.5000
2.5013
0.054
0.0040
348
14
6
839
6.836
-0.040
2.5000
2.5010
0.041
0.0036
373
15
7
442
7.439
-0.047
2.5000
2.5012
0.049
0.0033
398
16
8
041
8.039
-0.023
2.5000
2.5006
0.023
0.0030
66
Data from Douslin et al. [36] (continued)
T
P.exp
P.cal
Dev
p.exp
P.cal
Dev
Wt
K
MPa
MPa
%
mol • dm" ^
mol-dm"^
%
273
.15
5.884
5.881
-0.055
3.0000
3.0019
0.063
0.0044
298
14
6.641
6.638
-0.057
3.0000
3.0019
0.063
0.0038
303
14
6.794
6.788
-0.083
3.0000
3.0027
0.091
0.0037
323
14
7.393
7.389
-0.051
3.0000
3.0016
0.055
0.0034
348
14
8.139
8.136
-0.043
3.0000
3.0014
0.045
0.0030
373
15
8.884
8.879
-0.052
3.0000
3.0016
0.054
0.0027
398
16
9.623
9.619
-0.039
3.0000
3.0012
0.040
0.0025
273
15
6.722
6.719
-0.050
3.5000
3.5020
0.058
0.0038
298
14
7.631
7.627
-0.046
3.5000
3.5018
0.051
0.0033
303
14
7.815
7.808
-0.085
3.5000
3.5033
0.094
0.0032
323
14
8.532
8.528
-0.048
3.5000
3.5018
0.052
0.0029
348
14
9.428
9.424
-0.043
3.5000
3.5016
0.046
0.0026
373
15
10.320
10.315
-0.054
3.5000
3.5019
0.055
0.0024
398
16
11.207
11.202
-0.048
3.5000
3.5017
0.049
0.0022
273
15
7.531
7.529
-0.027
4.0000
4.0013
0.031
0.0034
298
14
8.599
8.596
-0.036
4.0000
4.0016
0.041
0.0029
303
14
8.814
8.809
-0.065
4.0000
4.0029
0.072
0.0029
323
14
9.658
9.655
-0.041
4.0000
4.0018
0.044
0.0026
348
14
10.709
10.706
-0.031
4.0000
4.0013
0.032
0.0023
373
15
11.758
11.752
-0.048
4.0000
4.0020
0.049
0.0021
398
16
12.799
12.793
-0.048
4.0000
4.0019
0.048
0.0019
273
15
8.316
8.315
-0.005
4.5000
4.5003
0.006
0.0031
298
14
9.551
9.549
-0.020
4.5000
4.5010
0.022
0.0027
303
14
9.800
9.795
-0.056
4.5000
4.5028
0.062
0.0026
323
14
10.778
10.773
-0.049
4 . 5000
4.5024
0.053
0.0023
348
14
11.992
11.988
-0.035
4.5000
4.5016
0.037
0.0020
373
15
13.201
13.196
-0.039
4.5000
4.5018
0.039
0.0018
398
16
14.408
14.399
-0.066
4.5000
4.5029
0.065
0.0017
273
15
9.080
9.083
0.030
5.0000
4.9982
-0.036
0.0029
298
14
10.491
10.491
0.003
5.0000
4.9998
-0.003
0.0024
303
14
10.774
10.772
-0.027
5.0000
5.0015
0.029
0.0023
323
14
11.891
11.888
-0.030
5.0000
5.0016
0.032
0.0021
348
14
13.278
13.274
-0.029
5.0000
5.0015
0.030
0.0018
373
15
14.658
14.653
-0.036
5.0000
5.0018
0.036
0.0016
398
16
16.035
16.025
-0.060
5.0000
5.0029
0.058
0.0015
67
Data from Douslin et al. [36] (continued)
T
P
,exp
P
, cal
Dev
p.exp
p.cal
Dev
Wt
K
MPa
MPa
%
mol • dm" ^
mol • dm" ^
%
273
.15
9
.832
9
.837
0.051
5.5000
5.4967
-0.061
0.0027
298
.14
11
.426
11
.428
0.013
5.5000
5.4992
-0.014
0.0022
303
14
11
.745
11
.744
-0.007
5.5000
5.5004
0.007
0.0021
323
14
13
.003
13
.005
0.014
5.5000
5.4992
-0.015
0.0019
348
.14
14
.575
14
.571
-0.024
5 . 5000
5.5014
0.025
0.0017
373
15
16
.132
16
.129
-0.021
5.5000
5.5012
0.021
0.0015
398
16
17
689
17
678
-0.059
5.5000
5.5031
0.057
0.0013
273
15
10
568
10
580
0.118
6.0000
5.9916
-0.141
0.0025
298
14
12
358
12
363
0.034
6.0000
5.9978
-0.037
0.0020
303
14
12
716
12
717
0.010
6.0000
5.9993
-0.011
0.0020
323
14
14
126
14
130
0.025
6.0000
5.9984
-0.026
0.0017
348
14
15
890
15
885
-0.032
6.0000
6.0019
0.032
0.0015
373
15
17
631
17
629
-0.009
6.0000
6.0005
0.009
0.0013
398
16
19
370
19
365
-0.026
6.0000
6.0015
0.025
0.0012
273
15
11
306
11
320
0.124
6 . 5000
6.4905
-0.146
0.0023
298
14
13
294
13
302
0.058
6.5000
6.4959
-0.063
0.0019
303
14
13
692
13
696
0.031
6.5000
6.4978
-0.033
0.0018
323
14
15
269
15
268
-0.010
6.5000
6.5007
0.010
0.0016
348
14
17
220
17
220
0.004
6.5000
6.4997
-0.004
0.0014
373
15
19
159
19
162
0.015
6.5000
6.4990
-0.015
0.0012
398
16
21
101
21
093
-0.042
6.5000
6.5025
0.039
0.0011
273
15
12
049
12
059
0.079
7.0000
6.9936
-0.092
0.0021
298
14
14
241
14
251
0.067
7.0000
6.9950
-0.071
0.0017
303
14
14
681
14
687
0.041
7.0000
6.9970
-0.043
0.0017
323
14
16
421
16
425
0.025
7.0000
6.9982
-0.026
0.0015
348
14
18
587
18
585
-0.008
7.0000
7.0006
0.008
0.0013
373
15
20
735
20
732
-0.011
7.0000
7.0007
0.010
0.0011
398
16
22
871
22
869
-0.008
7.0000
7.0005
0.007
0.0010
273
15
12
785
12
803
0.141
7.5000
7.4880
-0.160
0.0020
298
14
15
204
15
215
0.070
7.5000
7.4945
-0.073
0.0016
303
14
15
678
15
695
0.105
7.5000
7.4919
-0.108
0.0016
323
14
17
597
17
608
0.064
7.5000
7.4953
-0.063
0.0014
348
14
19
981
19
986
0.024
7.5000
7.4983
-0.023
0.0012
373
15
22
344
22
349
0.025
7.5000
7.4983
-0.022
0.0010
398
16
24
705
24
701
-0.017
7.5000
7.5011
0.015
0.0009
68
Data from Douslin et al, [36] (continued)
T
P
,exp
P
, cal
Dev
p,exp
p,cal
Dev
Wt
K
MPa
MPa
%
mol • dm" ^
mol • dm' ^
%
273
15
13
.541
13
.558
0.129
8.0000
7.9886
-0.143
0.0019
298
14
16
.187
16
.200
0.079
8.0000
7.9936
-0.080
0.0015
303
14
16
.713
16
.726
0.076
8.0000
7.9939
-0.076
0.0014
323
14
18
.814
18
.823
0.047
8.0000
7.9964
-0.045
0.0012
348
14
21
.422
21
.430
0.036
8.0000
7.9974
-0.033
0.0011
373
15
24
008
24
021
0.055
8.0000
7.9961
-0.048
0.0009
398
16
26
602
26
599
-0.013
8.0000
8.0009
0.011
0.0008
273
15
14
309
14
330
0.147
8.5000
8.4866
-0.158
0.0017
298
14
17
198
17
214
0.091
8.5000
8.4924
-0.089
0.0014
303
14
17
774
17
788
0.082
8.5000
8.4933
-0.079
0.0013
323
14
20
067
20
078
0.054
8.5000
8.4958
-0.050
0.0011
348
14
22
919
22
925
0.025
8.5000
8.4982
-0.022
0.0010
373
15
25
743
25
755
0.049
8.5000
8.4964
-0.042
0.0009
398
16
28
576
28
571
-0.017
8.5000
8.5012
0.014
0.0008
273
15
15
109
15
124
0.099
9.0000
8.9908
-0.102
0.0016
298
14
18
247
18
262
0.084
9.0000
8.9928
-0.080
0.0013
303
14
18
873
18
888
0.077
9.0000
8.9935
-0.072
0.0012
323
14
21
376
21
381
0.023
9.0000
8.9981
-0.021
0.0011
348
14
24
477
24
480
0.016
9.0000
8.9988
-0.014
0.0009
373
15
27
543
27
562
0.069
9.0000
8.9949
-0.057
0.0008
398
16
30
621
30
628
0.022
9.0000
8.9984
-0.018
0.0007
273
15
15
931
15
949
0.113
9.5000
9.4893
-0.112
0.0015
298
14
19
342
19
354
0.062
9.5000
9.4946
-0.057
0.0012
303
14
20
012
20
033
0.109
9.5000
9.4907
-0.098
0.0011
323
14
22
737
22
740
0.016
9.5000
9.4987
-0.014
0.0010
348
14
26
102
26
106
0.013
9.5000
9.4990
-0.011
0.0008
373
15
29
448
29
452
0.014
9.5000
9.4989
-0.012
0.0007
398
16
32
786
32
780
-0.020
9.5000
9.5015
0.016
0.0006
273
15
16
798
16
810
0.075
10.0000
9.9928
-0.072
0.0014
298
14
20
483
20
498
0.078
10.0000
9.9932
-0.068
0.0011
303
14
21
210
21
234
0.112
10.0000
9.9903
-0.097
0.0010
323
14
24
153
24
166
0.051
10.0000
9.9958
-0.042
0.0009
348
14
27
805
27
811
0.024
10.0000
9.9981
-0.019
0.0008
373
15
31
425
31
436
0.034
10.0000
9.9974
-0.026
0.0007
398
16
35
049
35
040
-0.027
10.0000
10.0021
0.021
0.0059
69
Data from Douslin et al. [36] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm'^ mol-dm"^
Dev
Wt
273
.15
17
.700
17,
.719
.104
10
.5000
10
.4902
-0
.094
.0013
298
.14
21
.694
21
.704
.047
10
.5000
10
.4959
-0
.039
.0010
303
.14
22
.480
22
.499
.082
10
.5000
10
.4929
-0
.068
.0010
323
.14
25
.657
25,
.668
.042
10
.5000
10
.4965
-0
.033
.0008
348
.14
29,
.601
29,
.608
.024
10
.5000
10
.4981
-0
.018
.0007
373,
.15
33
.510
33,
.525
.045
10
.5000
10
.4965
-0
.034
.0006
398
.16
37,
.430
37,
.420
-0
.027
10
.5000
10
.5021
.020
.0054
273,
.15
18,
.678
18,
.682
.023
11,
.0000
10
.9978
-0
.020
.0012
298,
.14
22,
.969
22,
.982
.057
11,
.0000
10
.9950
-0
.045
.0009
303,
.14
23,
.829
23,
.840
.043
11
.0000
10
.9963
-0
.034
.0009
323,
.14
27,
.254
27,
.259
.017
11
.0000
10
.9986
-0
.013
.0008
348,
,14
31,
.503
31,
.509
.020
11,
,0000
10
.9984
-0
.015
.0006
373,
,15
35,
.730
35,
,734
.013
11,
,0000
10
.9990
-0
.009
0,
.0055
398,
.16
39,
.952
39,
.935
-0
.044
11,
,0000
11
.0034
0,
.031
.0049
273.
.15
19,
.705
19,
.713
.038
11,
,5000
11
.4965
-0,
.031
0,
.0011
298,
,14
24,
.345
24.
.344
-0,
.006
11,
,5000
11,
,5005
0,
,004
0,
.0008
303.
,14
25,
.251
25.
.268
0,
.067
11,
,5000
11,
,4943
-0,
,050
0,
.0008
323.
,14
28,
.954
28.
.950
-0.
,014
11,
,5000
11,
,5011
0,
,010
0,
.0007
348.
,14
33,
.510
33.
.528
0,
,053
11,
,5000
11,
,4958
-0,
,037
0,
.0006
373.
,15
38.
.087
38.
.077
-0,
.025
11,
.5000
11,
,5020
0,
,017
0,
,0051
273.
.15
20.
,821
20.
,821
0,
.000
12.
,0000
12,
,0000
0,
,000
0,
,0010
298.
,14
25.
.795
25.
.803
0,
,029
12.
.0000
11,
,9975
-0.
,021
0.
.0008
303.
.14
26.
.788
26.
,796
0,
,029
12.
.0000
11,
,9975
-0.
,021
0.
.0007
323.
,14
30.
.755
30.
,757
0,
,004
12.
.0000
11.
.9997
-0.
.003
0,
.0006
348.
.14
35.
.665
35.
.679
0,
.039
12.
,0000
11.
.9969
-0.
.026
0.
,0053
373.
.15
40.
.593
40.
,569
-0.
.059
12.
,0000
12.
.0047
0.
,039
0.
,0046
273.
,15
22.
.028
22.
,021
-0.
,030
12.
.5000
12.
.5026
0.
,021
0.
0009
298.
,14
27.
.379
27.
,373
-0.
.023
12.
,5000
12.
,5019
0.
,015
0.
0007
303.
.14
28.
.425
28.
.440
0.
,052
12.
,5000
12.
,4957
-0.
,034
0.
0007
323.
.14
32.
.697
32.
,693
-0.
,012
12.
, 5000
12.
,5010
0.
008
0.
0006
348.
,14
37.
.999
37.
,978
-0.
,055
12.
5000
12.
5044
0.
035
0.
0048
473.
,19
3.
.924
3.
924
-0.
,006
1.
0000
1.
0001
0.
006
0.
0061
473.
.19
7.
.854
7.
852
-0.
,031
2.
0000
2.
0006
0.
030
0.
0031
473.
.19
11.
.832
11.
826
-0.
.056
3.
0000
3.
0017
0.
055
0.
0020
473.
,19
15.
.904
15.
,893
-0.
,064
4.
0000
4.
0025
0.
062
0.
0015
70
Data from Douslin et al. [36] (continued)
T
P,exp
P.cal
Dev
P.exp
p.cal
Dev
Wt
K
MPa
MPa
%
mol • dm' ^
mol • dm' ^
%
473,
.19
20.121
20.108
-0.063
5.0000
5.0030
0.059
0,
,0012
473.
.19
24.542
24.528
-0.055
6.0000
6.0030
0.050
0,
.0009
473,
.19
29.239
29.222
-0.058
7.0000
7.0035
0.050
0,
,0008
473,
.19
34.287
34.263
-0.072
8.0000
8.0047
0.059
0,
.0006
473,
.19
39.759
39.738
-0.053
9.0000
9.0037
0.041
0,
,0052
523,
.21
4.363
4.363
-0.012
1.0000
1.0001
0.012
0,
.0055
523,
.21
8.780
8.777
-0.038
2.0000
2.0007
0.037
0,
.0027
523,
.21
13.294
13.287
-0.054
3.0000
3.0016
0.052
0,
.0018
523,
.21
17.960
17.945
-0.087
4.0000
4.0033
0.082
0,
,0013
523.
,21
22.835
22.808
-0.119
5.0000
5.0054
0.109
0,
,0010
523,
,21
27.975
27.941
-0.122
6.0000
6.0065
0.108
0,
,0008
523,
,21
33.457
33.419
-0.114
7.0000
7.0067
0.096
0,
.0007
523.
.21
39.363
39.324
-0.100
8.0000
8.0064
0.080
0,
.0054
573.
.22
4.802
4.801
-0.017
1.0000
1.0002
0.017
0.
.0050
573.
.22
9.703
9.699
-0.037
2.0000
2.0007
0.036
0,
.0024
573.
.22
14.751
14.743
-0.055
3.0000
3.0016
0.053
0.
,0016
573.
,22
20.005
19.986
-0.093
4.0000
4.0035
0.087
0,
.0012
573.
.22
25.527
25.493
-0.131
5.0000
5.0059
0.118
0,
.0009
573.
,22
31.384
31.335
-0.156
6.0000
6.0081
0.135
0,
.0007
573.
.22
37.639
37.592
-0.125
7.0000
7.0072
0.103
0,
.0058
623.
.22
5.240
5.238
-0.032
1.0000
1.0003
0.031
0,
.0046
623.
.22
10.625
10.619
-0.056
2.0000
2.0011
0.055
0,
.0022
623.
,22
16.207
16.193
-0.085
3.0000
3.0024
0.081
0,
.0014
623.
,22
22.049
22.020
-0.133
4.0000
4.0049
0.123
0,
.0010
623,
,22
28.216
28.167
-0.173
5.0000
5.0077
0.154
0,
.0008
623.22 34.777 34.713
■0.183 6.0000 6.0094
0.156
0.0006
Number of Points (Ref . 36)
PRESSURE
DENSITY
AAD-%
AAD
AAD-%
AAD
0.048
0.009
0.046
0.003
201
BIAS-%
BIAS
BIAS-%
BIAS
•0.009
■0.001
0.009
0.000
RMS-%
RMS
RMS-%
RMS
0.059
0,013 MPa
0.057
0.004 mol -dm' 3
71
Data from Gammon and Douslin [37]
T P.exp P.cal Dev />,exp p,cal
K MPa MPa % mol-dm"^ mol-dm'^
Dev
Wt
323
.15
24
.595
24
602
0.027
10
1474
10
.1452
-0.022
0.0001
298
15
2
.378
2
377
-0.032
9998
1
.0001
0.033
0.0010
298
.15
5
.627
5
623
-0.061
2
5000
2
5017
0.067
0.0004
298
15
10
491
10
491
-0.003
4
9996
4
9998
0.003
0.0002
298
15
15
205
15
216
0.072
7
5002
7
4946
-0.075
0.0002
298
15
19
418
19
432
0.072
9
5344
9
5282
-0.065
0.0001
298
15
20
702
20
715
0.061
10
0914
10
0860
-0.053
0.0001
273
15
16
178
16
195
0.102
9
6452
9
6355
-0.100
0.0001
248
15
12
816
12
870
0.423
9
8009
9
7544
-0.474
0.0002
223
15
9
320
9
363
0.463
9
9547
9
8857
-0.693
0.0003
198
15
5
704
5
711
0.118
10
1081
10
0518
-0.557
0.0006
193
05
782
782
0.014
5168
5167
-0.015
0.0032
193
05
1
563
1
565
0.069
1
1071
1
1062
-0.079
0.0016
193
05
2
244
2
247
0.128
1
7074
1
7047
-0.160
0.0012
193
05
2
820
2
824
0.142
2
3052
2
3007
-0.197
0.0010
193
05
3
306
3
311
0.172
2
9109
2
9031
-0.267
0.0009
193
05
3
703
3
710
0.195
3
5146
3
5025
-0.346
0.0008
193
05
4
025
4
034
0.216
4
1234
4
1050
-0.445
0.0008
193
05
4
281
4
290
0.215
4
7353
4
7103
-0.527
0.0007
193
05
4
478
4
486
0.185
5
3479
5
3181
-0.557
0.0007
193
05
4
626
4
634
0.166
5
9688
5
9310
-0.633
0.0007
193
05
4
729
4
735
0.131
6
5599
6
5175
-0.646
0.0007
193
05
4
806
4
810
0.089
7
1780
7
1360
-0.585
0.0007
193
05
4
859
4
862
0.047
7
7943
7
7612
-0.424
0.0007
193
05
4
897
4
897
0.010
8
4106
8
4004
-0.122
0.0007
193
05
4
924
4
924
-0.009
9
0278
9
0390
0.124
0.0007
193
05
4
946
4
946
-0.004
9
6448
9
6509
0.063
0.0007
193
05
4
962
4
963
0.017
10
1433
10
1192
-0.237
0.0007
193
05
4
966
4
967
0.020
10
2656
10
2373
-0.276
0.0007
193
05
4
988
4
990
0.049
10
8790
10
8200
-0.543
0.0007
193
05
5
016
5
020
0.089
11
4941
11
4142
-0.695
0.0007
191
45
4
587
4
591
0.099
6
5658
6
5274
-0.584
0.0000
191
45
4
646
4
649
0.053
7
1849
7
1510
-0.471
0.0000
191
45
4
683
4
684
0.008
7
8031
7
7947
-0.108
0.0000
191
45
4
705
4
704
-0.019
8
4225
8.
4593
0.437
0.0000
72
Data from Gammon and Douslin [37] (continued)
T P.exp P.cal Dev p.exp p.cal
K MPa MPa % mol-dm"^ mol-dm'^
Dev
Wt
191
.45
4
717
4
716
-0.026
9
.0460
9
1297
926
0.0000
191
.45
4
725
4
724
-0.018
9
6692
9
7436
770
0.0000
191
45
4
730
4
730
0.002
10
1732
10
1671
-0
060
0.0000
191
.45
4
731
4
731
0.005
10
2951
10
2770
-0
176
0.0000
191
45
4
738
4
739
0.031
10
9028
10
8054
-0
893
0.0000
191
45
4
748
4
751
0.062
11
5131
11
3877
-1
090
0.0000
190
85
4
533
4
537
0.087
6
5680
6
5310
-0
564
0.0000
190
85
4
586
4
588
0.042
7
1876
7
1567
-0
431
0.0000
190
85
4
616
4
616
0.001
7
8070
7
8050
-0
026
0.0000
190
85
4
632
4
631
-0.018
8
4302
8
4869
672
0.0000
190
85
4
638
4
637
-0.019
9
0767
9
2125
1
496
0.0000
190
85
4
641
4
641
-0.012
9
7495
9
8937
1
479
0.0000
190
85
4
643
4
643
-0.002
10
2668
10
2893
220
0.0000
190
85
4
643
4
643
0.002
10
3899
10
3650
-0
239
0.0000
190
85
4
646
4
646
0.015
10
9572
10
8366
-1
101
0.0000
190
85
4
650
4
651
0.033
11
5304
11
4050
-1
088
0.0000
190
63
4
513
4
517
0.078
6
5688
6
5346
-0
520
0.0000
190
63
4
564
4
565
0.039
7
1886
7
1586
-0
418
0.0000
190
63
4
592
4
592
0.000
7
8086
7
8086
000
0.0000
190
63
4
605
4
604
-0.015
8
4349
8
4958
722
0.0000
190
63
4
609
4
609
-0.009
9
1376
9
2686
1
433
0.0000
190
63
4
610
4
610
0.004
10
0202
9
8346
-1
852
0.0000
190
63
4
611
4
611
0.005
10
6490
10
4918
-1
476
0.0000
190
63
4
611
4
611
0.010
10
7652
10
4918
-2
540
0.0000
190
63
4
612
4
612
0.002
11
1070
11
0773
-0
267
0.0000
190
63
4
615
4
615
0.015
11
5501
11
4704
-0
690
0.0000
190
56
4
507
4
510
0.083
6
5691
6
5324
-0
558
0.0000
190
56
4
556
4
558
0.038
7
1890
7
1593
-0
413
0.0000
190
56
4
584
4
584
0.000
7
8092
7
8088
-0
005
0.0000
190
56
4
596
4
595
-0.012
8
4377
8
4896
615
0.0000
190
56
4
600
4
600
-0.003
9
1450
9
2024
628
0.0000
190
56
4
601
4
601
0.000
10
1650
10
1392
-0
254
0.0000
190
56
4
601
4
601
-0.010
10
4400
10
9536
4
919
0.0000
190
56
4
601
4
601
-0.005
10
5100
10
8181
2
932
0.0000
190
56
4
602
4
601
-0.012
11
0320
11
2174
1
680
0.0000
73
Data from Gammon and Douslin [37] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm"^ mol-dm'^
Dev
Wt
190
56
4
603
4
604
0.006
11
.5780
11
5414
-0.316
0.0000
190
50
771
771
0.039
.5172
.5170
-0.041
0.0032
190
50
1
538
1
539
0.085
1
.1081
1
1070
-0.098
0.0017
190
50
2
203
2
206
0.126
1
.7090
1
.7063
-0.159
0.0012
190
50
2
760
2
765
0.161
2
.3075
2
3023
-0.226
0.0010
190
50
3
226
3
232
0.189
2
.9139
2
9052
-0.300
0.0000
190
50
3
603
3
610
0.203
3
.5185
3
5054
-0.372
0.0000
190
50
3
902
3
910
0.210
4
.1282
4
1093
-0.457
0.0000
190
50
4
133
4
141
0.195
4
.7411
4
7164
-0.521
0.0000
190
50
4
304
4
311
0.163
5
.3548
5
3249
-0.559
0.0000
190
50
4
425
4
430
0.124
5
9769
5
9421
-0.582
0.0000
190
50
4
501
4
505
0.083
6
5693
6
5320
-0.567
0.0000
190
50
4
550
4
552
0.037
7
.1893
7
1598
-0.411
0.0000
190
50
4
577
4
577
0.001
7
8097
7
8080
-0.021
0.0000
190
50
4
589
4
588
-0.010
8
4412
8
4898
0.575
0.0000
190
43
4
495
4
499
0.079
6
5696
6
5338
-0.545
0.0000
190
43
4
543
4
545
0.035
7
1896
7
1607
-0.402
0.0000
190
43
4
569
4
569
0.001
7
8103
7
8086
-0.022
0.0000
190
43
4
580
4
579
-0.008
8
4416
8
4823
0.483
0.0000
190
25
4
287
4
293
0.157
5
3555
5
3261
-0.548
0.0000
190
25
4
405
4
410
0.118
5
9777
5
9436
-0.570
0.0000
190
25
4
479
4
482
0.078
6
5703
6
5340
-0.553
0.0000
190
25
4
525
4
526
0.034
7
1905
7
1610
-0.410
0.0000
190
25
4
549
4
549
0.002
7
8122
7
8073
-0.063
0.0000
189
65
3
861
3
869
0.202
4
1298
4
1112
-0.450
0.0000
189
65
4
083
4
091
0.188
4
7430
4
7183
-0.521
0.0000
189
65
4
245
4
252
0.148
5
3571
5
3283
-0.537
0.0000
189
65
4
357
4
362
0.108
5
9796
5
9464
-0.555
0.0000
189
65
4
424
4
427
0.069
6
5726
6
5365
-0.549
0.0000
189
65
4
463
4
465
0.030
7
1938
7
1614
-0.450
0.0000
188
15
761
761
0.062
5176
5173
-0.066
0.0016
188
15
1
515
1
516
0.090
1
1089
1
1077
-0.104
0.0008
188
15
2
164
2
168
0.158
1
7104
1.
7070
-0.201
0.0006
188
15
2
705
2
710
0.178
2
3096
2.
3038
-0.253
0.0005
188
15
3
153
3
159
0.204
2
9168
2.
9071
-0.333
0.0000
74
Data from Gammon and Douslin [37] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm"^ mol-dm'^
Dev
Wt
188
.15
3,
.509
3
.516
0,
.215
3,
.5221
3,
.5077
-0,
.409
0.0000
188
.15
3,
.787
3,
.795
0,
.209
4,
.1327
4,
.1127
-0,
.485
0.0000
188,
.15
3,
.995
4,
.002
0,
.177
4,
.7465
4,
.7217
-0,
.522
0.0000
188,
.15
4,
.140
4,
.146
0,
.132
5,
.3612
5.
.3325
-0,
.535
0.0000
188
.15
4,
.235
4,
.239
0,
.086
5,
.9846
5,
.9525
-0,
.536
0.0000
183,
.15
0,
.738
0,
.739
0,
.102
0,
.5184
0,
.5178
-0,
.109
0.0017
183,
.15
1,
.465
1,
.466
0,
.104
1,
.1108
1.
.1095
-0,
,121
0.0009
183,
.15
2,
.083
2,
.086
0,
.156
1,
.7135
1,
.7100
-0,
,204
0.0006
183,
.15
2,
.587
2,
.592
0,
.200
2,
.3140
2.
.3072
-0,
,296
0.0005
183
.15
2,
.994
3,
.001
0,
.222
2,
.9228
2.
.9116
-0,
,384
0.0005
183,
.15
3,
.307
3,
.314
0,
.215
3,
.5298
3.
.5138
-0,
,454
0.0000
183,
.15
3,
.537
3,
.543
0.
.175
4,
.1424
4.
.1224
-0,
,483
0.0000
173,
.15
0,
.694
0,
.694
0,
.048
0,
.5192
0,
.5189
-0,
.052
0.0018
173,
.15
1,
,363
1,
,365
0.
.140
1,
.1143
1,
.1124
-0,
.168
0.0010
173,
.15
1,
,914
1,
,918
0,
.206
1,
.7193
1.
.7145
-0,
.282
0.0007
173,
,15
2,
,344
2,
,349
0,
.235
2,
.3220
2,
.3131
-0,
.382
0.0006
163,
.15
0,
,649
0,
,650
0,
.053
0,
.5204
0,
.5201
-0,
,058
0.0019
163,
,15
1,
,259
1,
,262
0.
.168
1,
.1175
1.
.1152
-0,
,208
0.0011
163,
,15
1,
,740
1,
,743
0,
.190
1,
.7223
1,
.7175
-0,
,280
0.0008
153,
,15
0,
,604
0,
,604
0.
.063
0,
.5215
0,
.5211
-0,
,070
0.0021
143.
.15
0,
,557
0,
,558
0.
.068
0,
.5223
0.
.5219
-0,
,077
0.0023
190,
,50
4.
,592
4,
,592
-0,
.009
11,
.1700
11.
.3105
1,
,258
0.0000
190,
,50
4,
,594
4,
,594
-0,
.005
11,
.5750
11,
.6031
0,
,242
0.0000
190,
,43
4.
,582
4,
,582
-0,
.009
11,
.5100
11.
,5827
0.
,631
0.0000
190,
,43
4,
,584
4,
,582
-0.
.032
11,
.5750
11,
.7644
1.
,636
0.0000
190,
,25
4.
,557
4,
,556
-0,
.033
12,
.0406
12.
,1414
0.
,837
0.0000
189,
,65
4,
,472
4,
.469
-0.
,076
12,
.9613
13.
,0260
0,
,499
0.0000
188,
,15
4.
,267
4,
.263
-0,
.094
14,
.1950
14.
,2176
0,
,159
0.0000
185,
,91
3,
,977
3.
.981
0.
111
15,
.3297
15.
,3186
-0.
,072
0.0000
183,
,15
3,
,642
3,
.663
0,
.571
16,
.3353
16,
,3056
-0.
,182
0.0000
183,
,15
3,
,642
3,
.663
0,
.563
16,
.3353
16.
,3061
-0,
,179
0.0000
178,
.15
3,
,092
3,
.138
1.
.512
17,
.7013
17.
,6660
-0.
,199
0.0001
173,
.15
2,
,606
2,
.668
2,
.360
18,
.7794
18,
,7493
-0.
,160
0.0000
170,
.75
2,
,394
2,
.460
2,
.767
19,
.2357
19.
,2083
-0.
,142
0.0000
163,
.15
1,
,804
1,
.883
4,
.381
20,
.5098
20,
,4886
-0.
,103
0.0000
75
Data from Gammon and Douslin [37] (continued)
T P.exp P.cal Dev p.exp p,cal
K MPa MPa % mol-dm"^ mol-dm"^
Dev
Wt
155
44
1.
321
1
412
6.862
21
6202
21
6029
-0.080
0.0000
153
15
1.
197
1
291
7.792
21
9245
21
9082
-0.074
0.0000
143
15
0.
753
849
12.744
23
1510
23
1390
-0.052
0.0000
140
02
643
0.
738
14.700
23
5070
23
4962
-0.046
0.0000
133
15
0.
443
529
19.524
24
2514
24
2432
-0.034
0.0001
125
09
271
348
28.161
25
0715
25
0655
-0.024
0.0001
123
15
239
313
30.974
25
2616
25
2561
-0.022
0.0001
113
15
115
186
61.893
26
2044
26
2001
-0.017
0.0001
190
37
4
572
4
572
0.000
8
4443
8
4441
-0.003
0.0000
190
35
4
569
4
570
0.006
8
4332
8
4024
-0.365
0.0000
190
03
4
523
4
524
0.011
7
8149
7
7887
-0.335
0.0000
189
50
4
448
4
449
0.034
7
1947
7
1554
-0.546
0.0000
188
70
4
336
4
339
0.063
6
5765
6
5362
-0.614
0.0000
187
60
4
189
4
193
0.092
5
9865
5
9491
-0.624
0.0000
186
10
3
993
3
999
0.137
5
3671
5
3312
-0.669
0.0000
184
15
3
751
3
758
0.170
4
7560
4
7259
-0.634
0.0000
181
55
3
451
3
456
0.142
4
1324
4
1151
-0.418
0.0000
174
25
2
699
2
703
0.169
2
9218
2
9118
-0.341
0.0006
169
15
2
241
2
245
0.190
2
3197
2
3121
-0.326
0.0007
162
65
1
730
1
733
0.190
1
7217
1
7168
-0.282
0.0008
155
05
1
173
1
175
0.172
1
1192
1
1167
-0.221
0.0011
138
15
533
533
0.071
5217
5213
-0.081
0.0024
190
85
4
533
4
537
0.089
6
5670
6
5291
-0.577
0.0000
190
85
4
586
4
588
0.041
7
1850
7
1551
-0.416
0.0000
190
85
4
616
4
616
0.001
7
8010
7
7989
-0.027
0.0000
190
.85
4
631
4
631
-0.018
8
4170
8
4730
0.665
0.0000
190
.85
4
638
4
637
-0.021
9
0330
9
1792
1.619
0.0000
190
.85
4
641
4
641
-0.014
9
6500
9
8155
1.715
0.0000
190
.85
4
643
4
642
-0.005
10
1480
10
2117
0.628
0.0000
190
.85
4
643
4
643
-0.002
10
2700
10
2893
0.188
0.0000
190
.85
4
.645
4
646
0.013
10
8860
10
7816
-0.959
0.0000
190
.85
4
.650
4
651
0.032
11
5030
11
3776
-1.090
0.0000
190
.43
4
.495
4
498
0.080
6
5680
6
5318
-0.551
0.0000
190
.43
4
543
4
545
0.036
7
1870
7
1571
-0.416
0.0000
190
.43
4
.569
4
.569
0.001
7
8030
7
8008
-0.028
0.0000
76
Data from Gammon and Douslin [37] (continued)
T P,exp P.cal Dev p.exp P.cal
K MPa MPa % mol-dm"^ mol-dm"^
Dev
Wt
190
43
4
.580
4
579
-0.008
8
.4190
8
.4589
0.474
0.0000
190
.56
4
507
4
510
0.082
6
5680
6
.5315
-0.556
0.0000
190
56
4
556
4
558
0.036
7
1860
7
.1576
-0.396
0.0000
190
56
4
583
4
583
0.000
7
8020
7
.8016
-0.005
0.0000
190
.56
4
596
4
595
-0.012
8
4180
8
.4701
0.619
0.0000
190
56
4
600
4
599
-0.006
9
0350
9
.1223
0.967
0.0000
190
56
4
600
4
600
0.004
9
6510
9
.4440
-2.145
0.0000
190
56
4
601
4
601
-0.004
10
1500
10
7195
5.610
0.0000
190
56
4
601
4
601
0.000
10
2720
10
1392
-1.293
0.0000
190
56
4
601
4
601
-0.011
10
8880
11
1261
2.186
0.0000
190
56
4
603
4
603
0.001
11
5050
11
5014
-0.031
0.0000
189
65
4
424
4
427
0.068
6
5710
6
5354
-0.542
0.0000
189
65
4
463
4
464
0.031
7
1900
7
1567
-0.463
0.0000
190
63
4
513
4
517
0.078
6
5670
6
5327
-0.522
0.0000
190
63
4
563
4
565
0.038
7
1860
7
1569
-0.405
0.0000
190
63
4
591
4
591
0.000
7
8020
7
8017
-0.004
0.0000
190
63
4
604
4
604
-0.015
8
4180
8
4778
0.710
0.0000
190
63
4
609
4
609
-0.013
9
0350
9
2010
1.838
0.0000
190
63
4
610
4
610
-0.001
9
6510
9
6743
0.241
0.0000
190
63
4
611
4
611
-0.004
10
1490
10
3218
1.702
0.0000
190
63
4
611
4
611
0.001
10
2720
10
2259
-0.449
0.0000
190
63
4
612
4
612
-0.006
10
8870
10
9885
0.932
0.0000
190
63
4
614
4
615
0.013
11
5040
11
4316
-0.629
0.0000
190
25
4
478
4
482
0.077
6
5690
6
5329
-0.549
0.0000
190
25
4
525
4
526
0.032
7
1870
7
1591
-0.388
0.0000
190
25
4
548
4
549
0.003
7
8040
7
7986
-0.069
0.0000
191
45
4
587
4
591
0.098
6
5640
6
5258
-0.583
0.0000
191
45
4
646
4
649
0.055
7
1830
7
1483
-0.483
0.0000
191
45
4
683
4
683
0.008
7
7990
7
7900
-0.115
0.0000
191
45
4
704
4
704
-0.019
8
4140
8
4509
0.438
0.0000
191
45
4
717
4
715
-0.027
9
0300
9
1159
0.951
0.0000
191
45
4
724
4
724
-0.018
9
6460
9
7179
0.746
0.0000
191
45
4
729
4
729
0.001
10
1450
10
1415
-0.035
0.0000
191
45
4
731
4
731
0.004
10
2670
10
2518
-0.148
0.0000
191
45
4
738
4
739
0.030
10
8820
10
7848
-0.893
0.0000
77
Data from Gammon and Douslin [37] (continued)
T P.exp P.cal Dev p.exp p.cal
K MPa MPa % mol-dm"^ mol-dm'^
191.45
190.50
190.50
190.50
190.50
190.50
190.50
4.748
4.501
4.550
4.577
4.588
4.591
4.594
4.751
4.505
4.552
4.577
4.588
4.592
4.593
0.061 11.4990 11.3741
0.083 6.5680 6.5311
0.037 7.1860 7.1563
0.001 7.8030 7.8006
■0.011 8.4190 8.4685
0.004
•0.006
9.0350
11.5050
8.9704
11.5478
Dev
%
■1.087
■0.562
■0.414
■0.030
0.588
■0.715
0.372
Wt
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Number of Points (Ref. 37) 217
PRESSURE:
AAD-%
0.963
BIAS-%
0.956
RMS-%
5.384
AAD
0.007
BIAS
0.007
RMS
0.018
MPa
DENSITY :
AAD-%
0.533
BIAS-%
-0.084
RMS-%
0.842
AAD
0.046
BIAS
-0.001
RMS
0.084
mol'dm" •^
Data from Goodwin [38]
T P.exp P.cal
K MPa MPa
Dev p , exp p , cal
% mol • dm" ^ mol • dm" ^
Dev
Wt
176
00
2
796
2
798
0.060
2
9954
2
9918
-0.120
0544
180
00
2
933
2
935
0.066
2
9936
2
9899
-0.123
0510
184
00
3
068
3
070
0.052
2
9918
2
9891
-0.092
0000
188
00
3
201
3
202
0.042
2
9901
2
9880
-0.070
0000
192
00
3
332
3
333
0.032
2
9883
2
9868
-0.051
0000
196
00
3
461
3
462
0.022
2
9866
2
9856
-0.033
24
7201
200
00
3
589
3
590
0.017
2
9848
2
9840
-0.026
23
6115
204
00
3
716
3
716
0.016
2
9831
2
9823
-0.024
22
6052
208
00
3
842
3
842
0.014
2
9813
2
9807
-0.020
21
6863
212
00
3
967
3
967
0.017
2
9796
2
9789
-0.023
20
8446
216
00
4
091
4
091
0.014
2
9779
2
9773
-0.019
20
0692
220
00
4
214
4
215
0.010
2
9761
2
9757
-0.013
19
3528
225
00
4
367
4
368
0.012
2
9739
2
9735
-0.015
18
5313
230
00
4
520
4
520
0.009
2
9717
2
9714
-0.011
17
7803
240
00
4
822
4
822
-0.003
2
9675
2
9676
0.004
16
4562
78
Data from Goodwin [38] (continued)
T P.exp P.cal Dev p.exp p.cal
K MPa MPa % mol-dra'^ mol-dm"^
Dev
Wt
250
.00
5
.120
5
120
-0.004
2
9630
2
9632
005
15
.3274
260
.00
5
.416
5
415
-0.010
2
9585
2
9589
012
14
.3516
270
.00
5
.709
5
708
-0.012
2
9540
2
9544
014
0450
280
.00
6
000
5
998
-0.018
2
9495
2
9501
020
.0425
290
00
6
287
6
287
-0.005
2
9450
2
9452
006
0403
300
00
6
575
6
572
-0.035
2
9402
2
9414
039
0383
184
00
3
516
3
531
0.444
3
9782
3
9350
-1
085
0000
188
00
3
710
3
724
0.374
3
9756
3
9430
-0
819
0000
192
00
3
899
3
912
0.327
3
9731
3
9469
-0
657
0000
196
00
4
090
4
097
0.165
3
9705
3
9581
-0
310
22
0316
200
00
4
275
4
280
0.110
3
9683
3
9605
-0
195
20
8002
204
00
4
456
4
460
0.104
3
9654
3
9584
-0
176
19
7117
208
00
4
635
4
639
0.094
3
9629
3
9568
-0
153
18
7340
212
00
4
812
4
817
0.091
3
9604
3
9548
-0
142
17
8526
216
00
4
988
4
993
0.087
3
9579
3
9526
-0
132
17
0531
220
00
5
163
5
168
0.087
3
9554
3
9503
-0
128
16
3251
225
00
5
380
5
385
0.085
3
9522
3
9474
-0
121
15
5011
230
00
5
595
5
600
0.088
3
9491
3
9443
-0
121
14
7598
240
00
6
020
6
026
0.089
3
9427
3
9381
-0
116
13
4790
250
00
6
441
6
446
0.088
3
9364
3
9320
-0
112
12
4111
260
00
6
857
6
862
0.082
3
9300
3
9260
-0
100
11
5065
270
00
7
268
7
274
0.082
3
9235
3
9196
-0
098
0358
280
00
7
676
7
682
0.083
3
9170
3
9132
-0
096
0335
290
00
8
080
8
087
0.075
3
9104
3
9071
-0
085
0316
300
00
8
482
8
488
0.068
3
9038
3
9008
-0
075
0298
188
00
4
028
4
041
0.343
4
9304
4
8761
-1
101
0000
192
00
4
277
4
292
0.354
4
9270
4
8800
-0
952
0000
196
00
4
522
4
537
0.335
4
9236
4
8845
-0
793
20
7942
200
00
4
764
4
778
0.297
4
9202
4
8888
-0
638
19
4180
204
00
5
004
5
016
0.250
4
9169
4
8925
-0
496
18
2088
208
00
5
241
5
251
0.200
4
9135
4
8953
-0
371
17
1392
212
00
5
474
5
484
0.182
4
9102
4
8945
-0
320
16
1910
216
00
5
705
5
715
0.178
4
9069
4
8922
-0
298
15
3436
220
00
5
933
5
945
0.195
4
9035
4
8882
-0
313
14
5828
225
00
6
218
6
229
0.176
4
8994
4
8862
-0
270
13
7288
79
Data from Goodwin [38] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm"^ ntol-dm"^
Dev
Wt
230,
.00
6
.500
6
.511
.171
4
.8952
4
.8829
-0.251
12.9716
240,
.00
7
.056
7.
.068
.166
4
.8868
4
.8757
-0.228
11.6871
250,
.00
7
.606
7
.618
.158
4
.8784
4
.8683
-0.206
10.6391
260,
,00
8
.149
8
.162
.153
4
.8699
4
.8606
-0.191
9.7686
270,
,00
8
.687
8,
.699
0,
.145
4
.8614
4
.8529
-0.174
0.0301
280,
,00
9,
.219
9
.232
0,
.137
4
.8527
4
.8450
-0.160
0.0280
290,
,00
9,
.747
9,
.759
0,
.125
4
.8441
4
.8372
-0.142
0.0262
300,
,00
10,
.270
10,
.282
0,
.117
4
.8354
4
.8291
-0.130
0.0246
192,
,00
4,
.537
4,
.546
0,
.193
5
.9478
5
.9012
-0.784
0.0000
196.
,00
4,
.849
4,
.860
0,
.216
5,
.9435
5
.9027
-0.686
20.0683
200,
,00
5,
.155
5,
.167
0,
.231
5,
.9392
5
.9024
-0.620
18.5422
204,
,00
5,
.458
5,
.470
0,
.230
5,
.9350
5,
.9028
-0.542
17.2123
208,
,00
5,
.758
5,
.770
0.
.215
5
.9307
5,
.9034
-0.460
16.0467
212,
,00
6,
.054
6,
.067
0,
.213
5,
.9264
5,
.9016
-0.419
15.0219
216.
,00
6,
.347
6,
.361
0,
.215
5,
.9222
5,
.8988
-0.395
14.1148
220.
,00
6.
.638
6,
.653
0.
,225
5,
.9179
5,
.8949
-0.389
13.3081
225.
,00
6.
.999
7,
.014
0.
,224
5,
.9126
5,
.8910
-0.364
12.4163
230.
,00
7.
.357
7,
.373
0.
,225
5,
.9072
5,
.8867
-0.347
11.6346
240.
,00
8,
,064
8,
,083
0.
,231
5,
.8965
5,
,8772
-0.328
10.3317
250.
,00
8,
.763
8,
.783
0.
,228
5,
.8857
5,
.8680
-0.302
9.2910
260,
,00
9,
.454
9,
.475
0.
,220
5.
,8749
5,
.8586
-0.277
8.4427
270,
,00
10,
.138
10.
.160
0.
,209
5,
,8640
5,
.8493
-0.251
0.0258
280,
,00
10,
.816
10,
,837
0,
,200
5,
,8531
5,
,8395
-0.232
0.0238
290,
,00
11,
.487
11.
.509
0.
,184
5.
,8422
5,
,8300
-0.208
0.0221
300,
.00
12,
.153
12,
,174
0.
,167
5.
,8312
5.
,8205
-0.184
0.0207
192,
.00
4.
.685
4.
,687
0.
,050
6.
,9818
6.
,9571
-0.354
0.0000
196,
,00
5,
.066
5.
.072
0.
,124
6.
,9765
6.
,9384
-0.546
19.6268
200,
.00
5,
.441
5.
.450
0.
,168
6.
,9712
6.
,9321
-0.561
17.9586
204,
.00
5,
.811
5,
,822
0.
,189
6.
,9659
6.
,9295
-0.524
16.5074
208,
.00
6,
.177
6.
,190
0.
,203
6.
,9607
6.
,9267
-0.489
15.2439
212,
.00
6.
.541
6.
,555
0.
208
6.
,9555
6.
,9243
-0.448
14.1394
216,
.00
6,
.901
6.
,917
0.
220
6.
9502
6.
,9202
-0.432
13.1713
220,
.00
7,
.259
7.
,276
0.
229
6.
,9450
6.
9159
-0.418
12.3179
225,
,00
7,
.703
7.
,722
0.
239
6.
,9384
6.
,9104
-0.403
11.3861
230,
,00
8,
.144
8.
,164
0.
251
6.
9317
6.
9042
-0.397
10.5795
80
Data from Goodwin [38] (continued)
T
P.exp
P.cal
Dev
p,exp
p,cal
Dev
Wt
K
MPa
MPa
%
mol • dm" ^
mol • dm" ^
%
240.00
9.016
9.040
0.272
6.9186
6.8917
-0.388
9
.2574
250.00
9.879
9.906
0.271
6.9053
6.8806
-0.357
8
.2230
260.00
10.732
10.761
0.272
6.8920
6.8688
-0.337
7
3956
270.00
11.579
11.608
0.250
6.8786
6.8583
-0.295
0224
280.00
12.417
12.446
0.234
6.8653
6.8471
-0.265
0205
290.00
13.249
13.277
0.214
6.8521
6.8360
-0.234
0190
300.00
14.074
14.101
0.191
6.8389
6.8250
-0.204
0176
192.00
4.753
4.754
0.018
7.9789
7.9598
-0.238
0000
196.00
5.201
5.206
0.101
7.9726
7.9253
-0.593
19
3188
200.00
5.642
5.651
0.176
7.9664
7.9110
-0.695
17
5209
204.00
6.078
6.092
0.223
7.9601
7.9055
-0.687
15
9544
208.00
6.512
6.528
0.248
7.9539
7.9033
-0.636
14
5935
212.00
6.944
6.962
0.250
7.9476
7.9031
-0.560
13
4110
216.00
7.373
7.392
0.263
7.9413
7.8994
-0.528
12
3843
220.00
7.800
7.821
0.273
7.9350
7.8952
-0.502
11
4881
225.00
8.329
8.353
0.288
7.9271
7.8888
-0.484
10
5213
230.00
8.857
8.882
0.291
7.9192
7.8832
-0.454
9
6936
240.00
9.901
9.931
0.305
7.9034
7.8699
-0.424
8
3608
250.00
10.936
10.969
0.303
7.8876
7.8570
-0.387
7
3402
260.00
11.961
11.996
0.292
7.8718
7.8443
-0.349
6
5379
270.00
12.978
13.014
0.276
7.8561
7.8315
-0.313
0196
280.00
13.986
14.022
0.257
7.8405
7.8186
-0.279
0179
290.00
14.985
15.021
0.237
7.8251
7.8056
-0.249
0164
300.00
15.977
16.012
0.217
7.8100
7.7927
-0.221
0152
192.00
4.789
4.788
-0.012
9.0890
9.1140
0.274
0000
196.00
5.308
5.311
0.051
9.0817
9.0489
-0.361
19
0038
200.00
5.824
5.831
0.118
9.0743
9.0286
-0.504
17
0385
204.00
6.336
6.348
0.187
9.0669
9.0135
-0.589
15
3320
208.00
6.850
6.864
0.205
9.0595
9.0121
-0.523
13
8561
212.00
7.361
7.379
0.231
9.0520
9.0063
-0.505
12
5916
216.00
7.871
7.891
0.254
9.0445
9.0000
-0.492
11
5063
220.00
8.380
8.402
0.262
9.0369
8.9953
-0.461
10
5709
225.00
9.013
9.038
0.280
9.0275
8.9873
-0.445
9
5774
230.00
9.644
9.671
0.286
9.0180
8.9801
-0.420
8
7405
240.00
10.897
10.930
0.300
8.9990
8.9638
-0.392
7
4207
81
Data from Goodwin [38] (continued)
T P.exp P.cal Dev p.exp p,cal
K MPa MPa % mol-dm"^ mol-dm"^
Dev
Wt
250
.00
12
.140
12
.177
306
8
9801
8
9473
-0
365
6
.4348
260
00
13
.373
13
.413
304
8
9614
8
9310
-0
339
5
.6753
270
00
14
.597
14
.639
288
8
9429
8
9156
-0
305
.0169
280
.00
15
.811
15
.855
274
8
9249
8
9001
-0
278
.0153
290
00
17
.017
17
.060
254
8
9072
8
8850
-0
249
.0140
300
00
18
215
18
.256
228
8
8900
8
8707
-0
216
0129
192
00
4
810
4
811
017
10
2380
10
1955
-0
415
0000
196
00
5
402
5
404
031
10
2296
10
2096
-0
196
18
.6281
200
00
5
998
6
003
075
10
2210
10
1922
-0
282
16
.4207
204
00
6
598
6
606
118
10
2123
10
1790
-0
326
14
5265
208
00
7
199
7
210
151
10
2036
10
1690
-0
339
12
9269
212
00
7
801
7
815
175
10
1947
10
1604
-0
336
11
5846
216
00
8
404
8
420
193
10
1858
10
1523
-0
329
10
4578
220
00
9
006
9
024
199
10
1769
10
1454
-0
309
9
5067
225
00
9
757
9
778
217
10
1657
10
1346
-0
305
8
5167
230
00
10
507
10
530
224
10
1545
10
1248
-0
292
7
6992
240
00
11
998
12
028
244
10
1321
10
1033
-0
284
6
4401
250
00
13
481
13
516
257
10
1100
10
0822
-0
275
5
5235
260
00
14
954
14
993
255
10
0882
10
0624
-0
256
4
8311
270
00
16
417
16
458
255
10
0671
10
0425
-0
244
0143
280
00
17
870
17
913
242
10
0466
10
0242
-0
223
0129
290
00
19
313
19
358
229
10
0271
10
0066
-0
204
0117
300
00
20
747
20
791
211
10
0081
9
9898
-0
183
0107
192
00
4
832
4
831
-0
026
11
1113
11
1567
408
0000
196
00
5
485
5
484
-0
035
11
1019
11
1205
167
18
1729
200
00
6
151
6
150
-0
018
11
0923
11
0983
054
15
6984
204
00
6
825
6
825
-0
005
11
0825
11
0837
Oil
13
6401
208
00
7
502
7
503
021
11
0725
11
0682
-0
039
11
9618
212
00
8
177
8
184
085
11
0625
11
0472
-0
138
10
5985
216
00
8
861
8
866
061
11
0523
11
0424
-0
089
9
4759
220
00
9
542
9
549
076
11
0422
11
0309
-0
102
8
5500
225
00
10
391
10
401
098
11
0294
11
0162
-0.
120
7
6027
230
00
11
240
11
253
115
11
0167
11.
0022
-0.
132
6
8329
240
00
12
934
12
951
133
10
9914
10
9763
-0.
138
5.
6668
250
00
14
617
14
641
161
10
9667
10
9497
-0.
155
4.
8327
82
Data from Goodwin [38] (continued)
T P.exp P.cal Dev P.exp p.cal
K MPa MPa % mol-dm"^ mol-dm"^
Dev
Wt
260
.00
16
.291
16
.319
.175
10
.9428
10
.9254
-0
159
4
.2102
270
.00
17
.955
17
.987
.179
10
.9198
10
.9028
-0
156
.0124
280
.00
19
.607
19
.643
.182
10
.8978
10
.8811
-0
154
.0112
290
.00
21
.250
21
.287
.177
10
.8769
10
.8612
-0
145
.0101
300
.00
22
.883
22
.920
164
10
.8570
10
.8428
-0
131
.0093
192
.00
4
869
4
.869
003
12
.0697
12
0670
-0
022
.0000
196
.00
5
.603
5
.604
021
12
.0591
12
0517
-0
062
17
.2314
200
.00
6
357
6
.359
021
12
.0482
12
0429
-0
044
14
4081
204
.00
7
122
7
123
027
12
.0370
12
0317
-0
044
12
.2259
208
00
7
891
7
894
038
12
0256
12
0191
-0
054
10
5450
212
.00
8
665
8
669
039
12
0142
12
0083
-0
049
9
2315
216
00
9
443
9
445
026
12
0026
11
9989
-0
031
8
1869
220
00
10
220
10
223
029
11
9912
11
9874
-0
032
7
3423
225
00
11
191
11
196
041
11
9767
11
9717
-0
042
6
4936
230
00
12
162
12
168
054
11
9624
11
9562
-0
052
5
8141
240
00
14
099
14
110
079
11
9342
11
9258
-0
071
4
7997
250
00
16
026
16
043
109
11
9069
11
8960
-0
091
4
0834
260
00
17
943
17
966
130
11
8808
11
8684
-0
104
3
5529
270
00
19
849
19
877
142
11
8562
11
8432
-0
110
0105
280
00
21
744
21
776
147
11
8330
11
8198
-0
111
0094
290
00
23
629
23
663
143
11
8112
11
7988
-0
105
0085
300
00
25
503
25
537
133
11
7906
11
7792
-0
097
0078
192
00
4
946
4
948
052
12
9815
12
9612
-0
157
0000
196
00
5
779
5
785
106
12
9695
12
9450
-0
189
15
3489
200
00
6
633
6
640
111
12
9570
12
9371
-0
154
12
4178
204
00
7
499
7
506
085
12
9442
12
9313
-0
100
10
3465
208
00
8
373
8
377
058
12
9313
12
9234
-0
061
8
8342
212
00
9
250
9
253
036
12
9184
12
9138
-0
035
7
6910
216
00
10
130
10
132
Oil
12
9053
12
9040
-0
010
6
8008
220
00
11
012
11
Oil
-0
003
12
8923
12
8926
002
6
0902
225
00
12
111
12
112
004
12
8761
12
8757
-0
003
5
3835
230
00
13
212
13
213
008
12
8600
12
8591
-0
007
4
8216
240
00
15
406
15
411
032
12
8286
12
8255
-0
024
3
9876
250
00
17
590
17
601
060
12
7988
12
7932
-0
044
3
4004
260
00
19
764
19
779
079
12
7708
12
7637
-0
056
2
9657
83
Data from Goodwin [38] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm"^ mol-dm'^
Dev
Wt
270
00
21
926
21
946
.091
12
.7448
12
.7369
-0
.062
.0088
280
00
24
075
24
099
.099
12
.7206
12
.7121
-0
.066
.0079
290
00
26
213
26
239
.097
12
.6980
12
.6898
-0
.065
.0072
300
00
28
339
28
363
.087
12
.6767
12
.6694
-0
.057
.0066
192
00
5
205
5
224
368
14
.2336
14
.1765
-0
.401
.0000
196
00
6
221
6
235
.223
14
2188
14
.1907
-0
.198
10
.8128
200
00
7
245
7
258
179
14
2038
14
1836
-0
.142
8
.7028
204
00
8
279
8
289
.130
14
1886
14
1750
-0
.096
7
.2808
208
00
9
318
9
325
.083
14
1733
14
1651
-0
.058
6
.2584
212
00
10
361
10
365
039
14
1580
14
1543
-0
026
5
.4884
216
00
11
404
11
406
019
14
1427
14
1409
-0
.012
4
8884
220
00
12
448
12
449
006
14
1275
14
1269
-0
004
4
4078
225
00
13
752
13
752
003
14
1089
14
1086
-0
002
3
9272
230
00
15
053
15
055
009
14
0906
14
0898
-0
005
3
5428
240
00
17
651
17
655
024
14
0557
14
0537
-0
014
2
9670
250
00
20
235
20
244
045
14
0234
14
0196
-0
027
2
5562
260
00
22
806
22
821
066
13
9939
13
9886
-0
038
2
2482
270
00
25
363
25
383
076
13
9669
13
9607
-0
044
0067
280
00
27
907
27
929
078
13
9421
13
9358
-0
045
0061
290
00
30
433
30
458
080
13
9190
13
9126
-0
046
0055
300
00
32
948
32
969
062
13
8972
13
8923
-0
035
0051
190
00
5
187
5
211
473
15
3796
15
3396
-0
260
0000
194
00
6
379
6
404
394
15
3621
15
3305
-0
205
7
3227
198
00
7
586
7
607
275
15
3444
15
3231
-0
139
6
0330
202
00
8
801
8
816
171
15
3267
15
3136
-0
085
5
1393
206
00
10
020
10
029
091
15
3088
15
3019
-0
045
4
4823
210
00
11
238
11
244
058
15
2911
15
2867
-0
029
3
9786
215
00
12
760
12
764
037
15
2692
15
2665
-0
018
3
4931
220
00
14
279
14
284
033
15
2478
15
2422
-0
016
3
1171
230
00
17
313
17
318
030
15
2072
15
2049
-0
015
2.
5722
240
00
20
329
20
340
056
15
1701
15
1660
-0.
027
2.
1958
250
00
23
331
23
348
070
15
1369
15
1317
-0
034
1.
9195
260
00
26
318
26
338
077
15
1069
15
1012
-0.
038
1.
7078
270
00
29
286
29
309
079
15
0797
15.
0738
-0.
039
0.
0051
280
00
32
240
32
260
062
15
0546
15.
0500
-0.
031
0.
0047
84
Data from Goodwin [38] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % inol-dm"^ mol-dm'^
Dev
Wt
290
.00
35
.168
35
.189
.061
15
.0313
15
.0268
-0
.030
.0430
186
.00
4
.562
4
.581
.423
16
.2733
16
.2502
-0
.142
.0000
190
.00
5
.908
5
.931
396
16
.2543
16
.2319
-0
.138
.0000
194
.00
7
.268
7
.292
325
16
.2348
16
2159
-0
116
4
7079
198
.00
8
.636
8
.658
251
16
2151
16
2002
-0
092
4
0524
202
00
10
.005
10
.027
225
16
1953
16
1817
-0
084
3
5641
206
00
11
.375
11
398
198
16
1755
16
1633
-0
076
3
1859
210
00
12
.745
12
768
179
16
1562
16
1450
-0
069
2
8837
215
00
14
440
14
480
276
16
1328
16
1152
-0
109
2
5822
220
00
16
161
16
188
172
16
1098
16
0987
-0
069
2
3408
230
00
19
563
19
595
166
16
0677
16
0567
-0
068
1
9781
240
00
22
944
22
984
176
16
0302
16
0184
-0
074
1
7178
250
00
26
311
26
354
162
15
9971
15
9861
-0
069
1
5211
260
00
29
654
29
702
162
15
9676
15
9564
-0
070
1
3671
270
00
32
976
33
026
153
15
9408
15
9301
-0
067
0041
182
00
4
132
4
164
761
17
2858
17
2607
-0
145
0000
186
00
5
695
5
724
505
17
2636
17
2444
-0
111
0000
190
00
7
268
7
292
334
17
2416
17
2277
-0
081
16
4604
194
00
8
835
8
863
325
17
2194
17
2048
-0
085
2
8998
198
00
10
408
10
436
266
17
1973
17
1847
-0
073
2
5967
202
00
11
977
12
007
245
17
1754
17
1633
-0
071
2
3554
206
00
13
546
13
575
214
17
1539
17
1429
-0
064
2
1583
210
00
15
108
15
141
219
17
1331
17
1215
-0
068
1
9940
215
00
17
060
17
094
196
17
1084
17
0976
-0
063
1
8231
220
00
19
003
19
040
192
17
0848
17
0740
-0
063
1
6815
230
00
22
872
22
915
188
17
0424
17
0313
-0
065
1
4589
240
00
26
719
26
766
176
17
0056
16
9948
-0
063
1
2916
250
00
30
544
30
589
146
16
9731
16
9639
-0
054
1
1609
260
00
34
336
34
382
136
16
9441
16
9353
-0
052
1
0558
176
00
3
217
3
267
1
543
18
3840
18
3568
-0
148
14
9925
180
00
5
044
5
087
848
18
3570
18
3368
-0
110
0000
184
00
6
869
6
914
648
18
3320
18
3134
-0
102
0000
188
00
8
691
8
740
572
18
3070
18
2883
-0
102
10
2954
192
00
10
509
10
560
490
18
2810
18
2633
-0
097
1
8752
196
00
12
323
12
377
440
18
2560
18
2389
-0
094
1
7245
85
Data from Goodwin [38] (continued)
T P.exp P.cal Dev ^,exp p.cal
K MPa MPa % mol-dm"^ mol-dm"^
Dev
%
Wt
200.00
205.00
210.00
215.00
220.00
225.00
230.00
235.00
240.00
245.00
14.131
16.386
18.631
20.869
23.100
25.324
27.539
29.748
31.949
34.140
14.189
16.444
18.687
20.925
23.155
25.379
27.590
29.796
31.998
34.184
0.407
0.353
0.298
0.270
0.240
18.2320
18.2030
18.1750
18.1500
18.1270
18.2151
18.1874
18.1611
18.1368
18.1149
0.217 18.1060 18.0947
0.185 18.0860 18.0760
0.163 18.0680 18.0590
0.153 18.0520 18.0434
0.128 18.0360 18.0286
•0.093
•0.086
•0.076
•0.073
•0.067
•0.063
•0.055
•0.050
•0.048
•0.041
1.5985
1.4674
1.3585
1.2655
1.1854
1.1155
1.0542
0.9996
0.9506
0.9068
170.00
174.00
178.00
182.00
186.00
190.00
194.00
198.00
202.00
205.00
2.637
4.774
6.901
9.012
11.113
13.206
15.291
17.367
19.435
20.984
2.753
4.887
7.021
9.146
11.259
13.357
15.449
17.534
19.608
21.158
4.431
2.363
1.743
1.487
1.312
19.5060
19.4750
19.4460
19.4170
19.3880
19.4631
19.4379
19.4101
19.3802
19.3509
1.144 19.3590 19.3231
1.031 19.3320 19.2968
0.963 19.3070 19.2717
0.891 19.2830 19.2484
0.831 19.2660 19.2324
•0.220
•0.190
•0.184
■0.189
•0.191
■0.186
•0.182
•0.183
■0.180
■0.174
9.4880
8.5028
7.7238
7.0969
6.5806
6.1472
1.1547
1.0894
1.0320
0.9932
210.00
215.00
220.00
225.00
230.00
23.558
26.121
28.676
31.221
33.754
23.734
26.297
28.855
31.397
33.930
0.750
0.677
0.624
0.562
0.521
19.2400
19.2160
19.1950
19.1750
19.1570
19.2080
19.1857
19.1658
19.1478
19.1309
•0.167
■0.158
■0.152
■0.142
■0.136
0.9351
0.8841
0.8385
0.7979
0.7612
164.00 2.029 2.115 4.230 20.4250 20.4016 -0.115 6.7743
168.00 4.469 4.532 1.405 20.3890 20.3734 -0.077 6.2045
172.00 6.882 6.949 0.975 20.3570 20.3416 -0.076 5.7318
176.00 9.270 9.345 0.807 20.3240 20.3080 -0.079 5.3435
180.00 11.639 11.724 0.733 20.2920 20.2748 -0.085 5.0142
184.00 13.997 14.082 0.608 20.2600 20.2438 -0.080 4.7326
188.00 16.342 16.432 0.553 20.2310 20.2147 -0.080 4.4836
192.00 18.678 18.783 0.566 20.2060 20.1879 -0.090 0.8519
196.00 21.008 21.095 0.411 20.1780 20.1639 -0.070 0.8132
200.00 23.332 23.415 0.354 20.1550 20.1421 -0.064 0.7773
86
Data from Goodwin [38] (continued)
T P.exp P,cal Dev P.exp p , cal
K MPa MPa % mol-dm'^ mol-dm"^
Dev
Wt
204
.00
25
.649
25
.727
303
20
.1340
20
1224
-0
.058
7448
208
.00
27
.960
28
.033
262
20
.1150
20
1045
-0
.052
7149
212
.00
30
263
30
.327
212
20
.0970
20
0881
-0
.044
6876
216
00
32
557
32
610
163
20
.0800
20
0729
-0
035
6626
220
00
34
843
34
890
135
20
0650
20
0589
-0
030
6392
158
00
1
984
2
061
3
912
21
3710
21
3554
-0
073
4
7922
162
00
4
754
4
809
1
155
21
3320
21
3217
-0
048
4
4733
166
00
7
475
7
533
775
21
2940
21
2838
-0
048
4
2049
170
00
10
160
10
238
769
21
2580
21
2450
-0
061
3
9735
174
00
12
829
12
917
691
21
2230
21
2090
-0
.066
3
7727
178
00
15
481
15
571
585
21
1890
21
1754
-0
064
3
5961
182
00
18
122
18
214
507
21
1580
21
1448
-0
063
3
4368
186
00
20
756
20
839
402
21
1290
21
1175
-0
054
3
2930
190
00
23
382
23
457
321
21
1030
21
0931
-0
047
3
1609
194
00
26
003
26
070
258
21
0800
21
0715
-0
041
6078
198
00
28
612
28
672
210
21
0590
21
0516
-0
035
5853
202
00
31
214
31
265
165
21
0400
21
0339
-0
029
5645
206
00
33
804
33
843
116
21
0220
21
0175
-0
021
5453
152
00
1
459
1
545
5
871
22
1250
22
1110
-0
063
3
7607
156
00
4
509
4
560
1
124
22
0800
22
0722
-0
035
3
5533
160
00
7
492
7
566
987
22
0400
22
0292
-0
049
3
3697
164
00
10
440
10
539
949
22
0010
21
9872
-0
063
3
2104
168
00
13
369
13
471
760
21
9620
21
9485
-0
061
3
0715
172
00
16
277
16
407
797
21
9290
21
9125
-0
075
2
9423
176
00
19
176
19
271
498
21
8920
21
8803
-0
053
2
8317
180
00
22
065
22
153
400
21
8620
21
8516
-0
048
2
7257
184
00
24
952
25
033
325
21
8360
21
8268
-0
042
2
6265
188
00
27
831
27
897
237
21
8120
21
8048
-0
033
2
5348
192
00
30
702
30
756
178
21
7910
21
7852
-0
027
4898
196
00
33
558
33
604
139
21
7720
21
7672
-0
022
4738
146
00
1
313
1
383
5
358
22
8730
22
8636
-0
041
2
9682
140
00
1
226
1
278
4
205
23
5700
23
5643
-0
024
2
4063
150
00
4
670
4
690
427
22
8240
22
8215
-0
Oil
2
8326
154
00
7
946
8
000
674
22
7820
22
7755
-0
028
2
7080
158
00
11
174
11
248
671
22
7390
22
7303
-0
038
2
6005
87
Data from Goodwin [38] (continued)
T P.exp P.cal Dev p.exp p.cal
K MPa MPa % mol-dm'^ mol-dm'^
Dev
Wt
162
.00
14,
,381
14,
.461
0,
,559
22,
,6980
22
.6890
-0,
.040
2
.5038
166,
.00
17,
,571
17,
.649
0,
,444
22,
,6600
22
.6516
-0,
.037
2
.4150
170,
.00
20,
,755
20
.825
0,
,335
22,
,6260
22
.6188
-0,
.032
2
.3320
174,
.00
23,
,933
23,
.993
0.
,250
22,
,5960
22
.5900
-0,
.027
2,
.2539
178.
,00
27,
,111
27,
.157
0.
,170
22,
, 5700
22,
.5655
-0,
.020
2,
.1800
182,
.00
30,
,277
30,
,302
0,
,082
22,
,5460
22,
.5436
-0,
.010
2,
.1112
186,
,00
33,
,428
33,
,440
0.
.035
22,
,5250
22
.5239
-0,
.005
2,
.0461
144,
,00
4,
,891
4,
,882
-0.
,181
23,
,5180
23,
.5189
0,
.004
2,
.3137
148,
,00
8,
,450
8,
,476
0.
.311
23,
,4720
23
.4693
-0
.011
2,
.2280
152,
,00
11,
,953
12,
,005
0.
,438
23,
,4260
23,
.4208
-0,
.022
2,
.1526
156,
,00
15.
.435
15,
,499
0.
.414
23,
,3830
23,
.3769
-0,
.026
2,
.0832
160,
,00
18,
.907
18,
,962
0.
.291
23.
,3430
23,
.3379
-0,
.022
2,
.0189
164,
,00
22.
.376
22,
,419
0.
.192
23.
,3080
23,
.3041
-0,
,017
1,
,9573
168,
,00
25,
,844
25,
,877
0.
.128
23,
,2780
23,
.2751
-0,
,012
1,
,8981
172,
,00
29.
.304
29,
,330
0,
.090
23.
.2520
23,
.2498
-0,
,010
1,
,8416
176,
,00
32.
.758
32,
,760
0.
.005
23.
,2280
23,
.2279
-0,
,001
1,
,7886
134,
,00
0.
,686
0,
,773
12.
.615
24.
,1830
24,
,1747
-0,
,034
27,
,0410
138,
,00
4.
,638
4,
,625
-0.
,286
24.
,1250
24,
,1262
0,
,005
1.
,9628
142,
,00
8.
,463
8,
,494
0.
,370
24.
,0760
24,
,0732
-0,
,012
1.
,8992
146,
,00
12.
,224
12,
,286
0.
,505
24.
,0270
24,
,0216
-0,
,022
1.
.8431
150,
.00
15.
,966
16,
,035
0.
.434
23,
.9810
23,
,9751
-0,
,024
1,
.7911
154,
.00
19.
,704
19,
,770
0.
.335
23.
,9400
23,
,9346
-0,
,023
1,
.7413
134,
.00
0.
,584
0,
,679
16,
.256
24.
.1740
24,
,1648
-0.
,038
27,
.1442
136,
.00
2.
,577
2,
,572
-0.
.207
24.
. 1410
24,
,1415
0.
,002
2,
.0050
138
.00
4.
,526
4,
,517
-0.
.185
24.
.1150
24,
,1158
0.
.003
1.
,9707
140
.00
6.
,451
6,
,454
0.
.049
24.
.0900
24,
.0897
-0.
,001
1.
,9380
142
.00
8.
,335
8,
,383
0,
.578
24,
,0660
24.
.0617
-0,
,018
1.
9066
144
.00
10,
.213
10,
,292
0.
,773
24.
.0420
24.
.0350
-0.
,029
1.
,8771
146
.00
12,
.094
12,
,171
0,
,632
24,
.0170
24,
.0103
-0,
,028
1.
,8501
148
.00
13,
.970
14,
,053
0,
.594
23.
.9940
23,
.9869
-0,
,030
1.
,8232
150
.00
15,
.837
15,
.917
0.
.500
23,
.9710
23,
.9643
-0.
,028
1.
7977
152
.00
17
.705
17,
.785
0,
.451
23.
.9500
23,
.9433
-0.
028
1.
7722
154
.00
19
.575
19
.660
0.
.437
23,
,9310
23,
,9240
-0.
,029
1.
7468
156
.00
21,
.442
21,
.518
0,
.357
23,
,9120
23,
,9058
-0.
026
1.
7226
158
.00
23
.289
23
.359
0,
,303
23.
,8930
23.
,8874
-0.
024
1.
6996
88
Data from Goodwin [38] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm"^ rool-dm"^
Dev
Wt
160
.00
25
.164
25
.222
231
23
.8770
23
8724
-0
019
6758
162
.00
27
.032
27
.081
184
23
8620
23
8581
-0
016
6525
164
.00
28
896
28
.952
194
23
8490
23
8447
-0
018
6292
166
.00
30
769
30
.809
129
23
8360
23
8330
-0
013
6068
168
.00
32
639
32
665
080
23
8240
23
8220
-0
008
5848
170
.00
34
499
34
508
028
23
8120
23
8113
-0
003
5636
130
.00
729
760
4
250
24
6050
24
6023
-0
Oil
8011
132
00
2
823
2
760
-2
227
24
5720
24
5774
022
7764
134
00
4
878
4
820
-1
195
24
5460
24
5509
020
7485
136
00
6
889
6
846
-0
635
24
5190
24
5226
015
7232
138
00
8
864
8
874
111
24
4940
24
4932
-0
003
6982
140
00
10
843
10
880
348
24
4690
24
4660
-0
012
6746
142
00
12
818
12
852
272
24
4430
24
4402
-0
Oil
6530
144
00
14
786
14
829
290
24
4190
24
4156
-0
014
6314
146
00
16
752
16
796
267
24
3960
24
3925
-0
014
6103
148
00
18
722
18
757
185
24
3740
24
3714
-0
Oil
5898
150
00
20
692
20
724
153
24
3540
24
3516
-0
010
5691
152
00
22
664
22
685
091
24
3350
24
3335
-0
006
5489
154
00
24
612
24
641
120
24
3170
24
3148
-0
009
5291
156
00
26
591
26
608
064
24
3010
24
2998
-0
005
5091
158
00
28
567
28
570
012
24
2860
24
2858
-0
001
4894
160
00
30
546
30
545
-0
002
24
2730
24
2730
000
4697
162
00
32
515
32
505
-0
033
24
2600
24
2607
003
4507
164
00
34
492
34
464
-0
083
24
2480
24
2500
008
4319
126
00
479
549
14
402
24
9960
24
9905
-0
022
21
6203
128
00
2
674
2
617
-2
151
24
9600
24
9645
018
6028
130
00
4
828
4
774
-1
109
24
9330
24
9371
017
5799
132
00
6
944
6
894
-0
719
24
9050
24
9088
015
5591
134
00
9
021
9
017
-0
044
24
8790
24
8793
001
5384
136
00
11
090
11
102
105
24
8520
24
8511
-0
003
5196
138
00
13
149
13
176
209
24
8260
24
8240
-0
008
5012
140
00
15
205
15
241
239
24
8010
24
7984
-0
Oil
4834
142
00
17
262
17
296
200
24
7770
24
7745
-0
010
4659
144
00
19
322
19
343
109
24
7540
24
7525
-0
006
4488
146
00
21
386
21
411
119
24
7340
24
7322
-0
007
4311
89
Data from Goodwin [38] (continued)
T P,exp P.cal Dev P.exp p.cal
K MPa MPa % mol-dra'^ mol-dm'^
Dev
Wt
148,
.00
23,
.459
23,
.473
0.
.058
24,
,7150
24,
.7141
-0.
.004
.4137
148,
,00
23,
.456
23,
.458
0.
,008
24,
,7140
24,
.7139
-0,
.001
.4142
150,
.00
25,
.529
25,
.529
-0,
.002
24,
.6970
24,
.6970
0,
.000
.3966
152,
.00
27,
.602
27,
.595
-0,
,026
24,
.6810
24,
.6815
0,
.002
.3793
154,
.00
29,
.668
29,
.658
-0,
.035
24,
.6660
24,
.6667
0,
.003
.3623
156,
,00
31,
.735
31,
.718
-0,
.052
24,
.6520
24,
.6531
0,
.004
.3455
158,
.00
33,
.803
33,
.776
-0,
.080
24,
.6390
24,
.6407
0,
.007
.3290
122,
.00
0.
.348
0,
.471
35,
.275
25,
.3860
25,
.3771
-0,
.035
19,
.4872
124,
.00
2,
.617
2,
.618
0,
.034
25,
,3480
25,
,3479
0,
.000
.4471
126,
.00
4,
.881
4,
.876
-0,
,116
25,
.3200
25,
,3204
0,
.002
.4283
128,
.00
7,
.036
7,
.122
1,
.213
25,
.2930
25,
.2870
-0,
.024
.4102
130,
.00
9,
.222
9,
.341
1,
.297
25,
.2660
25,
.2577
-0,
.033
.3933
132,
.00
11,
.404
11,
.535
1,
.148
25,
.2390
25,
.2301
-0,
.035
.3774
134,
.00
13,
.579
13,
.702
0,
.910
25,
.2120
25,
.2037
-0,
,033
.3624
134,
.00
13.
.581
13,
.687
0,
.780
25,
.2110
25,
.2038
-0,
.028
.3629
136,
.00
15,
.717
15,
.828
0,
.707
25,
.1840
25,
.1766
-0,
,029
.3487
138,
.00
17,
.880
17,
.989
0,
.610
25,
.1600
25,
.1528
-0,
.029
,3339
140,
.00
20,
.043
20,
.141
0,
.487
25,
.1370
25,
.1306
-0,
.025
.3193
142,
.00
22,
.214
22,
.299
0,
.381
25,
.1160
25,
.1105
-0,
.022
.3046
144,
.00
24,
.387
24,
.466
0,
.326
25,
.0970
25,
.0919
-0,
.020
.2897
146,
.00
26,
.564
26,
.642
0,
.294
25,
.0800
25,
.0751
-0,
.020
.2745
148,
.00
28,
.746
28,
.814
0,
.236
25,
.0640
25,
.0598
-0,
.017
.2596
150,
.00
30,
.928
30,
.982
0,
.173
25,
.0490
25,
.0457
-0,
.013
.2449
152,
.00
33,
.099
33,
.146
0,
.143
25,
.0350
25,
.0321
-0,
.012
.2304
154,
.00
35,
.273
35,
.308
0,
.101
25,
.0220
25,
.0199
-0,
.009
.0081
118,
.00
0,
.474
0,
.575
21,
.302
25,
.7770
25,
.7703
-0,
.026
17,
.5736
120
.00
2,
.849
2,
.830
-0,
.649
25,
.7390
25,
.7402
0,
.005
.3061
122
.00
5,
.181
5,
.192
0,
.204
25,
.7100
25,
.7093
-0,
.003
.2907
124,
.00
7,
.430
7,
.540
1,
.482
25,
.6820
25,
.6749
-0.
.028
.2760
126
.00
9,
.720
9,
.860
1,
.446
25,
.6540
25.
.6451
-0.
.035
.2622
128
.00
12,
.001
12,
.135
1,
.118
25,
.6250
25,
.6166
-0.
.033
,2497
130
.00
14,
.285
14,
.413
0,
.902
25,
.5980
25.
.5900
-0.
.031
,2371
132
.00
16,
.555
16,
,712
0,
.948
25,
.5740
25.
,5643
-0.
.038
,2239
134
.00
18
.832
18,
.984
0,
.808
25.
.5500
25.
.5407
-0.
.036
2113
136
.00
21
.106
21,
.196
0,
.426
25,
.5240
25.
,5186
-0.
,021
2002
90
Data from Goodwin [38] (continued)
T P.exp P.cal Dev P.exp p,cal
K MPa MPa % mol-dm'^ mol-dm'^
Dev
Wt
138
.00
23
.385
23
.465
.340
25
.5030
25
.4983
-0
.019
1
.1877
138
.00
23
.345
23
.465
.516
25
.5030
25
.4958
-0
.028
1
.1877
140
.00
25
.633
25
.743
.427
25
.4840
25
.4775
-0
.025
1
.1749
142
.00
27
.933
28
.014
.288
25
.4660
25
.4613
-0
.018
1
.1623
144
.00
30
.221
30
.296
.248
25
.4500
25
.4457
-0
.017
1
.1495
146
.00
32
.523
32
.574
.157
25
.4350
25
.4321
-0
.011
1
.1369
148
.00
34
815
34
866
.146
25
.4220
25
.4191
-0
Oil
1
.1240
114
.00
411
446
8
623
26
.1420
26
.1398
-0
008
16
.0215
116
.00
2
890
2
794
-3
317
26
.1030
26
.1088
022
1
.1919
118
00
5
297
5
240
-1
070
26
.0720
26
.0754
013
1
.1795
120
00
7
636
7
705
908
26
0440
26
.0399
-0
016
1
1668
122
00
10
016
10
106
892
26
0140
26
.0087
-0
020
1
1557
124
00
12
393
12
491
795
25
9850
25
.9792
-0
022
1
1449
126
00
14
766
14
846
547
25
9560
25
.9513
-0
018
1
1348
128
00
17
134
17
205
417
25
9290
25
9249
-0
016
1
1245
130
00
19
512
19
569
292
25
9040
25
9008
-0
012
1
1140
132
00
21
896
21
940
203
25
8810
25
8785
-0
010
1
1033
132
00
21
853
21
922
314
25
8800
25
8761
-0
015
1
1037
134
00
24
244
24
300
232
25
8590
25
8559
-0
012
1
0928
136
00
26
644
26
688
165
25
8400
25
8376
-0
009
1
0816
138
00
29
047
29
068
071
25
8220
25
8209
-0
004
1
0706
140
00
31
458
31
479
067
25
8070
25
8059
-0
004
1
0591
142
00
33
859
33
866
020
25
7920
25
7916
-0
001
1
0480
110
00
594
672
13
244
26
5190
26
5145
-0
017
14
5524
112
00
3
184
3
134
-1
578
26
4800
26
4828
Oil
1
0832
114
00
5
644
5
703
1
033
26
4490
26
4458
-0
012
1
0727
116
00
8
105
8
256
1
857
26
4190
26
4107
-0
031
1
0626
118
00
10
587
10
757
1
607
26
3880
26
3787
-0
035
1
0536
120
00
13
066
13
224
1
211
26
3570
26
3484
-0
033
1
0451
122
00
15
540
15
676
874
26
3270
26
3197
-0
028
1
0369
124
00
18
015
18
132
645
26
2990
26
2928
-0
023
1
0284
126
00
20
498
20
612
557
26
2740
26
2680
-0
023
1
0194
128
00
22
989
23
099
476
26
2510
26
2453
-0
022
1
0103
130
00
25
491
25
594
406
26
2300
26
2246
-0.
020
1
0009
132
00
28
002
28
100
347
26
2110
26
2060
-0.
019
9913
91
Data from Goodwin [38] (continued)
T P.exp P.cal Dev p.exp p.cal
K MPa MPa % mol-dm"^ mol-dm'^
Dev
Wt
134
.00
30,
.521
30,
,597
0.
.247
26,
.1930
26,
.1892
-0,
.015
0,
.9818
134,
.00
30,
.497
30,
.577
0.
,263
26,
.1920
26,
.1879
-0
.016
0,
.9821
136,
.00
33,
.019
33,
.086
0,
,206
26,
.1760
26,
.1726
-0,
.013
0,
.9724
106,
.00
1,
.202
1,
.190
-1.
,023
26,
.9010
26,
.9016
.002
0,
.9905
108,
.00
3,
.899
3,
.809
-2,
,291
26,
.8640
26,
.8686
.017
0,
.9830
110,
.00
6,
.459
6,
.507
0,
.749
26,
.8330
26,
.8305
-0,
.009
0,
.9741
112,
.00
9,
.030
9,
.150
1.
,324
26,
.8010
26,
.7949
-0
.023
0,
.9662
114,
,00
11,
,612
11,
.735
1,
.056
26,
.7680
26
.7618
-0
.023
0,
.9592
116,
.00
14,
,187
14,
.303
0,
,817
26,
.7360
26,
.7302
-0
.022
0,
,9524
118,
.00
16.
,765
16,
,875
0,
,652
26,
. 7060
26,
.7006
-0
.020
0,
.9455
120,
,00
19.
,354
19,
.471
0,
,606
26,
.6790
26,
.6732
-0,
.022
0,
.9380
122,
.00
21.
.954
22,
,054
0,
.452
26,
.6530
26,
.6482
-0
.018
0,
.9307
124.
,00
24.
,582
24,
,664
0,
,333
26,
.6300
26,
.6260
-0,
.015
0,
.9229
124,
,00
24,
,568
24,
.684
0,
,475
26,
.6310
26,
.6254
-0,
.021
0,
.9226
126,
,00
27.
,205
27,
,304
0,
,364
26,
.6100
26,
.6053
-0,
.018
0,
.9146
128,
,00
29,
,851
29,
.955
0,
,349
26,
.5920
26,
.5871
-0,
.019
0,
.9060
130,
.00
32.
,502
32,
.576
0,
,228
26,
.5740
26,
.5705
-0,
.013
0,
.8979
132.
,00
35,
,142
35,
.232
0,
,256
26,
.5590
26,
.5548
-0,
.016
0,
.0059
102.
,00
0,
,847
0,
.888
4,
,818
27,
.2320
27,
.2300
-0,
.007
0,
.9166
104,
,00
3,
,649
3,
.565
-2,
,295
27,
.1920
27.
.1961
0,
.015
0,
.9108
106,
.00
6,
.303
6,
,367
1,
,008
27,
.1600
27,
.1569
-0,
.011
0,
.9031
108,
.00
8,
.951
9,
.109
1.
,756
27,
.1270
27,
.1195
-0,
.028
0,
.8963
110,
.00
11,
.622
11,
.790
1,
,447
27,
.0930
27,
.0850
-0
.029
0,
.8904
112,
.00
14,
.294
14,
.453
1,
,113
27,
.0600
27,
.0525
-0,
.028
0,
,8847
114,
.00
16,
.961
17,
.119
0,
,931
27,
.0290
27,
.0216
-0,
.027
0,
,8788
116
.00
19,
.648
19,
.812
0,
,833
27,
.0010
26,
.9934
-0,
.028
0.
,8724
116
.00
19,
.647
19,
.812
0,
,838
27,
.0010
26,
.9934
-0,
.028
0.
,8724
118
.00
22,
.357
22,
.532
0,
,785
26,
.9760
26,
.9679
-0,
.030
0.
,8656
120
.00
25,
.086
25,
.239
0,
,608
26,
.9520
26,
.9450
-0,
.026
0,
,8589
122
.00
27
.828
27,
.977
0,
,535
26,
.9310
26,
.9243
-0,
,025
0.
,8518
124
.00
30
.590
30,
.725
0,
,442
26,
.9120
26,
.9059
-0,
.023
0,
,8444
126
.00
33
.342
33,
.486
0,
,432
26,
.8950
26,
.8886
-0,
.024
0.
,8369
98
.00
1
.244
1,
.232
-0,
,913
27,
.5880
27,
.5885
0,
.002
0.
,8411
100
.00
4
.141
4,
.034
-2,
,568
27,
.5480
27,
.5528
0,
,017
0.
,8361
102
.00
6
.870
6,
.970
1,
,467
27,
.5160
27,
.5115
-0,
,016
0.
,8294
104
.00
9
.627
9
.797
1,
,765
27,
.4810
27.
.4734
-0.
,027
0.
8241
92
Data from Goodwin [38] (continued)
T P , exp P , cal Dev p , exp p , cal Dev
K MPa MPa % rool-dm"^ mol-dm'^ %
106.00 12.400 12.603 1.638 27.4470 27.4380 -0.033
108.00 15.176 15.367 1.264 27.4130 27.4046 -0.031
110.00 17.965 18.158 1.075 27.3820 27.3736 -0.031
112.00 20.779 20.954 0.839 27.3530 27.3454 -0.028
114.00 23.615 23.803 0.796 27.3280 27.3199 -0.030
116.00 26.475 26.660 0.698 27.3050 27.2971 -0.029
116.00 26.489 26.660 0.644 27.3050 27.2977 -0.027
118.00 29.361 29.551 0.647 27.2850 27.2770 -0.029
120.00 32.245 32.430 0.576 27.2660 27.2582 -0.029
94.00 0.751 0.722 -3.843 27.9000 27.9012 0.004
96.00 3.752 3.604 -3.930 27.8580 27.8643 0.022
98.00 6.552 6.650 1.496 27.8250 27.8209 -0.015
100.00 9.406 9.578 1.828 27.7890 27.7818 -0.026
102.00 12.273 12.460 1.531 27.7530 27.7452 -0.028
104.00 15.138 15.345 1.368 27.7190 27.7104 -0.031
Wt
0.8190
0.8143
0.8092
0.8039
0.7980
0.7919
0.7919
0.7854
0.7790
0.7844
0.7804
0.7745
0.7699
0.7658
0.7615
106.00
108.00
110.00
112.00
114.00
18.022
20.935
23.873
26.839
29.826
18.210
21.128
24.053
27.036
30.028
1.042
0.922
0.755
0.731
0.678
27.6860
27.6570
27.6300
27.6070
27.5860
27.6783
27.6491
27.6227
27.5991
27.5779
■0.028
•0.029
■0.027
■0.029
■0.029
0.7574
0.7526
0.7477
0.7421
0.7365
116.00
92.00
94.00
96.00
98.00
32.835
4.412
7.285
10.254
13.235
33.033
4.258
7.428
10.443
13.459
0.603
■3.488
1.954
1.840
1.689
27.5670
28.2090
28.1750
28.1370
28.1010
27.5591
28.2151
28.1694
28.1296
28.0923
■0.029
0.022
■0.020
■0.026
■0.031
0.7306
0.7184
0.7135
0.7101
0.7065
100.00
100.00
102.00
104.00
106.00
108.00
110.00
112.00
94.00
96.00
16.218
16.219
19.224
22.269
25.355
28.464
31.602
34.753
12.813
15.889
16.451
16.451
19.473
22.500
25.587
28.708
31.868
35.013
13.088
16.157
1.437
1.431
1.293
1.039
0.913
0.859
0.842
0.750
2.141
1.682
28.0660
28.0660
28.0340
28.0040
27.9780
27.9550
27.9350
27.9160
28.3910
28.3540
28.0570
28.0570
28.0244
27.9951
27.9692
27.9458
27.9250
27.9063
28.3808
28.3441
■0.032
■0.032
■0.034
■0.032
■0.032
■0.033
■0.036
■0.035
■0.036
■0.035
0.7030
0.7030
0.6992
0.6953
0.6908
0.6859
0.6807
0.6756
0.6644
0.6617
93
Data from Goodwin [38] (continued)
T P.exp P.cal Dev p.exp p,cal
K MPa MPa % mol-dra""' mol-dm"'^
Dev
Wt
98,
.00
18,
.989
19,
.282
1,
.545
28,
,3210
28,
.3102
-0,
.038
0,
,6584
100,
,00
22,
.134
22,
.412
1,
,256
28,
,2900
28,
,2798
-0,
,036
0.
.6550
102,
.00
25,
.322
25,
.631
1,
,219
28,
,2640
28,
,2528
-0,
,040
0,
.6508
104,
.00
28,
.544
28,
.859
1,
,102
28,
,2400
28,
,2287
-0,
,040
0,
,6465
106,
.00
31,
.805
32,
.125
1,
,006
28,
,2190
28.
,2075
-0,
,041
0,
,6419
108,
.00
35,
.057
35,
.404
0,
,991
28,
,2000
28,
,1877
-0,
,044
0,
.0042
96,
.50
22,
.494
22,
.708
0,
,954
28,
,5520
28,
,5445
-0,
,026
0,
,6194
97,
.00
23,
.313
23,
.534
0,
,950
28,
.5450
28,
.5373
-0,
,027
0,
,6185
98,
.00
24,
.964
25,
.177
0,
,850
28,
.5310
28,
.5236
-0,
.026
0,
,6168
100,
.00
28,
.284
28,
.539
0,
,902
28,
.5070
28,
.4982
-0,
.031
0,
,6128
100,
.00
28,
.293
28
.539
0,
,869
28,
.5070
28,
.4985
-0,
.030
0,
,6128
102,
,00
31,
.643
31
.942
0,
,943
28,
.4860
28,
.4758
-0,
.036
0,
,6085
104,
.00
35,
.009
35
.327
0,
,908
28
.4660
28,
.4552
-0,
.038
0,
,0040
Number of Points (Ref. 38) 554
PRESSURE:
AAD-%
0.717
BIAS-%
0.585
RMS-%
2.258
AAD
0.060
BIAS
0.055
RMS
0.071
MPa
DENSITY :
AAD-%
0.117
BIAS-%
-0.112
RMS-%
0.170
AAD
0.012
BIAS
-0.012
RMS
0.012
mol • dm" ^
Data from Goodwin [39]
T
P.exp
P,cal
Dev
P.exp
^,cal
Dev
Wt
K
MPa
MPa
%
mol • dm" ^
mol •dm""'
%
150,
.00
1.026
1.025
-0.054
1.0000
1.0007
0.069
52,
.0934
155,
,00
1.074
1.074
-0.029
1.0000
1.0004
0.036
49
.2938
160,
,00
1.122
1.122
-0.014
1.0000
1.0002
0.017
46,
.8494
165,
,00
1.170
1.170
-0.004
1.0000
1.0000
0.004
44,
.6701
170,
,00
1.217
1.217
0.019
1.0000
0.9998
-0.022
42
.7086
175,
,00
1.263
1.264
0.032
1.0000
0.9996
-0.038
40,
.9250
180,
,00
1.310
1.310
0.049
1.0000
0.9994
-0.056
39
.2963
185,
,00
1.356
1.357
0.055
1.0000
0.9994
-0.063
37,
.7994
190,
,00
1.402
1.403
0.061
1.0000
0.9993
-0.069
36,
.4197
195,
,00
1.448
1.449
0.068
1.0000
0.9992
-0.077
35,
.1437
94
Data from Goodwin [39] (continued)
T
P.exp
P,cal
Dev
p.exp
p.cal
Dev
Wt
K
MPa
MPa
%
mol-dm"^
ntol • dm" ^
%
200.00
1.494
1.495
0.071
1.0000
0.9992
-0.079
33
9585
205.00
1.539
1.540
0.071
1.0000
0.9992
-0.079
32
8545
210.00
1.585
1.586
0.063
1.0000
0.9993
-0.069
31
8223
215.00
1.631
1.632
0.060
1.0000
0.9993
-0.066
30
8569
220.00
1.676
1.677
0.052
1.0000
0.9994
-0.057
29
9501
225.00
1.722
1.722
0.044
1.0000
0.9995
-0.048
29
0973
230.00
1.767
1.767
0.038
1.0000
0.9996
-0.041
28
2939
235.00
1.812
1.813
0.033
1.0000
0.9996
-0.036
27
5355
240.00
1.857
1.858
0.024
1.0000
0.9997
-0.026
26
8176
245.00
1.902
1.903
0.018
1.0000
0.9998
-0.020
26
1377
250.00
1.947
1.948
0.009
1.0000
0.9999
-0.010
25
4921
255.00
1.992
1.992
0.003
1.0000
1.0000
-0.003
24
8789
260.00
2.037
2.037
-0.001
1.0000
1.0000
0.001
24
2957
265.00
2.082
2.082
-0.007
1.0000
1.0001
0.007
23
7397
270.00
2.127
2.127
-0.015
1.0000
1.0002
0.016
1160
170.00
2.062
2.067
0.260
2.0000
1.9921
-0.393
27
5425
175.00
2.166
2.172
0.276
2.0000
1.9920
-0.400
25
8633
180.00
2.270
2.276
0.277
2.0000
1.9922
-0.389
24
4071
185.00
2.372
2.378
0.272
2.0000
1.9926
-0.371
23
1233
190.00
2.474
2.480
0.262
2.0000
1.9930
-0.349
21
9789
195.00
2.575
2.581
0.254
2.0000
1.9934
-0.330
20
9509
200.00
2.675
2.681
0.240
2.0000
1.9939
-0.306
20
0206
205.00
2.775
2.781
0.223
2.0000
1.9944
-0.281
19
1741
210.00
2.874
2.880
0.207
2.0000
1.9949
-0.256
18
4006
215.00
2.973
2.978
0.187
2.0000
1.9955
-0.227
17
6899
220.00
3.072
3.077
0.166
2.0000
1.9960
-0.200
17
0351
225.00
3.170
3.174
0.145
2 . 0000
1.9965
-0.173
16
4292
230.00
3.268
3.272
0.127
2.0000
1.9970
-0.150
15
8672
235.00
3.365
3.369
0.107
2.0000
1.9975
-0.124
15
3439
240.00
3.463
3.466
0.085
2.0000
1.9980
-0.099
14
8554
245.00
3.560
3.563
0.066
2.0000
1.9985
-0.076
14
3984
250.00
3.657
3.659
0.050
2.0000
1.9989
-0.057
13
9699
255.00
3.754
3.755
0.034
2.0000
1.9992
-0.039
13
5672
260.00
3.850
3.851
0.020
2.0000
1.9996
-0.022
13
1879
265.00
3.947
3.947
0.006
2.0000
1.9999
-0.006
12
8300
270.00
4.043
4.042 -0.006 2.0000 2.0001
0.007
0.0625
95
Data from Goodwin [39] (continued)
Number of Points (Ref. 39)
PRESSURE: AAD-%
AAD
DENSITY : AAD-%
AAD
46
0.091 BIAS-%
0.002 BIAS
0.114 BIAS-%
0.002 BIAS
0.085 RMS-%
0.002 RMS
■0.108 RMS-%
■0.002 RMS
0.095
0.002 MPa
0.130
0.003 mol-dm'3
Data from Kleinrahm et al. [7]
T P,exp P.cal
K MPa MPa
Dev p , exp p , cal
% mol • dm" ^ rool • dm" ^
Dev
Wt
180,
.00
3.
,286
3,
.286
0.000
3,
.8273
3,
.8272
-0.001
1
.4536
180,
.00
3.
,282
3,
.282
0.001
3,
.8140
3
.8139
-0.002
1,
.4542
182,
.00
3,
,508
3,
.508
0.007
4,
.2332
4,
.2323
-0.022
1,
.3828
184,
.00
3,
,741
3,
.742
0.016
4,
.7252
4,
.7223
-0.060
1,
.3163
186.
.00
3.
,986
3,
.987
0.022
5,
.3386
5,
.3329
-0.106
1,
.2529
186,
.00
3.
.989
3,
.981
-0.184
15,
.2634
15,
.2826
0.125
.7225
186,
.00
3,
,989
3,
.982
-0.184
15,
.2647
15,
.2838
0.125
0,
.7219
187,
.00
4.
,114
4,
.115
0.022
5,
.7225
5,
.7149
-0.133
1,
.2218
188,
.00
4.
,246
4,
.247
0.020
6,
.1997
6,
.1897
-0.161
1,
.1906
188,
.00
4.
,245
4,
.246
0.020
6,
.1893
6,
.1796
-0.157
1,
.1907
189,
.00
4,
,381
4,
.382
0.014
6,
.8197
6,
.8077
-0.175
1,
.1590
189,
.00
4.
.381
4,
.382
0.014
6,
.8158
6,
.8040
-0.172
1,
.1590
189,
.00
4,
,380
4,
.381
0.014
6,
.8030
6,
.7915
-0.169
1,
.1591
189,
.00
4,
.383
4,
.377
-0.118
13,
.5833
13,
.6338
0.372
1,
.1076
189,
.00
4.
.380
4,
.381
0.014
6,
.8028
6,
.7911
-0.171
1,
.1591
189,
.00
4.
.383
4,
.378
-0.119
13,
.5905
13,
.6406
0.368
1,
.1064
189,
.00
4,
.380
4,
.381
0.014
6,
.7987
6.
.7875
-0.165
1,
.1591
189,
.00
4,
.385
4,
.379
-0.118
13,
.6039
13.
.6526
0.358
1.
.1040
189,
.00
4,
.379
4,
.380
0.014
6,
.7843
6,
.7735
-0.160
1.
.1592
189
.00
4,
.386
4,
.381
-0.116
13.
.6144
13.
.6617
0.348
1,
.1022
189,
.00
4,
.379
4,
.380
0.014
6,
.7838
6.
.7729
-0.161
1.
,1592
189,
.00
4,
.379
4,
.380
0.014
6,
.7823
6,
.7715
-0.160
1.
.1592
189,
.00
4,
.379
4,
.379
0.014
6,
.7688
6.
.7583
-0.156
1.
,1593
189,
.00
4,
.378
4,
.379
0.014
6,
,7665
6.
,7556
-0.160
1.
,1593
189,
.00
4,
.378
4,
.378
0.013
6,
.7543
6,
,7442
-0.149
1.
,1593
96
Data from Kleinrahm et al. [7] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm'^ mol-dm'^
Dev
Wt
189
.00
4.377
4.378
0.014
6
.7486
6
.7384
-0.150
1
1594
189
.00
4.376
4.377
0.014
6
.7307
6
.7205
-0.150
1
1595
189
.50
4.450
4.450
0.009
7
.2303
7
.2199
-0.145
1
1429
189
.50
4.450
4.450
0.008
7
.2124
7
.2034
-0.125
1
1429
189
50
4.449
4.449
0.007
7
.1939
7
.1860
-0.109
1
1430
189
50
4.451
4.448
-0.074
13
1312
13
1832
0.396
1
1232
189
50
4.452
4.448
-0.075
13
1386
13
1902
0.393
1
1226
189
80
4.492
4.492
0.004
7
5430
7
5357
-0.098
1
1330
189
80
4.491
4.491
0.003
7
5151
7
5095
-0.073
1
1331
189
80
4.491
4.491
0.003
7
5131
7
5077
-0.071
1
1331
189
80
4.493
4.491
-0.046
12
7972
12
8460
0.382
1
1234
189
80
4.490
4.490
0.003
7
4848
7
4803
-0.060
1
1332
189
80
4.494
4.491
-0.047
12
8086
12
8566
0.375
1
1229
190
00
4.520
4.520
0.003
7
8171
7
8109
-0.079
1
1262
190
00
4.520
4.520
0.002
7
8018
7
7972
-0.058
1
1263
190
00
4.519
4.519
0.001
7
7588
7
7562
-0.034
1
1264
190
00
4.521
4.520
-0.028
12
5246
12
5673
0.341
1
1208
190
00
4.519
4.519
0.001
7
7547
7
7529
-0.023
1
1264
190
00
4.522
4.521
-0.028
12
5478
12
5888
0.326
1
1203
190
00
4.519
4.519
0.000
7
7206
7
7202
-0.005
1
1265
190
00
4.517
4.517
-0.001
7
6754
7
6765
0.014
1
1267
190
00
4.517
4.517
-0.001
7
6746
7
6761
0.020
1
1267
190
00
4.517
4.517
-0.001
7
6390
7
6409
0.025
1
1268
190
00
4.515
4.515
-0.002
7
5902
7
5934
0.042
1
1270
190
10
4.534
4.534
0.000
7
9530
7
9516
-0.018
1
1229
190
10
4.533
4.533
-0.001
7
9038
7
9056
0.024
1
1230
190
10
4.533
4.533
-0.002
7
8535
7
8579
0.057
1
1232
190
10
4.536
4.535
-0.018
12
3832
12
4172
0.275
1
1185
190
10
4.536
4.535
-0.018
12
4007
12
4339
0.268
1
1182
190
20
4.549
4.549
-0.001
8
1454
8
1492
0.047
1
1194
190
20
4.548
4.548
-0.003
8
0911
8
0998
0.107
1
1195
190
20
4.549
4.549
-0.011
12
1679
12
1958
0.230
1
1166
190
20
4.548
4.547
-0.004
8
0542
8
0661
0.147
1
1196
190
20
4.549
4.549
-0.010
12
1930
12
2179
0.204
1
1164
190
20
4.550
4.550
-0.009
12
2303
12
2521
0.178
1
1159
190
30
4.563
4.563
-0.003
8
3497
8
3653
0.187
1.
1160
97
Data from Kleinrahm et al. [7] (continued)
T
P.exp
P.cal
Dev
p.exp
p.cal
Dev
Wt
K
MPa
MPa
%
mol • dm" ^
mol • dm' ^
%
190,
.30
4.562
4.562
-0.005
8.2945
8.3159
0.259
1
.1161
190,
.30
4.563
4.563
-0.003
11.9523
11.9637
0.096
1
.1139
190,
.30
4.562
4.562
-0.005
8.2935
8.3149
0.258
1
.1161
190,
.30
4.564
4.564
-0.002
11.9815
11.9896
0.068
1
.1137
190
,30
4.562
4.562
-0.006
8.2513
8.2751
0.289
1
.1162
190,
.30
4.564
4.564
-0.002
12.0102
12.0169
0.056
1
.1135
190,
.30
4.561
4.561
-0.007
8.1952
8.2227
0.337
1
.1163
190,
.40
4.577
4.577
-0.004
8.6113
8.6423
0.360
1
.1125
190.
.40
4.577
4.577
-0.005
8.5691
8.6054
0.424
1
.1125
190.
.40
4.578
4,578
0.003
11.6797
11.6626
-0.146
1,
.1109
190.
.40
4.577
4.577
-0.005
8.5692
8.6037
0.403
1,
.1125
190.
.40
4.578
4.578
0.003
11.6847
11.6656
-0.164
1,
.1109
190.
.40
4.577
4.576
-0.005
8.5346
8.5700
0.415
1,
.1126
190.
.40
4.578
4.578
0.003
11.7123
11.6921
-0.173
1,
.1108
190.
,40
4.576
4.576
-0.007
8.4785
8.5178
0.464
1,
.1127
190.
,40
4.578
4.578
0.003
11.7585
11.7425
-0.136
1,
.1106
190.
,45
4.585
4.584
-0.004
8.8037
8.8536
0.568
1.
.1107
190.
,45
4.584
4.584
-0.005
8.7457
8.8017
0.640
1.
.1108
190.
,45
4.585
4.585
0.005
11.5101
11.4657
-0.386
1.
.1094
190.
,45
4.584
4.584
-0.007
8.6968
8.7582
0.707
1.
.1108
190.
.45
4.585
4.585
0.006
11.5532
11.5069
-0.401
1.
.1093
190.
,45
4.584
4.583
-0.009
8.6074
8.6764
0.801
1.
.1109
190.
,45
4.585
4.586
0.007
11.6058
11.5590
-0.403
1.
.1092
190.
,50
4.592
4.592
-0.003
9.0651
9.1299
0.715
1.
,1089
190.
,50
4.592
4.592
0.004
11.2133
11.1347
-0.701
1.
,1080
190.
.50
4.592
4.591
-0.004
8.9909
9.0650
0.824
1.
,1089
190.
,50
4.592
4.592
0.006
11.3065
11.2207
-0.759
1.
,1078
190.
,50
4.591
4.591
-0.006
8.9139
9.0038
1.009
1.
1090
190.
.50
4.592
4.593
0.007
11.3787
11.2962
-0.725
1.
1077
190.
,50
4.591
4.591
-0.007
8.8552
8.9428
0.989
1.
1090
190.
,50
4.592
4.593
0.008
11.4310
11.3476
-0.729
1.
1076
190.
,50
4.591
4.591
-0.009
8.7960
8.8903
1.072
1.
1091
190.
,53
4.596
4.596
-0.002
9.2923
9.3855
1.004
1.
1078
190,
53
4.596
4.596
0.004
11.0271
10.9014
-1.140
1.
1070
190.
,53
4.596
4.596
-0.004
9.1939
9.2931
1.079
1.
1078
98
Data from Kleinrahm et al. [7] (continued)
T
P.exp
P.cal
Dev
P.exp
p.cal
Dev
Wt
K
MPa
MPa
%
mol • dm" ^
mol • dm* ^
%
190
.53
4.596
4.597
0.005
11.1245
10.9995
-1.124
.1069
190
53
4.596
4.596
-0.005
9.1130
9.2232
1.210
.1079
190
.53
4.597
4.597
0.007
11.2014
11.0814
-1.071
.1068
190
53
4.596
4.595
-0.006
9.0545
9.1660
1.231
.1079
190
53
4.597
4.597
0.008
11.3041
11.1964
-0.953
1067
189
00
3.669
3.670
0.015
3.7558
3.7547
-0.031
4
1515
189
00
3.935
3.937
0.045
4.3927
4.3877
-0.113
4
0086
189
00
3.935
3.937
0.044
4.3931
4.3882
-0.111
4
0086
189
00
3.937
3.938
0.045
4.3966
4.3917
-0.112
4
0080
189
00
4.115
4.117
0.046
4.9766
4.9693
-0.147
3
9381
189
00
4.246
4.247
0.036
5.5754
5.5668
-0.154
3
8992
189
00
4.332
4.333
0.019
6.1936
6.1860
-0.123
3
8769
189
00
4.363
4.363
0.010
6.5300
6.5242
-0.088
3
8686
189
00
4.398
4.393
-0.117
13.7266
13.7680
0.301
3
5996
189
00
4.424
4.419
-0.108
13.9141
13.9447
0.220
3
4452
189
00
4.460
4.456
-0.094
14.1253
14.1465
0.150
3
2276
189
00
4.526
4.523
-0.067
14.4189
14.4303
0.079
2
8674
189
00
4.704
4.704
-0.004
14.9556
14.9561
0.003
2
1654
189
00
4.729
4.729
0.002
15.0158
15.0156
-0.002
2
0910
189
00
5.006
5.009
0.053
15.5378
15.5337
-0.027
1
5272
189
00
5.061
5.064
0.059
15.6221
15.6177
-0.028
1
4506
189
00
5.062
5.065
0.059
15.6243
15.6199
-0.029
1
4486
189
00
5.063
5.067
0.059
15.6260
15.6216
-0.028
1
4471
189
00
5.505
5.511
0.094
16.1752
16.1698
-0.034
1
0390
190
55
3.736
3.736
0.019
3.7521
3.7507
-0.038
4
0531
190
55
4.015
4.017
0.045
4.3825
4.3778
-0.107
3
9002
190
55
4.016
4.018
0.046
4.3840
4.3792
-0.109
3
9000
190
55
4.017
4.019
0.043
4.3862
4.3817
-0.101
3
8995
190
55
4.217
4.220
0.052
4.9880
4.9803
-0.155
3
8172
190
55
4.368
4.370
0.047
5.6108
5.6006
-0.182
3
7685
190
55
4.463
4.464
0.027
6.1780
6.1691
-0.144
3
7411
190
55
4.535
4.535
0.005
6.8560
6.8533
-0.039
3
7194
190
55
4.573
4.572
-0.013
7.4905
7.5055
0.201
3
7052
190
55
4.593
4.592
-0.016
8.2224
8.2710
0.591
3
6952
190
55
4.593
4.592
-0.015
8.2268
8.2745
0.580
3
6951
99
Data from Kleinrahm et al,
T P,exp P.cal
K MPa MPa
[7] (continued)
Dev p , exp p , cal
% mol • dm" ^ mol • dm" ^
Dev
Wt
190,
.55
4,
,594
4,
,593
-0.016
8,
.2945
8,
.3503
0.673
3
.6945
190,
.55
4,
,595
4,
,595
-0.015
8,
.4257
8,
.4923
0.790
3
.6934
190,
.55
4,
.597
4,
.596
-0.012
8,
.5869
8
.6570
0.816
3
.6924
190.
.55
4.
,598
4,
.597
-0.008
8,
.7544
8
.8219
0.771
3
.6916
190,
.55
4.
,599
4,
.599
0.000
9,
,3499
9,
.3421
-0.084
3
.6898
190.
,55
4.
,600
4,
.600
0.001
9,
.8684
9,
.7154
-1.550
3
.6889
190,
,55
4.
,600
4,
.600
0.001
10,
.4590
10,
.0083
-4.309
3
.6882
190,
.55
4.
.600
4,
.600
0.003
10,
.5041
9.
.7155
-7.507
3
.6881
190,
.55
4.
,600
4.
.600
0.003
10,
.7635
10.
.5900
-1.612
3
.6877
190,
.55
4.
,601
4.
.601
0.009
11,
,3080
11.
,1972
-0.979
3
.6857
190,
.55
4.
,601
4.
.601
0.010
11,
,3083
11.
.1972
-0.982
3
.6857
190,
.55
4.
,601
4.
.601
0.009
11.
,3101
11.
.2030
-0.947
3
.6857
190,
,55
4,
.606
4.
.607
0.016
11.
.8901
11,
.8407
-0.415
3
.6777
190,
.55
4.
.609
4.
.610
0.018
12.
.0818
12,
.0438
-0.315
3
.6714
190,
.55
4.
.627
4.
.628
0.009
12.
,5952
12,
.5864
-0.069
3
.6302
190,
.55
4.
.672
4.
.672
-0.003
13.
.1974
13.
.1987
0.009
3
.4780
190,
,55
4.
.764
4.
.764
-0.002
13.
.8216
13.
.8222
0.004
3
.0837
190,
,55
4.
.896
4.
.896
0.010
14.
.3460
14.
.3444
-0.011
2
.5578
190,
,55
4.
,925
4.
.926
0.017
14.
.4376
14,
.4351
-0.017
2
.4568
190,
,55
5.
.135
5.
.137
0.044
14.
.9548
14,
.9502
-0.031
1,
.8966
190,
,55
5.
.441
5.
.444
0.066
15.
.4796
15,
,4744
-0.034
1,
.4155
190.
,55
5.
,442
5.
.445
0.066
15.
.4813
15,
.4761
-0.034
1,
.4141
190.
,55
5.
,442
5.
.446
0.067
15.
.4818
15,
.4766
-0.034
1,
.4137
190.
,55
5.
,977
5.
.981
0.073
16.
.1186
16,
.1142
-0.027
0,
.9846
193.
,00
3.
,839
3.
.840
0.017
3.
.7459
3,
.7447
-0.032
3,
.9082
193.
,00
4.
,140
4.
.142
0.044
4,
.3693
4.
,3650
-0.098
3,
.7420
193.
,00
4.
.141
4.
.143
0.045
4,
,3708
4.
,3665
-0.099
3,
.7417
193.
,00
4.
,141
4.
.143
0.045
4.
.3710
4.
,3666
-0.100
3,
.7416
193.
,00
4.
.368
4.
.371
0.060
4.
.9772
4.
,9692
-0.160
3.
.6437
193.
.00
4.
.543
4.
.546
0.061
5.
,5930
5.
,5816
-0.204
3.
.5816
193.
,00
4.
.663
4.
.665
0.051
6.
.1558
6.
,1426
-0.214
3.
.5437
193.
.00
4.
.769
4.
,771
0.030
6.
,8657
6.
.8539
-0.172
3.
,5095
193,
.00
4.
.835
4.
,835
0.003
7.
,5080
7.
,5063
-0.023
3.
,4856
193,
.00
4.
.880
4.
.879
-0.018
8.
,1773
8,
,1939
0.203
3.
.4651
193.
.00
4.
,906
4.
,904
-0.030
8.
,7009
8.
.7366
0.410
3.
,4513
100
Data from Kleinrahra et al. [7] (continued)
T
P.exp
P.cal
Dev
p.exp
p.cal
Dev
Wt
K
MPa
MPa
%
mol • dm' ^
mol • dm" ^
%
193
.00
4.928
4.926
-0.032
9.2741
9.3200
0.495
3
4375
193
.00
4.930
4.928
-0.034
9.3316
9.3806
0.525
3
4361
193
00
4.944
4.942
-0.026
9.7518
9.7913
0.406
3
.4261
193
.00
4.954
4.953
-0.015
10.0802
10.1024
0.221
3
4180
193
.00
4.968
4.968
-0.001
10.5090
10.5104
0.014
3
4057
193
.00
4.996
4.997
0.023
11.2215
11.1975
-0.214
3
3760
193
.00
4.996
4.998
0.025
11.2217
11.1956
-0.233
3
.3760
193
00
4.997
4.998
0.025
11.2253
11.1994
-0.230
3
3758
193
00
5.029
5.031
0.037
11.8110
11.7831
-0.236
3
3303
193
00
5.042
5.044
0.043
11.9880
11.9596
-0.237
3
3094
193
00
5.089
5.091
0.046
12.4960
12.4747
-0.170
3
2159
193
00
5.173
5.175
0.048
13.1022
13.0878
-0.110
3
0004
193
00
5.330
5.333
0.056
13.8020
13.7915
-0.076
2
5546
193
00
5.522
5.526
0.064
14.3568
14.3483
-0.059
2
0887
193
00
5.522
5.526
0.068
14.3570
14.3479
-0.063
2
0885
193
00
5.816
5.820
0.066
14.9440
14.9376
-0.043
1
5960
193
00
6.109
6.113
0.060
15.3769
15.3721
-0.031
1
2821
193
00
6.123
6.127
0.061
15.3958
15.3909
-0.032
1
2697
193
00
6.123
6.127
0.070
15.3963
15.3907
-0.036
1
2694
193
00
6.127
6.130
0.063
15.4002
15.3953
-0.032
1
2668
193.00 6.704 6.707 0.042 16.0263 16.0237
Number of Points (Ref.7) 187
-0.016
0.9138
PRESSURE:
AAD-%
0.026
BIAS-%
0.005
RMS-%
0.041
AAD
0.001
BIAS
0.000
RMS
0.002
MPa
DENSITY :
AAD-%
0.347
BIAS-%
-0.043
RMS-%
0.766
AAD
0.035
BIAS
-0.005
RMS
0.079
mol • dm" ^
101
Data from Kvalnes and Gaddy [40]
T P,exp P.cal Dev p , exp p.cal
K MPa MPa % mol-dm"^ mol-dm'^
Dev
Wt
203,
.08
0.101
.101
-0.022
0.0604
0.0604
0.023
0.2381
223
.25
0.101
.101
0.079
0.0549
0.0548
-0.080
0.2378
248
.18
0.101
0,
.101
0.051
0.0493
0.0493
-0.051
0.2377
273
.15
0.101
.101
0.020
0.0447
0.0447
-0.020
0.2376
298,
.14
0.101
.101
0.032
0.0410
0.0409
-0.032
0.2375
323,
.14
0.101
.101
0.020
0.0378
0.0378
-0.020
0.2375
373,
.15
0.101
0,
.101
0.022
0.0327
0.0327
-0.022
0.2374
423,
.17
0.101
0,
.101
0.033
0.0288
0.0288
-0.033
0.2373
473,
,19
0.101
0,
.101
0.038
0.0258
0.0258
-0.038
0.2373
203,
,08
2.026
2,
.022
-0.214
1.3818
1.3853
0.251
0.0128
223,
.25
2.026
2,
.026
-0.010
1.2084
1.2085
0.011
0.0125
298,
,14
2.026
2,
.029
0.100
0.8479
0.8470
-0.103
0.0121
203.
,08
3.040
3,
.026
-0.465
2.2701
2.2841
0.616
0.0089
223.
,25
3.040
3,
.033
-0.211
1.9191
1.9239
0.251
0.0086
248.
,18
3.040
3,
.039
-0.037
1.6396
1.6402
0.041
0.0083
273.
.15
3.040
3,
.039
-0.013
1.4422
1.4424
0.014
0.0082
323.
,14
3.040
3,
.040
0.013
1.1757
1.1755
-0.013
0.0081
373.
.15
3.040
3,
.044
0.137
1.0004
0.9990
-0.139
0.0080
423.
,17
3.040
3,
,044
0.150
0.8729
0.8716
-0.151
0.0079
473.
,19
3.040
3,
,042
0.076
0.7750
0.7744
-0.076
0.0079
203.
.08
4.053
4,
,030
-0.573
3.4113
3.4421
0.905
0.0071
223.
.25
4.053
4,
,041
-0.298
2.7324
2.7429
0.385
0.0066
248.
,18
4.053
4,
,048
-0.120
2.2722
2.2753
0.139
0.0064
273,
,15
4.053
4,
,053
0.000
1.9734
1.9734
0.000
0.0062
298.
,14
4.053
4,
,051
-0.040
1.7541
1.7549
0.043
0.0061
323.
.14
4.053
4,
,050
-0.073
1.5853
1.5865
0.077
0.0061
203.
,08
5.066
5,
,028
-0.755
5.0533
5.1342
1.600
0.0061
223,
.25
5.066
5,
,052
-0.284
3.6845
3.6992
0.400
0.0055
273,
,15
5.066
5,
,066
0.002
2.5315
2.5315
-0.002
0.0050
373,
,15
5.066
5,
,070
0.080
1.6853
1.6839
-0.082
0.0048
423,
,17
5.066
5,
,068
0.033
1.4597
1.4592
-0.033
0.0048
473,
,19
5.066
5.
,068
0.034
1.2919
1.2914
-0.034
0.0047
203,
,08
6.079
5.
,994
-1.413
7.9718
8.3547
4.804
0.0000
223,
,25
6.079
6.
,076
-0.066
4.8339
4.8389
0.102
0.0047
248,
,18
6.079
6.
,070
-0.152
3.7047
3.7118
0.191
0.0044
102
Data from Kvalnes and Gaddy [40] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm'^ mol-dm"^
Dev
Wt
273
.15
6
.079
6
.078
-0
.019
3
.1161
3
.1168
.022
0.0042
298
.14
6
.079
6
.069
-0
.164
2
.7184
2
.7233
.181
0.0041
323
.14
6
.079
6
.079
-0
.010
2
.4349
2
.4352
.010
0.0041
423
.17
6
.079
6
.076
-0
.054
1
.7532
1
.7542
.054
0.0040
473
.19
6
.079
6
.083
.058
1
.5505
1
.5496
-0
.058
0.0040
203
.08
6
.586
6
.418
-2
.554
9
.9825
10
.7430
7
.618
0.0000
203
.08
7,
.093
6
.898
-2
.739
11
.8896
12
.4424
4
.649
0.0000
223
.25
7,
.093
7
.076
-0
.237
6
.1880
6
.2129
.401
0.0041
203
.08
8,
.106
7
.910
-2
.415
13
.9974
14,
.2613
1
.885
0.0027
223
.25
8,
.106
8
.073
-0,
.412
7
.7710
7,
.8270
.721
0.0036
248,
.18
8,
.106
8
.091
-0,
.180
5
.3793
5
.3922
.241
0.0034
273,
.15
8,
.106
8,
.103
-0,
.040
4,
.3636
4,
.3657
0,
.048
0.0032
298,
.14
8,
.106
8,
.092
-0,
.168
3
.7389
3,
.7459
.188
0.0031
323,
.14
8,
,106
8,
.099
-0,
.085
3,
.3109
3
,3139
.091
0.0031
223,
.25
9,
,119
9,
.057
-0,
.680
9,
,4350
9,
,5372
1,
.084
0.0032
203,
,08
10.
,132
9,
.971
-1,
,591
15,
.9266
16,
,0292
0,
,644
0.0013
223,
,25
10.
,132
10,
.035
-0.
,961
10,
.9398
11,
,0745
1,
,231
0.0027
248,
,18
10.
,132
10,
.110
-0.
,219
7,
.2518
7,
,2729
0,
,291
0.0027
273,
,15
10.
,132
10,
.127
-0.
.051
5,
.6949
5,
,6983
0,
,061
0.0026
298,
.14
10.
,132
10,
,114
-0.
.186
4,
.7990
4.
,8090
0,
,209
0.0025
323,
.14
10.
.132
10.
,113
-0.
,191
4,
.2048
4.
.2134
0.
,206
0.0025
203,
,08
12.
.159
11,
,801
-2.
,941
16.
.9027
17.
,0572
0.
,914
0.0009
223.
.25
12.
,159
11.
,974
-1,
,520
13,
,1053
13.
,2641
1,
,212
0.0018
248.
,18
12.
,159
12.
,113
-0.
,376
9.
,1316
9.
,1728
0.
,452
0.0021
273.
,15
12.
,159
12.
,144
-0.
,120
7.
,0576
7.
,0675
0.
,140
0.0021
298.
,14
12.
159
12.
,139
-0.
,163
5.
,8806
5.
,8912
0.
,181
0.0021
323.
,14
12.
,159
12.
,138
-0.
,176
5.
,1120
5.
,1216
0,
,188
0.0020
203.
,08
14.
,185
13.
.801
-2.
,713
17,
,6716
17.
,7979
0.
,715
0.0006
223.
,25
14.
185
13.
.983
-1,
,425
14.
,5471
14.
,6645
0.
.807
0.0012
248.
,18
14.
185
14.
.097
-0.
,624
10.
.7931
10.
,8604
0.
,624
0.0017
273.
,15
14.
185
14.
,168
-0.
,122
8.
.3962
8.
,4074
0,
,133
0.0018
298.
,14
14.
,185
14.
,164
-0.
,155
6.
,9544
6.
,9659
0,
,165
0.0018
323.
,14
14.
185
14.
,165
-0.
,145
6.
,0156
6.
0247
0.
,151
0.0017
203.
,08
16.
212
15.
,811
-2.
475
18.
,2771
18,
3842
0.
,586
0.0005
223.
,25
16.
212
15.
,959
-1.
560
15.
5520
15,
6617
0.
,705
0.0009
103
Data from Kvalnes and Gaddy [40] (continued)
T P , exp P , cal Dev p , exp p , cal Dev
K MPa MPa % nvol-dm'^ mol-dm'^ %
248.18 16.212 16.064 -0.911 12.1465 12.2367 0.743
273.15 16.212 16.181 -0.193 9.6370 9.6553 0.190
298.14 16.212 16.192 -0.125 7.9959 8.0060 0.127
323.14 16.212 16.197 -0.094 6.9022 6.9087 0.095
203.08 18.238 17.796 -2.427 18.7731 18.8735 0.534
Wt
0.0013
0.0015
0.0015
0.0015
0.0004
223.25 18.238 17.996 -1.331 16.3483 16.4319 0.511 0.0007
248.18 18.238 18.046 -1.057 13.2422 13.3369 0.715 0.0011
273.15 18.238 18.210 -0.155 10.7591 10.7737 0.136 0.0012
298.14 18.238 18.207 -0.171 8.9743 8.9888 0.162 0.0013
323.14 18.238 18.236 -0.012 7.7605 7.7613 0.011 0.0013
373.15 18.238 18.222 -0.093 6.1946 6.2002 0.090 0.0013
203.08 20.265 19.834 -2.128 19.2104 19.2956 0.443 0.0003
223.25 20.265 19.970 -1.455 16.9754 17.0600 0.498 0.0005
248.18 20.265 20.077 -0.927 14.1547 14.2305 0.536 0.0008
273.15 20.265 20.192 -0.359 11.7211 11.7539 0.280 0.0010
298.14
323.14
373.15
423.17
473.19
203.08
223.25
248.18
273.15
298.14
20.265
20.265
20.265
20.265
20.265
25.331
25.331
25.331
25.331
25.331
20.231
20.257
20.226
20.223
20.264
24.836
25.035
25.075
25.244
25.228
■0.167
•0.039
•0.193
•0.209
•0.004
■1.957
1.169
•1.013
•0.345
•0.407
9.8855
8.5699
6.8403
5.7691
5.0362
20.0834
18.2033
15.8229
13.6614
11.8074
9.9000
8.5730
6.8527
5.7804
5.0364
20.1587
18.2634
15.8932
13.6897
11.8424
0.147
0.036
0.181
0.196
0.004
0.375
0.331
0.444
0.207
0.296
0.0011
0.0011
0.0011
0.0011
0.0011
0.0003
0.0004
0.0005
0.0007
0.0008
323.14
373.15
473.19
203.08
223.25
248.18
273.15
298.14
323.14
373.15
25.331
25.331
25.331
30.398
30.398
30.398
30.398
30.398
30.398
30.398
25.286
25.284
25.327
29.824
29.983
30.131
30.351
30.281
30.340
30.363
•0.180
■0.186
0.019
1.887
■1.365
10.3753
8.3661
6.1747
20.7751
19.0983
10.3903
8.3795
6.1757
20.8465
19.1644
■0.878 17.0282 17.0832
■0.154 15.0985 15.1100
■0.382 13.3339 13.3649
■0.188 11.8878 11.9033
■0.114 9.7327 9.7415
0.144
0.161
0.017
0.344
0.346
0.323
0.076
0.233
0.130
0.090
0.0008
0.0009
0.0009
0.0002
0.0003
0.0004
0.0005
0.0006
0.0006
0.0007
104
Data from Kvalnes and Gaddy [40] (continued)
T P.exp P.cal Dev P.exp p,cal
K MPa MPa % mol-dra"^ mol-dra"^
Dev
Wt
423.
.17
30.
.398
30,
.321
-0,
,252
8,
,2645
8,
.2818
0,
,209
0,
,0007
473,
.19
30,
,398
30,
.391
-0,
,021
7,
,2389
7,
.2402
0,
,018
0,
.0007
203,
,08
40,
,530
39,
.804
-1,
,792
21,
,8555
21,
,9233
0,
,310
0,
.0014
223,
,25
40,
,530
40,
,012
-1,
,279
20,
,4443
20,
,5027
0,
,286
0,
.0018
248,
.18
40,
,530
40,
,102
-1.
,055
18,
,7101
18,
,7693
0,
,316
0,
.0024
273,
,15
40,
,530
40,
,410
-0.
,296
17,
,0890
17,
,1083
0.
,113
0,
.0030
298,
,14
40.
,530
40,
,425
-0.
,259
15,
,5568
15,
,5757
0.
,121
0,
.0036
323,
,14
40.
,530
40,
,427
-0.
,255
14,
,1884
14,
,2081
0.
,139
0,
.0040
373,
,15
40.
,530
40,
,479
-0.
,125
11,
,9825
11,
,9924
0.
,082
0,
.0046
423
,17
40.
,530
40,
,529
-0.
,001
10,
,3595
10,
,3596
0.
,001
0,
.0049
473,
,19
40.
,530
40,
,506
-0,
,058
9,
,1334
9,
,1375
0.
,045
0,
.0051
203,
,08
50.
,662
49,
,319
-2.
,651
22,
,6623
22,
,7642
0.
,449
0,
.0011
223,
,25
50.
,662
49,
,860
-1,
,584
21,
,4329
21,
,5039
0.
,332
0,
.0014
248,
,18
50.
,662
50,
,183
-0,
,947
19,
,9277
19,
,9781
0.
,253
0,
.0017
273,
,15
50.
,662
50.
,566
-0.
,190
18,
,5015
18,
,5131
0.
,063
0,
.0021
298,
,14
50.
,662
50,
,485
-0.
,351
17,
,1164
17,
,1403
0.
,139
0,
.0025
323.
,14
50.
,662
50,
,455
-0.
,410
15,
,8521
15,
,8819
0.
,189
0,
.0028
373.
,15
50.
,662
50,
,647
-0.
,030
13,
,7377
13,
,7401
0.
,017
0,
,0033
423.
,17
50.
,662
50.
,652
-0.
,021
12,
,0596
12,
,0612
0.
,013
0,
,0036
473.
,19
50.
,662
50.
,667
0.
,010
10,
,7489
10,
.7482
-0.
,007
0,
,0038
203.
,08
60.
,795
59,
,213
-2.
,603
23,
,3595
23,
.4610
0,
,434
0,
,0009
223,
,25
60.
,795
59,
,670
-1.
,851
22,
,2294
22,
.3120
0.
,372
0,
,0011
248,
,18
60.
,795
60,
,029
-1.
,260
20,
,8623
20,
.9275
0.
,313
0,
.0014
273,
,15
60.
,795
60,
,540
-0.
,419
19,
,5733
19,
.5978
0.
,125
0,
.0016
298,
,14
60.
,795
60,
.439
-0.
,585
18,
.3049
18,
.3427
0.
,207
0,
.0019
323,
,14
60.
,795
60,
,499
-0.
,487
17,
.1425
17,
.1763
0,
,198
0,
.0021
373,
,15
60.
,795
60,
,800
0,
,009
15,
.1351
15,
.1345
-0.
,004
0,
.0025
423,
,17
60,
,795
60,
,738
-0,
,093
13,
.4603
13,
.4675
0.
,054
0,
.0028
473,
,19
60,
,795
60,
,847
0,
,085
12,
.1247
12,
.1182
-0.
,054
0,
.0030
203,
.08
70,
,928
69,
.131
-2,
,533
23,
.9593
24,
.0597
0.
,419
0,
.0008
223
.25
70,
,928
69,
.689
-1,
,746
22,
.9158
22.
.9937
0.
,340
0,
.0009
248,
.18
70,
.928
69,
.916
-1,
,427
21,
.6406
21,
.7134
0.
,336
.0011
203,
.08
81,
,060
78,
.381
-3,
,305
24,
.4532
24,
.5866
0.
,546
0,
.0007
223
.25
81,
,060
78,
.917
-2,
,643
23,
.4668
23,
.5857
0,
,507
.0008
248
.18
81,
.060
79,
.631
-1,
,764
22
.2968
22
.3861
0,
,401
.0009
105
Data from Kvalnes and Gaddy [40] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm'^ mol-dm"^
Dev
Number of Points (Ref. 40) 158
PRESSURE: AAD-% 0.714 BIAS-% -0.686 RMS-%
AAD 0.331 BIAS -0.317 RMS
DENSITY : AAD-% 0.379 BIAS-% 0.359 RMS-%
AAD 0.049 BIAS 0.047 RMS
Wt
273
15
81
060
80
241
-1
010
21
1776
21
2342
267
0011
298
14
81
060
80
515
-0
672
20
0986
20
1396
204
0012
323
14
81
060
80
330
-0
901
19
0498
19
1089
310
0014
373
15
81
060
81
013
-0
058
17
2471
17
2513
024
0016
423
17
81
060
81
168
134
15
6726
15
6626
-0
064
0018
473
19
81
060
81
307
305
14
3402
14
3169
-0
163
0020
203
08
91
192
88
026
-3
472
24
9162
25
0585
571
0006
223
25
91
192
88
642
-2
797
23
9838
24
1105
528
0007
248
18
91
192
89
104
-2
291
22
8600
22
9759
507
0008
203
08
101
325
97
494
-3
781
25
3295
25
4869
621
0006
223
25
101
325
98
496
-2
792
24
4555
24
5827
520
0006
248
18
101
325
99
324
-1
975
23
4023
23
5018
425
0007
273
15
101
325
99
432
-1
869
22
3609
22
4640
461
0008
298
14
101
325
100
156
-1
154
21
4062
21
4747
320
0009
323
14
101
325
100
284
-1
027
20
4723
20
5374
318
0010
373
15
101
325
101
337
012
18
8247
18
8238
-0
005
0012
423
17
101
325
101
519
192
17
3361
17
3220
-0
081
0013
473
19
101
325
101
808
476
16
0518
16
0158
-0
224
0014
0.925
0.666 MPa
0.827
0.089 mol-dm'3
Data from Mollerup [41]
T P.exp P.cal
K MPa MPa
Dev p , exp p , cal
% mol • dm" ^ mol • dm" ^
Dev
Wt
310
00
0.154
0.154
0.001
0.0600
0.0600
-0.001
1
5600
310
00
0.435
0.435
-0.006
0.1700
0.1700
0.006
5541
310
00
0.714
0.714
-0.013
0.2800
0.2800
0.013
3385
310
00
0.990
0.990
-0.017
0.3900
0.3901
0.018
2445
310
00
2.484
2.483
-0.045
1.0000
1.0005
0.047
0985
106
Data from Mollerup [41] (continued)
T P.exp P.cal Dev P.exp p.cal
K MPa MPa % mol-dm"^ mol-dm"^
310.00
310.00
310.00
310.00
310.00
310.00
310.00
310.00
310.00
310.00
310.00
310.00
310.00
310.00
310.00
310.00
310.00
310.00
4.806
7.000
9.105
11.158
13.200
15.276
17.434
19.731
22.231
25.013
28.168
31.809
36.073
41.123
47.157
54.412
63.170
73.762
4.802
6.995
9.099
11.155
13.202
15.284
17.447
19.744
22.241
25.014
28.157
31.782
36.024
41.045
47.034
54.216
62.857
73.269
■0.076
■0.081
■0.061
■0.023
0.019
0.053
0.070
0.066
0.042
0.005
2.0000
3.0000
4.0000
5.0000
6.0000
7.0000
8.0000
9.0000
10.0000
11.0000
2.0016
3.0027
4.0027
5.0013
5.9988
6.9962
7.9945
8.9946
9.9964
10.9996
■0.040 12.0000 12.0033
■0.086 13.0000 13.0070
■0.134 14.0000 14.0105
•0.190 15.0000 15.0142
•0.262 16.0000 16.0188
•0.360
■0.495
•0.668
17.0000
18.0000
19.0000
17.0249
18.0329
19.0430
Dev
%
0.081
0.088
0.067
0.025
•0.020
•0.054
■0.068
■0.060
•0.036
•0.004
0.028
0.054
0.075
0.095
0.118
0.146
0.183
0.226
Wt
0.0516
0.0358
0.0276
0.0225
0.0188
0.0160
0.0137
0.0117
0.0099
0.0083
0.0069
0.0057
0.0461
0.0371
0.0296
0.0236
0.0187
0.0148
Number of Points (Ref. 41) 23
PRESSURE:
AAD-%
0.122
BIAS-%
-0.100
RMS-%
0.181
AAD
0.059
BIAS
-0.055
RMS
0.121
MPa
DENSITY :
AAD-%
0.066
BIAS-%
0.045
RMS-%
0.074
AAD
0.008
BIAS
0.006
RMS
0.012
mol- dm" ^
Data from Morris [42]
T P.exp P.cal
K MPa MPa
Dev p , exp p , cal
% mol • dm" ^ mol • dm" ^
Dev
Wt
250,
,00
171,
.797
168,
.904
-1,
.684
26,
.0000
26
.0864
0,
,332
0,
.0038
250,
.00
208,
,651
205,
,372
-1,
.572
27,
.0000
27,
.0816
0,
.302
0,
.0031
250,
.00
252,
.321
249,
.031
-1,
.304
28,
.0000
28,
.0687
0,
.245
0,
.0025
250,
.00
303,
.683
300,
.983
-0,
.889
29,
.0000
29,
.0476
0,
.164
0,
.0020
250,
,00
363,
.664
362,
.425
-0,
.341
30,
.0000
30
.0186
0,
.062
0,
.0017
107
Data from Morris [42] (continued)
T P,exp P.cal Dev p.exp p.cal
K MPa MPa % mol-dm'^ mol-dm'^
Dev
Wt
250
.00
433
.220
434
.637
.327
31
.0000
30
.9818
-0
.059
.0014
250,
.00
513
.328
518
.973
1
.100
32
.0000
31
.9376
-0
.195
.0011
265
.91
189,
.546
186
.791
-1,
.453
26
.0000
26
.0778
.299
.0036
265,
.91
228,
.152
225
.295
-1,
.253
27
.0000
27
.0676
.250
.0029
265
.91
273,
.660
271
.212
-0
.894
28
.0000
28
.0488
.174
.0024
265,
.91
326,
.938
325
.678
-0,
.385
29
.0000
29
.0213
.073
.0019
265,
.91
388,
.902
389
.929
.264
30
.0000
29
.9852
-0,
.049
.0016
265,
.91
460,
,501
465,
.293
1,
.041
31
.0000
30
.9409
-0,
.191
.0013
265,
.91
542,
.705
553,
.181
1,
,930
32
.0000
31
.8884
-0,
.349
.0011
281,
.82
206,
.953
204,
.514
-1,
.179
26
.0000
26
.0654
0,
.252
.0034
281,
.82
247,
,258
245,
.062
-0,
.888
27,
.0000
27,
.0495
0,
.183
.0028
281,
,82
294,
,549
293,
.257
-0,
,439
28,
.0000
28,
.0246
0,
.088
.0023
281.
,82
349,
,689
350,
.267
0,
,165
29,
.0000
28
.9907
-0,
,032
0,
.0018
281,
,82
413,
,585
417,
.367
0,
,915
30,
.0000
29
.9477
-0,
.174
.0015
281,
.82
487.
,179
495,
,937
1.
,798
31,
.0000
30,
.8959
-0,
,336
0,
.0013
281,
,82
571.
,437
587,
,447
2.
,802
32,
.0000
31,
.8355
-0.
,514
0,
.0011
297.
,73
188.
.335
186,
,301
-1.
,080
25,
,0000
25,
.0618
0.
,247
0,
.0040
297.
.73
224.
,024
222,
,104
-0.
,857
26,
,0000
26,
,0490
0.
,188
0,
.0033
297.
,73
265.
,977
264,
,708
-0.
,477
27,
,0000
27,
,0273
0.
,101
0,
.0026
297.
,73
315.
,000
315,
,199
0.
,063
28,
,0000
27.
,9964
-0.
,013
0,
,0022
297.
,73
371.
,949
374,
,779
0.
,761
29,
,0000
28,
,9560
-0,
,152
0,
,0018
297.
.73
437.
,726
444,
,767
1.
,609
30,
,0000
29.
,9063
-0.
,312
0.
,0015
297.
,73
513.
,267
526.
,592
2.
,596
31,
,0000
30.
,8472
-0.
,493
0,
,0012
297.
,73
599.
,534
621.
,785
3.
,711
32,
,0000
31.
,7792
-0.
,690
0.
,0010
313.
,64
145.
,261
143.
,802
-1.
,005
23.
,0000
23.
,0600
0.
,261
0.
,0059
313.
.64
171.
,962
170.
,302
-0.
,965
24.
,0000
24.
,0571
0.
,238
0.
,0047
313.
,64
203.
,566
201.
,936
-0.
,801
25.
,0000
25.
,0471
0.
,188
0.
,0038
313.
,64
240.
,772
239.
,589
-0,
,491
26.
,0000
26.
,0288
0.
111
0.
,0031
313.
.64
284.
,327
284.
,258
-0.
,024
27.
,0000
27,
,0014
0.
005
0.
,0025
313.
.64
335.
,034
337.
,062
0.
,605
28.
,0000
27.
,9645
-0.
127
0.
,0021
313.
,64
393.
,743
399.
,239
1.
,396
29.
,0000
28.
,9178
-0.
283
0.
0017
313.
.64
461.
,351
472.
,149
2.
,340
30.
,0000
29.
,8614
-0.
462
0.
0014
313.
.64
538.
,790
557.
,273
3.
430
31.
,0000
30.
,7954
-0.
660
0.
0012
313.
,64
627.
,020
656.
,206
4.
,655
32.
,0000
31.
,7200
-0.
875
0.
0010
329.
.55
157.
,527
156.
,197
-0.
,845
23.
,0000
23.
0517
0.
225
0.
0056
108
Data from Morris [42] (continued)
T P.exp P.cal Dev p.exp p,cal
K MPa MPa % mol-dm"^ mol-dm'^
Dev
Wt
329
.55
185
.533
184
.185
-0
.726
24
.0000
24
.0440
183
.0045
329
.55
218
.529
217
.480
-0
480
25
.0000
25
.0289
116
.0036
329
.55
257
.213
256
.988
-0
088
26
.0000
26
.0052
020
.0030
329
55
302
.329
303
.734
465
27
.0000
26
9722
-0
103
.0024
329
55
354
.675
358
.867
1
182
28
.0000
27
9294
-0
252
.0020
329
55
415
099
423
664
2
063
29
.0000
28
8766
-0
425
0016
329
55
484
492
499
528
3
103
30
.0000
29
8138
-0
621
0013
329
55
563
783
587
993
4
294
31
.0000
30
7410
-0
835
0011
329
55
653
930
690
716
5
625
32
0000
31
6585
-1
067
.0009
345
45
169
604
168
516
-0
641
23
.0000
23
0401
174
0053
345
45
198
885
197
993
-0
448
24
.0000
24
0277
116
0043
345
45
233
242
232
950
-0
125
25
0000
25
0077
031
0035
345
45
273
368
274
319
348
26
0000
25
9788
-0
082
0028
345
45
320
006
323
152
983
27
0000
26
9403
-0
221
0023
345
45
373
952
380
631
1
786
28
0000
27
8917
-0
387
0019
345
45
436
048
448
069
2
757
29
0000
28
8329
-0
576
0016
345
45
507
182
526
917
3
891
30
0000
29
7638
-0
787
0013
345
45
588
281
618
760
5
181
31
0000
30
6845
-1
018
0011
345
45
680
299
725
319
6
618
32
0000
31
5952
-1
265
0009
361
36
155
482
154
623
-0
552
22
0000
22
0357
162
0062
361
36
181
501
180
770
-0
403
23
0000
23
0257
112
0050
361
36
212
032
211
735
-0
140
24
0000
24
0088
037
0041
361
36
247
720
248
358
258
25
0000
24
9839
-0
064
0033
361
36
289
256
291
594
808
26
0000
25
9499
-0
193
0027
361
36
337
383
342
525
1
524
27
0000
26
9061
-0
348
0022
361
36
392
890
402
364
2
411
28
0000
27
8519
-0
529
0018
361
36
456
619
472
464
3
470
29
0000
28
7873
-0
734
0015
361
36
529
454
554
321
4
697
30
0000
29
7121
-0
960
0013
361
36
612
319
649
577
6
085
31
0000
30
6265
-1
205
0010
377
27
123
138
122
570
-0
461
20
0000
20
0313
157
0089
377
27
142
890
142
241
-0
454
21
0000
21
0303
144
0072
377
27
166
066
165
492
-0
346
22
0000
22
0227
103
0059
377
27
193
231
192
969
-0
135
23
0000
23
0088
038
0048
377
27
224
988
225
424
194
24
0000
23
9876
-0
052
0039
377
27
261
980
263
716
662
25
0000
24
9581
-0
168
0032
109
Data from Morris [42] (continued)
T P.exp P,cal Dev P.exp p,cal
K MPa MPa % mol-clm"^ mol-dm"^
Dev
Wt
377
.27
304
898
308
825
1
288
26
.0000
25
9191
-0
311
0026
377
27
354
480
361
862
2
083
27
.0000
26
8701
-0
481
0021
377
27
411
515
424
076
3
052
28
0000
27
8104
-0
677
0018
377
27
476
842
496
858
4
198
29
0000
28
7401
-0
896
0015
377
27
551
340
581
750
5
516
30
.0000
29
6590
-1
137
0012
377
27
635
931
680
448
7
000
31
0000
30
5673
-1
396
0010
393
18
131
568
131
135
-0
329
20
0000
20
0226
113
0084
393
18
152
288
151
874
-0
272
21
0000
21
0184
088
0068
393
18
176
513
176
314
-0
112
22
0000
22
0075
034
0056
393
18
204
805
205
123
155
23
.0000
22
9898
-0
044
0045
393
18
237
766
239
068
548
24
0000
23
9645
-0
148
0037
393
18
276
039
279
032
1
085
25
0000
24
9305
-0
278
0030
393
18
320
311
326
021
1
783
26
0000
25
8867
-0
436
0025
393
18
371
320
381
175
2
654
27
0000
26
8326
-0
620
0020
393
18
429
852
445
776
3
704
28
0000
27
7677
-0
830
0017
393
18
496
743
521
257
4
935
29
0000
28
6918
-1
063
0014
393
18
572
870
609
208
6
343
30
0000
29
6050
-1
317
0012
393
18
659
151
711
378
7
923
31
0000
30
5074
-1
589
0010
409
09
139
898
139
665
-0
167
20
0000
20
0116
058
0080
409
09
161
574
161
468
-0
066
21
0000
21
0045
021
0065
409
09
186
832
187
098
142
22
0000
21
9904
-0
044
0053
409
09
216
234
217
238
464
23
0000
22
9692
-0
134
0043
409
09
250
380
252
676
917
24
0000
23
9399
-0
250
0036
409
09
289
910
294
316
1
520
25
0000
24
9015
-0
394
0029
409
09
335
512
343
190
2
288
26
0000
25
8531
-0
565
0024
409
09
387
922
400
469
3
234
27
0000
26
7940
-0
763
0020
409
09
447
923
467
471
4
364
28
0000
27
7240
-0
986
0016
409
09
516
347
545
668
5
678
29
0000
28
6428
-1
232
0014
409
09
594
071
636
698
7
175
30
0000
29
5504
-1
499
0011
409
09
682
008
742
367
8
850
31
0000
30
4470
-1
784
0009
Number of Points (Ref . 42) 105
PRESSURE: AAD-%
AAD
DENSITY : AAD-%
AAD
1.920 BIAS-%
9.234 BIAS
0.404 BIAS-%
0.117 BIAS
1.448
RMS-%
2.381
8.254
RMS
13.539
MPa
0.296
RMS-%
0.490
0.090
RMS
0.146
mol • dm'''
110
Data from Robertson and Babb [43]
T P.exp P.cal
K MPa MPa
Dev p , exp p , cal
% mol • dm" ^ mol • dm" ^
Dev
Wt
308
.15
150
.000
146
.393
-2
.404
23,
.2830
23,
.4257
0,
.613
.0565
308
.15
200,
.000
196
.116
-1,
.942
24,
.9870
25,
.1008
0,
.455
.0390
308
.15
250,
.000
246
.617
-1,
.353
26,
.3150
26
.3940
0,
.300
0,
.0295
308
.15
300,
.000
298,
.063
-0,
.646
27,
.4150
27
.4527
0,
,137
0,
.0236
308
.15
350,
.000
350
.634
.181
28,
.3630
28
.3524
-0,
.037
0,
.0195
308,
.15
400,
.000
404,
.294
1,
.073
29,
.2000
29,
.1370
-0,
.216
0,
.0166
308,
,15
450,
.000
458,
.607
1,
.913
29,
.9470
29,
.8343
-0,
.376
0,
.0144
308,
.15
500,
.000
513,
.768
2,
.754
30,
.6260
30,
.4630
-0,
.532
0,
.0126
308,
,15
550,
.000
570,
.413
3,
,711
31,
,2570
31,
.0365
-0,
.706
0,
.0113
308,
.15
600,
.000
627,
.104
4,
.517
31,
. 8340
31,
.5643
-0,
.847
0,
.0102
308,
.15
650,
.000
685,
.244
5,
.422
32,
.3790
32,
.0538
_ ]_
,004
0,
.0092
308,
,15
700,
.000
743,
.943
6,
,278
32,
,8890
32,
.5107
-1 ,
,150
0,
.0084
308,
,15
750,
.000
803,
.580
7,
.144
33,
.3720
32,
.9396
-1 ,
,296
0,
,0078
308,
,15
800,
.000
863,
.680
7,
,960
33,
,8280
33,
.3439
-1 ,
,431
0,
,0072
308,
,15
850,
.000
924,
,468
8,
.761
34,
,2620
33,
.7267
-1,
,562
0,
.0067
308,
,15
900,
,000
986,
,160
9,
,573
34,
,6780
34,
.0904
. 1
,695
0,
,0063
308,
.15
950,
.000
1048,
,447
10,
,363
35,
,0760
34,
.4370
-1 ,
.822
0,
.0059
308,
.15
1000,
.000
1111,
.850
11,
,185
35,
,4610
34,
.7683
-1 ,
,954
0,
,0055
373.
.15
150,
.000
148,
.343
-1,
,105
21,
,3950
21,
,4682
0.
,342
0,
,0673
373,
.15
200,
.000
198,
,476
-0,
,762
23.
,2870
23,
.3361
0,
,211
0,
,0454
373,
.15
250,
,000
250,
,036
0,
,014
24,
,7590
24,
.7581
-0.
,004
0,
,0336
373,
.15
300.
.000
302,
,723
0,
,908
25.
,9660
25,
,9091
-0,
,219
0,
,0264
373,
.15
350,
.000
356,
,570
1,
,877
26.
,9950
26,
,8782
-0,
,433
0,
,0215
373,
.15
400,
.000
411,
.449
2,
,862
27,
,8940
27,
,7167
-0,
,636
0,
,0181
373,
.15
450,
.000
467,
.275
3,
.839
28,
,6940
28,
,4570
-0,
,826
0,
,0155
373,
.15
500,
.000
524,
,219
4,
,844
29.
,4190
29.
.1205
-1,
,015
0,
,0136
373,
.15
550,
.000
582,
,028
5,
,823
30.
,0810
29,
,7225
-1,
.192
0,
,0120
373,
.15
600,
.000
641,
,355
6,
,893
30,
,6980
30,
,2740
-1.
.381
0,
,0107
373,
.15
650,
,000
701,
,979
7,
,997
31.
,2750
30,
,7833
-1,
.572
0,
,0097
373,
.15
700,
.000
763,
,076
9,
,011
31,
,8110
31,
,2569
-1,
.742
0,
,0088
373,
.15
750,
.000
825,
,771
10,
,103
32.
,3210
31.
.6997
-1.
.922
0,
,0080
373,
.15
800,
,000
888,
.271
11,
.034
32,
,7950
32.
.1159
-2,
.071
0,
,0074
373,
.15
850,
,000
952,
,608
12,
.072
33,
,2520
32,
,5085
-2,
.236
0,
,0069
373,
.15
900,
.000
1016,
.834
12,
.982
33,
,6810
32,
,8805
-2.
.377
0,
.0064
373,
.15
950,
.000
1082,
.015
13,
.896
34,
,0920
33,
,2340
-2,
.517
0,
.0060
111
Data from Robertson and Babb [43] (continued)
T P.exp P.cal Dev p.exp p.cal
K MPa MPa % mol-dm"^ mol-dm'^
Dev
Wt
473,
,15
400,
.000
418,
.622
4,
.655
26.
,1050
25,
.7974
-1,
.178
0,
,0203
473,
,15
450,
.000
476,
.456
5,
.879
26.
,9770
26,
.5925
-1,
.425
0,
,0172
473,
.15
500,
.000
535,
.369
7,
.074
27,
,7600
27,
.3012
-1,
.653
0,
,0149
473,
,15
550,
.000
595,
.615
8,
.294
28,
,4750
27,
.9409
-1,
.876
0,
,0131
473,
.15
600,
.000
657,
.070
9,
.512
29.
.1330
28,
.5242
-2,
.090
0,
,0116
473,
,15
650,
.000
719,
.455
10.
.685
29,
,7410
29,
,0605
-2,
.288
0,
,0104
473,
,15
700,
.000
784,
.058
12,
.008
30,
,3180
29,
,5572
-2,
.509
0,
,0094
473,
.15
750,
.000
849,
.146
13,
.220
30.
,8540
30,
.0199
-2,
.703
0,
,0085
473,
,15
800,
.000
915,
.944
14,
.493
31,
.3640
30,
.4532
-2,
.904
0,
,0078
473,
.15
850,
.000
983,
.869
15.
.749
31,
.8470
30,
,8608
-3,
.097
0,
.0072
473,
.15
900,
.000
1052,
.419
16,
.935
32,
,3030
31,
.2456
-3,
.273
0,
.0066
473,
,15
950,
.000
1121,
.878
18,
.092
32,
,7370
31,
.6103
-3,
.442
0,
.0061
473,
.15
1000.
.000
1192,
.522
19.
.252
33,
.1530
31,
.9570
-3,
.608
0,
.0057
Number of Points (Ref. 43) 53
PRESSURE:
AAD-%
7.024
BIAS-%
6.714
RMS-%
5.581
AAD
52.863
BIAS
52.260
RMS
51.540
MPa
DENSITY :
AAD-%
1.394
BIAS-%
-1.317
RMS-%
1.070
AAD
0.437
BIAS
-0.418
RMS
0.347
mol'dm"''
Data from Sivaraman and Gammon [44]
T P , exp P , cal Dev p , exp p , cal Dev
K MPa MPa % mol-dm"^ mol-dm"^ %
193.05
193.05
193.05
193.05
193.05
193.05
193.05
193.05
195.15
195.15
1.456
3.446
4.429
4.818
4.937
5.019
5.174
5.643
1.475
3.517
1.454
3.443
4.427
4.821
4.978
5.016
5.173
5.604
1.474
3.514
■0.077
■0.090
■0.051
0.046
0.834
0186
0974
1435
2853
10.5749
1.0195
3.1019
5.1509
7.2617
9.3913
■0.058 11.4240 11.4766
■0.032 13.0245 13.0344
■0.696 14.5064 14.5900
■0.072 1.0183 1.0191
■0.099 3.0961 3.1010
0.088
0.145
0.144
-0.324
11.193
0.460
0.076
0.577
0.082
0.157
Wt
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
112
Data from Sivaraman and Gammon [44] (continued)
T P.exp P.cal Dev p.exp p,cal
K MPa MPa % mol-dm"^ mol-dm'^
Dev
Wt
193
.05
5
.019
5
.016
-0.058
11
.4240
11
.4766
0.460
0.0000
193
.05
5
.174
5
.173
-0.032
13
.0245
13
.0344
0.076
0.0000
193
.05
5
.643
5
.604
-0.696
14
.5064
14
.5900
0.577
0.0000
195
.15
1
.475
1
.474
-0.072
1
.0183
1
.0191
0.082
0.0000
195
.15
3
.517
3
.514
-0.099
3
.0961
3
.1010
0.157
0.0000
195
.15
4
.564
4
564
-0.015
5
.1447
5
.1467
0.039
0.0000
195
15
5
.028
5
035
0.126
7
.2887
7
2401
-0.667
0.0000
195
15
5
.217
5
244
0.510
9
.7392
9
3377
-4.122
0.0000
195
15
5
.379
5
398
0.347
11
.6649
11
4880
-1.516
0.0000
195
15
5
617
5
604
-0.232
12
.9654
13
0226
0.441
0.0000
195
15
6
197
6
155
-0.683
14
.4934
14
5701
0.529
0.0000
200
15
1
520
1
519
-0.070
1
.0171
1
0179
0.079
0.0000
200
15
3
683
3
680
-0.093
3
0919
3
0963
0.142
0.0000
200
15
4
882
4
883
0.026
5
1398
5
1368
-0.059
0.0000
200
15
5
344
5
352
0.140
6
5245
6
4968
-0.424
0.0000
200
15
5
884
5
902
0.299
9
4139
9
2974
-1.237
0.0000
200
15
6
252
6
250
-0.033
11
4638
11
4734
0.084
0.0000
200
15
6
684
6
654
-0.451
12
9066
12
9870
0.623
0.0000
200
15
7
523
7
480
-0.572
14
4680
14
5259
0.400
0.0000
210
15
1
610
1
608
-0.065
1
0147
1
0154
0.072
0.0000
210
15
3
982
3
978
-0.097
3
0540
3
0582
0.137
0.0000
210
15
5
498
5
500
0.040
5
1195
5
1157
-0.074
0.0000
210
15
6
475
6
489
0.211
7
2171
7
1821
-0.486
0.0000
210
15
7
202
7
215
0.176
9
2742
9
2367
-0.404
0.0000
210
15
7
973
7
959
-0.175
11
2795
11
3115
0.284
0.0000
210
15
8
839
8
802
-0.427
12
8555
12
9119
0.439
0.0000
210
15
10
170
10
137
-0.331
14
4030
14
4332
0.210
0.0000
223
15
1
725
1
724
-0.049
1
0117
1
0122
0.054
0.0000
223
15
4
378
4
373
-0.096
3
0313
3
0351
0.127
0.0000
223
15
6
273
6
275
0.034
5
0921
5
0894
-0.053
0.0000
223
15
7
678
7
692
0.185
7
1588
7
1357
-0.322
0.0000
223
15
8
859
8
872
0.152
9
1478
9
1251
-0.248
0.0000
223
15
10
227
10
216
-0.113
11
2105
11
2260
0.138
0.0000
223
15
11
815
11
784
-0.264
12
9553
12
9837
0.220
0.0000
248
15
1
942
1
941
-0.041
1
0056
1
0060
0.044
0.0000
113
Data from Sivaraman and Gammon [44] (continued)
T P,exp P.cal Dev P , exp p , cal
K MPa MPa % mol-dm'^ raol-dra'^
Dev
Wt
248
.15
5
.107
5
.103
-0.086
2.9907
2
.9938
0.104
0.0000
248
.15
7
.644
7
.645
0.016
4.9901
4
.9891
-0.021
0.0000
248
.15
9
.877
9
.891
0.146
7.0451
7
.0314
-0.195
0.0000
248
.15
11
.983
12
.001
0.151
9.0327
9
.0162
-0.183
0.0000
248
.15
14
.470
14
.474
0.022
11.0784
11
.0761
-0.021
0.0000
273
.15
2,
.155
2
.154
-0.029
0.9997
1
.0000
0.030
0.0000
273
.15
5,
.883
5
.878
-0.074
2.9984
3
.0009
0.085
0.0000
273
.15
9,
.037
9
.037
0.004
4.9698
4
.9696
-0.004
0.0000
273
.15
11,
.986
11,
.999
0.105
6.9596
6
.9511
-0.122
0.0000
273,
.15
15,
,110
15,
.130
0.135
9.0038
8
.9912
-0.140
0.0000
273,
.15
18.
.678
18,
.685
0.036
11.0011
10,
.9977
-0.031
0.0000
298,
,15
2,
.377
2,
,378
0.030
1.0000
0,
.9997
-0.031
0.0000
298,
.15
4,
,581
4,
.578
-0.055
2.0000
2
.0012
0.059
0.0000
298.
,15
6,
.641
6,
.638
-0.048
3.0000
3,
.0016
0.053
0.0000
298,
,15
8.
,599
8,
.596
-0.035
3.9999
4,
,0015
0.039
0.0000
298,
,15
10.
,493
10,
.491
-0.011
4.9998
5.
,0004
0.012
0.0000
298.
,15
12.
,360
12,
,362
0.016
5.9994
5.
,9984
-0.017
0.0000
298.
,15
14.
,242
14.
.249
0.048
6.9988
6,
.9952
-0.051
0.0000
298.
,15
16.
,188
16.
,201
0.080
8.0002
7.
.9937
-0.081
0.0000
298.
,15
18.
,247
18.
,264
0.090
9.0002
8.
.9925
-0.085
0.0000
298.
,15
20.
,484
20.
,500
0.080
10.0003
9.
,9933
-0.070
0.0000
298.
,15
22.
,973
22.
,985
0.051
11.0005
10.
,9960
-0.041
0.0000
323.
,15
2.
,600
2.
,602
0.068
1.0006
0.
,9999
-0.070
0.0000
323.
,15
5.
,052
5.
,052
-0.002
2.0007
2.
,0007
0.002
0.0000
323.
,15
7.
,392
7.
,391
-0.015
3.0008
3.
,0013
0.016
0.0000
323.
,15
9.
,659
9.
,658
-0.001
4.0016
4.
,0016
0.001
0.0000
323.
,15
11.
,891
11.
,894
0.024
5.0026
5.
,0013
-0.025
0.0000
323.
,15
14.
.126
14.
,135
0.066
6.0023
5.
,9982
-0.068
0.0000
323.
,15
16.
,421
16.
,434
0.078
7.0036
6.
,9981
-0.079
0.0000
323.
,15
18.
,815
18.
,834
0.104
8.0042
7.
9962
-0.099
0.0000
323.
,15
21.
,377
21.
,395
0.082
9.0047
8.
9981
-0.073
0.0000
323.
,15
24.
,156
24.
,183
0.112
10.0053
9.
9960
-0.093
0.0000
348.
,15
2.
,821
2.
822
0.034
1.0002
0.
9998
-0.035
0.0000
348.
,15
5.
522
5.
525
0.062
2.0015
2.
0002
-0.064
0.0000
348.
,15
11.
,993
12.
000
0.058
4.5045
4.
5018
-0.060
0.0000
114
Data from Sivaraman and Gammon [44] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm'^ mol-dm"^
Dev
Wt
348
.15
13
.280
13
.288
.060
5.0052
5
.0021
-0
061
.0000
348
.15
15
.891
15
.902
.074
6.0066
6
.0022
-0
074
.0000
348
.15
18
.588
18
.607
.101
7.0077
7
.0009
-0
097
0000
348
.15
21
.423
21
.456
155
8.0089
7
.9976
-0
141
0000
348
15
24
.479
24
.513
138
9.0099
8
.9993
-0
118
0000
373
15
3
.043
3
046
085
1.0011
1
0002
-0
087
0000
373
15
5
.993
5
.996
051
2.0023
2
0012
-0
053
0000
373
15
8
884
8
891
085
3.0043
3
0017
-0
088
0000
373
15
11
760
11
770
087
4.0064
4
0029
-0
088
0000
373
15
14
663
14
679
108
5.0087
5
0033
-0
108
0000
373
15
17
631
17
662
176
6.0109
6
0007
-0
170
0000
373
15
20
742
20
773
146
7.0126
7
0031
-0
135
0000
373
15
24
007
24
070
264
8.0144
7
9958
-0
232
0000
373
15
27
542
27
620
281
9.0155
8
9945
-0
232
0000
398
15
3
234
3
267
1
037
1.0012
9908
-1
040
0000
398
15
6
458
6
468
156
2.0037
2
0005
-0
158
0000
398
15
9
623
9
639
170
3.0064
3
0012
-0
172
0000
398
15
12
800
12
823
178
4.0095
4
0024
-0
178
0000
398
15
16
037
16
066
184
5.0128
5
0038
-0
180
0000
398
15
19
368
19
418
257
6.0156
6
0010
-0
242
0000
398
15
22
875
22
933
252
7.0180
7
0020
-0
227
0000
398
15
26
602
26
675
273
8.0199
8
0012
-0
234
0000
423
15
3
484
3
491
193
1.0020
1
0001
-0
194
0000
423
15
6
925
6
939
207
2.0049
2
0007
-0
209
0000
423
15
10
361
10
386
241
3.0087
3
0015
-0
241
0000
423
15
13
838
13
874
260
4.0129
4
0026
-0
256
0000
423
15
17
401
17
453
298
5.0173
5
0030
-0
285
0000
423
15
21
100
21
171
335
6.0209
6
0023
-0
310
0000
423
15
24
997
25
088
366
7.0236
7
0009
-0
323
0000
Number of Points (Ref . 44) 104
PRESSURE:
AAD-%
0.158
BIAS-%
0.055
RMS-%
0.229
AAD
0.016
BIAS
0.010
RMS
0.023
MPa
DENSITY :
AAD-%
0.337
BIAS-%
-0.218
RMS-%
1.189
AAD
0.030
BIAS
-0.018
RMS
0.125
mol-dra''^
115
Data from Trappeniers et al. [45]
T P.exp P.cal Dev p.exp p.cal
K MPa MPa % mol-dm"^ mol-dm"^
Dev
Wt
273
.15
1
.794
1
.794
-0.007
0.8250
0.8251
0.008
102
.6723
285
.65
1
.885
1
.885
-0.003
0.8250
0.8250
0.004
97
.4853
298
.15
1
.976
1
.976
-0.002
0.8250
0.8250
0.003
92
.8060
323
.15
2
.157
2
.157
0.005
0.8250
0.8250
-0.005
84
.7006
348
.15
2
.338
2
.338
0.005
0.8250
0.8250
-0.006
77
.9150
373
.15
2
.518
2
.518
0.012
0.8250
0.8249
-0.013
72
.1521
398,
.15
2
.698
2,
.698
0.011
0.8250
0.8249
-0.011
67
.1909
423.
.15
2
.878
2,
.878
0.012
0.8250
0.8249
-0.012
62
.8762
273,
.15
2
.226
2,
.224
-0.065
1.0340
1.0347
0.069
83
.1956
285,
,65
2,
.341
2,
.340
-0.060
1.0340
1.0347
0.063
78
.8476
298,
,15
2,
.457
2,
.455
-0.057
1.0340
1.0346
0.059
74
.9408
323.
,15
2,
.687
2,
,686
-0.050
1.0340
1.0345
0.052
68
.2048
348,
,15
2,
,917
2,
,915
-0.043
1.0340
1.0345
0.045
62,
.5998
373.
,15
3,
.146
3,
.144
-0.042
1.0340
1.0344
0.042
57,
.8583
398.
,15
3,
.374
3,
.373
-0.041
1.0340
1.0344
0.042
53,
.7940
423.
,15
3,
.603
3.
.601
-0.046
1.0340
1.0345
0.046
50,
.2694
273.
.15
2,
.648
2,
.646
-0.082
1.2430
1.2441
0.088
70,
.2786
285.
.65
2,
.789
2,
,787
-0.082
1.2430
1.2441
0.087
66,
,4800
298.
.15
2,
.930
2,
,927
-0.080
1.2430
1.2440
0.084
63.
.0814
323.
,15
3,
,210
3,
,208
-0.072
1.2430
1.2439
0.074
57.
.2518
348.
,15
3,
,490
3.
,487
-0.065
1.2430
1.2438
0.067
52.
,4271
373.
,15
3,
,769
3.
,766
-0.066
1.2430
1.2438
0.067
48,
,3639
398.
,15
4,
,047
4.
,044
-0.062
1.2430
1.2438
0.063
44.
,8957
423.
,15
4,
,325
4.
,322
-0.067
1.2430
1.2438
0.068
41.
,8972
273.
,15
3,
,050
3.
,047
-0.105
1.4460
1.4476
0.113
61.
,2998
285.
,65
3,
,216
3.
,213
-0.099
1.4460
1.4475
0.106
57.
,8828
298.
,15
3.
,382
3.
,379
-0.096
1.4460
1.4475
0.101
54.
8358
323.
,15
3,
,712
3,
,709
-0.084
1.4460
1.4473
0.088
49.
6336
348.
.15
4,
,042
4.
,038
-0.083
1.4460
1.4472
0.085
45.
3493
373.
,15
4.
,370
4.
,367
-0.081
1.4460
1.4472
0.083
41.
7586
398.
,15
4,
,698
4.
,694
-0.083
1.4460
1.4472
0.084
38.
7035
423,
,15
5,
,025
5.
,021
-0.092
1.4460
1.4473
0.093
36.
0704
273,
.15
3,
,463
3.
.461
-0.054
1.6600
1.6610
0.059
54.
2274
285,
.65
3,
.656
3.
.655
-0.047
1.6600
1.6608
0.051
51.
1061
298,
.15
3,
,849
3.
,848
-0.045
1.6600
1.6608
0.048
48.
3328
323,
,15
4,
,233
4.
,232
-0.036
1.6600
1.6606
0.038
43.
6213
116
Data from Trappenlers et al. [45] (continued)
T P.exp P.cal Dev p.exp p,cal
K MPa MPa % mol-dm'^ mol-dm"^
Dev
Wt
348
.15
4
.616
4
.615
-0.028
.6600
.6605
0.029
39
.7645
373
.15
4
.997
4
.996
-0.022
6600
.6604
0.023
36
.5463
398
.15
5
.378
5
.377
-0.025
6600
6604
0.025
33
.8178
423
.15
5
.758
5
756
-0.036
6600
6606
0.036
31
.4736
273
15
3
867
3
863
-0.082
8720
8737
0.090
48
.7882
285
65
4
075
4
085
0.235
8720
8672
-0.254
.0000
298
15
4
308
4
305
-0.071
8720
8734
0.076
43
3282
323
15
4
747
4
744
-0.058
8720
8731
0.061
38
9941
348
15
5
183
5
181
-0.041
8720
8728
0.043
35
4665
373
15
5
619
5
616
-0.041
8720
8728
0.042
32
5336
398
15
6
053
6
050
-0.045
8720
8729
0.045
30
0568
423
15
6
487
6
483
-0.059
8720
8731
0.060
27
9352
273
15
4
153
4
149
-0.110
2
0250
2
0275
0.121
45
5632
285
65
4
395
4
390
-0.104
2
0250
2
0273
0.114
42
7980
298
15
4
635
4
631
-0.095
2
0250
2
0271
0.103
40
3591
323
15
5
115
5
110
-0.084
2
0250
2
0268
0.089
36
2472
348
15
5
592
5
587
-0.079
2
0250
2
0267
0.082
32
9115
373
15
6
067
6
062
-0.082
2
0250
2
0267
0.085
30
1484
398
15
6
542
6
536
-0.090
2
0250
2
0269
0.092
27
8210
423
15
7
015
7
008
-0.097
2
0250
2
0270
0.098
25
8334
273
15
4
248
4
243
-0.108
2
0760
2
0785
0.120
44
5954
285
65
4
496
4
491
-0.101
2
0760
2
0783
0.111
41
8698
298
15
4
744
4
739
-0.101
2
0760
2
0783
0.109
39
4658
323
15
5
236
5
232
-0.082
2
0760
2
0778
0.087
35
4221
348
15
5
726
5
722
-0.074
2
0760
2
0776
0.077
32
1450
373
15
6
215
6
211
-0.076
2
0760
2
0776
0.079
29
4331
398
15
6
703
6
697
-0.081
2
0760
2
0777
0.083
27
1511
423
15
7
190
7
183
-0.094
2
0760
2
0780
0.095
25
2026
273
15
4
526
4
522
-0.096
2
2280
2
2304
0.107
41
9729
285
65
4
795
4
790
-0.089
2
2280
2
2302
0.098
39
3525
298
15
5
063
5
059
-0.086
2
2280
2
2301
0.093
37
0484
323
15
5
596
5
592
-0.075
2
2280
2
2298
0.080
33
1831
348
15
6
128
6
123
-0.073
2
2280
2
2297
0.076
30
0630
373
15
6
657
6
652
-0.073
2
2280
2
2297
0.075
27
4901
398
15
7
185
7
179
-0.081
2
2280
2
2298
0.083
25
3299
117
Data from Trappeniers et al. [45] (continued)
T P.exp P,cal Dev p.exp p,cal
K MPa MPa % mol-dm'^ mol-dm'^
Dev
Wt
423,
.15
7,
.711
7
.704
-0.088
2
.2280
2
.2300
0.088
23
.4906
273,
.15
4
.633
4
.628
-0.090
2
.2870
2
.2893
0.101
41
.0478
285,
.65
4
.910
4
.906
-0.082
2
.2870
2
.2891
0.090
38
.4648
298,
.15
5
.186
5
.182
-0.079
2
.2870
2
.2890
0.086
36
.1953
323,
.15
5
.735
5
.731
-0.063
2
.2870
2
.2885
0.067
32
.3941
348,
.15
6
.282
6
.278
-0.055
2
.2870
2
.2883
0.058
29
.3305
373,
.15
6
.827
6
.823
-0.059
2
.2870
2
.2884
0.060
26
.8058
398
.15
7,
.370
7
.366
-0.063
2
.2870
2
.2885
0.064
24,
.6892
423.
.15
7,
.912
7,
.907
-0.074
2
.2870
2
.2887
0.074
22
.8875
273,
.15
4,
.893
4
.889
-0.074
2
.4320
2
.4340
0.083
38
.9627
285,
.65
5,
.190
5
.187
-0.065
2,
.4320
2
.4338
0.072
36,
.4623
298,
,15
5,
.486
5,
.483
-0.060
2,
.4320
2
.4336
0.066
34,
.2712
323,
.15
6,
.075
6,
.072
-0.052
2
.4320
2
.4333
0.055
30,
.6113
348,
.15
6,
.662
6
.659
-0.054
2,
.4320
2
.4334
0.056
27,
.6716
373,
.15
7,
,247
7,
.242
-0.059
2,
.4320
2
.4335
0.061
25
.2574
398,
.15
7,
.829
7,
.824
-0.063
2,
.4320
2
.4336
0.064
23,
.2384
423,
.15
8,
.421
8,
.404
-0.206
2,
.4320
2,
.4371
0.208
21,
.5089
273,
.15
5,
.248
5,
,244
-0.081
2,
.6320
2,
.6344
0.092
36,
.4508
285,
.65
5,
.574
5,
,569
-0.077
2,
.6320
2
.6343
0.086
34,
.0478
298,
.15
5,
,898
5,
,894
-0.071
2,
.6320
2,
.6341
0.078
31,
,9507
323,
.15
6,
,543
6,
,539
-0.065
2,
,6320
2,
.6338
0.069
28,
,4619
348,
.15
7.
,186
7,
,181
-0.065
2,
,6320
2,
.6338
0.068
25,
,6739
373,
.15
7,
,825
7,
,820
-0.065
2,
,6320
2,
.6338
0.067
23.
,3937
398,
.15
8,
,462
8,
,456
-0.074
2,
,6320
2,
.6340
0.075
21,
,4919
423,
.15
9,
,099
9,
,090
-0.091
2,
,6320
2,
.6344
0.091
19,
,8809
273,
.15
5,
,601
5,
,596
-0.094
2,
,8340
2,
,8370
0.107
34,
.2644
285,
,65
5.
,956
5,
,951
-0.087
2,
,8340
2,
,8368
0.098
31,
.9463
298,
.15
6,
,310
6,
,304
-0.086
2,
,8340
2,
,8367
0.095
29,
.9290
323,
.15
7,
,013
7,
,007
-0.090
2,
,8340
2,
,8367
0.096
26.
.5876
348,
.15
7,
,713
7,
,706
-0.091
2,
,8340
2,
,8367
0.095
23,
.9317
373,
.15
8,
,410
8,
,401
-0.099
2,
,8340
2,
,8369
0.102
21.
,7673
398,
.15
9,
,104
9,
,094
-0.103
2.
,8340
2,
,8370
0.105
19.
,9692
423,
.15
9,
,796
9,
,785
-0.119
2.
,8340
2.
,8374
0.120
18.
,4499
273,
.15
5,
.828
5,
,825
-0.064
2,
,9670
2,
,9692
0.073
32.
,9898
285
.65
6,
.204
6
,199
-0.076
2,
,9670
2,
,9695
0.085
30.
7169
118
Data from Trappeniers et al . [45] (continued)
T P.exp P.cal Dev p.exp p , cal
K MPa MPa % mol-dm'^ mol-dm"^
Dev
Wt
348
.15
8
.243
8
.237
-0.071
3
.0390
3
.0413
0.075
22
.3971
373
.15
8
.998
8
.991
-0.081
3
.0390
3
.0415
0.083
20
.3353
398
.15
9
.750
9
.742
-0.086
3
.0390
3
.0417
0.087
18
.6283
423
15
10
.501
10
.491
-0.095
3
.0390
3
0419
0.095
17
.1905
273
15
6
306
6
.302
-0.058
3
.2490
3
2512
0.067
30
.6103
285
65
6
723
6
719
-0.062
3
.2490
3
2513
0.070
28
4281
298
15
7
138
7
134
-0.064
3
2490
3
2513
0.072
26
5433
323
15
7
964
7
959
-0.064
3
2490
3
2513
0.069
23
4503
348
15
8
785
8
778
-0.069
3
2490
3
2514
0.073
21
0150
373
15
9
601
9
594
-0.071
3
.2490
3
2514
0.073
19
.0472
398
15
10
415
10
406
-0.084
3
2490
3
2517
0.085
17
4218
423
15
11
226
11
215
-0.098
3
2490
3
2522
0.098
16
0567
273
15
6
330
6
327
-0.050
3
2640
3
2659
0.058
30
4962
285
65
6
750
6
746
-0.060
3
2640
3
2662
0.068
28
3171
298
15
7
168
7
163
-0.066
3
2640
3
2664
0.073
26
4360
323
15
7
998
7
993
-0.068
3
2640
3
2664
0.073
23
3505
348
15
8
823
8
817
-0.072
3
2640
3
2665
0.075
20
9225
373
15
9
644
9
637
-0.073
3
2640
3
2664
0.075
18
9609
398
15
10
463
10
454
-0.084
3
2640
3
2668
0.085
17
3412
423
15
11
278
11
267
-0.094
3
2640
3
2671
0.094
15
9814
273
15
6
622
6
618
-0.054
3
4390
3
4412
0.063
29
2175
285
65
7
068
7
064
-0.062
3
4390
3
4414
0.070
27
0861
298
15
7
513
7
508
-0.062
3
4390
3
4414
0.069
25
2520
323
15
8
397
8
390
-0.075
3
4390
3
4418
0.080
22
2517
348
15
9
275
9
267
-0.080
3
4390
3
4419
0.084
19
9013
373
15
10
148
10
140
-0.080
3
4390
3
4418
0.082
18
0090
398
15
11
018
11
008
-0.089
3
4390
3
4421
0.090
16
4507
423
15
11
885
11
873
-0.103
3
4390
3
4425
0.103
15
1450
273
15
6
824
6
821
-0.043
3
5620
3
5638
0.050
28
3923
285
65
7
290
7
286
-0.055
3
5620
3
5642
0.063
26
2901
298
15
7
754
7
749
-0.063
3
5620
3
5645
0.070
24
4847
323
15
8
674
8
669
-0.062
3
5620
3
5644
0.067
21
5420
348
15
9
590
9
583
-0.072
3
5620
3
5647
0.076
19
2414
373
15
10
501
10
493
-0.079
3
5620
3
5649
0.081
17
3932
398
15
11
408
11
398
-0.088
3
5620
3
5652
0.089
15
8748
119
Data from Trappeniers et al. [45] (continued)
T P.exp P.cal Dev p.exp p,cal
K MPa MPa % mol-dm'^ rool-dm"^
Dev
Wt
423
.15
12
.313
12
.300
-0.105
3.5620
3.5657
0.104
14
.6042
273
.15
7
.300
7
.298
-0.027
3.8560
3.8572
0.031
26
.6178
285
.65
7
.813
7
.810
-0.039
3.8560
3.8577
0.044
24
.5797
298
.15
8
.323
8
.319
-0.045
3.8560
3.8579
0.050
22
.8378
323
.15
9
.336
9
.332
-0.047
3.8560
3.8579
0.050
20
.0151
348
.15
10
.343
10
.337
-0.055
3.8560
3.8582
0.058
17
.8234
373
.15
11
.346
11,
.338
-0.075
3.8560
3.8589
0.076
16
.0710
398
.15
12
.344
12
.333
-0.086
3.8560
3.8593
0.087
14
.6384
423
.15
13
.338
13
.325
-0.101
3.8560
3.8599
0.100
13
.4444
273
.15
7
.771
7,
.770
-0.015
4.1520
4.1527
0.018
25
.0653
285,
.65
8
.333
8,
.330
-0.032
4.1520
4.1535
0.037
23
.0816
298,
,15
8,
.891
8,
.888
-0.042
4.1520
4.1540
0.047
21
.3945
348,
.15
11,
,102
11,
.096
-0.059
4.1520
4.1546
0.062
16
.5816
323,
.15
10.
.000
9,
.996
-0.048
4.1520
4.1541
0.052
18
.6773
373,
,15
12,
.200
12,
.190
-0.078
4.1520
4.1553
0.080
14
.9151
398,
,15
13,
.292
13,
.279
-0.095
4.1520
4.1560
0.095
13,
.5583
423,
,15
14,
.381
14,
.363
-0.119
4.1520
4.1568
0.117
12
.4314
273,
,15
8.
,192
8.
,192
0.004
4.4210
4.4208
-0.004
23,
.8185
285,
,65
8.
,799
8,
,798
-0.011
4.4210
4.4216
0.013
21,
.8790
298,
,15
9.
,401
9.
,400
-0.018
4.4210
4.4219
0.020
20,
,2367
323,
,15
10,
,600
10.
,597
-0.030
4.4210
4.4224
0.033
17,
.6040
348.
,15
11,
,790
11,
,785
-0.043
4.4210
4.4230
0.045
15,
.5862
373,
,15
12,
.975
12,
,967
-0.061
4.4210
4.4237
0.062
13.
,9894
398,
,15
14,
,155
14.
,143
-0.082
4.4210
4.4246
0.082
12.
,6941
423,
,15
15,
,328
15,
,315
-0.088
4.4210
4.4248
0.086
11.
,6229
273,
,15
8.
,240
8.
,241
0.008
4.4520
4.4516
-0.010
23.
,6838
285,
,65
8.
,852
8.
,851
-0.008
4.4520
4.4524
0.010
21.
,7487
298,
,15
9.
,461
9.
,459
-0.020
4.4520
4.4530
0.022
20.
,1106
323,
,15
10.
.669
10.
,666
-0.030
4.4520
4.4534
0.032
17.
,4876
348.
,15
11.
,870
11.
,865
-0.045
4.4520
4.4541
0.047
15.
,4781
373.
,15
13.
,066
13.
,057
-0.068
4.4520
4.4550
0.068
13.
,8887
398.
,15
14.
,256
14.
,243
-0.085
4.4520
4.4558
0.085
12.
6003
423.
.15
15.
.441
15.
,425
-0.103
4.4520
4.4565
0.101
11.
5344
273.
,15
8.
,714
8.
,715
0.017
4.7590
4.7581
-0.020
22.
4271
285.
,65
9.
,378
9.
,378
0.002
4.7590
4.7589
-0.002
20.
5363
120
Data from Trappeniers et al, [45] (continued)
T P,exp P.cal Dev P.exp p , cal
K MPa MPa % mol-dm"^ mol-dm'^
Dev
Wt
298
.15
10
.040
10
.039
-0.015
4,
.7590
4,
.7598
0.
.017
18
.9427
323
.15
11,
.354
11
.351
-0.027
4,
.7590
4,
.7604
0,
.029
16
.4069
348
.15
12
.660
12
.654
-0.047
4
.7590
4,
.7613
.049
14
.4768
373
.15
13,
.958
13
.949
-0.068
4,
.7590
4,
.7623
0,
.069
12
.9588
398
.15
15,
.252
15
.238
-0.095
4,
.7590
4,
.7634
0,
.093
11
.7330
423
.15
16,
,540
16
.521
-0.113
4,
.7590
4,
.7642
0.
.110
10
.7229
273
.15
8,
.740
8,
.743
0.029
4,
,7770
4,
.7753
-0,
.035
22
.3593
285,
.65
9,
.408
9
.409
0.009
4,
.7770
4,
.7765
-0,
.010
20,
.4701
298,
.15
10,
,073
10,
.073
-0.003
4,
.7770
4,
,7772
0,
.004
18
.8794
323,
.15
11,
,393
11,
.391
-0.018
4,
,7770
4,
.7779
0,
.019
16
.3481
348,
,15
12,
,705
12,
,700
-0.036
4,
,7770
4,
,7788
0,
,037
14,
.4225
373,
.15
14.
,008
14,
,001
-0.050
4,
.7770
4,
,7794
0,
,051
12,
.9087
398,
,15
15.
,307
15,
,296
-0.071
4,
,7770
4,
,7803
0,
,070
11,
.6866
423,
,15
16.
,600
16,
,586
-0.088
4,
,7770
4,
,7811
0,
,085
10,
.6796
273,
,15
9.
,136
9,
,141
0.046
5,
,0380
5,
,0352
-0,
,056
21,
.4016
285.
,65
9.
,851
9.
,854
0.025
5,
,0380
5,
,0366
-0,
,028
19,
.5460
298.
,15
10.
,562
10.
,563
0.013
5,
,0380
5,
,0373
-0,
,014
17,
.9899
323,
,15
11.
,974
11.
,973
-0.009
5.
,0380
5.
,0385
0,
,009
15,
,5254
348,
.15
13.
,377
13.
,373
-0.033
5.
,0380
5.
,0397
0.
,034
13,
,6613
373.
,15
14.
,773
14.
,765
-0.059
5.
,0380
5.
,0410
0.
,059
12,
,2019
398.
,15
16.
,162
16.
,149
-0.082
5.
,0380
5.
,0420
0.
,080
11.
,0285
423.
,15
17.
,546
17.
,528
-0.104
5.
,0380
5.
,0430
0.
,100
10.
,0644
273.
,15
9.
,282
9.
,286
0.039
5.
,1340
5.
,1316
-0.
,046
21.
,0679
285.
,65
10.
,015
10.
,017
0.016
5.
,1340
5.
,1331
-0.
,018
19.
,2241
298.
,15
10.
,743
10.
,743
0.002
5.
,1340
5,
,1339
-0.
,003
17.
,6802
323.
,15
12.
,189
12.
,187
-0.018
5.
,1340
5.
,1350
0.
,019
15,
,2397
348.
,15
13.
,627
13,
,621
-0.043
5.
,1340
5.
,1362
0.
,044
13,
,3974
373,
,15
15.
,056
15,
,046
-0.062
5.
,1340
5.
,1372
0.
,062
11,
,9578
398,
,15
16.
,478
16,
,465
-0.080
5.
,1340
5.
,1380
0.
,078
10,
,8018
423,
,15
17.
,894
17,
,877
-0.097
5.
,1340
5.
,1388
0.
,093
9,
.8529
273,
,15
9.
,832
9,
,839
0.072
5.
, 5020
5.
,4973
-0.
,086
19,
,8837
285,
,65
10.
,633
10,
,638
0.047
5.
,5020
5.
,4990
-0.
,054
18,
,0820
298,
,15
11.
,428
11,
,432
0.034
5.
,5020
5.
,4999
-0.
,038
16,
.5821
323,
,15
13.
,009
13,
,010
0.009
5.
,5020
5.
,5015
-0.
,009
14,
,2269
348,
,15
14.
,580
14,
,577
-0.022
5.
,5020
5.
,5032
0.
,022
12,
,4625
121
Data from Trappeniers et al. [45] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm'^ mol-dm"^
Dev
Wt
373
.15
16
.142
16
.135
-0.045
5
.5020
5
.5044
.044
11
.0923
398
.15
17
.696
17
.684
-0.065
5
.5020
5
.5055
.063
9
.9975
423,
.15
19
.244
19
.227
-0.087
5
.5020
5
.5065
.082
9
.1023
273,
.15
10
.364
10
.373
0.084
5
.8600
5
.8541
-0
.100
18
.8412
285
.65
11
.233
11
.239
0.059
5
.8600
5
.8561
-0
.067
17
.0782
298
.15
12
.096
12,
.101
0.042
5,
.8600
5
.8573
-0
.046
15
.6179
323,
.15
13
.813
13,
.814
0.012
5
.8600
5,
.8593
-0
.013
13
.3403
348,
.15
15,
.519
15,
.515
-0.023
5
.8600
5,
.8613
.023
11
.6465
373,
.15
17,
.215
17,
,206
-0.048
5
.8600
5,
.8628
.047
10,
.3388
398,
.15
18,
.902
18,
.888
-0.071
5,
.8600
5
.8640
.068
9
.2987
423,
.15
20,
.583
20,
.563
-0.099
5
.8600
5,
.8654
.093
8,
.4514
273,
,15
10,
.861
10,
.873
0.116
6
.1980
6
.1895
-0
.137
17,
.9411
285.
,65
11,
.796
11,
.806
0.087
6,
.1980
6,
.1919
-0
.099
16,
.2124
298.
,15
12,
,725
12,
.734
0.071
6
.1980
6
.1932
-0
.077
14,
.7880
323.
,15
14,
.574
14,
.579
0.036
6,
.1980
6,
.1957
-0
.037
12,
.5795
348.
,15
16.
,412
16,
.411
-0.005
6,
.1980
6,
.1983
0,
.005
10,
.9481
373.
,15
18.
,237
18,
,232
-0.029
6,
.1980
6,
.1998
0,
.028
9,
,6957
398.
,15
20.
,053
20,
,043
-0.051
6,
.1980
6,
.2010
0,
.048
8,
.7037
423.
,15
21.
,864
21,
,846
-0.080
6,
,1980
6,
.2026
0,
.074
7,
.8983
273.
15
10.
,993
11,
,005
0.108
6,
.2870
6,
.2790
-0,
.128
17,
,7137
285.
,65
11.
,945
11.
,956
0.090
6.
,2870
6,
,2806
-0,
,101
15.
,9951
298.
,15
12.
,892
12.
,901
0.072
6.
,2870
6,
,2820
-0,
.079
14.
,5800
323.
,15
14.
,777
14.
,782
0.034
6,
,2870
6,
,2848
-0,
.035
12.
,3892
348.
,15
16.
,649
16.
,649
-0.005
6.
,2870
6.
,2873
0,
,005
10.
,7740
373.
,15
18.
,511
18.
,504
-0.035
6.
,2870
6.
,2891
0,
,034
9,
,5353
398.
.15
20.
,361
20.
,351
-0.054
6.
,2870
6.
,2902
0.
,050
8.
5557
423.
,15
22.
,205
22.
,188
-0.076
6.
,2870
6.
,2914
0.
,070
7.
,7611
273.
.15
11.
,358
11.
,371
0.122
6.
,5350
6.
,5256
-0.
,144
17.
1058
285.
.65
12.
,360
12.
,372
0.097
6.
,5350
6.
,5279
-0.
,109
15.
,4115
298.
,15
13.
,358
13.
,368
0.076
6.
,5350
6.
,5296
-0.
,082
14.
0217
323.
.15
15.
,343
15.
,349
0.038
6.
,5350
6.
,5324
-0.
,039
11.
8801
348.
,15
17.
,315
17.
,315
0.004
6,
,5350
6.
,5348
-0.
,003
10.
3089
373.
.15
19.
,276
19.
,270
-0.032
6.
,5350
6.
,5370
0.
030
9.
1081
398.
.15
21.
,227
21.
,215
-0.061
6.
,5350
6.
5387
0.
056
8.
1611
423.
,15
23,
,170
23.
,150
-0.084
6.
,5350
6.
,5400
0.
077
7.
3951
122
Data from Trappeniers et al. [45] (continued)
T P.exp P.cal Dev P , exp p , cal
K MPa MPa % mol-dm"^ mol-dm'^
Dev
Wt
273
15
11
.738
11
.753
.128
6
.7930
6
.7829
-0
149
16
.5030
285
65
12
.793
12
.807
.108
6
.7930
6
.7848
-0
120
14
8353
298
15
13
.846
13
.857
.081
6
.7930
6
7871
-0
087
13
4715
323
15
15
937
15
944
044
6
7930
6
7900
-0
044
11
3799
348
15
18
017
18
017
.000
6
7930
6
7930
000
9
8526
373
15
20
084
20
077
-0
035
6
7930
6
7952
032
8
6902
398
15
22
139
22
126
-0
058
6
7930
6
7966
053
7
7764
423
15
24
186
24
166
-0
081
6
7930
6
7979
072
7
0389
273
15
11
839
11
855
133
6
8620
6
8514
-0
155
16
3469
285
65
12
911
12
924
099
6
8620
6
8544
-0
111
14
6850
298
15
13
977
13
988
081
6
8620
6
8561
-0
086
13
3289
323
15
16
097
16
104
044
6
8620
6
8590
-0
044
11
2506
348
15
18
205
18
206
006
6
8620
6
8616
-0
006
9
7353
373
15
20
300
20
295
-0
028
6
8620
6
8638
027
8
5829
398
15
22
385
22
372
-0
056
6
8620
6
8655
051
7
6776
423
15
24
462
24
441
-0
087
6
8620
6
8673
078
6
9473
273
15
12
489
12
508
147
7
3020
7
2897
-0
168
15
3909
285
65
13
654
13
672
133
7
3020
7
2914
-0
145
13
7754
298
15
14
816
14
831
105
7
3020
7
2939
-0
111
12
4635
323
15
17
126
17
137
062
7
3020
7
2975
-0
061
10
4685
348
15
19
424
19
427
017
7
3020
7
3008
-0
016
9
0257
373
15
21
761
21
703
-0
265
7
3020
7
3197
243
7
9266
398
15
23
976
23
967
-0
034
7
3020
7
3042
031
7
0837
423
15
26
237
26
221
-0
062
7
3020
7
3060
055
6
3990
273
15
13
271
13
293
167
7
8250
7
8104
-0
187
14
3315
285
65
14
554
14
575
146
7
8250
7
8128
-0
155
12
7714
298
15
15
833
15
853
127
7
8250
7
8148
-0
130
11
5144
323
15
18
380
18
395
081
7
8250
7
8189
-0
078
9
6183
348
15
20
912
20
919
034
7
8250
7
8226
-0
031
8
2597
373
15
23
431
23
429
-0
008
7
8250
7
8256
007
7
2401
398
15
25
931
25
926
-0
022
7
8250
7
8265
019
6
4480
423
15
28
422
28
410
-0
041
7
8250
7
8277
035
5
8143
273
15
14
050
14
073
166
8
3350
8
3200
-0
180
13
3587
285
65
15
454
15
477
151
8
3350
8
3220
-0
157
11
8574
298
15
16
855
16
876
128
8
3350
8
3244
-0
128
10
6554
323
15
19
643
19
660
087
8
3350
8
3282
-0
081
8
8572
123
Data from Trappeniers et al. [45] (continued)
T P.exp P.cal Dev p.exp p.cal
K MPa MPa % mol-dm'^ mol-dm'^
Dev
Wt
348
15
22
417
22
.426
0.038
8
3350
8
.3321
-0
034
7
.5793
373
15
25
176
25
176
-0.003
8
3350
8
.3352
003
6
.6265
398
15
27
916
27
910
-0.020
8
3350
8
3364
017
5
.8896
423
15
30
642
30
632
-0.036
8
3350
8
.3375
029
5
.3025
273
15
14
802
14
826
0.159
8
8140
8
7992
-0
168
12
.4877
285
65
16
.326
16
350
0.146
8
8140
8
8011
-0
146
11
.0456
298
15
17
.847
17
869
0.122
8
8140
8
8036
-0
118
9
.8981
323
15
20
874
20
891
0.083
8
8140
8
.8073
-0
.075
8
.1934
348
15
23
887
23
895
0.034
8
8140
8
8114
-0
030
6
.9909
373
15
26
882
26
881
-0.003
8
8140
8
8142
003
6
.0991
398
15
29
860
29
851
-0.029
8
8140
8
8161
024
5
.4119
423
15
32
823
32
806
-0.052
8
8140
8
8177
042
4
.8661
273
15
15
535
15
560
0.166
9
2670
9
2514
-0
169
11
.6951
285
65
17
177
17
203
0.153
9
2670
9
2533
-0
148
10
.3134
298
15
18
816
18
841
0.130
9
2670
9
2558
-0
121
9
.2199
323
15
22
079
22
100
0.097
9
2670
9
2591
-0
085
7
.6057
348
15
25
327
25
340
0.053
9
2670
9
2629
-0
045
6
.4741
373
15
28
558
28
561
0.010
9
2670
9
2662
-0
008
5
6385
398
15
31
773
31
763
-0.030
9
2670
9
2692
024
4
9965
423
15
34
971
34
950
-0.062
9
2670
9
2715
048
4
4881
273
15
15
582
15
607
0.156
9
2950
9
2803
-0
158
11
6463
285
65
17
232
17
257
0.146
9
2950
9
2819
-0
141
10
2687
298
15
18
877
18
902
0.130
9
2950
9
2838
-0
120
9
1791
323
15
22
156
22
177
0.093
9
2950
9
2874
-0
081
7
5704
348
15
25
419
25
431
0.049
9
2950
9
2912
-0
041
6
4432
373
15
28
663
28
667
0.012
9
2950
9
2941
-0
010
5
6111
398
15
31
891
31
884
-0.022
9
2950
9
2966
017
4
9721
423
15
35
102
35
085
-0.047
9
2950
9
2984
036
2
9773
273
15
16
369
16
392
0.136
9
7600
9
7471
-0
132
10
8579
285
65
18
147
18
170
0.125
9
7600
9
7487
-0
116
9
5477
298
15
19
921
19
943
0.112
9
7600
9
7502
-0
100
8
5169
323
15
23
455
23
474
0.080
9
7600
9
7534
-0
068
7
0035
348
15
26
973
26
983
0.039
9
7600
9
7569
-0
031
5
9489
373
15
30
470
30
471
0.002
9
7600
9
7599
-0
001
5
1735
398
15
33
950
33
939
-0.031
9
7600
9
7623
024
4
5797
124
Data from Trappeniers et al, [45] (continued)
T P,exp P.cal Dev /J.exp p,cal
K MPa MPa % mol-dm'^ mol-dm"^
Dev
Wt
423
.15
37
.408
37
.390
-0
.048
9
.7600
9
.7635
.036
2
.7403
273
.15
16
.812
16
.833
.130
10
.0130
10
.0007
-0
.123
10
.4388
285
.65
18
.661
18
.684
.123
10
.0130
10
.0018
-0
.112
9
.1675
298
.15
20
.509
20
.530
.105
10
.0130
10
.0038
-0
.092
8
.1695
323
.15
24
.187
24
.205
.074
10
.0130
10
.0069
-0
.061
6
.7088
348
.15
27
.848
27
.858
.035
10,
.0130
10
.0103
-0
.027
5
.6936
373
.15
31
.487
31,
.489
.005
10,
.0130
10
.0126
-0
.004
4
.9487
398
.15
35
.111
35,
.099
-0
.035
10,
.0130
10
.0157
.027
2
.9191
423
.15
38
.713
38,
.690
-0
.058
10,
.0130
10
.0173
.043
2
.6191
273
.15
18
.199
18
.218
.102
10,
.7630
10,
.7534
-0
.089
9
.2324
285,
.65
20
.275
20,
.295
.102
10,
,7630
10,
.7538
-0
.086
8,
.0848
298,
.15
22,
.347
22,
.368
0,
.091
10,
.7630
10
.7550
-0
.074
7,
.1896
323,
,15
26,
.479
26,
,495
0,
.060
10,
,7630
10,
.7580
-0
.047
5,
.8874
348,
.15
30,
.586
30,
.596
0,
.032
10,
,7630
10,
.7604
-0
.024
4,
,9883
373,
,15
34,
.672
34,
,672
-0,
.003
10,
,7630
10,
.7632
.002
4,
.3308
398,
,15
38,
,736
38,
.723
-0,
,031
10,
,7630
10,
,7654
.023
2,
.5528
423,
,15
42,
,777
42,
,754
-0,
.054
10,
,7630
10,
.7671
0,
.038
2,
.2893
273,
.15
19,
.771
19,
,785
0,
,075
11,
,5340
11,
,5271
-0,
.060
8,
,0511
285,
,65
22,
.098
22,
,116
0,
,080
11,
,5340
11,
,5269
-0,
.062
7,
,0412
298,
,15
24,
.423
24,
.441
0,
,077
11,
,5340
11,
,5274
-0,
,057
6,
.2565
323,
,15
29,
,055
29,
,071
0,
,056
11.
,5340
11,
,5294
-0,
.040
5,
,1193
348,
,15
33,
.661
33,
,671
0,
,030
11.
,5340
11,
,5316
-0,
,021
4,
,3363
373,
,15
38,
,241
38,
,242
0,
,001
11.
,5340
11,
,5339
-0,
,001
2,
,5098
398,
,15
42,
,799
42,
,784
-0,
.034
11.
,5340
11,
,5367
0,
,023
2,
,2193
423,
,15
47,
,325
47,
,301
-0,
,051
11.
,5340
11,
,5379
0,
.034
1,
,9905
273,
,15
21,
,491
21,
,498
0,
,031
12.
2870
12.
.2843
-0,
,022
6,
,9641
285,
,65
24,
,088
24,
,097
0,
,040
12.
2870
12,
,2835
-0,
,028
6,
,0938
298,
,15
26,
.680
26,
,691
0,
,042
12.
,2870
12,
,2834
-0,
,029
5,
,4183
323,
,15
31,
,837
31,
,853
0,
,051
12.
,2870
12.
,2829
-0,
,034
4.
,4398
348,
,15
36,
,971
36.
,981
0,
,027
12.
,2870
12,
,2848
-0,
,018
2,
,5103
373,
,15
42,
,073
42,
,074
0.
,001
12.
2870
12.
.2869
-0,
.001
2,
,1817
398,
,15
47,
,151
47.
,134
-0.
,036
12.
2870
12.
.2898
0,
.023
1,
,9310
423,
,15
52,
,196
52,
,165
-0,
.060
12.
2870
12.
2916
0,
.038
1,
.7332
273,
,15
23,
,308
23.
,310
0,
,010
12.
9940
12.
9931
-0,
.007
6,
.0171
285,
,65
26,
,178
26.
,184
0,
.022
12.
9940
12.
9922
-0,
.014
5,
.2764
125
Data from Trappeniers et al. [45] (continued)
T P.exp P.cal Dev P.exp p,cal
K MPa MPa % mol-dm'^ mol-dm"^
Dev
Wt
298,
,15
29,
.043
29.
.050
0.
.023
12,
.9940
12
.9921
-0
.015
4
.7004
323,
,15
34,
,746
34.
.753
0,
.021
12,
.9940
12,
.9923
-0,
.013
3
.8634
348,
,15
40,
.417
40.
.415
-0,
.006
12.
.9940
12,
.9945
.003
2
.1897
373,
,15
46,
.053
46.
.036
-0,
.036
12,
.9940
12,
.9969
.022
1
.9068
398,
,15
51,
.648
51.
.620
-0,
.056
12
.9940
12,
.9983
0,
.033
1
.6903
423,
,15
57,
.210
57.
.170
-0,
.069
12,
.9940
12,
.9994
0,
.041
1
.5191
273,
,15
24,
.678
24.
.677
-0,
.004
13,
.4740
13.
.4744
0,
.003
5
.4204
285,
,65
27,
.745
27,
.749
0,
.015
13,
.4740
13.
.4728
-0,
.009
4
.7642
298,
,15
30,
.809
30,
,813
0,
.012
13,
.4740
13
.4731
-0
.007
4,
.2522
323,
,15
36,
.907
36,
.906
-0,
.003
13,
.4740
13,
.4742
0,
.002
2
.3372
348,
,15
42,
.958
42,
.953
-0,
,011
13,
.4740
13,
.4749
.007
1
.9917
373,
.15
48,
.980
48,
.956
-0,
,050
13.
.4740
13,
.4779
.029
1,
.7374
398,
,15
54,
.953
54,
.917
-0,
,066
13.
.4740
13,
.4791
.038
1
.5423
423,
.15
60,
.890
60,
.842
-0,
,080
13.
.4740
13,
.4801
.046
1,
.3877
273,
.15
25,
.373
25,
.373
0,
.000
13.
,7030
13,
.7030
0,
.000
5
.1501
285,
.65
28,
.542
28,
.544
0,
.004
13,
.7030
13,
,7027
-0
.002
4,
.5323
298,
.15
31,
.704
31,
.705
0,
.004
13.
,7030
13,
,7027
-0
.002
4,
.0498
323,
.15
37,
.994
37,
.992
-0,
.007
13.
.7030
13,
,7035
0,
.004
2,
.2297
348,
.15
44,
.243
44,
.230
-0,
.031
13.
,7030
13,
.7054
0,
.018
1,
.9024
373,
.15
50,
.449
50,
.421
-0,
.056
13,
,7030
13,
,7074
0,
.032
1,
.6612
398.
,15
56,
.614
56,
.569
-0,
.080
13.
.7030
13,
.7092
0.
,045
1,
.4758
423,
,15
62,
.732
62,
.678
-0,
.086
13.
.7030
13.
.7096
0,
.048
1,
,3286
273.
.15
28,
.274
28,
.265
-0,
.029
14.
.5600
14.
,5622
0,
.015
4,
.2232
285.
.65
31,
.837
31,
,828
-0,
.027
14.
,5600
14.
,5620
0,
.014
3,
.7389
298,
.15
35.
.391
35,
,378
-0,
,038
14,
,5600
14.
.5629
0,
,020
2,
,2381
323
.15
42,
.458
42,
.431
-0,
.063
14.
.5600
14.
.5648
0,
.033
1,
,8624
348
.15
49,
.462
49,
.424
-0,
.076
14.
,5600
14.
.5658
0,
.040
1,
,5979
373
.15
56,
.415
56,
.361
-0,
.095
14.
.5600
14.
.5672
0,
.050
1,
,4012
398
.15
63,
.315
63,
.248
-0,
.106
14.
.5600
14.
.5681
0,
.056
1,
,2489
423
.15
70,
.160
70,
.090
-0,
.099
14.
.5600
14,
.5676
0,
.052
1.
,1274
273
.15
32,
.762
32
.750
-0,
.038
15.
.6530
15,
.6557
0.
.018
3,
,2389
285
.65
36,
.889
36,
.868
-0,
.058
15,
.6530
15,
.6572
0,
.027
1.
,9296
298
.15
40
.998
40,
.966
-0,
.078
15,
.6530
15,
.6587
0,
.036
1.
,7459
323
.15
49
.160
49,
.102
-0,
.118
15,
.6530
15,
.6616
0,
.055
1.
,4698
348
.15
57
.235
57,
.160
-0,
.131
15,
.6530
15,
.6627
0.
.062
1.
,2718
126
Data from Trappeniers et al . [45] (continued)
T P,exp P.cal Dev p.exp p,cal
K MPa MPa % mol-cin"^ mol-dm"^
Dev
Wt
373,
.15
65.
.243
65
.149
-0.
.145
15.
.6530
15,
.6638
.069
1.
.1225
398,
.15
73.
.175
73
.076
-0.
.135
15.
.6530
15,
.6631
.065
1,
.0055
423,
.15
81,
.041
80
.951
-0.
.111
15.
.6530
15,
.6614
0,
.054
0,
.9113
273,
.15
38.
.578
38
.545
-0.
.086
16.
.7770
16,
.7828
0,
.034
1.
.6288
285,
.65
43.
.355
43
.305
-0.
.114
16.
.7770
16,
.7847
0,
.046
1,
.4711
298,
.15
48.
.110
48,
.037
-0.
,151
16.
.7770
16,
.7874
0,
.062
1,
,3427
323,
.15
57.
.533
57,
.421
-0.
,196
16.
.7770
16,
.7908
0,
.082
1.
,1455
348,
.15
66.
.849
66,
.705
-0.
,214
16.
.7770
16,
.7924
0,
.092
1,
,0008
373,
.15
76.
.067
75,
.905
-0,
,213
16.
.7770
16,
.7925
0.
.092
0,
,8897
398,
.15
85.
.185
85,
.031
-0,
,180
16.
.7770
16,
.7902
0.
.079
0,
,8016
423.
,15
94.
,210
94.
.096
-0,
,121
16.
.7770
16.
.7860
0.
.053
0,
,7299
273.
.15
39.
,645
39,
.600
-0,
,112
16.
.9560
16.
.9634
0,
.044
1.
,5566
285.
.65
44.
,532
44,
.470
-0,
,139
16.
.9560
16.
.9653
0,
.055
1.
,4083
298.
,15
49.
,396
49.
.310
-0.
,175
16.
,9560
16,
.9679
0.
.070
1.
,2871
323.
,15
59.
,033
58,
.905
-0.
,217
16.
.9560
16,
.9712
0,
.090
1.
,1005
348.
,15
68.
,564
68.
.398
-0,
,241
16.
.9560
16.
.9732
0,
.102
0.
,9630
373.
,15
77.
,991
77.
.804
-0.
,240
16.
,9560
16.
.9734
0.
.103
0.
,8572
398.
,15
87.
,304
87.
.134
-0,
,195
16.
,9560
16.
.9702
0.
.084
0,
,7730
273.
,15
45.
,790
45,
.689
-0,
,221
17.
,8750
17.
.8889
0.
.078
1.
,2322
285.
,65
51.
,285
51.
.151
-0,
,261
17,
,8750
17.
.8918
0.
.094
1,
,1246
298.
,15
56.
,750
56.
.577
-0.
,305
17.
.8750
17.
.8950
0.
.112
1.
,0351
323.
,15
67.
,554
67,
.324
-0.
,340
17.
.8750
17,
.8981
0.
.129
0,
,8949
348.
,15
78.
,223
77,
.951
-0,
,349
17.
.8750
17,
.8993
0.
.136
0,
,7895
373.
.15
88.
,749
88,
.476
-0.
,308
17.
.8750
17.
.8968
0.
.122
0,
,7071
398.
.15
99.
,153
98,
.916
-0,
,239
17.
.8750
17,
.8921
0.
.096
0.
,6408
423.
.15
109.
,438
109,
.287
-0,
,139
17.
.8750
17,
.8851
0.
.056
0,
,5863
273.
.15
52.
,050
51,
.879
-0.
,329
18.
.6570
18.
.6769
0.
.107
1.
,0103
285.
.65
58.
,119
57,
.891
-0,
,393
18.
.6570
18,
.6815
0.
.131
0,
,9285
298.
.15
64.
,122
63
.858
-0,
,412
18.
.6570
18,
.6833
0.
.141
0,
,8597
323,
.15
76.
,008
75,
.673
-0.
,441
18.
.6570
18.
.6862
0.
.156
0.
,7500
348,
.15
87.
.717
87
.351
-0,
,417
18.
.6570
18.
.6854
0.
.152
0.
,6662
373,
.15
99.
.272
98,
.917
-0.
,358
18.
.6570
18.
.6819
0.
.133
0,
.5998
398,
.15
110.
.653
110
.390
-0.
,238
18.
.6570
18.
.6739
0.
.090
0,
.5459
273,
.15
54.
.294
54,
.090
-0.
,375
18.
.9080
18,
.9304
0.
.119
0.
.9481
285,
.65
60.
.544
60
.287
-0.
,424
18.
.9080
18,
.9342
0,
.138
0.
.8732
127
Data from Trappeniers et al. [45] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % inol-dm"^ mol-din'^
Dev
Wt
298
.15
66
.744
66
.437
-0
.460
18
.9080
18
.9371
.154
.8100
323
.15
78
.994
78
.613
-0
.482
18
.9080
18
.9397
.168
.7086
348
.15
91
.058
90
.648
-0
.451
18
.9080
18
.9385
.161
.6308
373
.15
102
.949
102
.566
-0
.373
18
.9080
18
.9338
.136
.5689
398
.15
114,
.685
114,
.388
-0
.259
18
.9080
18
.9262
.096
.5184
423
.15
126,
.275
126,
.133
-0,
.112
18
.9080
18
.9160
.042
.4764
273,
.15
64,
.911
64,
.537
-0,
.576
19
.9440
19
.9773
0.
.167
.7308
285,
.65
72,
.005
71,
.549
-0,
.633
19
.9440
19
.9818
0.
.189
.6788
298,
.15
79,
,018
78,
.505
-0,
.649
19
.9440
19
.9838
0.
.200
.6341
323.
,15
92,
.860
92,
.272
-0,
.634
19
.9440
19
.9846
0.
.203
.5610
348,
.15
106,
.475
105,
.877
-0,
.562
19
.9440
19
.9812
0.
.186
0.
.5036
373,
,15
119,
,862
119,
.351
-0,
.427
19.
.9440
19
.9729
0.
.145
.4572
398,
,15
133,
,045
132,
,721
-0,
.244
19.
.9440
19.
.9608
0.
.084
0.
.4189
423,
,15
146,
,052
146,
.006
-0,
.031
19.
.9440
19
.9462
0.
.011
0.
.3866
273,
,15
70,
,125
69,
.657
-0,
.668
20.
.3810
20.
.4191
0.
,187
0.
.6556
285.
,65
77,
,578
77,
.037
-0,
.697
20.
.3810
20.
.4221
0.
,202
0.
.6109
298.
,15
84,
,960
84,
,359
-0,
,707
20.
. 3810
20.
.4239
0,
.210
0.
.5722
323,
,15
99,
,515
98,
.848
-0,
.670
20.
.3810
20.
.4234
0,
,208
0.
.5085
348,
,15
113,
,813
113,
.168
-0,
.567
20.
.3810
20.
.4181
0,
,182
0.
,4581
373,
,15
127,
,867
127,
.352
-0,
,402
20.
,3810
20.
.4080
0,
,133
0.
.4170
398,
,15
141,
,711
141,
,428
-0,
,200
20.
.3810
20.
.3947
0,
,067
0,
.3829
273,
,15
95,
,434
94,
,444
-1,
,036
22.
.0790
22.
.1362
0.
,259
0,
,4334
285,
,65
104,
,481
103,
,419
-1,
,016
22,
,0790
22,
,1369
0,
,262
0,
,4083
298,
.15
113,
.423
112,
.323
-0,
,970
22,
.0790
22,
.1359
0,
,258
0,
,3861
323,
.15
131,
,013
129,
,949
-0,
,812
22,
,0790
22,
,1288
0.
,226
0,
,3485
348,
.15
148,
.245
147,
,381
-0,
,583
22,
,0790
22,
,1160
0.
.168
0.
,3177
373,
.15
165,
,122
164,
,662
-0,
,279
22,
,0790
22,
,0972
0.
.082
0.
,2920
398,
.15
181,
.755
181,
,825
0,
,038
22,
,0790
22,
,0764
-0.
.012
0.
.2702
273,
.15
132,
.872
131,
,161
-1,
,288
23,
,8640
23,
,9340
0.
293
0.
2851
285,
.15
143,
.821
141,
.692
-1,
,481
23,
,8640
23,
,9470
0.
.348
0.
2715
298,
.15
154,
.629
153,
.018
-1.
,042
23,
,8640
23.
,9239
0.
251
0.
2583
323
.15
175,
.817
174,
,600
-0,
.692
23,
.8640
23.
,9056
0.
174
0.
2362
348,
.15
196,
.524
195,
.978
-0.
,278
23.
,8640
23.
,8813
0.
072
0.
2176
373,
.15
216,
.792
217,
,200
0.
.188
23.
,8640
23.
,8520
-0.
050
0.
2018
398,
.15
236,
.696
238,
.305
0.
.680
23.
,8640
23.
.8197
-0.
186
0.
1881
128
Data from Trappeniers et al, [45] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm"^ mol-dm'^
273.15 183.811 181.441
285.65 196.882 194.750
298.15 209.721 207.981
323.15 234.829 234.252
348.15 259.361 260.330
•1.289 25.6140 25.6841
■1.083 25.6140 25.6745
•0.830 25.6140 25.6614
•0.246 25.6140 25.6286
0.374 25.6140 25.5911
Number of Points (Ref.45) 472
PRESSURE;
DENSITY
AAD-%
AAD
AAD-%
AAD
0.123
0.088
0.074
0.007
BIAS-%
BIAS
BIAS-%
BIAS
•0.084
•0.070
0.039
0.004
RMS-%
RMS
RMS-%
RMS
Dev
Wt
%
0.274
.1924
0.236
0,
.1841
0.185
0,
.1766
0.057
0,
.1631
-0.089
0,
.1516
0.209
0.284 MPa
0.082
0.013 mol-dm'3
Data from Van Itterbeek et al. [46]
T P.exp P,cal Dev p.exp p.cal Dev
K MPa MPa % mol-dm"^ mol-dm"^ %
Wt
114,
.52
0.
.894
1,
.160
29.
,684
26,
.1376
26,
.1213
-0,
.062
0,
.0001
114.
,52
4,
.752
4,
,946
4,
,082
26,
.3609
26,
.3498
-0,
.042
0,
.0001
114.
.52
7.
,542
7,
,638
1,
,275
26,
.5104
26,
.5052
-0,
.020
0,
.0001
114,
,52
10,
,382
10,
.424
0,
,398
26,
.6581
26,
.6560
-0,
.008
0,
.0001
114,
.52
13,
.326
13,
.312
-0,
,100
26,
.8046
26,
.8053
0,
.002
0,
.0001
114,
.52
16,
.344
16,
.378
0,
,211
26,
.9535
26,
.9518
-0,
.006
0,
.0001
114,
.52
19,
.666
19,
.599
-0,
.338
27,
.1032
27,
.1062
0,
.011
0,
.0001
114,
.52
23,
.245
23,
.219
-0,
.111
27,
.2643
27,
.2654
0,
.004
0,
.0001
114,
.52
27,
.155
27,
.140
-0,
.056
27,
.4311
27,
.4317
0,
.002
0,
.0001
114,
.52
31,
.299
31,
.523
0,
.718
27,
.6091
27,
.6001
-0,
.032
0,
.0000
119,
.42
0,
.833
1,
.149
37,
.950
25,
.6812
25,
.6598
-0,
.083
0,
.0001
119,
.42
3,
.027
3,
.477
14,
.846
25,
.8345
25,
.8055
-0,
.112
.0001
119,
.42
6,
.215
6,
.638
6,
.817
26,
.0308
26,
.0052
-0,
.098
.0001
119,
.42
10,
.401
10,
.733
3,
.194
26,
.2681
26,
.2495
-0,
.071
.0001
119,
.42
14,
.909
15,
.100
1,
.279
26,
.5034
26,
.4935
-0,
.037
0,
.0001
129
Data from Van Itterbeek et al . [46] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm'^ mol-drn'^
Dev
Wt
119
.42
19
.837
19
.972
.682
26
.7480
26
.7414
-0
.025
.0001
119
.42
25
.375
25
.475
.394
27
.0051
27
.0006
-0
.017
.0001
119
.42
31
.691
31
.198
-1
.556
27
.2546
27
.2754
.076
.0001
124
.92
.980
1
.819
85
.668
25
.2010
25
.1375
-0
.252
.0001
124
.92
4
.496
5
.182
15
.250
25
.4421
25
.3945
-0
.187
.0001
124
.92
8
.419
8
.952
6
.335
25
.6911
25
.6571
-0
.132
.0001
124
.92
12,
.519
13
.004
3
.872
25
.9383
25
.9097
-0
.110
.0001
124
.92
16,
.883
17
.136
1
.498
26
.1725
26
.1587
-0
.053
.0001
124
.92
21,
.799
21
.948
.687
26,
.4264
26
.4187
-0
.029
.0001
124
.92
27,
,364
27
.467
.378
26,
.6966
26
.6917
-0
.018
.0001
130,
.99
1.
.502
1,
.792
19,
.298
24,
.5924
24,
.5673
-0
.102
.0001
130,
,99
4.
.625
4,
.754
2,
.803
24,
.8361
24
.8258
-0
.041
.0001
130,
.99
7,
,934
8,
.684
9,
.448
25,
.1307
25
.0767
-0
.215
.0001
130,
.99
11,
,520
11,
,904
3,
.331
25,
.3524
25
.3268
-0
.101
.0001
130,
,99
15,
,774
15,
,495
-1,
.770
25,
.5826
25,
.5999
.067
.0001
130,
,99
20,
.071
19,
.558
-2,
.558
25,
,8251
25,
.8545
0,
.114
.0001
130,
,99
24,
,931
24,
,300
-2.
.530
26,
,0879
26.
.1214
0,
.128
0,
.0001
130.
,99
30,
,287
29.
,714
-1,
.895
26,
,3658
26,
.3940
0,
.107
0,
.0001
134,
,33
0,
,689
1.
,266
83,
.767
24,
,1949
24,
.1394
-0,
.229
0,
.0013
134,
,33
2,
,712
3.
,289
21,
.270
24,
,3807
24,
,3290
-0,
.212
0,
.0001
134,
,33
5,
,783
6.
,388
10,
.464
24,
,6433
24,
,5939
-0,
,200
0,
.0001
134,
,33
9.
,130
9,
,740
6,
.686
24,
,9029
24,
,8572
-0,
,183
0,
,0001
134,
,33
12,
,783
13,
,258
3,
.716
25,
,1534
25,
,1208
-0,
,130
0,
,0001
134,
,33
16,
,625
17.
,093
2.
,813
25,
,4059
25,
,3761
-0,
,117
0,
,0001
134,
,33
20,
,947
21,
,320
1,
,783
25,
,6634
25,
,6414
-0,
,086
0,
,0001
134,
,33
25,
,768
26,
.084
1,
.229
25.
,9323
25,
,9150
-0.
,067
0.
,0001
134,
,33
31.
,029
31,
,541
1,
,650
26.
,2171
26.
1913
-0.
098
0.
,0001
139,
,06
1.
,252
1,
,820
45,
,318
23.
7344
23.
,6737
-0.
256
0.
0002
139,
,06
3.
,825
4,
,420
15,
,546
23.
9958
23.
9382
-0.
240
0.
,0001
139,
,06
6.
,749
7,
,333
8,
,658
24.
2618
24.
2104
-0.
212
0.
0001
139,
,06
9.
,876
10.
,475
6.
,061
24.
5236
24.
4755
-0.
196
0.
0001
139,
,06
13.
230
13,
,827
4.
,515
24.
7801
24.
7359
-0.
178
0.
0001
139,
,06
16.
,900
17.
,415
3.
,045
25.
0332
24.
9981
-0.
140
0.
0001
139.
,06
20.
,966
21,
,404
2.
,087
25.
2934
25.
2658
-0.
109
0.
0001
139,
,06
25.
,497
25.
,770
1.
073
25.
5572
25.
5412
-0.
062
0.
0001
130
Data from Van Itterbeek et al. [46] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm'^ mol-dm'^
Dev
Wt
139
.06
30
.600
30,
.952
1,
.149
25
.8465
25,
,8276
-0,
.073
0,
.0001
145
.56
1
.300
1,
.826
40,
,516
22
.9848
22,
,9165
-0,
,297
0,
.0001
145,
.56
3
.528
4,
.119
16,
,770
23
.2623
23,
,1936
-0,
,296
0,
.0002
145,
.56
6
.037
6,
.627
9,
,784
23,
.5355
23,
,4736
-0,
,263
0,
.0001
145,
.56
8
.736
9,
.460
8,
,288
23
.8146
23,
,7458
-0,
,289
0,
.0001
145,
.56
11,
.719
12,
.461
6,
,333
24,
.0836
24,
,0193
-0,
,267
0,
.0001
145,
.56
14,
.913
15,
,735
5,
,509
24,
.3522
24,
,2870
-0,
,268
0,
.0001
145,
.56
18,
.402
19,
,290
4,
,829
24,
.6202
24,
,5553
-0,
,264
0,
.0001
145,
.56
22,
.258
23,
,265
4,
,525
24,
.8961
24.
,8283
-0,
,272
0,
.0001
145,
.56
26,
.589
27,
,697
4,
,168
25,
,1794
25,
,1107
-0,
,273
0,
,0001
145,
.56
31,
.458
32,
,637
3,
,746
25,
.4706
25.
,4032
-0,
,264
0,
.0001
150,
.75
3,
,102
3,
,779
21,
,826
22,
.6157
22,
,5220
-0,
,414
0,
.0001
150,
.75
5,
,188
5.
,938
14,
,450
22,
.8933
22,
,8002
-0,
,406
0,
,0002
150,
,75
7,
,511
8,
,297
10.
,462
23,
.1664
23.
,0784
-0,
,380
0,
,0002
150,
,75
10,
,039
10.
,879
8,
,363
23,
.4373
23.
,3520
-0,
,364
0,
,0001
150,
,75
12,
,807
13,
,617
6,
,322
23,
.6995
23,
,6243
-0,
,317
0,
,0001
150,
,75
15,
,745
16,
,618
5,
,542
23,
,9630
23,
,8887
-0,
,310
0,
,0001
150,
,75
19,
,000
19,
,859
4.
,520
24,
,2248
24,
,1575
-0.
,278
0,
,0001
150,
,75
22,
,614
23,
,517
3.
,997
24,
,4972
24,
,4319
-0.
,266
0,
,0001
150,
,75
26,
,640
27,
,539
3,
,371
24,
,7733
24,
,7135
-0,
,241
0,
,0001
150,
,75
30,
.986
32,
,023
3.
,346
25,
,0576
24,
,9939
-0,
,254
0,
,0001
158,
,24
2,
,289
3,
,073
34.
,213
21,
,5318
21,
,3814
-0,
,698
0,
,0001
158,
,24
3,
,963
4,
.812
21,
,438
21,
,8341
21.
,6913
-0,
,654
0,
,0003
158,
,24
5,
,895
6,
,788
15.
,154
22,
,1371
22,
,0047
-0,
,598
0,
,0002
158,
,24
8,
,025
8,
,989
12,
,005
22,
,4371
22,
,3099
-0,
,567
0,
,0002
158,
,24
10,
,390
11.
,379
9.
,520
22,
,7293
22,
.6121
-0,
,516
0,
,0002
158,
,24
12,
.936
13.
,985
8,
,111
23,
,0171
22,
,9046
-0,
,489
0,
,0002
158,
,24
15,
.762
16,
,813
6,
,667
23,
,3008
23,
,1984
-0,
,439
0,
,0001
158,
,24
18,
.908
19,
,904
5,
,269
23,
,5838
23,
,4953
-0.
,375
0,
,0001
158,
,24
22,
.362
23,
,344
4,
,389
23,
,8721
23,
,7923
-0,
,334
0,
,0001
158,
,24
26,
.172
27,
,213
3,
,977
24,
,1692
24,
,0918
-0,
,320
0,
,0001
158,
,24
30,
.459
31,
,495
3.
,401
24,
,4708
24,
,4002
-0,
,289
0,
,0001
165,
,82
3,
.056
3,
,428
12.
,197
20,
,4637
20,
,3671
-0.
,472
0,
,0002
165,
,82
4,
.220
4,
,701
11,
,393
20,
,7641
20.
,6554
-0,
,523
0,
,0004
165,
.82
5,
.627
6,
,145
9,
,204
21,
.0624
20.
,9598
-0,
,487
0,
,0003
131
Data from Van Itterbeek et al . [46] (continued)
T P.exp P.cal Dev P.exp p,cal
K MPa MPa % mol-dm"^ mol-dm'^
Dev
Wt
165
.82
7
.146
7
.760
8
.591
21
.3570
21
.2492
-0,
.505
0.0003
165
.82
8
.784
9
.569
8
.939
21
.6507
21
.5273
-0
.570
0.0002
165
.82
10
.628
11
.527
8
.466
21
.9356
21
.8084
-0
.580
0.0002
165
.82
12
.548
13
.687
9
.073
22
.2193
22
.0733
-0
.657
0.0002
165
.82
14
.671
16
.054
9
.427
22
.5012
22
.3398
-0,
.718
0.0002
165
.82
16
.984
18
.612
9
.589
22
.7790
22
.6051
-0,
.763
0.0002
165
.82
19
.490
21,
.436
9
.983
23
.0595
22
.8689
-0,
.827
0.0001
165
.82
22
.218
24,
.545
10
.473
23
.3427
23
.1331
-0,
.898
0.0001
165
.82
25
.243
27.
.980
10
.841
23
.6301
23
.4031
-0,
.960
0.0001
165
.82
28
.886
31
.669
9
.634
23
.9143
23
.7020
-0,
,888
0.0001
171,
.02
3,
.051
3,
.192
4
.632
19,
.4606
19,
.4090
-0,
.265
0.0003
171
.02
3,
.962
4,
.085
3
.117
19,
.7578
19
.7192
-0,
.195
0.0005
171,
.02
4,
,988
5,
.167
3,
.588
20,
.0678
20,
.0196
-0,
,241
0.0005
171,
.02
6,
.186
6,
,398
3
.437
20,
.3741
20,
.3241
-0,
,245
0.0004
171,
.02
7,
.532
7,
,792
3,
.455
20,
.6778
20,
.6240
-0,
,260
0.0003
171,
.02
9,
.017
9,
,363
3,
.830
20,
.9802
20,
,9167
-0,
,302
0.0003
171,
.02
10,
.629
11.
,079
4,
.230
21.
,2743
21,
,2004
-0,
,348
0.0003
171,
,02
12,
.408
12,
,955
4,
.407
21.
,5629
21,
,4818
-0,
,376
0.0002
171,
.02
14,
,286
15,
,010
5.
.070
21.
,8484
21,
,7510
-0,
,446
0.0002
171,
,02
16,
.366
17,
,222
5,
.226
22,
,1273
22,
,0225
-0,
,474
0.0002
171,
.02
18,
.630
19,
,697
5,
.727
22,
,4120
22,
,2925
-0,
,533
0.0002
171,
.02
21,
.083
22,
,342
5,
,969
22,
,6901
22,
,5608
-0.
,570
0.0002
171,
.02
23,
.817
25,
,314
6,
.287
22,
,9769
22,
,8355
-0.
.615
0.0001
171,
.02
26,
.800
28,
,592
6,
.688
23,
,2672
23,
,1115
-0.
,669
0.0001
171,
.02
30.
.081
32,
,194
7,
,025
23,
,5605
23,
,3913
-0.
,718
0.0001
172,
,81
2,
.692
2,
,762
2,
,606
18,
.9036
18,
,8712
-0.
,172
0.0004
172,
,81
3,
.418
3,
,510
2,
,709
19,
.2171
19,
,1811
-0.
,187
0.0003
172,
.81
4,
.311
4,
,432
2,
,801
19,
.5431
19,
.5033
-0.
,203
0.0006
172,
.81
5,
.364
5,
,511
2,
,735
19.
.8681
19,
.8267
-0.
208
0.0005
172,
.81
6,
,553
6,
,740
2.
,855
20,
,1873
20.
,1416
-0.
227
0.0004
172,
.81
7.
.894
8,
.130
2,
,984
20,
,5019
20.
,4514
-0.
246
0.0004
172,
.81
9,
.396
9,
.690
3,
,127
20.
.8125
20.
,7569
-0.
267
0.0003
172,
.81
11,
.031
11,
.402
3,
,366
21.
,1153
21.
,0525
-0.
297
0.0003
172,
.81
12.
.896
13,
.293
3.
.078
21.
,4142
21.
,3540
-0.
281
0.0002
172,
.81
14,
.873
15,
.388
3,
.462
21.
,7122
21.
6418
-0.
324
0.0002
132
Data from Van Itterbeek et al. [46] (continued)
T P,exp P.cal Dev p.exp p.cal
K MPa MPa % mol-dm'^ mol-dm"^
Dev
Wt
172
.81
16
.946
17
.676
4
.311
22
.0066
21
.9157
-0
.413
0.0002
172
.81
19
.340
20
.202
4
.457
22
.3015
22
.2039
-0
.438
0.0002
172
.81
21
.909
23
.007
5
.012
22
.5999
22
.4864
-0
.502
0.0002
172
.81
24
.749
26
.093
5
.429
22
.8995
22
.7724
-0,
.555
0.0001
172,
.81
27
.916
29,
.514
5
.725
23
.2035
23
.0648
-0
.598
0.0001
172,
.81
31
.343
33,
.285
6
.197
23
.5106
23
.3557
-0,
.659
0.0001
179,
.53
3
.829
3,
.941
2,
.941
17
.8514
17,
.7783
-0,
.409
0.0012
179,
.53
4,
.391
4,
.519
2,
.906
18
.1841
18.
.1158
-0,
.376
0.0010
179.
.53
5,
.037
5,
.212
3
.465
18
.5168
18,
.4383
-0,
.424
0.0008
179,
.53
5,
.837
6,
,014
3,
.045
18
.8423
18,
.7746
-0,
,360
0.0007
179,
.53
6,
,735
6.
.951
3,
,204
19,
.1674
19.
,0967
-0.
,369
0.0006
179,
.53
7,
.761
8,
.010
3,
.208
19.
.4852
19,
,4144
-0.
,363
0.0005
179,
,53
8,
.912
9.
,218
3,
.435
19,
,8016
19,
,7253
-0.
,385
0.0004
179,
,53
10,
,223
10,
.561
3,
.307
20.
.1110
20.
,0366
-0.
,370
0.0004
179,
.53
11,
.656
12,
.063
3.
,494
20,
,4182
20,
,3384
-0.
,391
0.0003
179,
,53
13,
.222
13.
.733
3.
.860
20,
,7228
20,
,6332
-0,
,432
0.0003
179.
,53
14,
.960
15.
.562
4.
.023
21.
,0225
20,
,9274
-0.
,453
0.0003
179,
,53
16,
,854
17.
.575
4.
,276
21,
,3201
21.
,2170
-0.
,484
0.0002
179.
,53
18.
,944
19.
.797
4.
,500
21,
,6179
21,
,5070
-0.
,513
0.0002
179.
,53
21.
.248
22.
.247
4.
,702
21.
,9164
21.
.7980
-0,
.540
0.0002
179.
,53
23.
.756
24.
.947
5.
,013
22,
,2163
22.
,0874
-0.
.580
0.0002
179.
,53
26.
.506
27.
,912
5.
,306
22,
,5175
22.
.3780
-0,
.620
0.0001
179.
,53
29.
,518
31.
,194
5.
.677
22,
,8227
22.
,6702
-0,
.668
0.0001
188.
.22
5.
.326
5.
,388
1.
,160
16,
,3228
16.
.2594
-0,
.388
0.0000
188.
,22
5.
.703
5.
,760
0.
,986
16,
,6622
16.
.6149
-0.
.284
0.0000
188.
,22
6.
,139
6.
,208
1,
,137
17.
,0016
16.
.9527
-0.
.288
0.0000
188.
,22
6.
,663
6.
,740
1.
,159
17.
,3388
17.
.2933
-0.
.263
0.0000
188.
.22
7.
,275
7.
,363
1.
.205
17.
,6728
17.
,6289
-0.
.249
0.0009
188.
,22
7.
.965
8.
.082
1.
,474
18.
.0034
17.
,9528
-0.
.281
0.0008
188.
,22
8.
.768
8.
.909
1.
,609
18.
,3308
18.
.2781
-0.
.287
0.0007
188.
,22
8.
,844
8.
.990
1.
,649
18.
.3604
18.
.3066
-0.
.293
0.0007
188.
,22
9.
,743
9.
.941
2.
,033
18.
.6839
18.
.6200
-0.
,342
0.0006
188.
,22
10.
,795
11.
,003
1.
,921
19.
.0009
18,
,9421
-0.
.309
0.0005
188.
,22
11.
,951
12.
,194
2.
,036
19,
.3151
19.
.2539
-0.
,317
0.0004
188.
,22
13.
,134
13.
,539
3.
,079
19.
,6298
19.
,5389
-0.
,463
0.0004
133
Data from Van Itterbeek et al. [46] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm"^ mol-dm"^
Dev
Wt
188,
.22
14,
.506
15,
.018
3,
.529
19,
.9390
19,
.8358
-0,
.518
0,
.0003
188,
.22
16,
.146
16,
.683
3,
.326
20,
.2511
20,
.1541
-0,
.479
0,
.0003
188,
.22
17,
.851
18,
.406
3,
.107
20,
.5427
20,
.4519
-0,
.442
0,
.0003
188,
.22
19,
.721
20,
.387
3,
.376
20,
.8468
20,
.7479
-0,
.475
0,
.0002
188,
.22
21,
.779
22,
,559
3,
.581
21,
.1497
21,
.0442
-0,
.499
0,
.0002
188,
.22
24,
,026
24,
,964
3,
.903
21,
.4551
21,
.3393
-0,
.539
0,
,0002
188,
.22
26,
,498
27,
.576
4,
.068
21,
.7581
21,
.6363
-0,
.560
0,
,0002
188,
.22
29,
,174
30,
,366
4,
.084
22,
.0546
21,
.9310
-0,
.560
0,
,0002
Number of Points (Ref. 46) 163
PRESSURE:
DENSITY
AAD-%
AAD
AAD-%
AAD
7.170
0.636
0.323
0.071
BIAS-%
BIAS
BIAS-%
BIAS
7.037
0.604
■0.317
•0.070
RMS-%
RMS
RMS-%
RMS
11.241
0.548 MPa
0.217
0.049 mol-dm"3
Data
from
Vennix
[47]
T
P.exp
P.cal
Dev
p,exp
p.cal
Dev
Wt
K
MPa
MPa
%
rool • dm' ^
mol • dm" ^
%
172,
.53
2.466
2.469
0.130
2.5593
2.5533
-0.233
0.0602
174,
,69
2.528
2.532
0.128
2.5593
2.5536
-0.222
0.0583
177,
,20
2.599
2.602
0.119
2.5586
2.5535
-0.200
0.0562
183,
.18
2.767
2.769
0.080
2.5580
2.5548
-0.125
0.0518
191,
.85
3.004
3.005
0.037
2.5568
2.5554
-0.054
0.0000
203,
.08
3.305
3.305
0.000
2.5555
2.5555
0.000
0.0831
213,
.04
3.567
3.566
-0.026
2.5543
2.5552
0.035
0.0758
217,
.86
3.693
3.692
-0.038
2.5537
2.5549
0.048
0.0727
223,
.83
3.848
3.846
-0.053
2.5530
2.5547
0.067
0.0692
233,
.55
4.099
4.095
-0.089
2.5518
2.5546
0.109
0.0643
239,
,80
4.259
4.255
-0.096
2.5512
2.5541
0.115
0.0614
252.
.83
4.590
4.585
-0.094
2.5499
2.5527
0.111
0.0563
263,
.40
4.856
4.851
-0.100
2.5487
2.5516
0.115
0.0528
273,
,38
5.106
5.100
-0.108
2.5474
2.5505
0.122
0.0499
190,
,43
4.472
4.488
0.358
6.4670
6.3251
-2.193
0.0000
134
Data from Vennix [47] (continued)
T P.exp P.cal Dev p.exp P.cal
K MPa MPa % mol-dm'^ mol-dm'^
Dev
Wt
208
.57
6
.027
6,
.045
.304
6
.4614
6
.4174
-0.682
0.0515
223
.23
7
.235
7,
.254
.271
6
.4571
6
.4274
-0.461
0.0405
234
.44
8
.143
8,
.163
.240
6
.4539
6
.4307
-0.360
0.0347
243
.73
8
.891
8,
.908
0,
.191
6
.4508
6
.4337
-0.265
0.0310
243
.77
8
.894
8,
.911
0,
.198
6
.4508
6
.4331
-0.274
0.0310
251
.38
9,
.502
9,
,517
0,
.160
6
.4483
6,
.4348
-0.210
0.0285
262
.19
10,
.360
10,
,373
0,
,122
6
.4452
6
.4354
-0.152
0.0255
272,
.15
11,
.148
11,
,156
0,
,072
6
.4421
6,
.4366
-0.085
0.0233
272
.18
11,
.149
11,
,158
0,
,079
6
.4421
6,
.4361
-0.093
0.0233
190,
.05
4,
.499
4,
,508
0,
,203
7,
.2329
7,
.0527
-2.491
0.0000
190,
.75
4.
.571
4,
,580
0,
,203
7,
.2329
7,
.0830
-2.072
0.0000
193,
.32
4,
,834
4.
,843
0,
,199
7,
.2316
7,
.1396
-1.272
0.0695
197,
.74
5,
,272
5,
.285
0,
,233
7,
.2304
7,
.1617
-0.951
0.0626
202,
.75
5,
,763
5,
,777
0,
,248
7,
.2285
7,
.1743
-0.750
0.0560
208,
.22
6,
,291
6.
,307
0,
,260
7,
.2266
7,
.1808
-0.634
0.0500
212,
,16
6,
,669
6,
.686
0,
,257
7,
.2254
7,
.1850
-0.559
0.0463
217.
,14
7,
,142
7.
.161
0,
,259
7,
,2235
7,
.1872
-0.502
0.0423
222,
.93
7,
,691
7,
.710
0,
,247
7,
,2217
7,
.1906
-0.431
0.0384
230,
,05
8,
,361
8,
.381
0,
,234
7,
,2192
7,
.1926
-0.369
0.0343
237,
,34
9,
,043
9,
.063
0,
,216
7,
,2167
7,
,1940
-0.314
0.0310
242,
,71
9,
,543
9,
.563
0,
,203
7,
,2148
7,
,1945
-0.282
0.0289
248,
,44
10,
,076
10,
.094
0.
,186
7,
,2129
7,
,1951
-0.247
0.0269
250,
,19
10,
,238
10,
.256
0.
,183
7,
,2123
7,
,1951
-0.239
0.0264
253.
,45
10,
,538
10,
.556
0.
,175
7,
,2111
7,
,1949
-0.224
0.0254
258,
,64
11,
,017
11,
.035
0.
,157
7,
,2092
7,
,1952
-0.194
0.0240
263,
,05
11,
,423
11,
.439
0.
,143
7,
,2079
7,
,1954
-0.174
0.0229
268,
,30
11,
,905
11.
.920
0.
,126
7,
,2061
7,
,1954
-0.148
0.0218
273,
,17
12,
,350
12,
.364
0.
,110
7,
,2042
7,
,1951
-0.127
0.0208
191,
.55
4,
,732
4.
.740
0,
,176
9,
,8370
9,
,2264
-6.207
0.0000
192,
,94
4,
,928
4.
.936
0,
,164
9,
,8364
9,
,5852
-2.554
0.0000
195,
,24
5,
,256
5.
.264
0,
,141
9,
,8351
9,
,7252
-1.117
0.0641
197,
,56
5,
,587
5.
.595
0,
,136
9,
,8345
9.
,7629
-0.728
0.0598
200,
,41
5,
,998
6.
.003
0.
,082
9,
,8333
9.
,8022
-0.316
0.0548
202,
.83
6,
,342
6.
.350
0.
,127
9,
,8320
9.
,7922
-0.405
0.0511
206,
.37
6.
,850
6.
.859
0,
,130
9,
,8301
9.
,7972
-0.335
0.0462
135
Data from Vennix [47] (continued)
T
P.exp
P.cal
Dev
^.exp
p.cal
Dev
Wt
K
MPa
MPa
%
mol • dm" ^
mol • dm" ^
%
213,
.50
7.877
7.888
0.137
9.8270
9.8011
-0.264
0.0383
223,
.65
9.339
9.352
0.139
9.8220
9.8014
-0.210
0.0303
236,
.40
11.177
11.190
0.122
9.8158
9.8008
-0.153
0.0238
248,
.15
12.867
12.881
0.105
9.8108
9.7993
-0.118
0.0197
255
.16
13.875
13.887
0.089
9.8071
9.7978
-0.095
0.0179
273
.17
16.450
16.462
0.067
9.7990
9.7926
-0.065
0.0144
190
.84
4.634
4.641
0.149
10.2128
8.8339
-13.501
0.0000
191,
.04
4.662
4.670
0.184
10.2128
9.0079
-11.798
0.0000
191,
.23
4.690
4.698
0.170
10.2128
9.3273
-8.670
0.0000
191
.43
4.719
4.727
0.174
10.2128
9.4927
-7.051
0.0000
191,
.82
4.776
4.784
0.171
10.2128
9.7203
-4.822
0.0000
192.
.08
4.813
4.822
0.182
10.2128
9.7765
-4.272
0.0000
193,
.52
5.026
5.035
0.165
10.2115
10.0120
-1.954
0.0673
195,
,16
5.270
5.277
0.130
10.2109
10.1103
-0.985
0.0639
197.
.93
5.684
5.690
0.107
10.2096
10.1575
-0.510
0.0585
200.
,57
6.081
6.087
0.098
10.2084
10.1726
-0.351
0.0538
204.
,04
6.604
6.610
0.093
10.2065
10.1804
-0.256
0.0484
207.
,85
7.180
7.188
0.116
10.2047
10.1781
-0.261
0.0433
207.
.85
7.183
7.188
0.068
10.2047
10.1890
-0.154
0.0432
213.
,04
7.969
7.977
0.098
10.2022
10.1837
-0.181
0.0375
233.
,39
11.069
11.078
0.081
10.1922
10.1819
-0.101
0.0239
252.
,89
14.039
14.048
0.063
10.1829
10.1762
-0.066
0.0175
273,
02
17.093
17.098
0.035
10.1729
10.1696
-0.033
0.0136
273,
,06
17.099
17.105
0.036
10.1729
10.1695
-0.034
0.0136
191,
,85
4.798
4.808
0.194
11.1543
10.7425
-3.692
0.0000
191,
,87
4.801
4.812
0.224
11.1543
10.6811
-4.243
0.0000
193,
,25
5.025
5.035
0.199
11.1537
10.9489
-1.836
0.0671
195,
,11
5.334
5.341
0.133
11.1531
11.0706
-0.740
0.0626
197,
,30
5.699
5.706
0.119
11.1518
11.0999
-0.466
0.0577
199,
,22
6.023
6.028
0.094
11.1506
11.1178
-0.294
0.0537
200,
.90
6.309
6.314
0.077
11.1500
11.1269
-0.207
0.0505
203,
,06
6.678
6.683
0.066
11.1487
11.1315
-0.155
0.0467
207,
,56
7.452
7.455
0.045
11.1462
11.1369
-0.083
0.0401
213,
.20
8.427
8.429
0.032
11.1431
11.1376
-0.049
0.0338
213,
,20
8.428
8.431
0.028
11.1431
11.1384
-0.042
0.0338
136
Data from Vennix [47] (continued)
T P.exp P.cal Dev p , exp p.cal
K MPa MPa % mol-dra'^ mol-dm'^
Dev
Wt
213
.21
8
.429
8
.432
.031
11
1431
11
1378
-0
.047
.0337
223
.18
10
.166
10
.168
.014
11
1375
11
1355
-0
.018
0260
233
16
11
912
11
.912
-0
003
11
1325
11
1329
003
0210
243
14
13
660
13
.658
-0
013
11
1269
11
1283
013
0175
253
15
15
412
15
.413
002
11
.1219
11
1217
-0
002
0150
263
12
17
155
17
156
002
11
1163
11
1161
-0
002
0131
273
09
18
898
18
895
-0
012
11
1113
11
1124
010
0116
273
15
18
893
18
906
068
11
1113
11
1049
-0
057
0116
192
50
4
929
4
940
214
11
7625
11
5548
-1
766
0000
195
84
5
526
5
533
124
11
7607
11
7079
-0
449
0592
198
18
5
951
5
956
082
11
7594
11
7331
-0
224
0535
203
43
6
919
6
922
037
11
7563
11
7483
-0
068
0433
212
03
8
531
8
530
-0
005
11
7513
11
7521
007
0321
212
04
8
531
8
531
-0
005
11
7513
11
7521
007
0321
222
63
10
541
10
536
-0
041
11
7451
11
7505
046
0239
233
40
12
596
12
589
-0
050
11
7395
11
7453
049
0188
233
40
12
597
12
589
-0
062
11
7395
11
7466
061
0188
237
03
13
292
13
282
-0
074
11
7370
11
7451
069
0175
237
03
13
292
13
283
-0
071
11
7370
11
7448
067
0175
243
38
14
505
14
495
-0
069
11
7332
11
7405
062
0157
243
38
14
505
14
496
-0
063
11
7332
11
7399
057
0157
253
28
16
399
16
391
-0
047
11
7283
11
7330
040
0134
263
45
18
340
18
332
-0
042
11
7220
11
7260
034
0117
268
30
19
268
19
259
-0
051
11
7195
11
7242
040
0110
268
30
19
268
19
259
-0
048
11
7195
11
7240
038
0110
272
69
20
105
20
096
-0
045
11
7170
11
7211
035
0104
272
70
20
105
20
096
-0
044
11
7170
11
7210
034
0104
272
70
20
105
20
097
-0
039
11
7170
11
7206
031
0104
190
70
4
660
4
673
280
12
8636
12
6660
-1
536
0000
191
45
4
810
4
824
287
12
8636
12
7111
-1
186
0000
192
40
4
997
5
014
350
12
8630
12
7163
-1
140
0000
196
51
5
852
5
865
212
12
8605
12
8106
-0
388
0507
203
57
7
364
7
371
089
12
8562
12
8421
-0
110
0358
209
29
8
611
8
612
017
12
8524
12
8501
-0
018
0286
218
62
10
668
10
662
-0
062
12
8468
12
8539
055
0213
137
Data from Vennix [47] (continued)
T P.exp P.cal Dev P,exp p,cal
K MPa MPa % mol-dm"^ mol-dm"^
Dev
Wt
228,
,10
12,
.775
12,
.764
-0,
.090
12,
.8406
12,
.8500
0,
.073
0.0168
238,
.55
15,
.109
15,
.094
-0,
.099
12,
.8343
12,
.8440
0,
.076
0.0136
245,
.92
16,
.755
16,
.741
-0
.079
12,
.8294
12,
.8368
0,
.058
0.0120
252,
.97
18,
.335
18,
.319
-0,
.087
12,
.8250
12,
.8330
0,
.062
0.0108
260,
.11
19,
.930
19.
.914
-0,
.080
12,
.8206
12,
.8278
0,
.056
0.0098
267,
.31
21.
.537
21,
.523
-0.
.067
12,
.8163
12,
.8222
0,
.046
0.0089
274,
.15
23,
.058
23,
.047
-0,
.048
12,
.8119
12,
.8160
0,
.032
0.0082
188,
.97
4,
.386
4,
.389
0,
.083
13,
.7516
13,
.7216
-0,
.218
0.0000
189,
.26
4,
.450
4,
.455
0,
.098
13,
.7510
13,
.7181
-0,
.239
0.0000
189,
.77
4,
.564
4,
.570
0,
.140
13,
.7510
13,
.7088
-0,
.307
0.0000
190,
.17
4,
.655
4,
.663
0,
.168
13,
.7504
13,
.7033
-0,
.342
0.0000
190,
.45
4,
.718
4,
.726
0,
.171
13,
.7504
13,
.7046
-0,
.333
0.0000
190,
.74
4,
.784
4,
.793
0,
.182
13,
.7504
13,
.7040
-0,
.338
0.0000
191,
.07
4,
.862
4,
.870
0,
.181
13,
.7497
13,
.7058
-0,
.320
0.0000
192,
.89
5,
.282
5,
.293
0,
.213
13,
.7485
13,
.7064
-0,
.306
0.0000
195,
.05
5,
.789
5,
.801
0,
.211
13,
.7473
13,
.7121
-0,
.256
0.0450
195,
.07
5,
.793
5,
.806
0,
.220
13,
.7473
13,
.7106
-0,
.267
0.0450
197,
.10
6,
.279
6,
.291
0,
.195
13,
.7460
13,
.7169
-0,
.212
0.0396
200,
.01
6,
.981
6,
.992
0,
.155
13,
.7441
13,
.7234
-0,
.150
0.0338
203,
.32
7,
.790
7,
.797
0,
.092
13.
. 7416
13,
.7305
-0,
.081
0.0288
207,
.20
8,
.744
8,
.748
0,
.051
13,
,7392
13,
.7335
-0,
.042
0.0246
213,
.32
10,
.271
10,
.264
-0,
.060
13,
,7348
13,
,7410
0,
.045
0.0199
222.
.79
12,
.643
12,
.631
-0,
.095
13,
.7286
13,
.7376
0,
,065
0.0153
227,
.85
13,
.917
13,
.903
-0,
.106
13.
,7254
13,
,7352
0,
,071
0.0136
233,
.27
15,
.288
15,
.271
-0,
.113
13,
,7217
13.
,7318
0,
,074
0.0122
238,
.51
16,
.611
16,
.594
-0,
.101
13.
.7180
13.
,7269
0,
,065
0.0111
242,
.99
17,
.743
17,
.726
-0,
.094
13,
,7148
13,
,7229
0.
,059
0.0102
248,
.77
19,
.203
19,
.190
-0,
.067
13,
,7111
13.
,7169
0.
,042
0.0094
253,
.11
20,
.301
20,
.290
-0,
.051
13.
,7086
13.
,7129
0.
,032
0.0088
258,
.31
21,
.615
21,
.605
-0,
.043
13,
,7049
13,
,7085
0.
,026
0.0082
262.
.93
22,
.781
22,
.772
-0,
.041
13,
,7018
13.
.7052
0.
.025
0.0077
267,
.82
24,
.012
24,
.005
-0,
.028
13.
.6986
13.
,7009
0.
017
0.0073
267,
.89
24,
.029
24,
.022
-0,
.028
13,
,6986
13.
,7009
0.
,017
0.0073
273,
.15
25,
.355
25,
.348
-0,
.027
13,
,6949
13.
,6971
0.
016
0.0069
187,
.65
4,
.327
4,
.336
0,
.199
14,
,9705
14.
,9463
-0.
,162
0.0000
138
Data from Vennix [47] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm'^ mol-dm"^
Dev
Wt
188
.93
4
.677
4
.689
.264
14
.9699
14
.9402
-0
.199
.0000
191
.45
5
.379
5
.396
.324
14
.9680
14
.9350
-0
.220
.0000
194
.80
6
.326
6
.347
.332
14
.9655
14
.9344
-0
.207
.0282
199
.61
7
.710
7
.729
.240
14
.9618
14
.9409
-0
.140
.0220
203
.05
8
.714
8
.729
.181
14
.9593
14
.9441
-0
.101
.0191
207
.63
10
.057
10,
.068
.106
14
.9562
14
.9476
-0,
.058
.0161
212
.93
11
.627
11,
.633
.056
14
.9524
14,
.9480
-0.
.030
.0137
221
.36
14,
.131
14,
.134
0,
.022
14
.9462
14,
.9445
-0.
.011
.0111
228,
.64
16
.302
16,
.305
0,
.019
14
.9406
14,
.9391
-0.
.010
.0095
236,
.60
18
.680
18,
.687
0,
.035
14,
.9350
14,
.9323
-0.
.018
.0083
245,
.09
21,
.214
21,
.226
0,
.057
14,
.9287
14,
.9244
-0,
.029
.0072
253.
.07
23,
.597
23,
,611
0,
.060
14,
.9225
14.
.9180
-0.
.030
.0065
260,
.84
25,
.904
25,
.928
0,
.094
14,
.9169
14,
.9098
-0.
.048
.0059
268,
.82
28,
.272
28,
.304
0,
.116
14,
.9113
14,
.9026
-0.
.059
.0054
275,
.15
30,
.147
30,
,180
0.
.107
14,
.9063
14,
.8982
-0.
.054
0,
.0051
183,
.35
3,
.825
3.
.877
1.
,346
16,
.5234
16,
.4599
-0.
.385
0,
.0000
185,
.27
4,
.488
4.
,548
1.
,328
16,
.5215
16,
.4568
-0,
.391
0,
.0000
189,
,26
5,
.897
5.
,964
1.
,139
16,
.5184
16,
.4601
-0,
.353
0,
.0000
194,
,42
7,
.751
7.
,819
0.
.878
16,
.5140
16,
.4669
-0,
.286
0.
.0134
198,
,42
9,
.196
9.
,271
0.
,818
16,
.5109
16.
.4657
-0.
,274
0,
.0116
201,
,04
10,
.164
10.
,228
0.
,634
16.
.5084
16.
.4728
-0.
.216
0.
.0107
207,
,77
12,
.617
12.
,695
0.
,619
16.
.5028
16.
.4668
-0.
,218
0.
.0089
213,
,67
14,
.788
14.
.869
0.
,547
16.
.4978
16.
.4652
-0.
.197
0,
.0078
222,
,89
18,
.182
18.
,279
0.
.531
16.
.4903
16.
.4576
-0.
,198
0.
.0065
232,
,81
21,
.835
21.
,946
0.
.510
16,
.4822
16.
.4500
-0.
,195
0.
.0056
241,
.29
24,
.958
25.
,076
0.
.476
16.
.4754
16.
.4448
-0.
,186
0.
,0049
254.
.53
29.
.803
29.
,938
0,
,454
16.
.4648
16.
.4348
-0.
,182
0.
.0042
261,
,83
32.
.459
32.
.601
0.
,437
16.
.4586
16.
.4294
-0,
,177
0.
.0039
267,
,88
34,
.658
34.
,804
0.
.420
16.
,4536
16.
,4253
-0.
,172
0.
.0037
272.
,98
36,
.500
36.
,650
0.
.413
16.
.4492
16.
,4212
-0.
,170
0.
,1773
179.
.14
3.
.304
3.
,368
1.
,913
17.
.5640
17.
,5143
-0.
,283
0.
.1481
179.
,83
3,
.585
3.
,650
1.
.818
17.
.5634
17.
.5140
-0.
,281
0.
.0143
181.
,01
4.
.065
4.
,134
1.
.689
17,
.5622
17.
,5132
-0.
,279
0.
.0000
184.
,44
5,
.477
5.
,554
1.
.402
17.
.5590
17.
5120
-0.
,268
0,
.0000
196.
,38
10,
.460
10.
,577
1.
.118
17.
.5485
17.
4999
-0.
,277
0,
.0077
139
Data from Vennix [47] (continued)
T P.exp P.cal Dev P.exp /? , cal
K MPa MPa % raol-dm"^ mol-dra"^
Dev
Wt
200
.54
12
.224
12
.340
.949
17
.5447
17
.5012
-0
.248
.0070
208
.82
15
.743
15
.872
.821
17
.5379
17
.4971
-0,
.232
.0058
217
.04
19
.228
19,
.378
0,
.781
17
.5304
17
.4893
-0
.234
.0051
225
.02
22
.597
22
.775
0,
.787
17
.5235
17
.4802
-0
.247
.0045
233
.08
25,
.996
26
.192
0,
.755
17
.5160
17
.4729
-0
.246
.0040
241
.00
29
.322
29,
.538
0,
.736
17
.5092
17
.4660
-0,
.247
.0037
250
.74
33
.392
33
.628
0,
.705
17
.5005
17
.4578
-0
.244
.0033
258
.65
36,
.660
36,
.930
0,
.737
17
.4936
17
.4480
-0,
.261
.1540
266
.75
40,
.009
40,
.295
0,
.713
17
.4868
17
.4419
-0.
.257
.1436
274,
.30
43,
.114
43,
.408
0,
.683
17
.4799
17
.4362
-0,
.250
.1351
182,
.83
6,
.552
6,
.741
2,
.882
18
.4888
18,
.4116
-0,
.417
.0000
182,
.83
6,
.549
6,
.741
2,
.925
18
.4888
18
.4105
-0,
.423
0,
.0000
175,
,63
3,
.138
3,
.303
5,
.268
18,
.4956
18,
.4080
-0,
.474
0,
.0946
178,
,08
4,
.293
4,
.466
4,
.028
18,
.4931
18,
.4100
-0,
.449
0,
.0086
188,
,29
9,
.165
9,
.372
2,
.258
18
.4838
18,
.4112
-0,
.393
.0063
193,
,63
11,
.730
11,
.957
1,
.928
18,
.4788
18,
.4089
-0,
.379
.0055
198.
,67
14,
,156
14,
.399
1,
.719
18,
.4738
18
.4059
-0,
.368
0,
.0050
203,
,16
16,
.318
16,
.577
1,
.587
18,
.4695
18
.4028
-0,
.361
0,
.0046
208,
,21
18,
.751
19,
.031
1,
.491
18,
.4651
18
.3989
-0,
.359
0,
.0042
212,
,42
20,
.769
21,
.066
1,
.430
18,
.4607
18,
.3946
-0,
.358
0,
.0039
218,
,76
23,
,805
24,
.125
1,
,346
18,
.2251
18,
,3897
-0,
.354
0,
.0036
223,
.74
26,
.187
26,
.521
1,
.275
18,
.4501
18,
.3860
-0,
.348
0,
.0034
229,
.13
28,
.748
29,
.106
1,
.242
18,
.4452
18,
.3807
-0,
.350
0,
.0032
233,
.40
30,
.768
31,
.140
1,
.209
18,
.4414
18,
.3772
-0,
.348
0,
.0030
237,
.61
32,
.760
33,
.146
1,
.178
18,
.4377
18,
.3739
-0,
.346
0.
.0029
243,
.05
35,
.325
35,
.724
1,
,128
18,
.4321
18,
.3695
-0,
,339
0,
.1378
248,
.04
37,
.659
38,
.076
1,
.109
18,
.4277
18,
.3650
-0,
,340
0,
,1316
253,
.13
40,
.035
40,
.464
1,
.071
18,
.4227
18,
.3611
-0.
,335
0,
,1259
263,
.28
44,
.752
45,
.203
1,
.007
18,
.4134
18,
.3536
-0,
,325
0,
,1160
272,
.93
49,
.184
49,
.666
0,
.980
18,
.4047
18,
.3450
-0,
,324
0,
,1080
172,
.57
5,
.501
5,
.835
6,
.070
19,
.9962
19,
.9059
-0,
,452
0,
,0045
178,
.48
9,
.008
9,
.383
4.
.159
19,
.9899
19,
.9012
-0.
,444
0.
,0039
186,
.85
13,
.976
14,
.405
3,
,065
19,
.9812
19,
.8944
-0.
,434
0.
.0034
196
.09
19,
.431
19,
.925
2,
.540
19,
.9719
19,
,8849
-0.
,436
0.
0029
204
.18
24,
.179
24,
.721
2.
,243
19.
.9631
19.
,8769
-0.
,432
0.
0026
211,
.52
28,
.463
29,
.044
2,
.041
19,
.9557
19,
,8707
-0.
426
0.
0024
140
Data from Vennix [47] (continued)
T P , exp P , cal Dev p , exp p , cal
K MPa MPa % mol-dm"^ mol-dra"^
Dev
Wt
219,
.06
32,
.825
33,
,441
1,
,877
19,
,9476
19.
,8641
-0,
.419
0,
.0022
227,
.10
37,
.434
38,
.096
1,
.768
19,
,9395
19.
,8562
-0.
.418
0,
.1034
235,
.30
42,
.100
42,
.797
1,
.655
19,
,9314
19.
,8495
-0,
.411
0,
.0964
244,
.17
47,
.089
47,
.834
1,
.581
19,
,9220
19.
,8402
-0,
.411
0,
,0899
253,
.83
52,
.486
53,
.260
1,
,475
19,
,9120
19.
,8326
-0,
.399
0,
,0839
259,
.34
55,
.544
56,
.336
1,
,426
19,
,9064
19.
,8280
-0,
.394
0,
.0808
267,
.73
60,
.105
60,
.981
1,
,456
19,
,8977
19.
,8154
-0,
.413
0,
.0766
274,
,49
63,
.813
64,
,695
1,
,383
19,
,8909
19.
,8112
-0,
.401
0,
,0736
172,
,77
11,
,383
11,
,966
5,
,119
21,
,2132
21.
,1176
-0,
.451
0,
,0026
176,
,89
14,
,280
14,
,906
4,
,377
21,
,2088
21.
,1124
-0,
.454
0,
,0024
181,
,67
17,
,634
18,
,294
3,
,745
21,
,2032
21.
,1079
-0,
.450
0,
.0023
189,
,78
23,
,252
24,
,001
3,
,218
21,
,1939
21.
,0960
-0,
.462
0,
,0020
197,
,32
28,
,439
29,
,245
2,
,836
21,
,1858
21.
,0885
-0,
.459
0,
,0019
204,
,17
33,
.127
33,
,968
2,
,540
21.
,1783
21.
,0833
-0,
.449
0,
,0018
212,
,64
38,
,858
39,
,743
2,
,278
21,
,1689
21.
,0761
-0,
.438
0,
,0817
228,
,43
49,
,346
50,
,311
1,
,956
21,
,1509
21.
.0613
-0,
.424
0,
,0722
235,
,78
54,
,155
55,
,158
1,
.851
21,
,1428
21.
.0542
-0,
.419
0,
,0686
247,
,38
61,
,653
62,
,722
1,
,734
21.
,1303
21.
.0425
-0,
.415
0,
,0636
252,
,99
65.
,231
66,
,342
1,
,703
21,
,1241
21.
.0359
-0,
.418
0,
.0615
168,
,75
16,
,942
17,
,767
4,
.870
22,
,4109
22.
,3163
-0,
.422
0,
,0017
180,
,12
26,
,268
27,
,188
3,
,500
22,
.3972
22.
,3039
-0,
.416
0,
.0015
188,
,53
33,
.045
34,
,037
3,
,003
22,
,3872
22.
,2941
-0,
.416
0,
,0014
196,
,79
39,
,639
40,
,662
2,
,579
22.
,3772
22.
,2876
-0,
.400
0,
,0650
204,
,37
45,
,592
46,
,648
2,
,316
22.
,3679
22.
,2806
-0,
.390
0,
,0613
211,
,26
50,
,940
52,
,030
2,
,138
22.
,3598
22.
,2740
-0,
.384
0,
,0583
218,
,29
56,
,352
57,
,469
1,
,983
22.
,3517
22.
,2677
-0,
.376
0,
,0556
226,
,29
62,
,408
63,
.563
1,
,852
22.
,3417
22.
,2590
-0,
.370
0,
,0528
234,
,42
68,
,503
69,
,708
1,
,758
22.
,3324
22.
,2502
-0,
.368
0,
,0503
Number of Points (Ref . 47) 254
PRESSURE:
DENSITY
AAD-%
AAD
AAD-%
AAD
0.676
0.154
0.552
0.066
BIAS-%
BIAS
BIAS-%
BIAS
0,653
0.151
■0.533
■0.064
RMS-%
RMS
RMS-%
RMS
1.068
0.287 MPa
1.467
0.150 mol-dm'3
141
Total Points 2777
PRESSURE:
DENSITY
AAD-%
AAD
AAD-%
AAD
1.028
1.484
0.260
0.038
BIAS-
BIAS
BIAS-
BIAS
0.811
RMS-%
3.917
1.345
RMS
10.521
MPa
0.115
RMS-%
0.703
0.021
RMS
0.107
mol • dm" ^
Total Points 2574 with pressures less than 100 MPa
PRESSURE:
DENSITY
AAD-%
AAD
AAD-%
AAD
0.871
0.116
0.232
0.026
BIAS-%
BIAS
BIAS - %
BIAS
0.690
0.053
-0.088
-0.011
RMS-%
RMS
RMS-%
RMS
3.856
0.381 MPa
0.683
0.073 mol -dm' 3
142
TABLE A5
COMPARISONS FOR SECOND VIRIAL COEFFICIENTS
Notes for Table A5 . Data reported from Ref . [51] were from a correlation
and are not direct experimental measurements.
LEF
T
B.exp
B.cal
K
dm^ -mol'^
dm^ -mol"^
48
110,
.830
-0.330
10
-0.328 62
48
112
.430
-0.319
90
-0.319 41
48
114,
.440
-0.307
80
-0.308 41
48
116
.780
-0.295
50
-0.296 33
48
121,
.240
-0.274
50
-0.275 30
49
126.
.571
-0.242
27
-0.253 14
48
128,
.830
-0.244
30
-0.244 61
50
131,
.920
-0.224
00
-0.233 65
49
135,
.984
-0.215
20
-0.220 40
49
147,
.581
-0.185
00
-0.188 51
49
158,
,916
-0.161
51
-0.163 80
51
168,
,000
-0.147
50
-0.147 38
49
173,
,507
-0.137
63
-0.138 59
51
176,
,000
-0.134
90
-0.134 86
48
178,
,444
-0.132
20
-0.131 35
51
184,
,000
-0.123
80
-0.123 82
50
191,
.090
-0.116
31
-0.115 07
49
191,
.129
-0.114
29
-0.115 02
51
192,
.000
-0.113
90
-0.114 01
51
200,
.000
-0.105
10
-0.105 23
50
200,
.030
-0.106
68
-0.105 19
48
202,
.520
-0.103
40
-0.102 65
51
210,
.000
-0.095
30
-0.095 47
50
215,
,030
-0.092
59
-0.091 00
51
220,
,000
-0.086
60
-0.086 84
48
221,
,130
-0.085
80
-0.085 92
51
230,
,000
-0.078
90
-0.079 15
51
240,
,000
-0.072
00
-0.072 26
50
240,
,020
-0.072
72
-0.072 25
48
243,
,820
-0.070
30
-0.069 82
51
260,
,000
-0.060
20
-0.060 43
36
273,
,150
-0.053
35
-0.053 80
50
273,
.150
-0.053
28
-0.053 80
48
273,
.170
-0.053
70
-0.053 79
51
280,
.000
-0.050
50
-0.050 64
Dev
Wt
0,
,448
3514,
.1
0,
,153
3626,
.1
0,
,197
3768,
.7
0,
,281
3925,
.5
0,
,292
4225,
.9
4,
,488
0,
.0
0,
,125
4748,
.3
4,
,310
0,
.0
2,
,418
0,
.0
1,
,898
627,
.0
1,
,417
718,
.2
0,
,080
7864,
.4
0,
,699
842,
,8
0,
,028
8599,
.0
0,
,646
8774,
.6
0,
.017
9369,
.9
1,
,068
997,
.3
0,
,641
1015,
.0
0,
,094
10184,
.4
0,
,119
11037,
.1
1.
,393
1087,
,4
0.
,728
11218,
,6
0,
,173
12172,
,1
1.
.722
0,
,0
0.
.271
13394,
,9
0.
.142
13519,
.8
0.
.316
14702,
.1
0.
.362
16111,
,1
0.
.649
1595,
,2
0,
.691
16500,
,7
0.
.381
7225,
,9
0.
.835
8153,
,7
0.
.967
816,
,4
0.
.160
8100,
,6
0.
.275
8613,
.9
143
Table A5 (continued)
EF
T
B.exp
B.cal
K
dm'' -mol"^
dm'' -mol"^
36
298
.142
-0.042
82
-0.043 12
51
300
.000
-0.042
30
-0.042 41
36
303
.141
-0.040
91
-0.041 24
51
320
.000
-0.035
40
-0.035 41
36
323
.140
-0.034
23
-0.034 40
51
340
.000
-0.029
40
-0.029 38
36
348
.143
-0.027
06
-0.027 17
51
360
.000
-0.024
20
-0.024 15
36
373,
.150
-0.021
00
-0.021 07
51
380,
.000
-0.019
70
-0.019 57
36
398,
.160
-0.015
87
-0.015 88
51
400,
.000
-0.015
70
-0.015 53
36
423,
.170
-0.011
40
-0.011 42
36
448,
.182
-0.007
56
-0.007 54
51
450,
,000
-0.007
40
-0.007 28
36
473,
.193
-0.004
16
-0.004 15
36
498,
,203
-0.001
16
-0.001 16
36
523.
,211
0.001
49
0.001 49
36
548,
,218
0.003
89
0.003 86
36
573,
,223
0.005
98
0.005 97
36
598.
,226
0.007
88
0.007 88
36
623.
,227
0.009
66
0.009 60
Dev
Wt
.701
10158
.8
.264
10283
.7
.802
10633
.1
.026
1228
.8
0,
.508
12708,
.1
0,
.053
1479,
.6
0,
.396
16075,
.4
0,
.198
1797,
.5
0,
.354
20714,
.3
0,
.653
2208,
.1
0,
.087
27410,
.2
1,
.067
2770,
.7
0.
.153
38157,
.9
0,
.270
57539,
.6
1.
.652
5878,
.4
0.
.318
104566,
.8
0.
.219
374982,
.4
0.
.179
291939.
.7
0.
,888
111824,
.9
0.
,120
72742.
,4
0.
,012
55203.
,0
0.
,594
45031.
,0
Number of Points (Total)
57
AAD-%
AAD
0.667
0.001
BIAS-%
BIAS
0.188
-0.001
RMS-%
RMS
1.086
0.002
dm^ 'mol' ^
144
TABLE A6
GCMPARISONS KR ISOOCRIC SPBCIELC HEAT CAPACITY
Notes for Table A6. Since the experiment directly measured neither the pressure nor
density, but calculated both fron a filling pressure and the equation of state of Goodwin
(Ref. [3]), we have included 5 types of deviations in the tables. Our tabulated
tenperatures , densities, pressures, and ejqserimental heat capacities are identical to
those given by Roder [53] . The colum Dev refers to deviations between the experimental
isochoric specific heat capacity and that calculated from the tabulated tenperature and
density; this latter quantity is presented in our table as Cy.cal. The colum marked
Devi measures deviations between the densities tabulated by Roder [53] and those
calculated from our SWEOS from his tabulated taiperatxire and pressure. Dev2 similarly
ccmpares pressures tabulated in Ref. [53] and those calculated frcxn the tabulated
tenperature and density. These two deviations represent direct ccnparisons between the
current SWBOS and the equation of state in Ref. [3] . Dev3 gives the deviations between
the experimental heat capacities and those calculated form the tabulated tenperature and
pressure. Finally, Dev4 gives the deviations between the heat capacities calculated from
tabulated tenperature and density and those calculated from the tabulated tenperature and
pressure.
Data are from Younglove [52] and Roder [53] as adjusted by Roder [53]
T p Cy.exp C^.cal Dev Wt P Devi Dev2 Dev3 Dev4
K niol-dm'3 J-mol'^-K"^ % MPa % % % %
273.601
7.992
29.341
29.203
-0.469
38.5
13.5573
-0.30
0.27
-0.481
-0.013
266.349
7.996
29.282
29.199
-0.282
1828.1
12.7921
-0.34
0.30
-0.297
-0.015
259.066
8.000
29.486
29.251
-0.796
1704.7
12.0212
-0.39
0.32
-0.813
-0.018
252.815
8.003
29.560
29.347
-0.720
1614.4
11.3576
-0.42
0.34
-0.740
-0.020
245.476
8.007
29.555
29.530
-0.084
1521.3
10.5762
-0.47
0.35
-0.108
-0.024
244.733
8.007
29.514
29.553
0.133
1516.1
10.4969
-0.47
0.35
0.109
-0.024
238.128
8.010
29.637
29.801
0.553
1422.5
9.7912
-0.50
0.35
0.526
-0.028
237.534
8.011
29.854
29.827
-0.089
1395.1
9.7276
-0.51
0.36
-0.118
-0.028
230.453
8.014
29.853
30.197
1.152
1312.0
8.9684
-0.53
0.34
1.119
-0.032
230.373
8.014
30.094
30.202
0.358
1290.5
8.9599
-0.53
0.34
0.325
-0.032
222.937
8.018
30.399
30.727
1.080
1183.5
8.1593
-0.55
0.32
1.042
-0.037
222.993
8.018
30.413
30.723
1.018
1183.1
8.1654
-0.55
0.32
0.980
-0.037
215.402
8.022
31.0!^2
31.474
1.393
1059.1
7.3443
-0.55
0.27
1.349
-0.043
207.854
8.025
32.420
32.656
0.728
904.4
6.5226
-0.47
0.18
0.679
-0.049
208.168
8.025
32.410
32.592
0.562
907.7
6.5569
-0.48
0.19
0.513
-0.049
295.822
10.119
29.665
29.744
0.265
44.1
20.4199
-0.05
0.06
0.263
-0.002
289.146
10.124
29.524
29.615
0.308
42.5
19.4252
-0.07
0.08
0.306
-0.002
282.516
10.129
29.531
29.517
-0.048
40.5
18.4348
-0.09
0.10
-0.051
-0.003
266.154
10.141
29.232
29.427
0.668
1831.5
15.9810
-0.13
0.14
0.665
-0.003
259.403
10.145
29.307
29.468
0.549
1729.9
14.9654
-0.14
0.14
0.547
-0.002
145
Table A6 (continued)
T p Cy.exp Cy.cal
K mol-dm'3 J-mol'^-K"!
Dev
Wt
MPa
Devi Dev2 Dev3 Dev4
251. A88
10.151
29.316
29.588
0.927
1623.6
13.7727
-0.15
0.15
0.925
-0.002
2V^.636
10.156
29.506
29.764
0.875
1515.7
12.7389
-0.16
0.15
0.875
-0.001
231.156
10.161
29.623
30.021
1.344
1419.3
11.7001
-0.16
0.13
1.344
0.000
230.790
10.166
30.028
30.376
1.158
1300.9
10.6480
-0.14
0.11
1.159
0.001
223.396
10.171
30.879
30.881
0.005
1152.4
9.5315
-0.09
0.06
0.007
0.002
216.467
10.176
31.281
31.527
0.786
1053.8
8.4860
0.00
0.00
0.786
0.000
216.813
10.176
31.717
31.489
-0.719
1028.8
8.5382
-0.01
0.00
-0.718
0.000
214. 04A
10.178
31.996
31.815
-0.567
985.1
8.1207
0.05
-0.03
-0.569
-0.002
209.853
10.180
32.524
32.437
-0.267
916.3
7.4892
0.17
-0.08
-0.278
-0.011
209.057
10.181
32.947
32.580
-1.115
886.5
7.3695
0.19
-0.09
-1.128
-0.014
209.526
10.181
32.381
32.494
0.350
921.4
7.4401
0.17
-0.08
0.338
-0.012
208.704
10.182
32.577
32.646
0.212
903.3
7.3164
0.20
-0.09
0.197
-0.015
203.375
10.185
34.274
33.984
-0.846
775.5
6.5152
0.46
-0.16
-0.901
-0.055
203.731
10.185
33.864
33.869
0.015
796.9
6.5686
0.43
-0.15
-0.035
-0.050
202.601
10.185
34.297
34.251
-0.135
768.5
6.3990
0.52
-0.17
-0.201
-0.067
296.364
11.741
29.712
29.909
0.664
44.1
24.7179
0.07
-0.10
0.667
0.003
276.534
11.759
29.448
29.561
0.383
39.0
20.9399
0.04
-0.05
0.384
0.001
266.957
11.768
29.402
29.494
0.313
1821.8
19.1060
0.03
-0.03
0.314
0.000
257.453
11.777
29.307
29.514
0.705
1703.6
17.2822
0.02
-0.02
0.705
0.000
217.783
11.786
31.121
31.045
-0.244
1077.7
9.6540
0.14
-0.12
-0.260
-0.016
248.734
11.786
29.365
29.623
0.878
1582.5
15.6069
0.01
-0.01
0.878
0.000
212.330
11.791
31.627
31.567
-0.190
991.5
8.6216
0.21
-0.16
-0.222
-0.032
212.697
11.791
31.557
31.527
-0.097
999.4
8.6908
0.20
-0.15
-0.126
-0.029
240.923
11.793
29.393
29.810
1.419
1480.5
14.1057
0.02
-0.02
1.419
-0.001
239.625
11.794
29.780
29.851
0.237
1427.1
13.8564
0.02
-0.03
0.236
-0.001
208.095
11.795
32.238
32.109
-0.400
916.6
7.8235
0.29
-0.19
-0.455
-0.055
208.469
11.795
32.162
32.054
-0.336
924.2
7.8939
0.28
-0.19
-0.388
-0.052
204.724
11.798
32.865
32.692
-0.526
853.7
7.1915
0.37
-0.21
-0.615
-0.090
205.115
11.798
32.768
32.615
-0.468
862.0
7.2646
0.35
-0.21
-0.551
-0.084
233.566
11.800
29.846
30.078
0.777
1348.9
12.6929
0.04
-0.04
0.775
-0.002
202.217
11.801
33.410
33.269
-0.422
806.1
6.7237
0.42
-0.22
-0.550
-0.129
202.608
11.801
33.469
33.168
-0.899
806.4
6.7965
0.41
-0.22
-1.018
-0.120
231.675
11.801
29.864
30.163
1.001
1325.2
12.3302
0.05
-0.05
0.998
-0.003
200.564
11.802
34.091
33.749
-1.004
761.9
6.4166
0.47
-0.22
-1.169
-0.167
200.945
11.802
34.008
33.630
-1.113
768.5
6.4874
0.46
-0.22
-1.269
-0.158
146
Table A6 (cxantinued)
T p Cy.ejqp Cy.cal
K mol-clm"^ J-nol-i-K"^
Dev Wt
MPa
Devi Dev2 Dev3
Dev4
198.915
11.804
34.646
34.333
-0.902
725.8
6.1116
0.51
-0.21
-1.112
-0.211
197.280
11.805
35.386
35.052
-0.944
0.0
5.8105
0.53
-0.19
-1.203
-0.261
226.191
11.806
30.035
30.451
1.384
124S.1
11.2792
0.08
-0.07
1.378
-0.006
223.653
11.808
30.288
30.607
1.053
1199.9
10.7937
0.10
-0.09
1.0^5
-0.008
218.787
11.813
30.582
30.955
1.221
1125.8
9.8645
0.13
-0.11
1.207
-0.014
215.626
11.815
30.797
31.225
1.390
1078.0
9.2626
0.17
-0.14
1.368
-0.022
211.370
11.819
31.543
31.665
0.387
987.6
8.4547
0.23
-0.17
0.351
-0.036
203.924
11.826
32.837
32.840
0.010
848.3
7.0511
0.38
-0.22
-0.091
-0.101
297.427
13.094
30.056
30.070
0.(Xt6
43.4
29.2487
0.02
-0.04
0.047
0.001
290.591
13.101
29.801
29. 90^
0.344
42.1
27.6775
0.01
-0.02
0.345
0.000
283.783
13.109
29.617
29.762
0.489
40.6
26.1074
-0.01
0.02
0.489
0.000
276.944
13.117
29.613
29.646
0.112
38.7
24.5256
-0.03
0.05
0.111
-0.001
276.780
13.117
29.807
29.644
-0.548
38.2
24.4876
-0.03
0.05
-0.548
-0.001
262.566
13.133
29.446
29.508
0.209
1756.4
21.1874
-0.07
0.10
0.208
0.000
248.387
13.149
29.481
29.549
0.229
1565.8
17.8847
-0.10
0.14
0.232
0.003
241.245
13.157
29.485
29.656
0.579
1475.4
16.2201
-0.11
0.15
0.584
0.005
234.072
13.164
29.642
29.835
0.651
1373.2
14.5496
-0.11
0.15
0.659
0.008
226.524
13.173
29.927
30.114
0.623
1260.8
12.7957
-0.12
0.16
0.637
0.013
219.265
13.180
30.289
30.486
0.649
1152.4
11.1153
-0.13
0.16
0.668
0.019
212.016
13.188
30.879
30.990
0.360
1036.2
9.4478
-0.15
0.16
0.388
0.028
204.751
13.196
31.761
31.729
-0.100
913.2
7.7933
-0.17
0.16
-0.053
0.047
280.167
13.402
29.622
29.719
0.329
39.6
26.1595
-0.03
0.05
0.328
-0.001
272.763
13.411
29.475
29.606
0.446
37.9
24.3748
-0.05
0.09
0.445
-0.001
265.168
13.420
29.421
29.529
0.368
1794.8
22.5388
-0.08
0.12
0.367
-0.001
257.310
13.429
29.215
29.497
0.966
1712.3
20.6355
-0.09
0.15
0.967
0.000
249.756
13.437
29.470
29.521
0.173
1584.5
18.8031
-0.11
0.16
0.176
0.002
242.161
13.446
29.393
29.609
0.733
1496.0
16.9600
-0.12
0.18
0.739
0.006
234.527
13.455
29.418
29.772
1.205
1399.4
15.1083
-0.14
0.20
1.215
0.010
226.091
13.464
29.853
30.059
0.690
1262.0
13.0669
-0.15
0.21
0.707
0.017
218.423
13.473
30.077
30.435
1.189
1159.3
11.2192
-0.17
0.22
1.215
0.026
212.499
13.479
30.501
30.822
1.053
1066.5
9.8001
-0.18
0.22
1.089
0.035
210.717
13.481
30.583
30.961
1.235
10^2.8
9.3752
-0.19
0.23
1.275
0.039
203.443
13.489
31.440
31.699
0.825
919.6
7.6538
-0.23
0.23
0.893
0.067
202.980
13.490
31.670
31.760
0.284
902.3
7.5453
-0.23
0.23
0.355
0.071
194.862
13.498
33.868
33.421
-1.319
0.0
5.6658
-0.31
0.21
-1.138
0.184
147
Table A6 (continued)
T p Cy.exp C,,,cal
K nDl-dif^ J-mor^-K-i
Dev
Wt
MPa
Devi Dev2 Dev3 Dev4
289.349
14.301
30.189
30.001
-0.622
40.7
31.7855
-0.02
0.03
-0.623
-0.001
281.439
14.311
29.734
29.826
0.309
39.7
29.6385
-0.04
0.07
0.307
-0.002
lllA9k
14.317
29.565
29.750
0.625
39.0
28.5645
-0.06
0.11
0.623
-0.003
273.495
14.322
29.585
29.681
0.325
37.8
27.4733
-0.07
0.13
0.323
-0.003
269.538
14.327
29.398
29.622
0.763
1858.1
26.3919
-0.08
0.15
0.761
-0.003
265.537
14.333
29.395
29.573
0.605
1803.0
25.2966
-0.10
0.18
0.602
-0.003
262.143
14.338
29.372
29.539
0.568
1759.4
24.3660
-0.11
0.21
0.566
-0.002
255.197
14.347
29.214
29.496
0.965
1684.0
22.4587
-0.13
0.24
0.964
-0.001
248.293
14.356
29.190
29.493
1.037
1595.5
20.5599
-0.15
0.27
1.039
0.002
242.493
14.363
29.277
29.525
0.848
1511.9
18.9632
-0.16
0.29
0.854
0.005
241.372
14.365
29.337
29.536
0.678
1491.7
18.6545
-0.17
0.30
0.684
0.006
234.287
14.373
29.495
29.636
0.479
1389.3
16.7043
-0.18
0.31
0.491
0.012
234.417
14.374
29.475
29.634
0.539
1392.8
16.7399
-0.19
0.33
0.551
0.012
227.167
14.383
29.714
29.805
0.306
1286.0
14.7466
-0.20
0.34
0.326
0.020
225.394
14.385
29.674
29.859
0.623
1269.0
14.2599
-0.20
0.35
0.646
0.023
220.066
14.392
29.777
30.054
0.930
1200.6
12.8000
-0.22
0.36
0.961
0.031
217.103
14.395
29.907
30.186
0.932
1157.9
11.9904
-0.22
0.36
0.968
0.035
212.954
14.401
30.188
30.403
0.711
1093.1
10.8603
-0.24
0.38
0.756
0.045
208.733
14.406
30.531
30.671
0.457
1026.4
9.7159
-0.25
0.39
0.513
0.056
205.816
14.410
30.756
30.891
0.440
983.1
8.9293
-0.26
0.40
0.507
0.066
200.323
14.416
31.434
31.428
-0.020
891.4
7.4605
-0.27
0.38
0.069
0.089
198.638
14.419
31.571
31.638
0.212
868.7
7.0140
-0.28
0.37
0.314
0.102
195.039
14.422
32.331
32.208
-0.380
798.8
6.0693
-0.25
0.30
-0.260
0.121
191.539
14.427
33.603
33.005
-1.779
0.0
5.1655
-0.19
0.20
-1.651
0.130
265.198
15.950
29.596
29.712
0.390
1774.3
31.3546
-0.09
0.20
0.385
-0.006
259.333
15.960
29.610
29.627
0.056
1694.2
29.3643
-0.11
0.25
0.049
-0.006
253.443
15.969
29.479
29.559
0.273
1631.3
27.3593
-0.13
0.29
0.267
-0.006
249.308
15.973
28.662
29.524
3.009
0.0
25.9480
-0.12
0.28
3.004
-0.004
247.521
15.979
29.445
29.513
0.230
1558.5
25.3373
-0.15
0.34
0.226
-0.005
239.424
15.989
29.394
29.488
0.319
1461.8
22.5652
-0.15
0.35
0.318
-0.001
241.503
15.989
29.466
29.489
0.080
1480.5
23.2777
-0.16
0.38
0.077
-0.002
270.623
16.003
29.602
29.813
0.714
37.0
33.4902
-0.06
0.14
0.710
-0.004
229.421
16.005
29.529
29.532
0.010
1328.3
19.1327
-0.16
0.40
0.015
0.006
229.453
16.008
29.483
29.531
0.164
1332.8
19.1436
-0.18
0.44
0.170
0.006
264.035
16.014
29.704
29.701
-0.011
1746.0
31.2435
-0.08
0.20
-0.016
-0.006
148
Table A6 (continued)
T p <^,exp Cy.cal
K mol-dn"3 J-mol'^-ICi
Dev
Wt
MPa
Devi Dev2 Dev3 Dev4
223.903
16.017
29.506
29.600
0.317
1266.1
17.2378
-0.19
0.47
0.330
0.012
111. Ilk
16.018
29.500
29.611
0.375
1258.8
17.00^9
-0.19
0.46
0.388
0.013
Tbl.klk
16.025
29.450
29.609
0.540
1687.0
28.9799
-0.11
0.25
0.534
-0.006
217.884
16.026
29.449
29.718
0.912
1202.3
15.1722
-0.19
0.47
0.932
0.019
ly^.iii
16.036
29.381
29.540
0.543
1607.2
26.6958
-0.13
0.30
0.537
-0.005
209.230
16.037
29.880
29.989
0.365
1075.9
12.2102
-0.17
0.43
0.394
0.029
24A.O^
16.047
29.337
29.499
0.552
1525.5
24.3763
-0.15
0.35
0.548
-0.004
200.031
16.052
30.364
30.460
0.316
951.2
9.08^
-0.16
0.41
0.358
0.043
199.628
16.058
30.448
30.484
0.117
942.2
8.9482
-0.19
0.50
0.169
0.052
237.251
16.058
29.456
29.490
0.114
1429.0
22.0273
-0.16
0.39
0.114
0.000
197.622
16.061
30.772
30.625
-0.47Z
904.0
8.2721
-0.19
0.48
-0.422
0.055
195.615
16.064
30.656
30.785
0.420
891.9
7.5981
-0.18
0.46
0.479
0.058
192.871
16.065
31.025
31.041
0.052
0.0
6.6817
-0.14
0.36
0.105
0.053
193.605
16.067
30.778
30.966
0.612
866.6
6.9263
-0.16
0.42
0.672
0.060
230.437
16.069
29.349
29.520
0.581
1356.5
19.6687
-0.18
0.43
0.586
0.005
191.595
16.070
31.347
31.174
-0.551
0.0
6.2582
-0.14
0.37
-0.492
0.059
189.591
16.073
31.445
31.415
-0.097
0.0
5.5958
-0.12
0.31
-O.OW
0.056
187.587
16.076
31.801
31.697
-0.328
0.0
4.9389
-0.08
0.22
-0.283
0.045
185.501
16.079
32.221
yi.Wi,
-0.537
0.0
4.2614
-0.02
0.07
-0.520
0.016
223.900
16.080
29.472
29.593
0.409
1268.9
17.4046
-0.19
0.46
0.420
0.011
223.352
16.081
29.495
29.601
0.359
1260.7
17.2150
-0.19
0.46
0.371
0.012
216.494
16.091
29.582
29.740
0.533
1176.3
14.8411
-0.18
0.46
0.553
0.020
216.509
16.091
29.546
29.739
0.655
1179.3
14.84M
-0.18
0.46
0.675
0.020
209.569
16.102
29.912
29.956
0.147
1077.2
12.4502
-0.18
0.46
0.176
0.029
209.408
16.102
29.858
29.962
0.349
1079.3
12.3948
-0.18
0.46
0.378
0.029
202.632
16.113
30.083
30.274
0.634
994.6
10.0671
-0.17
0.45
0.674
0.040
202.277
16.113
30.311
30.294
-0.057
976.5
9.9456
-0.17
0.44
-0.017
0.039
199.140
16.118
30.308
30.486
0.587
946.0
8.8745
-0.16
0.42
0.631
0.04!^
195.637
16.124
30.676
30.746
0.227
891.0
7.6852
-0.15
0.40
0.276
0.0^9
195.118
16.124
30.702
30.789
0.285
884.7
7.5098
-0.14
0.38
0.332
0.047
191.577
16.130
31.179
31.128
-0.162
0.0
6.3184
-0.12
0.32
-0.114
0.048
188.669
16.134
31.621
31.480
-0.446
0.0
5.3^93
-0.08
0.21
-0.407
0.039
187.947
16.135
31.669
31.581
-0.279
0.0
5.1103
-0.06
0.18
-0.245
0.034
259.304
16.612
29.709
19.101
-0.008
1682.7
32.3473
-0.08
0.20
-0.014
-0.006
253.921
16.622
29.624
29.634
0.033
1621.8
30.3550
-0.10
0.26
0.026
-0.007
149
Table A6 (continued)
K mol-ckn'3 J-mor^-KT^
Dev
Wt
MPa
Devi Dev2 Dev3
Dev4
248.519
16.632
29.472
29.575
0.351
1568.4
28.3488
-0.12
0.31
0.344
-0.007
243.097
16.641
29.579
29.533
-0.156
1489.1
26.3288
-0.13
0.34
-0.162
-0.006
237.657
16.651
29.416
29.508
0.314
1437.8
24.2969
-0.15
0.39
0.309
-0.005
232.337
16.661
29.337
29.504
0.570
1380.5
22.3052
-0.16
0.43
0.568
-0.002
230.407
16.664
29.196
29.508
1.070
1370.2
21.5817
-0.16
0.43
1.069
-0.001
227.102
16.670
29.097
29.523
1.462
1339.4
20.3420
-0.17
0.45
1.464
0.002
225.003
16.673
29.481
29.537
0.189
1280.9
19.5541
-0.16
0.45
0.193
0.003
219.582
16.683
29.444
29.595
0.512
1221.9
17.5183
-0.17
0.48
0.521
0.009
216.658
16.688
29.633
29.640
0.025
1174.1
16.4203
-0.17
0.49
0.037
0.012
215.024
16.691
29.546
29.671
0.422
1162.9
15.8067
-0.17
0.49
0.436
0.014
214.143
16.692
29.551
29.689
0.466
1152.8
15.4759
-0.17
0.48
0.480
0.015
211.348
16.697
29.684
29.753
0.232
1112.5
14.4271
-0.17
0.49
0.250
0.018
210.401
16.699
29.578
29.777
0.674
1110.1
14.0717
-0.17
0.49
0.694
0.020
208.680
16.701
29.876
29.826
-0.166
1070.4
13.4263
-0.16
0.48
-0.145
0.021
206.062
16.706
29.891
29.911
0.066
1042.2
12.4457
-0.16
0.48
0.091
0.025
206.122
16.707
29.711
29.908
0.664
1055.2
12.4681
-0.17
0.50
0.690
0.026
202.937
16.710
29.921
30.030
0.366
1008.2
11.2772
-0.15
0.45
0.393
0.027
201.094
16.714
29.875
30.111
0.791
992.6
10.5894
-0.15
0.46
0.821
0.030
195.445
16.723
30.354
30.421
0.220
907.8
8.4891
-0.13
0.41
0.256
0.036
194.733
16.723
30.360
30.468
0.356
900.7
8.2252
-0.12
0.39
0.391
0.034
190.103
16.732
30.829
30.826
-0.010
0.0
6.5191
-0.10
0.36
0.029
0.039
187.826
16.735
31.032
31.046
0.0^
0.0
5.6863
-0.08
0.30
0.082
0.036
184.764
16.741
31.395
31.403
0.026
0.0
4.5748
-0.06
0.24
0.060
0.034
252.926
16.894
29.489
29.657
0.571
1623.5
31.2877
-0.08
0.21
0.565
-0.006
245.293
16.908
29.446
29.576
0.442
1530.1
28.3488
-0.10
0.27
0.436
-0.007
235.598
16.926
29.533
29.519
-0.046
1401.6
24.5973
-0.13
0.35
-0.051
-0.005
227.768
16.940
29.468
29.520
0.175
1314.3
21.5545
-0.14
0.39
0.174
-0.001
219.901
16.954
29.531
29.572
0.138
1218.4
18.4899
-0.14
0.42
0.142
0.004
211.988
16.968
29.763
29.692
-0.238
1113.6
15.4046
-0.14
0.43
-0.226
0.012
203.953
16.982
29.834
29.909
0.251
1024.4
12.2749
-0.13
0.41
0.271
0.020
196.587
16.996
30.106
30.225
0.395
933.5
9.4174
-0.11
0.40
0.422
0.028
193.924
17.001
30.219
30.377
0.522
901.2
8.3890
-0.11
0.39
0.553
0.030
187.325
17.011
30.929
30.880
-0.157
0.0
5.8591
-0.07
0.30
-0.127
0.031
240.990
17.941
29.691
29.682
-0.029
1452.2
31.7566
-0.07
0.21
-0.036
-0.007
234.304
17.955
29.518
29.626
0.365
1387.4
28.8038
-0.08
0.26
0.358
-0.007
150
Table A6 (ccaitinued)
T p Cy.exp Cy.cal
K iiol-dn"3 J-nor^-K"^
Dev
Wt
MPa
Devi Dev2 Dev3
Dev4
228.488
17.967
29.563
29.594
0.105
1314.4
26.2230
-0.09
0.30
0.098
-0.007
222.620
17.979
29.618
29.581
-0.125
1242.1
23.6084
-0.10
0.34
-0.130
-0.005
216.641
17.992
29.533
29.592
0.199
1181.8
20.9345
-0.10
0.38
0.196
-0.003
210.370
18.005
29.581
29.634
0.180
1109.6
18.1216
-0.10
0.40
0.180
0.001
204.379
18.017
29.725
29.713
-0.041
1036.2
15.4279
-0.10
0.40
-0.036
0.005
198.354
18.029
29.850
29.841
-0.031
966.8
12.7163
-0.09
0.38
-0.022
0.010
192.299
18. Oil
30.133
30.035
-0.325
890.8
9.9914
-0.08
0.37
-0.310
0.014
186.224
18.053
30.360
30.322
-0.125
1233.1
7.2642
-0.07
0.40
-0.105
0.020
181.649
18.065
30.767
30.621
-0.474
0.0
5.2194
-0.09
0.62
-0.439
0.036
178.581
18.071
31.036
30.878
-0.509
10.8
3.8554
-0.11
0.85
-0.459
0.050
222.829
19.346
29.543
29.809
0.900
1250.7
31.3168
-0.02
0.10
0.897
-0.004
223.411
19.348
29.637
29.814
0.596
1249.5
31.6548
-0.02
0.07
0.594
-0.003
221.388
19.349
29.333
29.800
1.591
1251.7
30.5529
-0.02
0.09
1.588
-0.003
220.207
19.352
29.696
29.793
0.326
1208.6
29.9262
-0.02
0.10
0.322
-0.004
220.387
19.356
29.677
29.795
0.397
1212.1
30.0506
-0.02
0.10
0.393
-0.004
217.303
19.360
29.709
29.778
0.232
1175.3
28.3806
-0.03
0.14
0.228
-0.005
217.573
19.363
29.586
29.780
0.656
1188.0
28.5526
-0.03
0.12
0.652
-0.004
215.238
19.364
29.794
29.769
-0.084
1146.3
27.2787
-0.03
0.12
-0.087
-0.004
214.493
19.366
29.584
29.766
0.617
1154.1
26.8804
-0.03
0.13
0.613
-0.004
214.522
19.370
29.610
29.767
0.532
1152.4
26.9228
-0.03
0.12
0.528
-0.004
211.785
19.373
29.560
29.759
0.673
1126.4
25.4300
-0.03
0.15
0.669
-0.004
211.480
19.378
29.665
29.759
0.317
1115.3
25.2928
-0.03
0.15
0.313
-0.004
209.060
19.379
29.638
29.755
0.394
1091.4
23.9668
-0.03
0.14
0.390
-0.004
208.755
19.380
29.659
29.754
0.322
1086.6
23.8025
-0.03
0.15
0.318
-0.004
208.615
19.385
29.669
29.755
0.291
1084.4
23.7528
-0.03
0.16
0.287
-0.004
205.568
19.393
29.607
29.756
0.503
1056.7
22.1095
-Q.QU
0.18
0.500
-0.0O4
202.844
19.395
29.583
29.761
0.601
1030.0
20.6130
-0.04
0.18
0.598
-0.003
202.557
19.395
29.748
29.762
0.046
1015.9
20.4578
-0.03
0.16
0.043
-0.003
202.661
19.400
29.781
29.762
-0.064
1014.7
20.5377
-0.04
0.18
-0.067
-0.003
199.616
19.407
29.719
29.775
0.187
987.8
18.8860
-0.03
0.17
0.185
-0.002
196.210
19.411
29.755
29.797
0.143
951.5
17.0112
-0.03
0.18
0.141
-0.001
195.819
19.412
29.778
29.801
0.076
946.2
16.7984
-0.03
0.18
0.075
-0.001
196.693
19.414
29.778
29.794
0.053
954.8
17.2961
-0.03
0.17
0.052
-0.001
193.640
19.422
29.818
29.822
0.015
922.3
15.6310
-0.03
0.18
0.014
-0.001
189.912
19.426
29.755
29.872
0.392
1335.1
13.5728
-0.03
0.16
0.392
0.000
151
Table A6 (continued)
T p Cy.exp Cv.cal
K mol-ckn'3 J-mori-K"^
Dev
Wt
MPa
Devi Dev2 Dev3
Dev4
189.464
19.427
29.826
29.879
0.177
1322.5
13.3278
-0.03
0.16
0.177
0.000
189.446
19.427
29.896
29.879
-0.057
1316.2
13.3178
-0.03
0.16
-0.056
0.000
190.680
19.429
29.878
29.860
-0.060
890.2
14.0129
-0.03
0.18
-0.060
0.000
187.628
19.436
29.890
29.911
0.069
1290.9
12.3409
-0.02
0.16
0.070
0.001
183.556
19.441
30.224
30.002
-0.736
1207.7
10.0867
-0.02
0.17
-0.734
0.002
183.084
19.442
30.061
30.014
-0.156
1214.1
9.8271
-0.02
0.17
-0.154
0.002
183.063
19.442
30.107
30.015
-0.306
1210.2
9.8159
-0.02
0.16
-0.304
0.002
184.637
19.443
30.060
29.974
-0.285
1235.4
10.6985
-0.02
0.16
-0.284
0.002
181.613
19.451
30.105
30.055
-0.166
1190.8
9.0348
-0.03
0.22
-0.163
0.003
180.587
19.453
30.258
30.087
-0.565
1165.5
8.4696
-0.03
0.23
-0.562
0.004
177.160
19.456
30.226
30.214
-0.041
1122.9
6.5659
-0.03
0.31
-0.035
0.006
176.684
19.457
30.313
30.234
-0.262
1110.5
6.3037
-0.03
0.33
-0.255
0.007
176.618
19.457
30.236
30.236
0.002
1115.1
6.2669
-0.03
0.33
0.008
0.007
178.550
19.458
30.384
30.158
-0.745
1129.5
7.3475
-0.03
0.29
-0.740
0.005
174.095
19.464
30.202
30.354
0.504
1085.1
4.8760
-0.05
0.62
0.517
0.013
174.742
19.467
30.416
30.320
-0.315
1078.4
5.2466
-0.05
0.55
-0.303
0.012
172.603
19.472
30.453
30.432
-0.068
10.5
4.0666
-0.06
0.86
-0.050
0.018
182.089
20.470
30.087
30.015
-0.238
1198.6
13.9877
-0.01
0.05
-0.239
0.000
178.506
20.479
30.163
30.058
-0.347
1145.1
11.7168
0.00
0.02
-0.347
0.000
174.898
20.489
30.217
30.120
-0.321
1094.3
9.4196
-0.01
0.06
-0.321
0.000
172.193
20.499
30.325
30.181
-0.474
1052.5
7.6896
-0.02
0.31
-0.473
0.001
170.403
20.504
30.295
30.230
-0.214
1032.1
6.5423
-0.03
0.44
-0.212
0.003
200.078
21.167
29.929
30.201
0.908
978.9
31.0692
0.03
-0.16
0.915
0.007
198.229
21.171
29.957
30.192
0.784
958.8
29.8244
0.04
-0.21
0.793
0.009
194.626
21.184
30.043
30.179
0.453
918.4
27.3861
0.03
-0.16
0.459
0.006
191.734
21.191
29.987
30.170
0.610
893.9
25.4175
0.04
-0.23
0.618
0.008
189.153
21.201
30.047
30.165
0.392
1299.1
23.6514
0.03
-0.18
0.398
0.006
185.182
21.211
30.004
30.161
0.522
1247.4
20.9182
0.04
-0.28
0.530
0.008
183.640
21.218
30.035
30.162
0.422
1223.8
19.8512
0.03
-0.21
0.427
0.006
178.582
21.231
30.088
30.173
0.281
1151.7
16.3306
0.04
-0.36
0.288
0.007
178.091
21.234
30.120
30.175
0.182
1142.8
15.9873
0.03
-0.30
0.188
0.006
172.488
21.251
30.155
30.214
0.197
1067.8
12.0442
0.03
-0.36
0.201
0.004
171.921
21.252
30.323
30.220
-0.339
1049.2
11.6427
0.04
-0.41
-0.335
0.004
166.828
21.269
30.358
30.294
-0.210
984.1
8.0183
0.02
-0.30
-0.209
0.001
165.189
21.272
30.406
30.327
-0.258
961.4
6.8445
0.02
-0.40
-0.258
0.000
152
Table A6 (continued)
T p C,;,exp Cv'^^
K nol-dn'^ J-mor^-KT^
Dev
Wt
MPa
Devi
Dev2 Dev3
Dev4
161.1^
21.286
30.358
30.436
0.256
9.2
3.9294
-0.01
0.19
0.257
0.000
187.701
21.988
30.282
30.456
0.573
1259.5
29.3776
0.03
-0.23
0.583
0.010
183.514
22.003
30.245
30.441
0.649
1205.5
26.2195
0.03
-0.23
0.658
0.009
179.314
22.017
30.429
30.430
0.003
1136.2
23.0213
0.03
-0.28
0.013
0.010
175.011
22.032
30.383
30.425
0.137
1084.1
19.7127
0.03
-0.32
0.146
0.009
170.767
22.0^
30.536
30.428
-0.354
1020.8
16.4170
0.04
-0.40
-0.345
0.009
166.497
22.060
30.671
30.444
-0.740
960.8
13.0668
0.04
-0.50
-0.732
0.008
162.200
22.075
30.653
30.480
-0.565
911.5
9.6595
0.03
-0.52
-0.559
0.005
157.876
22.090
30.769
30.544
-0.732
855.8
6.1932
0.02
-0.41
-0.730
0.002
153.984
22.102
30.845
30.635
-0.682
0.1
3.0412
0.00
-0.01
-0.682
0.000
175.530
22.813
30.720
30.775
0.180
1067.5
27.7047
0.05
-0.47
0.200
0.020
175.122
22.815
30.620
30.774
0.50^
1069.2
27.3613
0.05
-0.46
0.523
0.019
169.076
22.838
30.651
30.757
0.345
992.9
22.2365
0.06
-0.58
0.366
0.020
168.648
22.839
30.749
30.756
0.022
981.6
21.8708
0.06
-0.62
0.043
0.021
162.555
22.862
30.764
30.752
-0.040
909.2
16.6099
0.06
-0.82
-0.020
0.021
162.130
22.864
30.799
30.752
-0.152
902.3
16.2388
0.06
-0.81
-0.132
0.020
156.936
22.881
30.901
30.770
-0.425
838.3
11.6734
0.07
1.24
-0.405
0.021
155.969
22.887
30.957
30.777
-0.581
824.8
10.8146
0.06
1.11
-0.565
0.017
155.536
22.888
30.956
30.780
-0.568
820.2
10.4300
0.06
1.19
-0.551
0.017
148.828
22.913
31.148
30.871
-0.888
74.0
4.3941
0.0^
1.76
-0.881
0.007
164.346
23.368
30.934
31.013
0.256
920.0
23.5208
0.04
-0.40
0.271
0.015
160.058
23.385
31.014
31.005
-0.028
866.9
19.5801
0.04
-0.54
-0.011
0.017
156.170
23.403
31.053
31.007
-0.14«
822.1
15.9591
0.03
-0.53
-0.134
0.013
152.695
23.417
31.101
31.017
-0.269
782.4
12.6822
0.03
-0.64
-0.256
0.012
150.090
23.431
31.142
31.035
-0.343
753.2
10.1996
0.02
-0.39
-0.337
0.006
148.358
23.438
31.134
31.051
-0.266
7356.9
8.5366
0.01
-0.38
-0.261
0.005
146.608
23.445
31.162
31.073
-0.287
7166.1
6.8455
0.01
-0.34
-0.284
0.003
164.072
23.885
31.111
31.320
0.671
906.7
29.5630
0.02
-0.22
0.681
0.010
160.011
23.903
31.104
31.308
0.657
861.5
25.6422
0.03
-0.30
0.670
0.012
155.908
23.921
31.397
31.300
-0.308
801.9
21.6240
0.03
-0.42
-0.2%
0.014
151.599
23.939
31.303
31.299
-0.014
761.3
17.3398
0.04
-0.63
0.003
0.017
147.448
23.957
31.480
31.310
-0.539
7110.5
13.1452
0.04
-0.83
-0.522
0.017
143.270
23.975
31.525
31.342
-0.580
6681.4
8.8550
0.04
1.10
-0.566
0.014
139.073
23.993
31.633
31.405
-0.720
62.4
4.4671
0.03
1.41
-0.712
0.008
154.473
24.651
31.706
31.784
0.247
772.0
30.0452
0.02
-0.25
0.258
0.011
153
Table A6 (continued)
T p Cv.exp C^'^^
K nol-dnf^ J-nor^-ICi
Dev
Wt
MPa
Devi
Dev2 Dev3
Dev4
153.185
24.657
31.595
31.782
0.591
764.0
28.6816
0.02
-0.31
0.605
0.013
149.124
24.676
31.598
31.777
0.565
7226.0
24.3346
0.03
-0.51
0.585
0.019
147.886
24.682
31.651
31.776
0.396
7079.7
22.9952
0.04
-0.57
0.416
0.021
143.713
24.702
31.844
31.781
-0.199
6594.8
18.4271
0.04
-0.83
-0.175
0.024
142.547
24.708
31.794
31.785
-0.030
6504.3
17.1361
0.04
-0.88
-0.006
0.024
139.337
24.723
31.826
31.801
-0.078
6192.4
13.5454
0.05
1.18
-0.054
0.025
138.242
24.728
32.209
31.809
-1.240
5953.1
12.3089
0.05
1.32
-1.216
0.025
137.159
24.733
31.953
31.820
-0.417
5947.5
11.0794
0.05
1.47
-0.393
0.025
134.136
24.749
32.039
31.860
-0.558
5649.2
7.6115
0.04
1.65
-0.540
0.018
132.694
24.754
32.346
31.885
-1.426
5423.4
5.9387
0.04
2.29
-1.408
0.019
131.693
24.759
32.305
31.906
-1.236
5351.8
4.7717
0.04
2.57
-1.220
0.016
130.508
24.772
32.470
31.938
-1.640
52.0
3.3808
0.00
-0.45
-1.638
0.002
130.274
25.807
32.609
32.642
0.102
5139.3
18.3466
0.02
-0.46
0.115
0.012
127.262
25.823
32.654
32.675
0.064
4882.1
14.4728
0.03
-0.81
0.081
0.017
124.223
25.840
32.844
32.723
-0.369
4590.9
10.4959
0.03
1.13
-0.353
0.016
121.160
25.856
33.035
32.789
-0.745
4309.8
6.4101
0.03
1.76
-0.730
0.015
127.100
26.539
33.110
33.300
0.573
4741.4
27.6133
0.02
-0.43
0.589
0.016
127.123
26.539
33.141
33.300
0.478
4734.7
27.6449
0.02
-0.42
0.494
0.016
122.094
26.569
33.244
33.350
0.319
4326.9
20.7254
0.04
1.10
0.350
0.031
122.089
26.569
33.348
33.350
0.006
4300.8
20.7187
0.04
1.11
0.037
0.031
117.051
26.599
33.396
33.426
0.091
3927.5
13.5645
0.06
2.19
0.130
0.039
116.030
26.605
33.471
33.446
-0.075
3839.6
12.0862
0.06
2.53
-0.036
0.039
111.917
26.629
33.691
33.537
-0.457
3515.7
6.0116
0.06
4.88
-0.424
0.034
111.855
26.629
33.625
33.538
-0.258
3524.7
5.9191
0.06
5.06
-0.224
0.034
110.867
26.635
33.783
33.563
-0.650
34.3
4.4383
0.06
6.48
-0.619
0.032
117.361
27.268
33.843
34.0^5
0.598
3850.3
28.2504
0.03
-0.60
0.620
0.021
115.142
27.283
33.956
34.070
0.336
3676.1
24.9294
0.0^
-0.93
0.365
0.029
112.446
27.300
34.003
34.100
0.284
3489.0
20.8258
0.05
1.56
0.324
0.040
110.058
27.315
34.021
34.125
0.30^
3331.9
17.1238
0.06
2.27
0.351
0.0%
107.466
27.332
34.088
34.147
0.174
3157.3
13.0295
0.07
3.23
0.222
0.048
105.029
27.347
34.237
34.156
-0.236
2983.6
9.1061
0.07
4.91
-0.187
0.049
102.424
27.365
34.360
34.144
-0.628
2810.5
4.8191
0.07
8.14
-0.589
0.040
106.655
28. 0«)
34.664
34.825
0.466
3010.2
28.4769
0.00
-0.05
0.467
0.002
105.104
28.051
34.616
34.813
0.569
2926.5
25.9193
0.01
-0.34
0.579
0.010
103.902
28.060
34.807
34.797
-0.028
2826.8
23.9163
0.02
-0.54
-0.014
0.014
102.319
28.070
34.748
34.762
0.041
2745.6
21.2466
0.03
1.05
0.066
0.024
101.123
28.079
34.886
34.726
-0.458
2658.3
19.2058
0.03
1.29
-0.431
0.027
154
Table A6 (continued)
Nuiber of Points (Total) 337
C^iT,p), Dev : AAD-% 0.462 BIAS-% 0.165 RMS% 0.571
AAD 0.142 BIAS 0.047 RMS 0.176 J-nor^-K"!
p(T,P), Devi : AAD-% 0.119 BIAS-% -0.052 FMS% 0.162
AAD 0.017 BIAS -0.007 PMS 0.020 nDl-dn"^
P(T,p), Dev2 : AAD-% 0.463 BIAS-% -0.105 RMS% 0.916
AAD 0.059 BIAS -0.007 RMS 0.088 MPa
Cv(T,P), Dev3 : AAD-% 0.468 BIAS-% 0.171 RMS% 0.574
AAD 0.144 BIAS 0.049 RMS 0.177 J-nol'^-K:^
Cv(T,P) vs. AAD-% 0.021 BIAS-% 0.006 RMS% 0.037
Qf(T,p), Dev4: AAD 0.007 BIAS 0.002 RMS 0.012 J-nol-i-IC^
155
TABLE A7
COMPARISONS FOR ISOBARIC SPECIFIC HEAT CAPACITY
Notes for Table A7 . Entries for the first 3 coltimns, the temperature,
pressure, and isobaric specific heat capacity, are directly from the
experimental data. The primary isobaric specific heat capacity data were
exclusively from Ref.[54]; 12 points from this reference, indicated by
negative weights, were excluded from the primary data set.
Data from Jones et al. [54]
T P Cp.exp Cp,cal
K MPa J-mol'i-K"! J-mol'^-K'^
116.483 1.034 55.420 56.387
116.483 2.068 55.360 56.165
116.483 2.413 55.360 56.094
116.483 3.103 55.290 55.955
116.483 3.792 55.220 55.820
116.483 4.137 55.160 55.755
116.483 4.309 55.090 55.723
116.483 4.688 55.090 55.653
116.483 5.516 55.020 55.504
116.483 6.895 54.950 55.268
116.483 8.274 54.890 55.047
116.483 10.342 54.550 54.739
116.483 13.790 54.010 54.281
122.039 1.034 56.570 57.103
122.039 2.068 56.500 56.828
122.039 2.413 56.430 56.739
122.039 3.103 56.300 56.568
122.039 3.792 56.160 56.403
122.039 4.137 56.030 56.323
122.039 4.309 55.960 56.283
122.039 4.688 55.960 56.198
122.039 5.516 55.830 56.017
122.039 6.895 55.690 55.732
122.039 8.274 55.420 55.467
122.039 10.342 54.890 55.100
122.039 13.790 54.350 54.560
127.594 1.034 57.910 57.982
127.594 2.068 57.510 57.635
127.594 2.413 57.440 57.524
127.594 3.103 57.370 57.310
156
Dev
Wt
%
1.745
467.80
1.454
93.76
1.325
93.76
1.202
93.99
1.087
94.23
1.079
94.43
1.148
94.66
1.021
94.66
0.879
94.90
0.579
95.14
0.286
95.34
0.346
96.51
0.501
98.41
0.943
409.96
0.580
82.19
0.548
82.39
0.476
82.77
0.433
83.17
0.523
83.55
0.578
83.76
0.425
83.76
0.335
84.14
0.076
84.56
0.084
85.37
0.382
87.00
0.386
88.71
0.125
358.60
0.217
72.71
0.146
72.88
0.105
73.06
Data from Jones et al. [54] (continued)
T
P
Cp , exp
Cp.cal
Dev
Wt
K
MPa
J-mol-i-K"!
J-mol-i-K-i
%
127.594
3.792
57.040
57.105
0.115
73.89
127.594
4.137
56.970
57.006
0.064
74.07
127.594
4.309
56.900
56.958
0.101
74.25
127.594
4.688
56.770
56.852
0.145
74.59
127.594
5.516
56.500
56.630
0.231
75.29
127.594
6.895
56.370
56.284
-0.153
75.63
127.594
8.274
56.030
55.963
-0.120
76.54
127.594
10.342
55.360
55.523
0.295
78.38
127.594
13.790
54.750
54.885
0.246
80.11
133.150
1.034
59.390
59.086
-0.511
313.65
133.150
2.068
58.780
58.640
-0.238
64.02
133.150
2.413
58.580
58.499
-0.139
64.45
133.150
3.103
56.380
58.227
3.277
-0.00
133.150
3.792
58.040
57.970
-0.120
65.64
133.150
4.137
57.910
57.846
-0.111
65.94
133.150
4.309
57.780
57.785
0.009
66.23
133.150
4.688
57.710
57.654
-0.097
66.39
133.150
5.516
57.310
57.378
0.119
67.31
133.150
6.895
57.100
56.952
-0.259
67.79
133.150
8.274
56.700
56.561
-0.245
68.74
133.150
10.342
55.960
56.032
0.128
70.55
133.150
13.790
55.160
55.273
0.206
72.58
138.706
1.034
61.140
60.496
-1.054
273.15
138.706
2.068
60.130
59.909
-0.368
56.46
138.706
2.413
59.930
59.725
-0.342
56.83
138.706
3.103
59.660
59.374
-0.479
57.34
138.706
3.792
59.460
59.044
-0.699
57.73
138.706
4.137
59.190
58.886
-0.513
58.25
138.706
4.309
58.990
58.809
-0.307
58.64
138.706
4.688
58.850
58.643
-0.352
58.91
138.706
5.516
58.520
58.296
-0.382
59.57
138.706
6.895
57.840
57.766
-0.129
60.97
138.706
8.274
57.370
57.285
-0.149
61.96
138.706
10.342
56.570
56.642
0.128
63.70
138.706
13.790
55.560
55.737
0.319
66.01
157
Data from Jones et al. [54] (continued)
T
P
Cp , exp
Cp.cal
Dev
Wt
K
MPa
J-mor^-K'^
J-mol-i-K-i
%
144.261
1.034
63.420
62.334
-1.713
100.73
144.261
2.068
61.740
61.536
-0.330
21.25
144.261
2.413
61.610
61.290
-0.519
21.34
144.261
3.103
61.000
60.825
-0.287
21.76
144.261
3.792
60.530
60.392
-0.228
51.56
144.261
4.137
60.400
60.186
-0.354
51.78
144.261
4.309
60.190
60.086
-0.172
52.14
144.261
4.688
60.060
59.872
-0.313
52.36
144.261
5.516
59.720
59.428
-0.489
52.95
144.261
6.895
58.850
58.758
-0,157
54.51
144.261
8.274
58.110
58.159
0.085
55.89
144.261
10.342
57.370
57.372
0.004
57.33
144.261
13.790
56.100
56.285
0.330
59.92
149.817
2.068
63.760
63.677
-0.130
18.50
149.817
2.413
63.690
63.335
-0.558
18.54
149.817
3.103
62.880
62.695
-0.294
19.01
149.817
3.792
62.140
62.110
-0.048
45.41
149.817
4.137
61.810
61.835
0.040
45.90
149.817
4.309
61.670
61.702
0.052
46.10
149.817
4.688
61.270
61.418
0.241
46.70
149.817
5.516
60.930
60.837
-0.153
47.22
149.817
6.895
59.790
59.973
0.307
49.02
149.817
8.274
59.120
59.218
0.165
50.13
149.817
10.342
58.250
58.242
-0.014
51.62
149.817
13.790
56.700
56.928
0.402
54.45
155.372
1.034
42.120
43.390
3.016
13.01
155.372
2.068
66.580
66.606
0.039
15.79
155.372
2.413
66.380
66.102
-0.419
15.88
155.372
3.103
65.230
65.179
-0.078
16.45
155.372
3.792
64.160
64.353
0.301
39.65
155.372
4.137
63.890
63.971
0.127
39.99
155.372
4.309
63.620
63.788
0.263
40.32
155.372
4.688
63.080
63.399
0.505
41.01
155.372
5.516
62.410
62.614
0.328
41.89
155.372
6.895
61.200
61.476
0.451
43.55
158
Data from Jones et al. [54] (continued)
T
P
Cp , exp
Cp.cal
Dev
Wt
K
MPa
J-mol-i-K-i
J-mol-i-K-i
%
155.372
8.274
60.260
60.504
0.404
44.91
155.372
10.342
59.320
59.279
-0.070
46.33
155.372
13.790
57.510
57.676
0.289
49.26
160.928
1.034
40.510
41.624
2.751
13.11
160.928
2.068
71.350
70.876
-0.665
12.83
160.928
2.413
69.870
70.068
0.283
13.38
160.928
3.103
68.590
68.633
0.063
13.88
160.928
3.792
67.050
67.396
0.516
33.88
160.928
4.137
66.910
66.836
-0.110
34.02
160.928
4.309
66.380
66.570
0.286
34.57
160.928
4.688
65.500
66.012
0.782
35.49
160.928
5.516
64.630
64.911
0.435
36.45
160.928
6.895
63.080
63.362
0.448
38.25
160.928
8.274
61.740
62.082
0.553
39.91
160.928
10.342
60.530
60.518
-0.020
41.51
160.928
13.790
58.450
58.545
0.162
44.49
166.483
1.034
39.370
40.416
2.656
12.97
166.483
2.413
76.050
76.317
0.351
10.57
166.483
3.103
73.770
73.806
0.049
11.23
166.483
3.792
71.620
71.770
0.209
27.78
166.483
4.137
70.940
70.883
-0.080
28.31
166.483
4.309
70.680
70.469
-0.298
28.52
166.483
4.688
69.200
69.614
0.599
29.75
166.483
5.516
68.320
67.978
-0.500
30.51
166.483
6.895
65.770
65.781
0.017
32.91
166.483
8.274
63.820
64.043
0.350
34.94
166.483
10.342
62.010
62.006
-0.006
36.99
166.483
13.790
59.520
59.550
0.051
40.13
172.039
1.034
38.560
39.487
2.403
12.67
172.039
2.068
55.490
55.055
-0.785
1.23
172.039
3.103
82.830
82.634
-0.236
8.35
172.039
3.792
78.940
78.698
-0.307
21.44
172.039
4.137
77.660
77.104
-0.716
22.15
172.039
4.309
77.190
76.381
-1.049
22.42
172.039
4.688
75.710
74.928
-1.032
23.30
159
Data from Jones et al. [54] (continued)
T P
177,
.594
1.034
177,
.594
2.068
177,
.594
2.413
177,
.594
3.103
177,
.594
3.792
177,
.594
4.137
177,
.594
4.309
177,
.594
4.688
177,
.594
5.516
177,
.594
6.895
177,
.594
8.274
177,
.594
10.342
177,
.594
13.790
183,
.150
1.034
183,
.150
2.068
183,
.150
2.413
183,
,150
3.103
183.
.150
3.792
183,
.150
4.137
183.
,150
4.309
183.
.150
4.688
183.
,150
5.516
183.
,150
6.895
183.
,150
8.274
183.
.150
10.342
183.
.150
13.790
188.
.706
1.034
188.
,706
2.068
188.
,706
2.413
188.
.706
3.103
188.
.706
3.792
188.
.706
4.137
188.
,706
4.309
188.
,706
4.688
188.
,706
5.516
188.
,706
6.895
188.
.706
8.274
188.
.706
10.342
188.
,706
13.790
Cp . exp
Cp.cal
Dev
Wt
•mol-i-K-^
J-mol"^-K"i
%
38.020
38.743
1.902
12.24
50.650
50.001
-1.281
1.39
58.180
57.990
-0.327
1.06
106.080
102.644
-3.239
-0.00
93.720
91.854
-1.991
14.30
89.080
88.205
-0.982
15.82
87.940
86.653
-1.464
16.23
84.580
83.704
-1.036
17.54
80.210
78.825
-1.727
19.50
74.370
73.408
-1.294
22.66
69.730
69.770
0.058
25.77
65.430
66.026
0.911
29.24
62.010
62.060
0.080
32.54
37.620
38.139
1.380
11.76
47.360
46.952
-0.862
1.49
52.740
52.149
-1.121
1.21
75.040
74.155
-1.179
0.01
132.480
132.968
0.369
0.00
114.410
116.342
1.688
0.00
109.370
110.792
1.301
0.00
102.920
101.852
-1.037
0.00
89.750
90.150
0.446
0.00
81.090
79.939
-1.419
0.01
74.300
74.136
-0.220
21.36
67.790
68.781
1.461
25.63
63.490
63.618
0.202
29.20
37.290
37.646
0.954
11.28
44 . 940
44.836
-0.232
1.56
49.240
48.624
-1.252
1.30
62.010
61.310
-1.128
0.01
100.240
97.671
-2.563
0.00
164.660
174.573
6.020
-0.00
352.170
410.075
16.442
-0.00
184.480
178.776
-3.092
0.00
115.420
115.902
0.417
0.00
90.900
90.598
-0.332
0.00
80.480
80.302
-0.221
17.16
70.810
72.260
2.048
22.15
65.030
65.420
0.599
26.24
160
Data from Jones et al. [54] (continued)
T P
K MPa
194.261
1.034
194.261
2.068
194.261
2.413
194.261
3.103
194.261
3.792
194.261
4.137
194.261
4.309
194.261
4.688
194.261
5.516
194.261
6.895
194.261
8.274
194.261
10.342
194.261
13.790
199.817
1.034
199.817
2.068
199.817
2.413
199.817
3.103
199.817
3.792
199.817
4.137
199.817
4.309
199.817
4.688
199.817
5.516
199.817
6.895
199.817
8.274
199.817
10.342
199.817
13.790
205.372
1.034
205.372
2.068
205.372
2.413
205.372
3.103
205.372
3.792
205.372
4.137
205.372
4.309
205.372
4.688
205.372
5.516
Cp , exp
Cp.cal
Dev
Wt
•mol-i-K-i
J-mor^-K-i
%
37.020
37.243
0.602
162.12
43.260
43.262
0.005
23.84
46.690
46.200
-1.050
20.50
54.950
54.871
-0.144
14.84
73.300
72.008
-1.762
8.36
91.500
89.294
-2.411
1.34
101.180
103.278
2.073
1.10
193.210
172.350
-10.797
-0.00
240.850
243.740
1.200
-0.00
107.090
110.944
3.599
0.98
88.680
89.537
0.966
5.72
75.180
76.723
2.053
7.95
66.850
67.494
0.963
10.05
36.750
36.913
0.444
155.58
41.920
42.048
0.305
23.99
44.680
44.416
-0.591
21.15
50.790
50.874
0.165
16.40
62.010
61.517
-0.794
11.03
71.820
69.973
-2.571
2.06
77.330
75.553
-2.298
1.78
94.460
93.311
-1.216
1.19
231.440
217.015
-6.233
-0.00
148.070
155.359
4.922
-0.00
102.250
103.941
1.654
4.07
81.760
82.477
0.877
6.36
68.860
69.859
1.451
8.95
36.550
36.646
0.261
148.98
40.850
41.090
0.587
23.92
43.130
43.051
-0.182
21.48
47.900
48.116
0.451
17.45
55.760
55.601
-0.286
12.90
61.940
60.863
-1.738
2.62
65.640
64.047
-2.427
2.33
75.380
72.907
-3.281
1.77
111.050
108.656
-2.156
0.82
161
Data from Jones et al. [54] (continued)
T
P
Cp , exp
Cp.cal
Dev
Wt
K
MPa
J-mor^-K'^
J-mor^-K"^
%
205.372
6.895
194.830
202.733
4.057
-0.00
205.372
8.274
123.010
124.144
0.922
2.66
205.372
10.342
90.490
89.615
-0.967
4.92
205.372
13.790
70.940
72.496
2.193
7.99
210.928
1.034
36.410
36.430
0.054
142.41
210.928
2.068
40.040
40.323
0.707
23.60
210.928
2.413
41.790
41.982
0.459
21.69
210.928
3.103
45.820
46.095
0.600
18.07
210.928
3.792
51.600
51.743
0.278
14.27
210.928
4.137
55.630
55.429
-0.360
3.07
210.928
4.309
58.250
57.554
-1.194
2.80
210.928
4.688
64.960
63.092
-2.875
2.26
210.928
5.516
84.310
81.295
-3.576
1.34
210.928
6.895
139.000
141.210
1.590
0.49
210.928
8.274
138.460
140.483
1.461
1.99
210.928
10.342
97.880
97.331
-0.561
3.99
210.928
13.790
73.560
75.300
2.366
7.05
216.483
1.034
36.280
36.258
-0.061
136.24
216.483
2.068
39.370
39.704
0.848
23.18
216.483
2.413
40.850
41.130
0.685
21.55
216.483
3.103
44.270
44.557
0.649
18.38
216.483
3.792
48.770
49.020
0.513
15.16
216.483
4.137
51.600
51.790
0.368
3.39
216.483
4.309
53.280
53.338
0.109
3.18
216.483
4.688
57.980
57.220
-1.311
2.69
216.483
5.516
69.940
68.677
-1.806
1.85
216.483
6.895
103.260
100.997
-2.192
05
216.483
8.274
127.710
129.476
1.383
2.22
216.483
10.342
103.120
103.472
0.341
3.41
216.483
13.790
76.180
78.021
2.417
6.24
222.039
1.034
36.080
36.125
0.124
131.01
222.039
2.068
38.900
39.202
0.776
22.58
222.039
2.413
40.110
40 . 444
0.833
21.25
222.039
3.103
43.130
43.357
0.527
18.40
222.039
3.792
46.690
47.000
0.665
15.72
162
Data from Jones et al, [54] (continued)
T
P
Cp , exp
Cp.cal
Dev
Wt
K
MPa
J-mol'i-K-i
J-mol'i-K-i
%
222.039
4.137
48.910
49.181
0.553
3.58
222.039
4.309
50.180
50.374
0.386
3.41
222.039
4.688
53.280
53.289
0.016
3.02
222.039
5.516
61.740
61.339
-0.649
2.25
222.039
6.895
85.320
81.518
-4.456
-0.00
222.039
8.274
105.340
105.634
0.279
3.11
222.039
10.342
103.660
104.748
1.050
3.21
222.039
13.790
79.010
80.282
1.610
5.52
227.594
1.034
36.010
36.025
0.043
125.25
227.594
2.068
38.500
38.794
0.764
21.95
227.594
2.413
39.570
39.889
0.806
20.79
227.594
3.103
42.190
42.404
0.508
18.31
227.594
3.792
45.080
45.453
0.827
16.05
227.594
4.137
46.890
47.227
0.719
3.71
227.594
4.309
47.770
48.183
0.865
3.58
227.594
4.688
50.320
50.476
0.310
3.22
227.594
5.516
56.500
56.530
0.052
2.56
227.594
6.895
74.100
70.501
-4.856
-0.00
227.594
8.274
87.940
87.938
-0.002
4.24
227.594
10.342
97.680
99.199
1.555
3.44
227.594
13.790
81.220
81.671
0.555
4.97
233.150
1.034
35.940
35.956
0.045
119.87
233.150
2.068
38.230
38.464
0.613
21.22
233.150
2.413
39.100
39.438
0.865
20.29
233.150
3.103
41.380
41.639
0.627
18.13
233.150
3.792
44.000
44.239
0.543
16.05
233.150
4.137
45.480
45.720
0.528
3.76
233.150
4.309
46.290
46.508
0.472
3.63
233.150
4.688
48.030
48.374
0.716
3.37
233.150
5.516
53.070
53.139
0.130
2.77
233.150
6.895
65.770
63.501
-3.450
-0.00
233.150
8.274
76.520
76.295
-0.294
5.33
233.150
10.342
88.210
90.061
2.098
4.02
233.150
13.790
80.890
81.812
1.139
4.77
238.706
1.034
35.940
35.914
-0.073
114.42
163
Data from Jones et al. [54] (continued)
T P
K MPa
238.706
2.068
238.706
2.413
238.706
3.103
238.706
3.792
238.706
4.137
238.706
4.309
238.706
4.688
238.706
5.516
238.706
6.895
238.706
8.274
238.706
10.342
238.706
13.790
244.261
1.034
244.261
2.068
244.261
2.413
244.261
3.103
244.261
3.792
244.261
4.137
244.261
4.309
244.261
4.688
244.261
5.516
244.261
6.895
244.261
8.274
244.261
10.342
244.261
13.790
249.817
1.034
249.817
2.068
249.817
2.413
249.817
3.103
249.817
3.792
249.817
4.137
249.817
4.309
249.817
4.688
249.817
5.516
249.817
6.895
Cp , exp
Cp.cal
Dev
Wt
mol-i-K-^
J-mor^-K-i
%
37.960
38.199
0.631
20.53
38.760
39.073
0.808
19.70
40.780
41.020
0.590
17.82
43.060
43.272
0.493
15.99
44.270
44.533
0.594
3.78
45.080
45.198
0.262
3.65
46.420
46.754
0.720
3.44
50.790
50.632
-0.311
2.88
59.660
58.696
-1.616
2.09
68.860
68.431
-0.624
6.28
79.480
81.165
2.120
4.72
78.870
80.474
2.034
4.79
35.880
35.896
0.046
109.69
37.760
37.990
0.609
19.83
38.500
38.780
0.727
19.08
40.240
40.519
0.692
17.48
42.260
42.495
0.555
15.86
43.400
43.585
0.426
3.76
43.740
44.156
0.951
3.70
45.410
45.480
0.155
3.44
48.440
48.717
0.572
3.02
55.560
55.218
-0.616
2.30
63.220
62.883
-0.533
7.11
72.350
73.831
2.047
5.44
76.320
77.831
1.979
4.89
35.940
35.901
-0.107
104.56
37.620
37.828
0.554
19.10
38.290
38.547
0.671
18.44
39.840
40.112
0.683
17.05
41.590
41 . 864
0.660
15.65
42.730
42.820
0.211
3.71
43.130
43.317
0.434
3.64
44 . 340
44.463
0.277
3.45
46.960
47.219
0.551
3.07
52.740
52.602
-0.262
2.44
164
Data from Jones et al
K
[54] (continued)
MPa
Cp , exp
Cp.cal
Dev
J-mor^-iri J-mol"i-K'i
Wt
249.817
8.274
59.050
58.814
-0.399
7.79
249.817
10.342
66.780
68.064
1.923
6.10
249.817
13.790
73.360
74.419
1.443
5.06
255.372
1.034
35.940
35.927
-0.035
100.10
255.372
2.068
37.550
37.709
0.422
18.35
255.372
2.413
38.160
38.366
0.539
17.78
255.372
3.103
39.570
39.784
0.542
16.54
255.372
3.792
41.120
41.353
0.566
15.33
255.372
4.137
42.060
42.200
0.332
14.65
255.372
4.309
42.390
42.638
0.585
14.43
255.372
4.688
43.470
43.642
0.396
13.72
255.372
5.516
45.680
46.026
0.758
12.44
255.372
6.895
50.650
50.580
-0.137
10.13
255.372
8.274
55.830
55.736
-0.168
8.34
255.372
10.342
62.340
63.565
1.966
6.69
255.372
13.790
70.140
70.805
0.948
5.29
260.928
1.034
36.010
35.973
-0.103
95.55
260.928
2.068
37.490
37.625
0.361
17.64
260.928
2.413
38.020
38.229
0.550
17.16
260.928
3.103
39.370
39.523
0.389
16.01
260.928
3.792
40.780
40.938
0.388
14.93
260.928
4.137
41.590
41.696
0.254
14.36
260.928
4.309
41.790
42.086
0.708
14.22
260.928
4.688
42.790
42.976
0.434
13.57
260.928
5.516
44.940
45.066
0.281
12.31
260.928
6.895
49.110
48.985
-0.255
10.32
260.928
8.274
53.340
53.348
0.015
8.75
260.928
10.342
58.920
60.030
1.884
7.18
260.928
13.790
67.050
67.359
0.461
5.55
266.483
1.034
36.080
36.037
-0.120
91.29
266.483
2.068
37.420
37.575
0.414
16.98
266.483
2.413
37.960
38.133
0.455
16.51
266.483
3.103
39.170
39.319
0.381
15.51
266.483
3.792
40.440
40.604
0.407
14.56
266.483
4.137
41.050
41.287
0.578
14.13
165
Data from
Jones et al .
[54] (continue
5d)
T
P
Cp , exp
Cp.cal
Dev
Wt
K
MPa
J-mori-Kr^
J-mor^-K'!
%
266.483
4.309
41.380
41.638
0.623
13.91
266.483
4.688
42.190
42.434
0.578
13.38
266.483
5.516
44.270
44.287
0.038
12.16
266.483
6.895
47.830
47.707
-0.257
10.43
266.483
8.274
51.390
51.460
0.136
9.04
266.483
10.342
56.430
57.222
1.404
7.50
266.483
13.790
64.090
64.255
0.257
5.82
272.039
1.034
36.140
36.118
-0.062
5.82
272.039
2.068
37.420
37.554
0.359
1.09
272.039
2.413
37.890
38.071
0.478
1.06
272.039
3.103
39.030
39.164
0.344
1.00
272.039
3.792
40.240
40.339
0.245
0.94
272.039
4.137
40.780
40.959
0.438
0.92
272.039
4.309
41.050
41.276
0.550
0.90
272.039
4.688
41.850
41.993
0.343
0.87
272.039
5.516
44.000
43.652
-0.792
0.79
272.039
6.895
46.890
46.672
-0.466
0.69
272.039
8.274
49.980
49.944
-0.071
0.61
272.039
10.342
54.550
54.965
0.762
0.51
272.039
13.790
61.540
61.539
-0.001
0.40
277.594
1.034
36.210
36.215
0.013
5.57
277.594
2.068
37.420
37.560
0.375
1.04
277.594
2.413
37.890
38.041
0.398
1.02
277.594
3.103
38.970
39.053
0.212
0.96
277.594
3.792
40.170
40.131
-0.096
0.91
277.594
4.137
40.640
40.697
0.141
0.89
277.594
4.309
40.850
40.986
0.334
0.88
277.594
4.688
41.590
41.638
0.116
0.85
277.594
5.516
43.600
43.134
-1.069
0.77
277.594
6.895
46.020
45.827
-0.419
0.69
277.594
8.274
48.910
48.715
-0.400
0.61
277.594
10.342
53.140
53.133
-0.012
0.52
277.594
13.790
59.460
59.201
-0.435
0.42
283.150
1.034
36.280
36.327
0.131
5.34
283.150
2.068
37.350
37.590
0.644
1.01
166
Data from Jones et al. [54] (continued)
T P Cp , exp Cp , cal Dev Wt
K MPa J-mori-K"i J-mol"^-K"i %
283.150 2.413 37.820 38.039
283.150 3.103 38.900 38.979
283.150 3.792 40.110 39.974
283.150 4.137 40.510 40.494
283.150 4.309 40.780 40.759
283.150 4.688 41.520 41.354
283.150 5.516 42.930 42.713
283.150 6.895 45.480 45.136
283.150 8.274 48.030 47.708
283.150 10.342 52.070 51.632
283.150 13.790 57.780 57.203 -0.999 0.42
Number of Points (Ref. 54, Primary) 388
AAD-% 0.669 BIAS-% 0.160 RMS-% 0.931
AAD 0.445 BIAS 0.069 RMS 0.749 J-mol-^-K'^
Number of Points (Ref. 54, Total) 400
AAD-% 0.821 BIAS-% 0.162 RMS-% 1.514
AAD 0.772 BIAS 0.165 RMS 3.345 J-mol'^-K'^
0.579
0.98
0.203
0.93
0.339
0.87
0.039
0.86
0.052
0.85
0.399
0.82
0.506
0.76
0.757
0.68
0.671
0.61
0.841
0.52
Data from Van Kasteren
and Zeldenrust
[55]
T
P
Cp , exp
Cp.cal
Dev
Wt
K
MPa
J-mol-i-K-i
J-mol'^-K"^
%
121.1
5.00
55.188
56.032
1.530
0.00
121.1
5.00
55.060
56.032
1.766
0.00
121.1
5.00
54.979
56.032
1.916
0.00
121.0
5.00
55.156
56.022
1.570
0.00
136.1
5.00
57.338
58.033
1.213
0.00
136.2
5.00
57.402
58.051
1.130
0.00
136.2
5.00
57.241
58.051
1.415
0.00
151.3
5.00
61.268
61.654
0.630
0.00
151.3
5.00
61.044
61.654
1.000
0.00
151.2
5.00
60.963
61.622
1.081
0.00
167
Data from Van Kasteren and Zeldenrust [55]
T
P
Cp , exp
Cp.cal
Dev
Wt
K
MPa
J-mor^-K-i
J-mol-i-K-^
%
165.1
5.00
67.846
68.011
0.244
0.00
165.1
5.00
67.830
68.011
0.267
0.00
165.1
5.00
68.054
68.011
-0.063
0.00
165.0
5.00
67.734
67.946
0.313
0.00
175.6
5.00
78.579
78.367
-0.270
0.00
175.7
5.00
79.092
78.516
-0.728
0.00
175.6
5.00
78.707
78.367
-0.432
0.00
175.5
5.00
79.076
78.219
-1.084
0.00
182.7
5.00
94.622
94.846
0.237
0.00
182.7
5.00
94.573
94.846
0.289
0.00
182.7
5.00
94.654
94.846
0.203
0.00
184.2
5.00
101.841
01.159
-0.670
0.00
186.4
5.00
116.248
14.823
-1.226
0.00
188.5
5.00
140.408
38.418
-1.417
0.00
191.0
5.00
251.298
18.727
-12.961
0.00
192.7
5.00
558.746
11.247
9.396
0.00
192.6
5.00
549.681
46.601
-0.560
0.00
195.4
5.00
279.662
64.189
-5.533
0.00
198.0
5.00
149.408
46.547
-1.915
0.00
201.5
5.00
103.959
02.911
-1.008
0.00
201.5
5.00
103.927
02.911
-0.978
0.00
209.5
5.00
73.108
71.555
-2.124
0.00
209.5
5.00
73.108
71.555
-2.124
0.00
220.0
5.00
57.659
57.625
-0.060
0.00
220.0
5.00
57.851
57.625
-0.391
0.00
230.5
5.00
50.712
51.165
0.894
0.00
240.0
5.00
47.359
47.755
0.836
0.00
240.4
5.00
47.311
47.642
0.699
0.00
250.6
5.00
44.985
45.313
0.729
0.00
144.4
3.20
59.850
60.803
1.592
0.00
144.3
3.20
60.690
60.773
0.137
0.00
144.4
3.20
59.960
60.803
1.405
0.00
146.2
3.20
61.600
61.353
-0.402
0.00
146.5
3.20
60.890
61.449
0.918
0.00
154.9
3.20
63.990
64.819
1.296
0.00
168
Data from Van Kasteren and Zeldenrust [55] (continued)
I
I
T
P
Cp . exp
Cp , cal
Dev
Wt
K
MPa
J-mol-i-K-i
J-mor^-K'i
%
154.8
3.20
64.140
64.769
0.981
0.00
164.9
3.20
71.560
71.818
0.360
0.00
164.9
3.20
71.310
71.818
0.712
0.00
174.3
3.20
89.160
87.547
-1.809
0.00
185.5
3.20
72.530
71.596
-1.288
0.00
193.2
3.20
57.960
57.691
-0.464
0.00
193.1
3.20
58.070
57.803
-0.459
0.00
202.9
3.20
50.180
50.219
0.077
0.00
202.9
3.20
50.000
50.219
0.438
0.00
Number of Points (Ref . 55) 54
AAD-% 1.356 BIAS-% -0.050 RMS-% 2.524
AAD 2.530 BIAS -0.021 RMS 8.717 J-mol'^-K'^
Total Points 454
AAD-% 0.885 BIAS-% 0.137 RMS-% 1.668
AAD 0.981 BIAS 0.143 RMS 4.347 J-mol'^-K'^
169
TABLE A8
COMPARISONS FOR SPECIFIC HEAT CAPACITY OF THE SATURATED LIQUID
Notes for Table A8. The densities above were calculated from the experimental
temperatures and the ancillary eq (2) for the density of the saturated
liquid. These densities were used to calculate the heat capacity along the
saturation boundary according to the equation given in Table 7.
Data are from Younglove [52] and Roder [53] as adjusted by Roder [53] .
T p C^L.exp C^L.cal Dev Wt
K mol-dm"3 J-mor^-lT^ J-mol'^-K"^ %
95.402
27.7468
54.206
54.130
-0.141
2004.81
95.846
27.7089
54.066
54.209
0.264
1996.77
99.021
27.4363
54.590
54.680
0.165
1887.59
101.651
27.2086
54.782
54.981
0.363
1812.19
101.961
27.1817
54.691
55.013
0.589
1807.43
102.574
27.1282
54.820
55.074
0.464
1787.90
106.891
26.7486
55.505
55.462
-0.077
1666.02
108.219
26.6304
55.459
55.573
0.206
1638.81
108.800
26.5785
55.187
55.622
0.788
0.00
112.604
26.2351
55.960
55.946
-0.026
1536.67
115.165
26.0002
56.292
56.178
-0.202
1480.87
116.044
25.9188
56.582
56.263
-0.564
1457.92
118.479
25.6912
56.761
56.509
-0.443
1412.62
119.117
25.6310
56.685
56.578
-0.189
1404.24
122.089
25.3474
57.292
56.919
-0.650
1343.73
122.474
25.3103
57.137
56.967
-0.298
1341.72
123.367
25.2237
56.845
57.079
0.411
1335.66
125.766
24.9886
57.514
57.400
-0.198
1286.54
130.765
24.4848
58.092
58.175
0.142
1210.31
132.274
24.3287
58.640
58.439
-0.343
1181.30
132.751
24.2790
58.441
58.526
0.145
1179.95
135.455
23.9929
58.701
59.048
0.591
1145.11
137.805
23.7385
59.285
59.546
0.441
1109.70
139.970
23.4989
59.463
60.046
0.980
1085.54
144.305
23.0028
60.317
61.176
1.424
1032.07
144.401
22.9915
60.686
61.203
0.852
1024.84
148.500
22.4989
61.780
62.463
1.106
975.23
148.881
22.4518
61.751
62.591
1.361
973.01
150.824
22.2082
63.536
63.275
-0.411
0.00
152.809
21.9528
63.632
64.033
0.630
918.27
170
Table A8
(continued)
T
P
C^L.exp
C^L.cal
Dev
Wt
K
mol-dm"''
J-mor^-lCi
J-mol-i-K"!
%
153.157
21.9073
63.781
64.172
0.613
913.99
155.542
21.5891
64.754
65.189
0.672
886.59
157.043
21.3829
65.156
65.888
1.123
873.29
157.355
21.3395
65.288
66.039
1.151
869.94
159.127
21.0883
66.400
66.946
0.822
846.84
161.181
20.7875
67.440
68.103
0.983
825.06
161.483
20.7424
67.604
68.284
1.006
821.86
163.136
20.4906
67.864
69.331
2.162
0.00
163.782
20.3900
69.643
69.768
0.179
789.49
165.128
20.1760
70.569
70.734
0.233
775.06
165.249
20.1565
70.232
70.824
0.843
778.55
165.548
20.1080
70.442
71.052
0.866
775.40
166.549
19.9435
71.232
71.846
0.861
764.24
169.253
19.4795
73.657
74.282
0.849
733.94
169.565
19.4239
74.109
74.595
0.656
729.00
170.157
19.3173
74.426
75.211
1.054
725.27
170.197
19.3100
74.846
75.253
0.544
721.05
170.251
19.3002
75.280
75.311
0.041
716.76
171.097
19.1444
76.029
76.249
0.290
709.01
173.180
18 . 7445
78.254
78.869
0.786
688.53
173.480
18.6848
78.910
79.289
0.481
682.86
173.505
18.6798
78.214
79.325
1.420
689.15
174.032
18.5734
79.372
80.094
0.910
679.30
174.429
18.4920
80.836
80.700
-0.168
667.15
175.228
18.3248
81.869
81.999
0.158
659.75
176.295
18.0938
84.010
83.917
-0.111
644.79
177.029
17.9294
85.230
85.379
0.175
637.38
177.420
17.8397
87.184
86.213
-1.114
0.00
177.902
17.7272
86.393
87.299
1.049
631.65
178.557
17.5703
88.222
88.890
0.757
620.93
180.613
17.0442
94.968
94.981
0.014
5868.77
181.034
16.9292
96.269
96.493
0.232
5817.64
181.645
16.7569
98.591
98.894
0.308
5725.55
182.572
16.4822
103.209
103.107
-0.099
5547.41
184.222
15.9437
113.503
113.028
-0.418
5223.69
171
Table A8
(continued)
T
P
C^L.exp
C^L.cal
Dev
Wt
K
mol-dm'^
J-mol-i-K-i
J-mol-i-K-i
%
185.271
15.5577
121.885
121.882
-0.003
5021.62
186.127
15.2079
132.650
131.567
-0.816
0.00
187.577
14.5088
152.131
157.745
3.690
0.00
187.633
14.4781
157.474
159.174
1.079
0.00
Number of Points (Refs. 52 and 53) 69
AAD-% 0.626 BIAS-% 0.444 RMS-% 0.716
AAD 0.496 BIAS 0.354 RMS 0.791 J-mol-i-K-^
172
TABLE A9
COMPARISONS FOR SOUND SPEED
Notes for Table A9. The temperatures and pressures refer to experimentally
reported conditions, except that, for data reported on the saturation
boundary (in Refs. 57-59), an iteration of the SWEOS equation of state
was used to calculate a pressure and density. Other reported densities
were also from this SWEOS. These quantities were used to determine the
"experimental" value for 3P/9p|j from the experimental sound speed and
calculated values for the isobaric and isochoric specific heat capacities
(according to 5P/9/)|j = u N^^ M w^ Cy/Cp). This derivative was used to
determine the coefficients in the final SWEOS according to the weights in
the final column of the table. Calculated values of the sound speed and
derivative were from the final SWEOS. Values missing in the tables or
statistics have been omitted for any of several reasons including recent
acquisition, replicate points, critical region data, etc.
Data from Baidakov et al. [56]
T P p W,exp W,cal Devi
K
MPa mol • dm" ^
m-s
m-s
-1
aP/a/j|i d?/dp\j Dev2
exp cal
MPa-dm^ -mol"^ %
Wt
150.0
4.001
22.74
980.7
978.0
-0.3
7.68
7.63
-0.6
0.0
150.0
3.807
22.71
977.2
974.4
-0.3
7.60
7.55
-0.7
0.0
150.0
3.625
22.69
973.5
970.9
-0.3
7.53
7.48
-0.6
0.0
150.0
3.419
22.66
970.0
966.9
-0.3
7.45
7.39
-0.7
0.0
150.0
3.219
22.63
965.7
963.0
-0.3
7.36
7.31
-0.7
0.0
150.0
3.022
22.60
962.3
959.2
-0.3
7.29
7.23
-0.8
0.0
150.0
2.825
22.58
958.1
955.2
-0.3
7.20
7.15
-0.7
0.0
150.0
2.631
22.55
954.5
951.3
-0.3
7.13
7.07
-0.8
0.0
150.0
2.437
22.52
950.5
947.4
-0.3
7.05
6.99
-0.8
0.0
150.0
2.242
22.49
946.3
943.3
-0.3
6.96
6.91
-0.8
0.0
150.0
2.045
22.46
942.1
939.2
-0.3
6.88
6.83
-0.8
0.0
150.0
1.851
22.44
938.3
935.1
-0.3
6.80
6.75
-0.8
0.0
150.0
1.658
22.41
934.2
930.9
-0.4
6.72
6.66
-0.9
0.0
150.0
1.459
22.38
930.0
926.5
-0.4
6.64
6.58
-0.9
0.0
150.0
1.265
22.35
925.8
922.2
-0.4
6.56
6.49
-0.9
0.0
150.0
1.068
22.32
921.5
917.8
-0.4
6.47
6.41
-1.0
0.0
155.0
3.999
22.12
922.5
919.6
-0.3
6.54
6.49
-0.7
0.0
155.0
3.806
22.09
918.3
915.5
-0.3
6.46
6.41
-0.7
0.0
155.0
3.609
22.06
914.4
911.2
-0.3
6.38
6.33
-0.8
0.0
155.0
3.417
22.03
909.9
907.0
-0.3
6.30
6.25
-0.7
0.0
173
Data from Baidakov et al. [56] (continued)
T P p W.exp W.cal Devi
K
MPa mol-dra"^
m-s
-1
m-s
aP/ap|x dF/dp\j Dev2
exp cal
MPa-dm^ -mol'^ %
Wt
155.0
3.218
22.00
905.8
902.5
-0.4
6.22
6.17
-0.8
0.0
155.0
3.022
21.97
901.3
898.1
-0.4
6.13
6.08
-0.8
0.0
155.0
2.827
21.93
896.8
893.6
-0.4
6.05
6.00
-0.8
0.0
155.0
2.632
21.90
892.2
889.0
-0.4
5.97
5.92
-0.8
0.0
155.0
2.436
21.87
887.7
884.4
-0.4
5.88
5.83
-0.9
0.0
155.0
2.244
21.83
883.0
879.7
-0.4
5.80
5.75
-0.9
0.0
155.0
2.047
21.80
878.3
874.9
-0.4
5.71
5.66
-0.9
0.0
155.0
1.850
21.76
873.4
870.0
-0.4
-
-
-
0.0
155.0
1.656
21.73
868.5
865.0
-0.4
5.54
5.48
-0.9
0.0
155.0
1.459
21.69
863.7
860.0
-0.4
5.45
5.40
-1.0
0.0
160.0
3.998
21.46
861.2
858.2
-0.3
5.46
5.41
-0.8
0.0
160.0
3.981
21.45
861.1
857.8
-0.4
5.45
5.41
-0.9
0.0
160.0
3.805
21.42
856.5
853.4
-0.4
5.37
5.33
-0.8
0.0
160.0
3.787
21.42
856.4
852.9
-0.4
5.37
5.32
-0.9
0.0
160.0
3.621
21.39
852.2
848.7
-0.4
5.30
5.25
-0.9
0.0
160.0
3.608
21.38
851.9
848.4
-0.4
5.29
5.24
-0.9
0.0
160.0
3.588
21.38
851.3
847.9
-0.4
5.28
5.23
-0.9
0.0
160.0
3.419
21.35
847.3
843.5
-0.4
5.21
5.16
-1.0
0.0
160.0
3.230
21.31
842.3
838.6
-0.4
5.13
5.08
-1.0
0.0
160.0
3.033
21.27
837.0
833.3
-0.4
5.04
4.99
-1.0
0.0
160.0
2.826
21.23
831.3
827.7
-0.4
4.94
4.89
-1.0
0.0
160.0
2.613
21.19
825.4
821.8
-0.4
4.84
4.80
-1.0
0.0
160.0
2.434
21.15
820.4
816.7
-0.5
4.76
4.71
-1.0
0.0
160.0
2.240
21.11
814.8
811.1
-0.5
4.72
4.62
-2.0
0.0
160.0
2.043
21.06
809.0
805.3
-0.5
4.58
4.53
-1.0
0.0
160.0
1.850
21.02
803.4
799.5
-0.5
4.49
4.44
-1.1
0.0
160.0
1.737
20.99
799.8
796.0
-0.5
4.43
4.38
-1.1
0.0
160.0
1.655
20.98
797.3
793.5
-0.5
4.39
4.34
-1.1
0.0
160.0
1.644
20.97
797.2
793.1
-0.5
4.39
4.34
-1.2
0.0
163.0
4.000
21.03
823.3
819.5
-0.5
4.84
4.79
-1.0
0.0
163.0
3.806
20.99
818.0
814.2
-0.5
4.75
4.70
-1.0
0.0
163.0
3.613
20.95
812.7
808.8
-0.5
4.66
4.61
-1.0
0.0
163.0
3.422
20.91
807.3
803.3
-0.5
4.57
4.53
-1.1
0.0
163.0
3.223
20.86
801.5
797.5
-0.5
4.48
4.43
-1.1
0.0
163.0
3.024
20.82
795.5
791.6
-0.5
4.39
4.34
-1.1
0.0
174
Data from Baidakov et al. [56] (continued)
T P p W.exp W.cal Devi
MPa mol-dm"^ m-s"^
m-s
-1
d?/dp\j d?/dp\T. Dev2
exp cal
MPa-dm^ -mol"^ %
Wt
163.0
2.826
20.77
789.6
785.5
-0.5
4.30
4.25
-1.1
0.0
163.0
2.632
20.72
783.7
779.5
-0.5
4.21
4.16
-1.2
0.0
163.0
2.435
20.68
777.3
773.2
-0.5
4.11
4.06
-1.2
0.0
163.0
2.244
20.63
771.2
766.9
-0.6
4.02
3.97
-1.2
0.0
163.0
2.051
20.58
764.7
760.5
-0.6
3.92
3.87
-1.2
0.0
163.0
1.854
20.53
757.9
753.7
-0.6
3.82
3.77
-1.2
0.0
167.0
3.995
20.42
769.5
765.0
-0.6
4.03
3.98
-1.2
0.0
167.0
3.802
20.37
763.1
758.9
-0.6
3.93
3.89
-1.2
0.0
167.0
3.616
20.32
757.2
752.8
-0.6
3.85
3.80
-1.2
0.0
167.0
3.490
20.28
752.9
748.6
-0.6
3.78
3.74
-1.2
0.0
167.0
3.423
20.27
750.6
746.3
-0.6
3.75
3.70
-1.2
0.0
167.0
3.219
20.21
743.8
739.3
-0.6
3.65
3.60
-1.3
0.0
167.0
3.036
20.16
737.1
732.8
-0.6
3.56
3.51
-1.2
0.0
167.0
2.823
20.10
729.7
725.1
-0.6
3.45
3.41
-1.3
0.0
167.0
2.623
20.04
722.2
717.6
-0.6
3.35
3.31
-1.4
0.0
167.0
2.462
19.99
715.8
711.4
-0.6
3.27
3.22
-1.3
0.0
167.0
2.435
19.98
714.9
710.3
-0,6
3.25
3.21
-1.4
0.0
167.0
2.325
19.95
710.3
706.0
-0.6
3.19
3.15
-1.3
0.0
167.0
2.267
19.93
708.2
703.6
-0.6
3.16
3.12
-1.4
0.0
167.0
2.240
19.92
707.1
702.5
-0.6
3.15
3.11
-1.4
0.0
167.0
2.121
19.88
702.2
697.7
-0.6
3.09
3.04
-1.4
0.0
167.0
2.104
19.87
701.5
697.0
-0.6
3.08
3.04
-1.4
0.0
170.0
4.000
19.91
726.4
721.8
-0.6
3.43
3.39
-1.3
0.0
170.0
3.810
19.86
719.3
714.9
-0.6
3.34
3.30
-1.3
0.0
170.0
3.608
19.79
711.9
707.4
-0.6
3.24
3.20
-1.3
0.0
170.0
3.412
19.73
704.2
699.8
-0.6
3.14
3.10
-1.3
0.0
170.0
3.217
19.67
696.7
692.1
-0.7
3.04
3.00
-1.4
0.0
170.0
3.027
19.60
688.8
684.3
-0.7
2.94
2.90
-1.4
0.0
170.0
2.829
19.53
680.4
675.8
-0.7
2.83
2.79
-1.4
0.0
170.0
2.629
19.46
671.4
667.0
-0.7
2.72
2.69
-1.4
0.0
170.0
2.434
19.39
662.4
658.1
-0.7
2.62
2.58
-1.4
0.0
170.0
2.354
19.35
658.6
654.3
-0.7
2.57
2.53
-1.4
0.0
173.0
4.001
19.36
680.2
675.6
-0.7
2.86
2.82
-1.4
0.0
173.0
3.806
19.29
671.9
667.4
-0.7
2.75
2.72
-1.4
0.0
173.0
3.610
19.22
663.2
658.8
-0.7
2.65
2.61
-1.3
0.0
175
Data from Baidakov et al. [56] (continued)
T P p W.exp W.cal Devi d?/dp\^ dF/dplj Dev2 Wt
exp cal
K
MPa
mol • dm' ^
m-s"^
m-s"^
%
MPa-dra^
•mol"^
%
173.0
3.419
19.14
654.7
650.2
-0.7
2.55
2.51
-1.4
0.0
173.0
3.221
19.06
645.2
640.9
-0.7
2.44
2.40
-1.4
0.0
173.0
3.024
18.98
635.4
631.2
-0.7
2.33
2.29
-1.4
0.0
173.0
2.824
18.89
624.9
620.9
-0.6
2.21
2.18
-1.3
0.0
173.0
2.628
18.80
614.0
610.3
-0.6
2.09
2.07
-1.2
0.0
177.0
4.003
18.52
612.2
607.8
-0.7
2.10
2.07
-1.4
0.0
177.0
3.807
18.42
601.4
597.4
-0.7
1.99
1.96
-1.3
0.0
177.0
3.617
18.32
590.4
586.8
-0.6
1.88
1.85
-1.2
0.0
177.0
3.610
18.32
590.0
586.3
-0.6
1.87
1.85
-1.2
0.0
177.0
3.414
18.21
578.0
574.7
-0.6
1.75
1.74
-1.1
0.0
177.0
3.219
18.09
565.0
562.4
-0.5
1.63
1.62
-0.9
0.0
177.0
3.023
17.97
551.0
549.2
-0.3
1.50
1.50
-0.6
0.0
177.0
2.982
17.94
547.9
546.3
-0.3
1.48
1.47
-0.6
0.0
180.0
4.000
17.76
553.3
550.0
-0.6
1.54
1.52
-1.2
0.0
180.0
3.907
17.70
547.0
543.8
-0.6
1.49
1.47
-1.1
0.0
180.0
3.808
17.63
540.0
537.0
-0.5
1.42
1.41
-1.1
0.0
180.0
3.716
17.56
532.9
530.5
-0.4
1.36
1.35
-0.9
0.0
180.0
3.613
17.48
524.3
522.9
-0.3
1.29
1.29
-0.5
0.0
180.0
3.520
17.41
516.8
515.7
-0.2
1.23
1.23
-0.4
0.0
180.0
3.416
17.32
507.4
507.3
0.0
1.16
1.16
0.0
0.0
180.0
3.346
17.26
500.9
501.4
0.1
1.11
1.11
0.2
0.0
180.0
3.338
17.25
500.0
500.7
0.1
1.10
1.10
0.3
0.0
183.0
3.996
16.79
482.4
481.6
-0.2
0.98
0.98
-0.3
0.0
183.0
3.977
16.78
481.2
479.9
-0.3
0.97
0.96
-0.5
0.0
183.0
3.912
16.71
474.4
473.9
-0.1
0.92
0.92
-0.2
0.0
183.0
3.808
16.59
462.1
463.6
0.3
0.84
0.85
0.7
0.0
183.0
3.731
16.49
452.8
455.5
0.6
0.78
0.79
1.3
0.0
183.0
3.690
16.44
447.1
450.9
0.9
0.75
0.76
1.8
0.0
183.0
3.649
16.39
441.7
446.2
1.0
0.71
0.73
2.1
0.0
Number of Points (Ref . 56) 119
SOUND SPEED: AAD-% 0.475 BIAS-% -0.425 RMS-% 0.267
AAD 3.504 BIAS -3.277 RMS 1.589 m-s"^
Number of Points (Ref. 56) 118
DERIVATIVE: AAD-% 1.037 BIAS- -0.929 RMS-% 0.567
AAD 0.040 BIAS -0.039 RMS 0.018 MPa-dm^-mol'i
176
Data from Blagoi et al. [57]
T
P
P
W.exp
W,cal
Devi
sp/SpIt
aP/ap T Dev2
Wt
exp
cal
K
MPa
mol-dm
"^ m-s'
1 m-s-i
%
MPa-dm^-mol"^
%
90.9
0.012
28.13
1531.0
1546.2
1.0
23.80
24.37
2.4
0.132
93.6
0.017
27.90
1509.0
1514.2
0.3
23.12
23.31
0.8
0.134
97.7
0.027
27.56
1472.0
1469.8
-0.1
21.84
21.76
-0.4
0.138
99.9
0.034
11. yi
1444.0
1447.3
0.2
20.89
20.95
0.3
0.141
101.1
0.038
11.11
1430.0
1435.2
0.4
20.41
20.52
0.5
0.000
103.6
0.049
11.05
1406.0
1410.3
0.3
19.56
19.64
0.4
0.000
105.2
0.057
26.91
1388.0
1394.5
0.5
18.95
19.08
0.7
0.000
110.1
0.089
26.48
1347.0
1346.3
-0.1
17.49
17.42
-0.4
0,000
115.5
0.138
25.98
1285.0
1292.8
0.6
15.53
15.68
0.9
0.000
118.2
0.168
25.73
1262.0
1265.7
0.3
14.79
14.83
0.3
0.000
121.0
0.206
25.46
1236.0
1237.3
0.1
13.99
13.98
-0.1
0.000
124.7
0.264
25.10
1201.0
1199.2
-0.2
12.96
12.89
-0.6
0.000
127.3
0.312
24.84
1173.0
1172.0
-0.1
12.19
12.14
-0.4
0.000
131.6
0.404
24.41
1125.0
1126.3
0.1
10.95
10.94
0.0
0.000
133.7
0.456
24.18
1101.0
1103.5
0.2
10.36
10.38
0.2
0.000
137.7
0.568
23.75
1063.0
1059.5
-0.3
9.42
9.34
-0.9
0.000
143.3
0.758
23.12
994.0
996.1
0.2
7.93
7.95
0.2
0.000
147.4
0.923
22.63
954.0
948.3
-0.6
7.08
6.98
-1.4
0.000
152.9
1.184
21.94
885.0
881.8
-0.4
5.82
5.76
-0.9
0.000
156.2
1.363
21.50
848.0
840.5
-0.9
5.17
5.07
-1.9
0.000
160.1
1.599
20.95
795.0
790.2
-0.6
4.35
4.29
-1.3
0.000
164.4
1.892
20.29
741.0
732.5
-1.1
3.57
3.49
-2.4
0.000
168.8
2.230
19.56
672.0
670.6
-0.2
2.73
2.72
-0.5
0.000
171.7
2.475
19.03
637.0
627.9
-1.4
2.31
2.25
-2.9
0.000
176.5
2.924
18.05
560.0
553.7
-1.1
1.57
1.53
-2.2
0.000
177.8 3.055 17.75 536.0 532.7
•0.6
1.37
1.35 -1.2 0.000
Number of Points (Ref . 57) 26 on saturation boundary
SOUND SPEED:
AAD-%
0.461
BIAS-%
-0.134
RMS-%
0.572
AAD
4.506
BIAS
-0.030
RMS
5.524 m-s"^
DERIVATIVE:
AAD-%
0.928
BIAS-%
-0.411
RMS-%
1.147
AAD
0.086
BIAS
0.018
RMS
0.135 MPa-cJra^-mor^
177
Data from Gammon and Douslin [37]
T P p W.exp W.cal Devi
K
MPa mol • dm'
-3
m-s
m-s
aP/a^lx dP/dp\j Dev2
exp cal
MPa-dm^-mol"^ %
Wt
323.15
24.595
10.14
574.3
573.3
-0.2
2.98
2.97
-0.4
0.000
298.15
2.378
1.00
441.9
442.0
0.0
2.28
2.28
0.0
0.857
298.15
5.627
2.50
437.1
437.0
0.0
2.06
2.06
-0.1
0.586
298.15
10.491
5.00
444.6
444.6
0.0
1.88
1.88
0.0
0.489
298.15
15.205
7.49
474.5
474.1
-0.1
1.95
1.95
-0.2
0.000
298.15
19.418
9.53
518.3
517.5
-0.1
2.25
2.24
-0.3
0.000
298.15
20.702
10.08
533.9
532.9
-0.2
2.38
2.37
-0.4
0.000
273.15
16.178
9.63
478.4
477.4
-0.2
1.71
1.70
-0.4
0.000
248.15
12.816
9.75
430.9
429.5
-0.3
1.17
1.16
-0.6
0.000
223.15
9.320
9.88
371.6
370.1
-0.4
0.63
0.62
-0.6
0.000
198.15
5.704
10.05
282.6
282.5
0.0
0.12
0.12
-0.1
0.000
193.05
0.782
0.52
353.2
353.1
0.0
1.42
1.42
0.0
3.567
193.05
1.563
1.11
340.6
340.4
-0.1
1.23
1.23
-0.2
2.485
193.05
2.244
1.70
328.7
328.4
-0.1
1.05
1.05
-0.2
2.039
193.05
2.820
2.30
317.7
317.5
-0.1
0.89
0.88
-0.2
1.789
193.05
3.306
2.90
307.5
307.4
0.0
0.73
0.73
-0.1
1.625
193.05
3.703
3.50
298.3
298.4
0.1
0.60
0.60
0.1
1.511
193.05
4.025
4.10
289.9
290.3
0.1
0.47
0.48
0.2
1.428
193.05
4.281
4.71
282.4
282.9
0.2
0.37
0.37
0.4
1.365
193.05
4.478
5.32
275.6
276.3
0.2
0.28
0.28
0.2
1.319
193.05
4.626
5.93
269.5
270.2
0.3
0.20
0.21
0.4
1.283
193.05
4.729
6.51
264.2
265.0
0.3
0.15
0.15
0.4
0.000
193.05
4.806
7.13
258.9
260.0
0.4
0.10
0.10
1.0
0.000
193.05
4.859
7.75
254.1
255.6
0.6
0.07
0.07
0.8
0.000
193.05
4.897
8.39
249.9
252.0
0.9
0.05
0.05
1.0
0.000
193.05
4.924
9.03
246.7
249.7
1.2
0.04
0.04
2.9
0.000
193.05
4.946
9.64
245.7
249.3
1.5
0.03
0.03
2.9
0.000
193.05
4.962
10.12
246.8
250.6
1.5
0.03
0.03
4.4
0.000
193.05
4.966
10.24
247.5
251.3
1.5
0.03
0.04
3.1
0.000
193.05
4.988
10.83
253.1
256.4
1.3
0.04
0.04
3.0
0.000
193.05
5.016
11.43
263.1
265.7
1.0
0.05
0.05
3.2
0.000
191.45
4.587
6.52
258.4
259.2
0.3
0.12
0.12
0.6
0.000
191.45
4.646
7.15
251.8
253.3
0.6
0.07
0.07
0.8
0.000
191.45
4.683
7.79
244.5
247.8
1.4
0.04
0.04
2.6
0.000
191.45
4.705
8.45
236.8
243.0
2.6
0.02
0.02
3.6
0.000
178
Data from Gammon and Douslin [37] (continued)
T
P
P
W.exp
W.cal
Devi
d?/dp T
exp
dY/dp T
cal
Dev2
Wt
K
MPa
mol • dm" '
m-s"^
m-s"^
%
MPa-dm^
•mol-i
%
191.45
4.717
9.12
229.5
239.4
4.3
0.01
0.01
11.5
0.000
191.45
4.725
9.74
224.5
237.9
6.0
0.01
0.01
16.6
0.000
191.45
4.730
10.17
223.7
238.4
6.5
0.01
0.01
17.2
0.000
191.45
4.731
10.28
224.1
238.7
6.5
0.01
0.01
19.6
0.000
191.45
4.738
10.82
229.2
242.3
5.7
0.01
0.01
13.1
0.000
191.45
4.748
11.40
240.2
250.2
4.2
0.02
0.02
6.8
0.000
190.85
4.533
6.53
256.1
257.0
0.3
0.11
0.11
0.7
0.000
190.85
4.586
7.15
248.6
250.7
0.8
0.06
0.06
1.3
0.000
190.85
4.616
7.80
239.8
244.8
2.1
0.03
0.03
3.0
0.000
190.85
4.632
8.48
228.9
239.4
4.6
0.01
0.01
11.3
0.000
190.85
4.638
9.21
215.8
235.0
8.9
0.00
0.01
18.5
0.000
190.85
4.641
9.89
205.1
233.2
13.7
0.00
0.00
26.9
0.000
190.85
4.643
10.29
204.4
233.7
14.3
0.00
0.00
30.4
0.000
190.85
4.643
10.37
205.1
233.9
14.1
0.00
0.00
34.4
0.000
190.85
4.646
10.86
212.9
237.0
11.3
0.00
0.01
14.2
0.000
190.85
4.650
11.42
225.9
244.5
8.3
0.01
0.01
14.4
0.000
190.63
4.513
6.53
255.2
256.1
0.3
0.10
0.10
0.5
0.000
190.63
4.564
7.15
247.4
249.7
1.0
0.06
0.06
1.5
0.000
190.63
4.592
7.80
237.7
243.6
2.5
0.03
0.03
4.4
0.000
190.63
4.605
8.49
224.5
238.0
6.0
0.01
0.01
10.8
0.000
190.63
4.609
9.28
204.1
233.2
14.2
0.00
0.00
36.6
0.000
190.63
4.610
9.86
191.3
231.5
21.0
0.00
0.00
10.8
0.000
190.63
4.611
10.53
195.2
232.6
19.2
0.00
0.00
36.8
0.000
190.63
4.611
10.51
195.5
232.6
18.9
0.00
0.00
33.9
0.000
190.63
4.612
11.08
205.9
237.2
15.2
0.00
0.00
22.4
0.000
190.63
4.615
11.48
219.1
243.3
11.1
0.01
0.01
17.6
0.000
190.56
4.507
6.53
255.0
255.8
0.3
0.10
0.10
0.4
0.000
190.56
4.556
7.16
246.9
249.4
1.0
0.06
0.06
2.8
0.000
190.56
4.584
7.80
237.0
243.3
2.7
0.03
0.03
4.0
0.000
190.56
4.596
8.48
222.8
237.6
6.7
0.01
0.01
14.0
0.000
190.56
4.600
9.21
199.1
233.0
17.0
0.00
0.00
11.5
0.000
190.56
4.601
10.23
184.2
231.0
25.4
0.00
0.00
127.9
0.000
190.56
4.601
10.95
198.0
235.1
18.8
0.00
0.00
79.3
0.000
190.56
4.601
10.83
196.6
234.0
19.0
0.00
0.00
22.3
0.000
190.56
4.602
11.24
205.4
238.6
16.2
0.00
0.00
30.4
0.000
179
Data from Gammon and Douslin [37] (continued)
T
P
P
W.exp
W.cal
Devi
ap/ap|i
exp
ap/apli
cal
Dev2
Wt
K
MPa
mol • dm" ^
m-s"^
m-s'^
%
MPa-dm^
•mol-^
%
190.56
4.603
11.55
217.0
243.9
12.4
0.01
0.01
32.8
0.000
190.50
0.771
0.52
350.5
350.4
0.0
1.40
1.40
-0.1
3.549
190.50
1.538
1.11
337.6
337.3
-0.1
1.21
1.20
-0.1
2.466
190.50
2.203
1.71
325.3
325.0
-0.1
1.02
1.02
-0.2
2.023
190.50
2.760
2.30
313.9
313.7
-0.1
0.85
0.85
-0.2
1.775
190.50
3.226
2.91
303.2
303.2
0.0
0.70
0.70
-0.1
0.000
190.50
3.603
3.51
293.5
293.7
0.0
0.56
0.56
0.0
0.000
190.50
3.902
4.11
284.7
284.9
0.1
0.44
0.44
0.2
0.000
190.50
4.133
4.72
276.5
276.8
0.1
0.33
0.33
0.2
0.000
190.50
4.304
5.32
269.0
269.3
0.1
0.24
0.24
0.0
0.000
190.50
4.425
5.94
261.7
262.1
0.1
0.16
0.16
0.4
0.000
190.50
4.501
6.53
254.7
255.6
0.4
0.10
0.10
0.4
0.000
190.50
4.550
7.15
246.6
249.1
1.0
0.06
0.06
2.9
0.000
190.50
4.577
7.80
236.3
243.0
2.8
0.03
0.03
4.4
0.000
190.50
4.589
8.48
221.0
237.3
7.4
0.01
0.01
17.4
0.000
190.50
4.592
9.04
200.0
233.5
16.8
0.00
0.00
28.7
0.000
190.43
4.495
6.53
254.4
255.3
0.4
0.10
0.10
1.0
0.000
190.43
4.543
7.16
246.1
248.8
1.1
0.05
0.06
2.4
0.000
190.43
4.569
7.80
235.5
242.6
3.0
0.02
0.03
8.4
0.000
190.43
4.580
8.48
218.3
236.9
8.5
0.01
0.01
20.7
0.000
190.25
4.287
5.33
268.3
268.5
0.1
0.23
0.23
0.2
0.000
190.25
4.405
5.94
260.9
261.2
0.1
0.16
0.16
0.0
0.000
190.25
4.479
6.53
253.7
254.6
0.4
0.10
0.10
0.7
0.000
190.25
4.525
7.16
245.0
248.0
1.2
0.05
0.05
2.1
0.000
190.25
4.549
7.80
233.2
241.7
3.6
0.02
0.02
5.3
0.000
189.65
3.861
4.11
282.9
283.1
0.1
0.42
0.42
0.0
0.000
189.65
4.083
4.72
274.5
274.7
0.1
0.31
0.31
0.1
0.000
189.65
4.245
5.33
266.7
266.8
0.0
0.22
0.22
-0.2
0.000
189.65
4.357
5.94
258.9
259.2
0.1
0.14
0.14
-0.1
0.000
189.65
4.424
6.53
251.0
252.3
0.5
0.09
0.09
0.7
0.000
189.65
4.463
7.16
240.5
245.3
2.0
0.04
0.04
4.0
0.000
188.15
0.761
0.52
348.0
347.9
0.0
1.38
1.38
-0.1
0.012
188.15
1.515
1.11
334.8
334.5
-0.1
1.18
1.18
-0.2
0.008
188.15
2.164
1.71
322.1
321.8
-0.1
0.99
0.99
-0.2
0.007
188.15
2.705
2.30
310.3
310.1
-0.1
0.82
0.82
-0.1
0.006
180
Data from Ganmion and Douslin [37] (continued)
T P p W.exp W.cal Devi
K
MPa mol'dm"'' m-s"^
m-s
-1
d?/dp\j d?/dp\^ Dev2
exp cal
MPa-dm^-mor^ %
Wt
188.15
3.153
2.91
299.2
299.2
0.0
0.67
0.66
0.0
0.000
188.15
3.509
3.51
289.1
289.1
0.0
0.52
0.52
0.0
0.000
188.15
3.787
4.11
279.6
279.7
0.0
0.40
0.40
0.0
0.000
188.15
3.995
4.72
270.9
270.8
0.0
0.29
0.29
0.0
0.000
188.15
4.140
5.33
262.4
262.2
-0.1
0.19
0.19
0.0
0.000
188.15
4.235
5.95
253.4
253.8
0.1
0.11
0.12
0.3
0.000
183.15
0.738
0.52
342.6
342.5
0.0
1.33
1.33
-0.1
0.012
183.15
1.465
1.11
328.6
328.3
-0.1
1.13
1.13
-0.2
0.008
183.15
2.083
1.71
315.1
314.8
-0.1
0.94
0.93
-0.2
0.007
183.15
2.587
2.31
302.4
302.2
-0.1
0.76
0.76
-0.1
0.006
183.15
2.995
2.91
290.4
290.3
-0.1
0.59
0.59
-0.2
0.005
183.15
3.307
3.51
279.1
278.9
-0.1
0.45
0.45
-0.2
0.000
183.15
3.537
4.12
268.4
267.6
-0.3
0.31
0.31
-0.6
0.000
173.15
0.694
0.52
331.5
331.3
-0.1
1.24
1.24
-0.1
0.011
173.15
1.363
1.11
315.8
315.5
-0.1
1.02
1.02
-0.2
0.008
173.15
1.915
1.71
300.4
300.1
-0.1
0.82
0.81
-0.3
0.006
173.15
2.344
2.31
285.7
285.2
-0.2
0.62
0.62
-0.4
0.006
163.15
0.649
0.52
319.9
319.7
-0.1
1.14
1.14
-0.2
0.011
163.15
1.259
1.12
302.2
302.0
-0.1
0.91
0.91
-0.2
0.008
163.15
1.740
1.72
284.6
283.9
-0.2
0.69
0.68
-0.4
0.006
153.15
0.604
0.52
307.7
307.5
-0.1
1.05
1.05
-0.1
0.011
143.15
0.557
0.52
294.9
294.7
-0.1
0.95
0.95
-0.2
0.010
190.50
4.592
11.19
200.3
237.3
18.4
0.00
0.00
19.1
0.000
190.50
4.592
11.33
203.1
239.4
17.9
0.00
0.00
27.3
0.000
190.50
4.592
11.28
203.4
238.6
17.3
0.00
0.00
63.1
0.000
190.50
4.592
11.33
203.6
239.4
17.5
0.00
0.00
25.3
0.000
190.50
4.594
11.61
215.4
244.4
13.4
0.01
0.01
30.0
0.000
190.43
4.582
11.59
209.1
243.3
16.4
0.00
0.01
51.9
0.000
190.43
4.584
11.77
217.7
247.2
13.5
0.01
0.01
38.9
0.000
190.25
4.556
12.09
224.4
253.7
13.0
0.01
0.02
25.5
0.000
190.25
4.557
12.15
227.1
255.3
12.4
0.01
0.02
31.0
0.000
189.65
4.471
13.01
259.0
281.4
8.6
0.05
0.05
18.4
0.000
189.65
4.472
13.03
259.7
282.0
8.6
0.05
0.06
18.5
0.000
188.15
4.267
14.21
314.1
331.0
5.4
0.16
0.18
11.0
0.000
188.15
4.267
14.22
314.2
331.1
5.4
0.16
0.18
10.6
0.000
181
Data from Gammon and Douslin [37] (continued)
T P p W,exp W,cal Devi
K
MPa mol-dm'-' m-s"^ m-s"^
aP/ap|x d?/dp\j Dev2
esq) cal
MPa-dm^ -mol'i %
Wt
185.91
3.977
15.32
374.2
385.6
3.0
0.37
0.40
6.0
0.000
183.15
3.642
16.31
434.9
440.5
1.3
0.68
0.69
2.5
0.000
183.15
3.642
16.31
435.0
440.5
1.3
0.68
0.69
2.6
0.000
178.15
3.092
17.67
528.4
527.1
-0.2
1.31
1.31
-0.5
9.928
173.15
2.606
18.75
610.0
606.1
-0.6
2.05
2.02
-1.3
5.181
170.75
2.394
19.21
646.5
642.1
-0.7
2.43
2.40
-1.4
4.019
163.15
1.804
20.49
754.1
749.6
-0.6
3.77
3.72
-1.3
2.608
155.44
1.321
21.60
854.4
850.2
-0.5
5.29
5.23
-1.1
2.024
153.15
1.197
21.91
882.8
878.7
-0.5
5.77
5.71
-1.1
1.908
143.15
0.753
23.14
1001.9
997.9
-0.4
8.06
7.98
-1.0
1.544
140.02
0.643
23.50
1037.6
1033.5
-0.4
8.84
8.75
-1.0
1.461
133.15
0.443
24.24
1113.9
1109.5
-0.4
10.64
10.53
-1.0
1.311
125.09
0.271
25.06
1200.3
1195.1
-0.4
12.92
12.77
-1.1
1.174
123.15
0.239
25.26
1220.6
1215.2
-0.4
13.49
13.34
-1.1
1.146
113.15
0.115
26.20
1322.7
1316.2
-0.5
16.64
16.43
-1.3
1.022
190.43
4.582
8.78
206.8
234.7
13.5
0.00
0.00
38.7
0.000
190.37
4.572
8.44
215.8
236.8
9.8
0.01
0.01
17.3
0.000
190.35
4.569
8.40
215.6
237.0
9.9
0.01
0.01
24.2
0.000
190.25
4.556
8.22
220.8
237.9
7.7
0.01
0.01
21.7
0.000
190.03
4.523
7.79
229.7
240.7
4.8
0.02
0.02
12.0
0.000
189.97
4.516
7.74
230.0
240.9
4.7
0.02
0.02
9.8
0.000
189.65
4.471
7.36
235.9
243.1
3.1
0.03
0.03
6.1
0.000
189.65
4.471
7.36
235.9
243.2
3.1
0.03
0.03
6.6
0.000
189.50
4.448
7.15
239.3
244.7
2.3
0.04
0.04
3.5
0.000
189.40
4.436
7.12
239.1
244.6
2.3
0.04
0.04
4.3
0.000
188.70
4.336
6.54
246.2
248.4
0.9
0.07
0.07
1.6
0.000
188.60
4.326
6.52
245.9
248.3
0.9
0.07
0.07
1.4
0.000
188.15
4.266
6.26
248.2
249.7
0.6
0.08
0.08
1.4
0.000
187.60
4.189
5.95
251.3
251.9
0.2
0.10
0.11
0.3
0.000
187.45
4.173
5.92
251.2
251.8
0.2
0.11
0.11
0.1
0.000
186.10
3.993
5.33
256.1
255.7
-0.2
0.16
0.16
-0.6
0.000
185.90
3.974
5.30
256.0
255.5
-0.2
0.16
0.16
-0.4
0.000
184.15
3.751
4.73
260.5
259.5
-0.4
0.22
0.21
-0.7
0.000
183.90
3.729
4.70
260.4
259.3
-0.4
0.22
0.22
-0.9
0.000
183.15
3.641
4.50
261.7
260.6
-0.4
0.24
0.24
-0.7
0.000
182
Data from Gairanon and Douslin [37] (continued)
T P p W.exp W,cal Devi
MPa mol • dm" ^
m-s
-1
m-s
aP/ap|i dF/dplj. Dev2
e^ cal
MPa-dm^ -mol"^ %
Wt
181.55
3.451
4.12
264.7
263.5
-0.5
0.29
0.28
-1.1
0.000
181.30
3.429
4.08
264.8
263.4
-0.5
0.29
0.29
-1.1
0.000
178.25
3.098
3.51
269.0
267.7
-0.5
0.37
0.37
-0.9
0.005
178.05
3.080
3.48
269.1
267.8
-0.5
0.37
0.37
-0.9
0.005
174.25
2.699
2.91
273.7
272.5
-0.4
0.46
0.46
-1.0
0.005
173.95
2.678
2.89
273.6
272.4
-0.5
0.46
0.46
-0.9
0.005
173.15
2.605
2.79
274.4
273.2
-0.5
0.48
0.48
-1.0
0.005
169.15
2.241
2.31
278.6
277.6
-0.4
0.57
0.56
-0.7
0.005
168.55
2.209
2.28
278.3
277.3
-0.4
0.57
0.56
-0.8
0.005
163.15
1.803
1.81
281.9
281.0
-0.3
0.65
0.65
-0.7
0.006
162.65
1.730
1.72
283.8
283.1
-0.3
0.68
0.68
-0.5
0.006
161.45
1.687
1.68
282.8
282.0
-0.3
0.68
0.67
-0.6
0.006
155.05
1.173
1.12
290.5
290.2
-0.1
0.82
0.82
-0.2
0.007
153.15
1.196
1.17
285.8
285.2
-0.2
0.77
0.77
-0.4
0.007
150.65
1.071
1.05
286.3
285.8
-0.2
0.80
0.79
-0.4
0.007
148.15
0.956
0.94
286.6
286.1
-0.2
0.82
0.81
-0.3
0.008
143.15
0.752
0.74
286.6
286.2
-0.1
0.85
0.85
-0.3
0.009
138.15
0.533
0.52
288.2
288.0
-0.1
0.90
0.90
-0.2
0.010
133.15
0.442
0.44
284.6
284.2
-0.1
0.89
0.88
-0.3
0.011
123.15
0.238
0.25
279.9
279.4
-0.2
0.89
0.89
-0.3
0.014
113.15 0.114
0.13 272.8 271.8
-0.4
0.87
0.87
■0.8 0.019
Number of Points (Ref.37) 196
SOUND SPEED:
AAD-%
3.379
BIAS-%
3.196
RMS-%
5.712
AAD
7.556
BIAS
6.649
RMS
11.888
m-s"^
DERIVATIVE:
AAD-%
7.363
BIAS-%
6.963
RMS-%
15.048
AAD
0.007
BIAS
-0.005
RMS
0.025
MPa-dm^ -mol"^
Number of Points (Ref . 37) 138 outside critical region
SOUND SPEED: AAD-% 0.844 BIAS-% 0.584 RMS-%
AAD 2.489 BIAS 1.200 RMS
1.752
4.765 m-s"i
183
Data from Sivaramin and Gammon [44]
T P p W.exp W.cal Devi d?/dp\j d?/dp\j Dev2 Wt
exp cal
K MPa mol-dm"^ m-s"^ m-s"^ % MPa-dm^ -mol"^ %
193.05 1.4555 -
193.05 3.4464 -
193.05 4.4289
193.05 4.8182
193.05 4.9370 -
193.05 5.0192 -
193.05 5.1745 -
193.05 5.6433 -
195.15 1.4748 -
195.15 3.5174 -
195.15 4.5645
195.15 5.0281
195.15 5.2175
195.15 5.3794 -
195.15 5.6169
195.15 6.1971 -
200.15 1.5200 -
200.15 3.6831 -
200.15 4.8817
200.15 5.3444 -
200.15 5.8840 -
200.15 6.2521 -
200.15 6.6840 -
200.15 7.5229
210.15 1.6096
210.15 3.9818 -
210.15 5.4978 -
210.15 6.4755
210.15 7.2020 -
210.15 7.9731 -
210.15 8.8393 -
210.15 10.1705
223.15 1.7246
223.15 4.3776
223.15 6.2730 -
342.31
342.20
-0.032
304.34
304.34
0.000
277.41
278.04
0.228
257.92
259.05
0.439
245.84
249.23
1.378
264.32
266.94
0.992
313.12
315.90
0.889
392.17
393.83
0.424
344.79
344.64
-0.042
307.89
307.88
-0.001
282.46
283.24
0.276
266.32
267.32
0.377
261.11
261.87
0.294
283.72
284.34
0.218
330.36
331.88
0.460
406.00
406.25
0.062
350.48
350.36
-0.034
316.08
316.10
0.004
293.83
294.72
0.303
285.38
286.65
0.443
286.39
286.68
0.101
315.80
316.11
0.097
361.70
361.84
0.041
433.29
431.98
-0.301
361.65
361.42
-0.064
331.92
331.97
0.016
314.59
315.28
0.221
310.70
311.65
0.306
322.91
322.90
-0.001
357.87
357.09
-0.218
407 . 26
405.64
-0.398
476.05
473.81
-0.470
375.27
375.11
-0.043
350.79
350.77
-0.004
338.77
339.21
0.131
184
Data from Sivaramin and Gammon [44] (continued)
T ? p W,exp W.cal Devi d?/dp\j d?/dp\j Dev2 Wt
exp cal
K MPa mol-dm'^ m-s'^ m-s"^ % MPa-dm^ -mol"^ %
341.08 341.36 0.082 - . . .
360.17 358.52 -0.458 - . . .
400.90 398.98 -0.478 - . . .
453.11 456.85 0.825 - . . .
399.71 399.49 -0.055 - . . .
383.14 383.12 -0.005 - . . .
379.16 379.36 0.055 - . . .
389.83 389.51 -0.081 - - - -
417.23 415.15 -0.497 - . . .
464.55 463.08 -0.317 - . . .
421.74 421.67 -0.017 - . . .
411.50 411.42 -0.019 - . . .
413.83 413.86 0.007 - . . _
430.46 429.89 -0.133 - . . .
463.69 462.90 -0.171 - . . .
516.55 515.58 -0.189 - . . .
441.86 441.95 0.022 - . . .
438.02 437.88 -0.032 - . . .
437.04 436.87 -0.039 - . - .
439.19 439.07 -0.027 - . . .
444.59 444.61 0.004 - . . .
453.65 453.61 -0.007 - . . .
466.56 466.31 -0.053 - . . .
483.45 483.05 -0.083 - . . .
504.86 504.20 -0.131 - . . .
531.11 530.26 -0.160 - . . .
562.60 561.69 -0.162 - . . .
460.66 460.70 0.010 - . . .
459.14 458.86 -0.061 - . . .
460.30 460.03 -0.058 - . . .
323.15 9.6586 - 464.64 464.41 -0.049 - . . .
323.15 11.8912 - 472.31 472.12 -0.039 - . . .
323.15 14.1263 - 483.53 483.31 -0.045 - . . .
223
.15
7.6782
223
.15
8.8588
223
.15
10.2272
223
.15
11.8153
248
.15
1.9419
248
.15
5.1074
248
.15
7.6438
248
.15
9.8765
248
15
11.9829
248
15
14.4705
273
15
2.1550
273
15
5.8826
273
15
9.0367
273
15
11.9865
273
15
15.1102
273
15
18.6778
298
15
2.3772
298
15
4.5805
298
15
6.6411
298
15
8.5992
298
15
10.4926
298
15
12.3602
298
15
14.2422
298
15
16.1884
298
15
18.2474
298
15
20.4839
298
15
22.9728
323
15
2.5998
323
15
5.0523
323
15
7.3921
185
Data from Sivaramin and Gammon [44] (continued)
T P p W,exp W.cal Devi dP/dp\^ d?/dp\j Dev2 Wt
exp cal
K MPa mol-dm"^ m-s"^ m-s"^ % MPa-dm^ -mor^ %
323.15
16.4214 -
498.55
498.27
-0.055
323.15
18.8148 -
517.76
517.22
-0.105
323.15
21.3771 -
541.31
540.62
-0.126
323.15
24.1556 -
569.45
568.68
-0.135
348.15
2.8212 -
478.08
478.19
0.023
348.15
5.5215 -
478.58
478.28
-0.063
348 . 15
11.9927 -
492.36
491.99
-0.074
348 . 15
13.2802 -
497.55
497.23
-0.065
348.15
15.8908 -
510.84
510.36
-0.093
348.15
18.5881 -
527.81
527.21
-0.114
348.15
21.4232 -
548.62
548.02
-0.109
348 . 15
24.4792 -
573.98
573.27
-0.124
373.15
3.0434 -
494.48
494.64
0.033
373.15
5.9932 -
496.63
496.45
-0.035
373.15
8.8836 -
501.54
501.22
-0.063
373.15
11.7603 -
509.58
509.17
-0.081
373.15
14.6627 -
520.99
520.46
-0.102
373.15
17.6313 -
535.78
535.22
-0.104
373.15
20.7423 -
554.36
553.81
-0.098
373.15
24.0067 -
576.81
576.19
-0.108
373.15
27.5422 -
603.75
602.97
-0.129
398.15
3.2337 -
510.22
510.24
0.003
398.15
6.4583 -
513.95
513.61
-0.065
398.15
9.6228 -
520.31
519.91
-0.077
398.15
12.8003 -
529.93
529.37
-0.106
398.15
16.0370 -
542.82
542.18
-0.119
398.15
19.3679 -
559.18
558.45
-0.130
398.15
22.8752 -
579.33
578.53
-0.139
398.15
26.6023 -
603.37
602.55
-0.136
423.15
3.4839 -
525.07
525.18
0.022
423.15
6.9249 -
530.37
529.96
-0.077
423.15
10.3612 -
538.16
537.66
-0.092
423.15
13.8385 -
549.13
548.51
-0.112
423.15
17.4008 -
563.41
562.69
-0.127
423.15
21.1001 -
581.48
580.38
-0.188
423.15 24.9969 - 602.88 601.80 -0.179
186
Data from Sivaramin and Gammon [44] (continued)
Number of Points (Ref .44) 104
SOUND SPEED: AAD-% 0.164 BIAS-% 0.005 RMS-% 0.272
AAD 0.643 BIAS -0.124 RMS 0.939 m-s'^
Data from Strat})
' [58]
T
P
P
W.exp
W.cal
Devi
bY/bp T
exp
5P/ap T
cal
Dev2
Wt
K
MPa
mol • dm'
3 m-s-i
m-s'^
%
MPa-dm^
•mol-i
%
91.00
0.012
28.12
1538.1
1544.9
0.4
24.03
24.33
1.3
8.604
92.00
0.014
28.04
1528.7
1532.8
0.3
23.74
23.93
0.8
8.658
96.00
0.022
27.70
1490.6
1487.7
-0.2
22.48
22.39
-0.4
8.913
100.00
0.034
27.36
1452.2
1446.2
-0.4
21.13
20.92
-1.0
9.213
101.73
0.041
27.21
1435.5
1428.9
-0.5
20.53
20.30
-1.1
-0.000
104.00
0.051
11. Ql
1413.4
1406.3
-0.5
19.74
19.50
-1.2
9.553
108.00
0.074
26.66
1373.8
1367.0
-0.5
18.36
18.12
-1.3
9.933
112.00
0.104
26.30
1334.1
1327.6
-0.5
17.01
16.80
-1.3
10.349
116.00
0.143
25.94
1294.0
1287.8
-0.5
15.71
15.52
-1.2
10.807
120.00
0.192
25.56
1252.9
1247.5
-0.4
14.45
14.28
-1.1
2.263
124.00
0.252
25.17
1211.3
1206.4
-0.4
13.23
13.09
-1.1
2.377
128.00
0.325
Ik. 11
1169.1
1164.6
-0.4
12.06
11.94
-1.0
2.503
132.00
0.414
24.36
1126.0
1121.9
-0.4
10.94
10.84
-1.0
2.646
136.00
0.518
23.94
1082.2
1078.4
-0.4
9.86
9.77
-0.9
2.809
140.00
0.642
23.50
1037.4
1033.8
-0.4
8.84
8.76
-0.9
2.997
144.00
0.785
23.04
991.7
988.0
-0.4
7.85
7.78
-0.9
3.218
120.00
0.192
25.56
1252.8
1247.5
-0.4
14.44
14.28
-1.1
-0.000
140.00
0.642
23.50
1037.4
1033.8
-0.4
8.84
8.76
-0.9
-0.001
148.00
0.949
22.56
944.8
941.1
-0.4
6.91
6.85
-1.0
3.482
150.00
1.040
22.31
921.0
917.2
-0.4
6.46
6.40
-1.0
3.635
152.00
1.138
22.06
896.6
892.9
-0.4
6.02
5.96
-1.0
3.807
156.00
1.352
21.53
846.9
843.1
-0.5
5.17
5.11
-1.1
4.219
160.00
1.593
20.96
795.5
791.5
-0.5
4.36
4.31
-1.1
4.767
160.00
1.593
20.96
795.5
791.5
-0.5
4.36
4.31
-1.1
-0.001
164.00
1.863
20.36
742.2
738.0
-0.6
3.61
3.56
-1.3
5.545
187
Data from Straty [58] (continued)
T
P
P
W.exp
W,cal
Devi
ap/ap X
exp
ap/apli
cal
Dev2
Wt
K
MPa
mol • dm"
3 m-s-i
m-s"^
%
MPa-dni^
•mol-i
%
168.00
2.166
19.70
686.3
682.1
-0.6
2.89
2.85
-1.3
6.789
170.00
2.329
19.35
657.5
653.1
-0.7
2.56
2.52
-1.4
7.766
172.00
2.502
18.97
627.5
623.4
-0.6
2.23
2.20
-1.3
9.281
176.00
2.874
18.16
564.1
561.7
-0.4
1.62
1.60
-0.8
84.709
178.00
3.075
17.70
530.5
529.5
-0.2
1.33
1.33
-0.4
86.608
180.00
3.286
17.20
495.0
496.1
0.2
1.06
1.07
0.4
0.000
182.00
3.508
16.65
457.7
461.3
0.8
0.81
0.83
1.6
0.000
184.00
3.742
16.03
417.2
424.3
1.7
-
-
-
-
186.00
3.988
15.28
370.9
383.5
3.4
-
-
-
-
100.00*
33.385
28.67
1672.6
1670.2
-0.1
30.30
30.28
-0.1
3.277
100.00
26.077
28.42
1630.7
1629.1
-0.1
28.40
28.39
0.0
3.388
100.00
19.123
28.17
1588.1
1586.8
-0.1
26.54
26.53
0.0
3.508
100.00
13.088
27.93
1548.5
1546.8
-0.1
24.88
24.84
-0.1
3.627
100.00
7.244
27.69
1507.4
1504.6
-0.2
23.23
23.14
-0.4
3.759
100.00
1.661
27.44
1465.1
1460.1
-0.3
21.61
21.43
-0.8
3.903
120.00
31.161
27.21
1517.2
1508.6
-0.6
23.78
23.53
-1.1
0.745
120.00
26.233
27.00
1482.8
1475.6
-0.5
22.41
22.20
-0.9
0.769
120.00
19.980
26.70
1436.0
1430.4
-0.4
20.62
20.46
-0.8
0.803
120.00
15.149
26.46
1397.0
1392.3
-0.3
19.20
19.06
-0.7
0.834
120.00
9.258
26.13
1345.2
1341.1
-0.3
17.40
17.27
-0.7
0.878
120.00
4.367
25.84
1290.5
1293.3
0.2
15.66
15.70
0.3
0.929
150.00
34.530
25.26
1339.6
1326.9
-0.9
17.56
17.24
-1.8
0.881
150.00
28.845
24.91
1290.0
1279.6
-0.8
15.92
15.67
-1.6
0.929
150.00
23.669
24.57
1240.3
1232.1
-0.7
14.37
14.19
-1.3
0.982
150.00
18.433
24.18
1184.6
1178.6
-0.5
12.73
12.61
-1.0
1.050
150.00
12.667
23.68
1114.5
1110.7
-0.3
10.83
10.76
-0.7
1.149
150.00
7.263
23.13
1036.6
1034.0
-0.3
8.92
8.87
-0.6
1.284
150.00
3.020
22.60
962.1
959.1
-0.3
7.28
7.23
-0.7
3.378
170.00
31.457
23.58
1183.8
1172.5
-1.0
12.99
12.75
-1.9
1.045
170.00
26.994
23.21
1135.5
1126.4
-0.8
11.66
11.48
-1.6
1.111
170.00
20.773
22.62
1059.2
1053.0
-0.6
9.72
9.61
-1.1
1.235
170.00
17.538
22.27
1013.9
1009.2
-0.5
8.65
8.58
-0.9
1.322
170.00
13.012
21.68
940.7
937.9
-0.3
7.08
7.04
-0.6
1.494
170.00
7.774
20.81
833.5
831.5
-0.2
5.09
5.06
-0.5
1.857
170.00
4.528
20.06
742.9
740.1
-0.4
3.67
3.64
-0.8
2.367
188
Data from Straty [58] (continued)
T P p W,exp W,cal Devi
K
MPa mol • dm" ^
m-s
-1
ni'S
-1
dP/dp\^ SP/SpIt Dev2 Wt
exp cal
MPa-dm^ -mol'i %
184.00
34.254
22.75
1129.0
1117.6
-1.0
11.68
11.45
-2.0
4.466
184.00
27.883
22.15
1055.1
1046.9
-0.8
9.81
9.66
-1.5
4.946
184.00
22.511
21.54
982.8
977.2
-0.6
8.14
8.06
-1.1
5.533
184.00
17.862
20.90
909.0
905.6
-0.4
6.62
6.58
-0.7
6.306
184.00
13.839
20.21
831.9
830.0
-0.2
5.22
5.19
-0.4
7.413
184.00
10.436
19.46
751.2
749.2
-0.3
3.93
3.91
-0.5
9.183
184.00
7.722
18.65
666.6
664.2
-0.4
2.79
2.77
-0.7
12.672
184.00
5.770
17.79
579.9
579.7
0.0
1.84
1.84
0.0
0.000
184.00
5.301
17.52
552.8
553.9
0.2
1.58
1.59
0.4
0.000
210.00
34.073
20.74
987.0
979.0
-0.8
8.56
8.43
-1.6
0.182
210.00
27.598
19.88
898.0
893.4
-0.5
6.72
6.65
-1.0
0.213
210.00
22.264
18.96
809.8
807.7
-0.3
5.13
5.10
-0.5
0.258
210.00
17.486
17.86
711.5
710.9
-0.1
3.63
3.62
-0.1
0.346
210.00
14.832
17.02
643.9
643.2
-0.1
2.76
2.75
-0.2
0.472
210.00
12.703
16.12
577.5
576.9
-0.1
2.02
2.02
-0.2
0.901
210.00
10.944
15.08
511.5
509.6
-0.4
1.41
1.40
-0.7
0.817
210.00
12.705
16.12
578.0
576.9
-0.2
2.03
2.02
-0.3
-0.001
210.00
10.951
15.09
511.5
509.9
-0.3
1.41
1.40
-0.6
-0.001
210.00
10.173
14.47
477.0
475.2
-0.4
1.14
1.13
-0.7
0.607
210.00
9.646
13.96
451.2
449.6
-0.4
0.95
0.95
-0.7
0.533
240.00
34.638
18.49
863.5
858.7
-0.6
6.40
6.33
-1.1
0.226
240.00
29.111
17.51
782.7
780.0
-0.3
5.00
4.96
-0.7
0.274
240.00
24.656
16.49
707.0
705.7
-0.2
3.86
3.84
-0.4
0.348
240.00
20.885
15.36
632.6
632.2
-0.1
2.89
2.89
-0.1
0.500
240.00
24.662
16.49
706.8
705.8
-0.1
3.85
3.84
-0.3
-0.000
240.00
20.886
15.36
632.8
632.2
-0.1
2.90
2.89
-0.2
-0.000
240.00
18.890
14.61
588.8
588.4
-0.1
2.40
2.40
-0.2
0.746
240.00
16.841
13.65
540.2
539.4
-0.2
1.91
1.91
-0.3
1.662
240.00
15.186
12.68
498.4
497.3
-0.2
1.55
1.54
-0.4
0.711
240.00
14.071
11.90
469.8
468.4
-0.3
1.33
1.32
-0.6
0.582
270.00
34.769
16.30
771.5
769.1
-0.3
5.12
5.09
-0.6
0.001
270.00
30.486
15.37
711.2
709.9
-0.2
4.20
4.19
-0.4
0.001
270.00
25.972
14.15
641.6
641.0
-0.1
3.27
3.27
-0.2
0.002
270.00
21.837
12.70
572.8
572.3
-0.1
2.49
2.49
-0.2
0.004
300.00
34.838
14.33
713.9
712.2
-0.2
4.52
4.50
-0.5
0.001
189
Data from Straty [58] (continued)
T P p W.exp W.cal Devi d?/dp\j d?/dp\j Dev2 Wt
exp cal
K MPa mol-dm'^ m-s"^ m-s'^ % MPa-dm^ -mol'^ %
300.00
29.732
13.07
649.5
648.3
-0.2
3.64
3.63
-0.4
0.002
300.00
27.295
12.36
618.0
616.8
-0.2
3.26
3.24
-0.4
0.002
300.00
24.427
11.41
580.4
579.5
-0.2
2.84
2.83
-0.4
0.003
300.00
20.983
10.09
537.3
536.0
-0.2
2.42
2.41
-0.5
0.007
Number of Points (Ref . 58) 99 Data above the starred temperature for this
reference were at saturation boundary.
SOUND SPEED: AAD-% 0.414 BIAS-% -0.268 RMS-% 0.502
AAD 3.835 BIAS -3.043 RMS 3.667 m-s'^
Number of Points (Ref. 58) 91 Selected data (omitting those with negative
weights) , These 91 points contribute to
total below.
SOUND SPEED: AAD-% 0.424 BIAS-% -0.264 RMS-% 0.522
AAD 3.910 BIAS -3.048 RMS 3.773 m-s'^
Number of Points (Ref. 58) 97
DERIVATIVE: AAD-% 0.783 BIAS-% -0.683 RMS-% 0.593
AAD 0.079 BIAS -0.067 RMS 0.091 MPa-dm^ -mol'^
190
Data from Van Dael et al. [59]
T
P
P
W.exp
W.cal
Devi
3P/ap|x
exp
ap/ap|x
cal
Dev2
Wt
K
MPa
mol • dm'
3 m-s-i
m-s"^
%
MPa-dm^
•mol-i
%
94.05
0.018
27.86
1509.0
1509.1
0.0
23.11
23.13
0.1
0.001
94.36
0.018
27.84
1507.0
1505.6
-0.1
23.04
23.02
-0.1
0.001
96.17
0.023
27.69
1489.8
1485.9
-0.3
22.45
22.33
-0.5
0.001
98.50
0.029
21 A9
1466.6
1461.5
-0.3
21.64
21.46
-0.8
0.001
101.79
0.041
27.21
1433.9
1428.3
-0.4
20.48
20.27
-1.0
0.001
105.45
0.059
26.89
1400.0
1392.0
-0.6
19.26
18.99
-1.4
0.001
109.09
0.082
26.57
1363.8
1356.2
-0.6
18.01
17.76
-1.4
0.001
112.79
0.111
26.23
1326.8
1319.7
-0.5
16.77
16.54
-1.4
0.001
116.07
0.144
25.93
1293.3
1287.1
-0.5
15.69
15.50
-1.2
0.001
119.78
0.189
25.58
1256.0
1249.7
-0.5
14.54
14.35
-1.3
0.001
123.81
0.249
25.19
1214.5
1208.4
-0.5
13.31
13.15
-1.3
0.001
127.96
0.325
24.78
1170.3
1165.0
-0.4
12.09
11.95
-1.1
0.001
131.97
0.413
24.37
1127.2
1122.3
-0.4
10.97
10.84
-1.1
0.001
136.17
0.523
23.92
1081.0
1076.5
-0.4
9.83
9.73
-1.0
0.001
140.23
0.649
23.47
1035.3
1031.2
-0.4
8.79
8.70
-1.0
0.001
144.49
0.804
22.98
986.7
982.4
-0.4
7.74
7.66
-1.1
0.001
149.01
0.995
22.44
933.3
929.1
-0.5
6.69
6.62
-1.1
0.001
153.78
1.230
21.83
875.7
870.9
-0.5
5.65
5.58
-1.3
0.001
158.02
1.470
21.25
822.2
817.3
-0.6
4.77
4.70
-1.3
0.001
162.81
1.780
20.54
759.1
754.1
-0.7
3.83
3.78
-1.4
0.002
167.50
2.126
19.78
694.3
689.2
-0.7
2.99
2.94
-1.6
0.002
172.02
2.503
18.97
628.2
623.1
-0.8
2.23
2.20
-1.6
0.003
176.44
2.918
18.06
558.1
554.7
-0.6
1.56
1.54
-1.2
0.008
179.47
3.229
17.34
506.0
505.1
-0.2
1.14
1.14
-0.4
0.004
182.51
3.567
-
449.0
452.1
0.7
-
-
-
-
185.93
3.979
.
374.3
385.0
2.9
_
.
.
.
187.55
4.187
-
331.5
346.9
4.7
-
-
-
-
189.60
4.464
•
273.0
283.3
3.8
-
-
-
-
Number of Points (Ref . 59) 28 on saturation boundary
SOUND SPEED: AAD-%
AAD
0.820 BIAS-% 0.037 RMS-% 1.342
5.481 BIAS -2.647 RMS 5.657 m-s"i
Number of Points (Ref. 59) 24
DERIVATIVE: AAD-%
AAD
1.074 BIAS-% -1.064 RMS-%
0.115 BIAS -0.112 RMS
0.430
0.080 MPa-dm^ -mol'i
191
Data from Van Itterbeek et al. [60]
T
P
P
W,exp
W.cal
Devi
ap/ap T
exp
ap/ap X
cal
Dev2
Wt
K
MPa
mol • dm'
3 m-s-i
m-s"^
%
MPa-dm^
•mol-i
%
111.33
0.112
26.37
1340.9
1334.3
-0.5
17.24
17.02
-1.3
0.000
111.33
0.505
26.39
1345.0
1338.3
-0.5
17.38
17.15
-1.3
0.000
111.33
0.981
26.42
1349.6
1343.1
-0.5
17.53
17.31
-1.2
0.000
111.33
1.973
IS.Ul
1358.7
1352.8
-0.4
17.84
17.64
-1.1
0.000
111.33
2.937
26.53
1367.0
1362.0
-0.4
18.12
17.95
-0.9
0.000
111.33
3.932
26.58
1376.6
1371.4
-0.4
18.45
18.27
-1.0
0.000
111.33
4.913
26.64
1384.8
1380.3
-0.3
18.74
18.59
-0.8
0.000
111.33
5.884
26.69
1393.1
1389.1
-0.3
19.03
18.89
-0.7
0.000
111.33
6.815
le.lh
1402.1
1397.3
-0.3
19.34
19.18
-0.8
0.000
111.33
7.569
26.78
1408.5
1403.8
-0.3
19.57
19.42
-0.8
0.000
125.09
0.281
25.07
1200.6
1195.3
-0.4
12.93
12.78
-1.2
0.000
125.09
0.530
25.09
1202.9
1198.4
-0.4
13.00
12.87
-1.0
0.000
125.09
1.010
25.12
1209.0
1204.4
-0.4
13.17
13.04
-1.0
0.000
125.09
1.991
25.20
1220.8
1216.5
-0.4
13.51
13.38
-0.9
0.000
125.09
2.958
25.27
1232.1
1227.9
-0.3
13.84
13.72
-0.9
0.000
125.09
3.917
25.34
1242.7
1239.0
-0.3
14.16
14.05
-0.8
0.000
125.09
4.864
25.40
1253.8
1249.6
-0.3
14.49
14,37
-0.8
0.000
125.09
5.924
25.48
1265.1
1261.2
-0.3
14.84
14.73
-0.8
0.000
125.09
6.846
25.54
1275.0
1270.9
-0.3
15.14
15.03
-0.8
0.000
125.09
7.796
25.60
1285.0
1280.8
-0.3
15.46
15.34
-0.8
0.000
125.09
8.775
25.66
1295.0
1290.7
-0.3
15.77
15.65
-0.8
0.000
125.09
9.788
25.73
1305.2
1300.7
-0.3
16.10
15.98
-0.8
0.000
140.02
0.647
23.50
1038.5
1033.6
-0.5
8.85
8.75
-1.1
0.000
140.02
1.112
23.55
1045.0
1041.6
-0.3
9.01
8.94
-0.8
0.000
140.02
1.988
23.65
1059.5
1056.3
-0.3
9.35
9.28
-0.8
0.000
140.02
2.981
23.75
1075.0
1072.1
-0.3
9.73
9.66
-0.7
0.000
140.02
3.934
23.85
1089.1
1086.7
-0.2
10.07
10.02
-0.6
0.000
140.02
4.931
23.95
1104.0
1101.3
-0.2
10.44
10.38
-0.6
0.000
140.02
5.899
24.04
1117.9
1114.9
-0.3
10.80
10.73
-0.6
0.000
140.02
6.835
24.12
1130.6
1127.6
-0.3
11.13
11.06
-0.6
0.000
140.02
7.893
24.22
1145.3
1141.5
-0.3
11.52
11.43
-0.7
0.000
140.02
8.836
24.30
1157.0
1153.4
-0.3
11.83
11.75
-0.7
0.000
140.02
9.788
24.38
1169.5
1165.1
-0.4
12.17
12.08
-0.8
0.000
140.02
10.609
24.45
1178.7
1174.9
-0.3
12.43
12.35
-0.7
0.000
140.02
11.034
24.48
1183.9
1179.8
-0.3
12.58
12.49
-0.7
0.000
192
Data from Van Itterbeek et al. [60] (continued)
T P p W.exp W.cal Devi dP/dplj. d?/dp\^ Dev2 Wt
exp cal
K
MPa
mol • dm"
3 m-s-i
m-s"^
%
MPa-dm^
•mol-i
%
155. 4A
1.368
21.61
854.0
851.4
-0.3
5.29
5.25
-0.8
0.000
155.44
2.145
21.76
872.9
871.5
-0.2
5.63
5.60
-0.5
0.000
155.44
2.915
21.89
891.3
890.0
-0.1
5.96
5.94
-0.4
0.000
155.44
3.981
22.06
915.1
914.0
-0.1
6.41
6.39
-0.3
0.000
155.44
4.953
22.21
935.5
934.3
-0.1
6.81
6.79
-0.3
0.000
155.44
5.929
22.35
954.5
953.5
-0.1
7.20
7.18
-0.3
0.000
155.44
6.737
22.46
970.5
968.5
-0.2
7.52
7.49
-0.5
0.000
155.44
7.843
22.60
990.5
988.0
-0.2
7.95
7.91
-0.5
0.000
155.44
8.876
22.73
1007.7
1005.3
-0.2
8.33
8.29
-0.5
0.000
155.44
9.778
22.84
1022.5
1019.8
-0.3
8.66
8.61
-0.6
0.000
155.44
10.842
22.96
1038.6
1036.1
-0.2
9.04
8.99
-0.5
0.000
155.44
11.814
23.07
1053.6
1050.4
-0.3
9.39
9.33
-0.6
0.000
155.44
12.777
23.17
1068.6
1064.0
-0.4
9.74
9.66
-0.9
0.000
155.44
13.770
23.27
1080.9
1077.6
-0.3
10.05
9.99
-0.6
0.000
155.44
14.773
23.37
1094.9
1090.8
-0.4
10.40
10.33
-0.7
0.000
155.44
15.594
23.45
1105.5
1101.3
-0.4
10.67
10.59
-0.7
0.000
170.75
2.402
19.21
646.8
642.5
-0.7
2.44
2.40
-1.4
0.000
170.75
3.001
19.45
672.2
670.4
-0.3
2.75
2.73
-0.6
0.000
170.75
3.957
19.77
710.2
708.9
-0.2
3.24
3.22
-0.4
0.000
170.75
4.915
20.04
743.7
742.4
-0.2
3.70
3.68
-0.4
0.000
170.75
6.200
20.37
782.7
781.5
-0.1
4.28
4.26
-0.3
0.000
170.75
7.843
20.73
826.0
824.8
-0.2
4.97
4.96
-0.3
0.000
170.75
8.876
20.93
849.9
849.0
-0.1
5.38
5.37
-0.2
0.000
170.75
9.829
21.10
871.1
869.9
-0.1
5.76
5.74
-0.3
0.000
170.75
10.690
21.24
890.3
887.6
-0.3
6.10
6.07
-0.6
0.000
170.75
11.673
21.40
909.0
906.7
-0.2
6.46
6.43
-0.5
0.000
170.75
12.696
21.56
927.0
925.6
-0.2
6.82
6.80
-0.3
0.000
170.75
13.578
21.68
944.1
941.0
-0.3
7.16
7.11
-0.6
0.000
170.75
14.611
21.82
961.4
958.3
-0.3
7.52
7.47
-0.6
0.000
170.75
15.614
21.96
977.9
974.3
-0.4
7.87
7.81
-0.7
0.000
170.75
16.871
22.11
995.3
993.5
-0.2
8.26
8.23
-0.3
0.000
170.75
18.289
22.28
1015.6
1014.0
-0.2
8.72
8.70
-0.3
0.000
185.91
4.521
0.00
450.0
456.4
1.4
0.00
0.00
0.0
0.000
185.91
5.003
16.74
494.8
497.6
0.6
1.11
1.12
1.2
0.000
185.91
5.934
17.42
556.2
557.3
0.2
1.63
1.63
0.4
0.000
193
Data from Van Itterbeek et al. [60] (continued)
T P p W.exp W.cal Devi aP/3/?|x d?/dp\^ Dev2
exp cal
Wt
K
MPa
mol • dm" ^
m-s"^
m-s"^
%
MPa-dm^
•mol-i
%
185.91
6.886
17.93
603.0
604.8
0.3
2.10
2.11
0.6
0.000
185.91
7.893
18.36
646.6
646.5
0.0
2.58
2.58
0.0
0.000
185.91
8.927
18.73
685.6
683.3
-0.3
3.05
3.03
-0.6
0.000
185.91
9.808
19.01
707.4
711.3
0.5
3.36
3.39
1.1
0.000
185.91
10.811
19.29
733.7
740.0
0.9
3.73
3.80
1.8
0.000
185.91
11.825
19.54
766.8
766.6
0.0
4.19
4.19
0.0
0.000
185.91
13.253
19.86
800.6
800.5
0.0
4.72
4.72
0.0
0.000
185.91
14.814
20.17
836.3
833.9
-0.3
5.31
5.28
-0.5
0.000
185.91
15.888
20.37
856.1
855.2
-0.1
5.66
5.65
-0.2
0.000
185.91
17.357
20.62
884.2
882.3
-0.2
6.18
6.15
-0.4
0.000
185.91
18.340
20.78
901.8
899.3
-0.3
6.51
6.48
-0.5
0.000
190.03
4.553
0.00
264.2
288.5
9.2
0.00
0.00
0.0
0.000
190.03
4.775
0.00
340.2
359.2
5.6
0.00
0.00
0.0
0.000
190.03
5.295
0.00
415.6
430.5
3.6
0.00
0.00
0.0
0.000
190.03
5.953
16.26
482.3
486.4
0.9
1.04
1.06
1.8
0.000
190.03
6.840
16.96
539.8
541.9
0.4
1.51
1.52
0.8
0.000
190.03
7.792
17.50
590.9
589.0
-0.3
1.99
1.98
-0.6
0.000
190.03
8.856
17.99
634.5
632.8
-0.3
2.46
2.45
-0.5
0.000
190.03
10.102
18.45
677.7
676.4
-0.2
2.99
2.98
-0.3
0.000
190.03
11.348
18.83
715.7
714.1
-0.2
3.49
3.47
-0.4
0.000
190.03
12.574
19.16
748.8
747.1
-0.2
3.96
3.94
-0.4
0.000
190.03
13.790
19.46
778.2
776.7
-0.2
4.40
4.39
-0.3
0.000
190.03
15.037
19.73
807.2
804.5
-0.3
4.86
4.83
-0.6
0.000
190.03
16.334
19.98
833.3
831.2
-0.3
5.31
5.28
-0.5
0.000
190.03
17.509
20.20
855.1
853.7
-0.2
5.69
5.68
-0.3
0.000
190.03
18.735
20.41
878.5
875.8
-0.3
6.12
6.08
-0.6
0.000
190.03
19.971
20.60
900.5
896.8
-0.4
6.53
6.48
-0.8
0.000
Number of Points (Ref . 60) 97
SOUND SPEED: AAD-%
AAD
0.492 BIAS-%
3.540 BIAS
-0.007 RMS-%
-1.751 RMS
1.205
4.508 m-s"i
Number of Points (Ref. 60) 93
DERIVATIVE: AAD-%
AAD
0.663 BIAS-% -0.496 RMS-%
0.064 BIAS -0.060 RMS
0.548
0.059 MPa-dm^ -mol"!
194
Data from Van Itterbeek et al. [60] (continued)
Number of Points Total 661
SOUND SPEED: AAD-% 1.297 BIAS-% 0.831 RMS-% 3.524
AAD 4.AA0 BIAS 0.573 RMS 8.170 m-s'^
Number of Points Total 603 excluding critical region data of Ref . [37]
SOUND SPEED: AAD-% 0.516 BIAS-% 0.006 RMS-% 1.108
AAD 2.980 BIAS -1.259 RMS 4.142 m-s-^
195
TABLE AlO
COMPARISONS FOR COLLISION INTEGRAL
Notes for Table AlO. The temperature in kelvins corresponds to the
given reduced temperature for the methane fluid (t = kT/e). The
collision integral n<2,2)* ^^^ ^^ from the integration results of
Ref.[14]; the "cor" result is from the correlation of eq (10).
t T 0(2.2)* 0(2.2)* De^
K int cor %
0.50
87.000
2.136
15
2.138
73
0.121
0.55
95.700
2.051
91
2.053
45
0.075
0.60
104.400
1.972
92
1.975
11
0.111
0.65
113.100
1.903
93
1.903
50
-0.023
0.70
121.800
1.839
99
1.838
22
-0.096
0.75
130.500
1.778
44
1.778
77
0.019
0.80
139.200
1.725
05
1.724
65
-0.023
0.85
147.900
1.677
59
1.675
33
-0.135
0.90
156.600
1.632
61
1.630
31
-0.141
0.95
165.300
1.590
74
1.589
15
-0.100
1.00
174.000
1.552
45
1.551
43
-0.065
1.10
191.400
1.485
92
1.484
91
-0.068
1.20
208.800
1.428
35
1.428
28
-0.005
1.30
226.200
1.379
36
1.379
63
0.020
1.40
243.600
1.337
06
1.337
48
0.031
1.50
261.000
1.300
37
1.300
65
0.022
1.60
278.400
1.267
48
1.268
24
0.060
1.70
295.800
1.238
42
1.239
51
0.088
1.80
313.200
1.212
81
1.213
90
0.090
1.90
330.600
1.190
00
1.190
92
0.077
2.00
348.000
1.169
43
1.170
20
0.066
2.20
382.800
1.133
94
1.134
34
0.035
2.40
417.600
1.104
30
1.104
39
0.008
2.60
452.400
1.079
11
1.079
00
-0.010
2.80
487.200
1.057
60
1.057
19
-0.039
3.00
522.000
1.038
97
1.038
24
-0.070
3.20
556.800
1.022
62
1.021
61
-0.098
3.40
591.600
1.008
09
1.006
89
-0.119
3.60
626.400
0.995
07
0.993
74
-0.134
3.80
661.200
0.983
32
0.981
91
-0.143
196
Table AlO (continued)
t T Q(2.2)* 0(2.2)* De^
K int cor %
4.00
696.000
0.972 66
0.971 20
-0.150
4.50
783.000
0.949 72
0.948 32
-0.147
5.00
870.000
0.930 87
0.929 62
-0.135
5.50
957.000
0.914 94
0.913 91
-0.112
6.00
1044.000
0.901 18
0.900 43
-0.083
6.50
1131.000
0.889 09
0.888 65
-0.050
Number of Points (Ref . 14) 36
AAD-% 0.077 BIAS-% -0.031 RMS-% 0.084
AAD 0.001 BIAS 0.000 RMS 0.001
197
TABLE All
COMPARISONS FOR ZERO DENSITY VISCOSITY
Notes for Table All. The column r;,exp refers to the reported experimental value
at the lowest pressure at the given temperature. These pressures were often at
0.101 325 MPa (1 atm) . In the column rjo.exp, the reported viscosities were
corrected to zero pressure by subtracting the value of the excess viscosity
at the reported conditions and calculated from the current correlation. The
deviations and statistics refer to these corrected values of tjq . When the
experimental data have already been extrapolated to zero pressure, (that is
for Refs. 62, 65, 66), there are no entries in the r/Q.exp column. The weights
refer to weighting in the determination of the intermolecular parameters e
and a.
Data from Hellemans et al. [61]
K
exp
/iPa- s
r?o , exp
/iPa-s
298,
,15
11.092
11,
,076
323,
.15
11.941
11,
,926
373,
.15
13.514
13,
,501
423,
,15
14.896
14,
,884
468,
,15
16.116
16,
,105
r?o ,cal
Dev
/iPa- s
%
11.121
0.407
11.920
-0.053
13.445
-0.410
14.885
0.006
16.115
0.064
Wt
Number of points (Ref.61) 5
AAD-%
0.188
BIAS-%
0.003
RMS-%
0.261
AAD
0.024
BIAS
-0.001
RMS
0.032
/iPa- s
Data from
Dawe et al.
[62]
T
r\, exp
'?o
,exp
K
^Pa- s
/iPa-s
293.0
11.00
.
403.0
14.39
-
497.0
16.92
-
601.0
19.45
-
676.0
21.13
-
749.0
22.68
_
823.0
24.26
-
900.0
25.78
-
1050.0
28.55
-
r^o ,cal
Dev
Wt
/xPa-s
%
10.954
-0.421
0.0
14.314
-0.525
0.0
16.875
-0.266
0.0
19.452
0.011
0.0
21.178
0.229
0.0
22.771
0.403
0.0
24.312
0.214
0.0
25.847
0.259
0.0
28.673
0.431
0.0
198
Data from Dawe et al. [62]
Number of points (Ref.62) 9
AAD-%
0.306
BIAS-%
0.037
RMS-%
0.337
AAD
0.061
BIAS
0.024
RMS
0.065
/iPa- s
Data from Kestin et al. [63]
T
»7, exp
r/o , exp
rjo .cal
Dev
Wt
K
/iPa-s
/iPa-s
/iPa- s
%
296.22
11.023
11.007
11.059
0.471
0.0
302.44
11.226
11.210
11.260
0.445
0.0
Number of points (Ref.63) 2
AAD-%
0.458
BIAS-%
0.458
RMS-%
0.013
AAD
0.051
BIAS
0.051
RMS
0.001
fiVa- s
Data from
Timrot et al.
[64]
T
V, exp
r/o ,exp
rio ,cal
Dev
Wt
K
^Pa- s
/iPa-s
/iPa- s
%
296.85
11.13
11.125
11.079
-0.416
0.0
325.74
12.03
12.026
12.001
-0.204
0.0
375.85
13.53
13.526
13.525
-0.007
0.0
423.45
14.93
14.927
14.893
-0.223
0.0
471.05
16.22
16.217
16.193
-0.149
0.0
523.75
17.59
17.587
17.561
-0.148
0.0
569.35
18.73
18.727
18.693
-0.186
0.0
622.45
19.96
19.957
19.956
-0.007
0.0
675.25
21.18
21.178
21.162
-0.076
0.0
Number of points (Ref.64) 9
AAD-%
AAD
0.157
0.023
BIAS-%
BIAS
■0.157
-0.023
RMS-%
RMS
0.118
0.014
/iPa- s
199
Data from Kestin and Yata [65]
T
n, exp
»7o , exp
Vo ,cal
Dev
Wt
K
/iPa-s
/xPa-s
/iPa-s
%
293.15
10.924
_
10.959
0.316
0.0
303.15
11.258
-
11.283
0.222
0.0
Number of points (Ref.65) 2
AAD-%
0.269
BIAS-%
0.269
RMS-%
0.047
AAD
0.030
BIAS
0.030
RMS
0.005
/iPa-s
Data from
De Roc CO and
Halford [66]
T
V. exp
r)Q , exp
t}q ,cal
Dev
Wt
K
fi?a-s
/iPa-s
/iPa«s
%
210.70
8.10
_
8.122
0.2711
0.0
250.10
9.67
-
9.514
-1.6134
0.0
273.16
10.31
-
10.298
-0.1205
0.0
292.70
11.03
-
10.944
-0.7810
0.0
300.70
11.25
-
11.204
-0.4099
0.0
308.20
11.55
_
11.445
-0.9066
0.0
320.70
11.89
-
11.843
-0.3983
0.0
328.70
12.20
-
12.094
-0.8711
0.0
337.30
12.53
-
12.361
-1.3494
0.0
351.10
12.81
-
12.784
-0.2040
0.0
363.10
13.22
_
13.146
-0.5597
0.0
373.20
13.55
-
13.447
-0.7612
0.0
387.90
13.91
-
13.879
-0.2266
0.0
394.40
14.19
-
14.067
-0.8666
0.0
407.20
14.49
-
14.434
-0.3842
0.0
424.40
15.06
_
14.920
-0.9311
0.0
439.90
15.41
-
15.350
-0.3921
0.0
451.60
15.74
-
15.669
-0.4486
0.0
459.40
15.94
-
15.881
-0.3735
0.0
473.16
16.35
-
16.249
-0.6193
0.0
Number of points (Ref.66) 20
-%
0.624
BIAS-%
-0.597
RMS-%
0.420
0.080
BIAS
-0.078
RMS
0.048
/;Pa-s
200
Data from Maitland and Smith [67]
T
ri, exp
Vo , exp
Vo ,cal
Dev
Wt
K
/iPa-s
/iPa* s
/iPa-s
%
295.0
11.09
11.0747
11.0189
-0.5036
0.0
394.0
14.08
14.0635
14.0555
-0.0572
0.0
547.0
18.21
18.1926
18,1436
-0.2691
0.0
698.0
21.63
21.6120
21.6668
0.2533
0.0
873.0
25.42
25.4016
25.3158
-0.3379
0.0
873.0
25.23
25.2116
25.3158
0.4132
0.0
1022.0
27.83
27.8114
28.1600
1.2536
0.0
Number of points (Ref.67) 7
AAD-%
0.441
BIAS-%
0.107
RMS-%
0.557
AAD
0.101
BIAS
0.044
RMS
0.139
/iPa-s
Data from Abe et al.
[68;
1
T
n, exp
Vo , exp
Vq ,cal
Dev
Wt
K
/zPa-s
/iPa- s
/iPa-s
%
298.15
11.10
11.0842
11.1213
0.3346
0.0
333.15
12.28
12.2655
12.2323
-0.2701
0.0
373.15
13.48
13.4667
13.4454
-0.1582
0.0
418.15
14.78
14.7679
14.7444
-0.1586
0.0
468.15
16.10
16.0889
16.1152
0.1636
0.0
Number of points (Ref.68) 5
AAD-%
0.217
BIAS-%
-0.018
RMS-%
0.228
AAD
0.028
BIAS
-0.003
RMS
0.029
/xPa-s
201
Data from Clarke and Smith [69]
T
V. exp
Vo , exp
rio .cal
Dev
Wt
K
/xPa-s
fi?a'S
/xPa>s
%
113.8
4.47
4.4656
4.4739
0.1853
0.0
140.1
5.50
5.4905
5.4799
-0.1931
0.0
171.4
6.68
6.6710
6.6702
-0.0126
0.0
200.3
7.76
7.7516
7.7435
-0.1042
0.0
234.1
8.95
8.9423
8.9568
0.1614
0.0
273.0
10.29
10.2831
10.2922
0.0891
0.0
299.1
11.14
11.1307
11.1521
0.1922
0.0
333.2
12.23
12.2214
12.2339
0.1021
0.0
373.9
13.48
13.4721
13.4676
-0.0338
0.0
Number of points (Ref.69) 10
AAD-%
0.119
BIAS-%
0.043
RMS-%
0.128
AAD
0.010
BIAS
0.005
RMS
0.010
/xPa-s
Data from Giddings et al. [70]
T ri , exp riQ , exp
K /iPa-s /iPa-s
Number of points (Ref.70) 5
/iPa-s
Dev
AAD-%
AAD
0.622
0.081
BIAS-%
BIAS
-0.622
-0.081
RMS-%
RMS
0.212
0.031
/iPa- s
Wt
283.15
10.67
10.6536
10.6300
-0.2216
0.0
310.93
11.62
11.6047
11.5326
-0.6212
0.0
344.26
12.69
12.6758
12.5751
-0.7945
0.0
377.59
13.70
13.6868
13.5765
-0.8058
0.0
410.93
14.65
14.6377
14 . 5404
-0.6647
0.0
202
Data from Carmichael et al. [71]
T
ri, exp
»7o « exp
»7o ,cal
Dev
Wt
K
/iPa-s
/iPa-s
/iPa- s
%
111 .59U
10.530
10.5117
10.4456
-0.6280
0.0
310.928
11.585
11.5667
11.5325
-0.2956
0.0
377.594
13.631
13.6145
13.5766
-0.2777
0.0
444.261
15.597
15.5817
15.4692
-0.7219
0.0
477.594
16.543
16.5198
16.3663
-0.9287
0.0
Number of points (Ref.71) 5
AAD-%
AAD
0.570
0.081
BIAS-%
BIAS
-0.570
-0.081
RMS-%
RMS
0.251
0.046
^i?a• s
Number of Points Total
78
AAD-%
AAD
0.388
0.056
BIAS-%
BIAS
-0.211
-0.024
RMS-%
RMS
0.456
0.073
//Pa- s
203
TABLE A12
COMPARISONS FOR ZERO DENSITY THERMAL CONDUCTIVITY
Notes for Table A12. The column A,exp refers to the reported experimental
value at the lowest pressure at the given temperature. These pressures were
often at 0.101 325 MPa (1 atm) . In the column AQ.exp, the reported thermal
conductivities were corrected to zero pressure by subtracting the value of the
excess thermal conductivity at the reported conditions and calculated from the
current correlation. The deviations and statistics refer to these corrected
values of Aq . When the experimental data have already been extrapolated to
zero pressure, (that is for Refs. 8, 72, 73, and 76), there are no entries in
the AQ,exp column. The weights refer to weighting in the determination of the
intermolecular parameters in the damping function, eq (12).
Data from Roder [8]
T A.exp Ag.exp Aq ,cal Dev Wt
K mW-m"i-K-i mW-m'^-K"^ mW-m'^-K'^ %
133.0
13.92
143.0
14.97
155.0
16.40
163.0
17.33
175.0
18.70
183.0
19.62
197.0
21.31
215.0
23.12
235.0
25.60
255.0
28.03
275.0
30.54
295.0
33.01
310.0
35.36
13.72
-1.458
1.0
14.90
-0.448
1.0
16.32
-0.459
1.0
17.27
-0.339
1.0
18.69
-0.060
1.0
19.63
0.067
1.0
21.29
-0.103
1.0
23.43
1.339
1.0
25.85
0.975
1.0
28.34
1.101
1.0
30.92
1.253
1.0
33.62
1.854
1.0
35.73
1.048
1.0
Number of points (Ref. 8) 13
AAD-% 0.808 BIAS-% 0.367 RMS-% 0.919
AAD 0.206 BIAS 0.139 RMS 0.235 mW-m"^-K
rl .v-l
204
Data from Clifford et al. [72]
T A , exp Aq , exp Aq , cal Dev
K mW-m"^-K"i mW-m'^-K"^ mW-m'^-K'^ %
300.65 34.93 - 34.41 -1.496
Wt
0.0
Number of points (Ref.72) 1
AAD-%
AAD
1.496
0.523
BIAS-%
BIAS
-1.496
-0.523
RMS-%
RMS
mW-m"^ -K'l
Data from Assael and Wakeham [73]
T A, exp Ag.exp Ajj.cal
K mW-m"^-K"^ mW-m'^-K"^ mW-m'^-K"^
308.15 35.35 - 35.47
Dev
%
0.329
Wt
0.0
Number of points (Ref.73) 1
AAD-%
AAD
0.329
0.116
BIAS-%
BIAS
0.329
0.116
RMS-%
RMS
raW-m'i -K'l
Data from
Johnston and
Grilly [74]
T
A, exp
\q ,exp
Aq ,cal
Dev
Wt
K
mW-m"i -K-i
mW-m'i -K'l
mW-m-i-K'^
%
96.76
10.2550
10.2161
9.4505
-7.494
0.0
125.35
13.3679
13.3413
12.8104
-3.979
0.0
140.49
15.0959
15.0703
14.6053
-3.085
0.0
155.29
16.7569
16.7310
16.3591
-2.223
0.0
169.93
18.4347
18.4069
18.0901
-1.721
0.0
185.41
20.1041
20.0700
19.9178
-0.758
0.0
201.24
21.9451
21.9155
21.7905
-0.571
0.0
216.69
23.7819
23.7583
23.6321
-0.531
0.0
231.71
25.5935
25.5734
25.4474
-0.493
0.0
246.86
27.4219
27.4042
27.3154
-0.324
0.0
205
Data from Johnston and Grilly [74] (continued)
T
A.exp
Aq ,exp
Xq ,cal
Dev
Wt
K
mW-m"i -K'l
mW-m"i -K'^
mW-m'i -K"^
%
262.85
29.3926
29.3768
29.3402
-0.124
0.0
278.72
31.4218
31.4075
31.4154
0.025
0.0
294.49
33.5808
33.5677
33.5515
-0.048
0.0
324.00
37.5974
37.5861
37.7669
0.481
0.0
338.60
39.9112
39.9006
39.9620
0.154
0.0
353.96
42.4509
42.4410
42.3495
-0.215
0.0
368.33
44.8901
44.8808
44.6538
-0.506
0.0
383.57
47.5972
47.5883
47.1688
-0.882
0.0
Number of points (Ref.74) 18
AAD-%
1.312
BIAS-%
-1.239
AAD
0.228
BIAS
-0.200
RMS-% 1.896
RMS 0.230 mW-m'i-K"i
Data from Zheng et al. [75]
T A.exp Ag.exp Ag.cal
K mW-m"^-K"^ mW-m"^-K"^ mW-m'^-K'^
299.45 34.74 34.68 34.24
Number of points (Ref.75) 1
AAD-%
AAD
1.233
0.427
BIAS-%
BIAS
-1.233
-0.427
RMS-%
RMS
Dev
%
•1.233
Wt
0.0
mW-m'^ -K'^
Data from Mann and Dickins [76]
T A.exp Ag ,exp AQ.cal
K mW-m'^-K"i mW-m'^-K'^ mW-m'^-K"^
275,
.18
30,
.480
276,
,18
30,
.619
277,
,17
30,
.853
279,
,17
31,
.079
281,
,18
31,
,372
283,
.18
31,
.665
Dev
Wt
30.946
1.530
0.0
31.078
1.501
0.0
31.210
1.156
0.0
31.475
1.275
0.0
31.744
1.184
0.0
32.012
1.095
0.0
206
Data from Mann and Dickins [76] (continued)
Number of points (Ref.76) 6
AAD-%
1.290
BIAS-%
1.290
AAD
0.400
BIAS
0.400
RMS-% 0.168
RMS 0.047 mW-m"i-K"i
Data from
Misic and Thodos [77]
T
A.exp
Aq ,exp
Aq
cal
Dev
K
mW-m"^ -K-i
mW-m"^ -K-i
mW-m'
i.K-i
%
275.05
31.4637
31.3798
30
9292
-1.436
297.75
34.3506
34.2750
34
0029
-0.794
316.75
37.0702
37.0002
36
7040
-0.801
348.25
41.8818
41.8195
41
4527
-0.877
Number of points (Ref.77) 4
AAD-%
AAD
0.977
0.346
BIAS-%
BIAS
-0.977
-0.346
Wt
0.0
0.0
0.0
0.0
RMS-% 0.267
RMS 0.069 mW-m"^-K'^
Data from Carmichael et al. [78]
T A.exp Aq ,exp AQ.cal
K mW-m"i-K"^ mW-m'^-K'^ mW-m-i-K"^
Number of points (Ref.78) 5
Dev
AAD-%
AAD
2.550
1.205
BIAS-%
BIAS
Wt
277.594
31.219
31.126
31.266
0.450
0.0
310.928
35.235
35.155
35.863
2.017
0.0
377.594
44.628
44.565
46.174
3.612
0.0
410.928
50.505
50.444
51.854
2.794
0.0
444.261
55.717
55.661
57.818
3.876
0.0
2.550 RMS-% 1.236
1.205 RMS 0.706 mW-m'^-K'^
207
Data from Baker and Brokaw [79]
T A.exp Ao,exp Ag ,cal
K mW-m"^-K"i mW-m'^-K"^ mW-m'^-K'^
Dev
Wt
299.8
33.7649
33.6912
34.2885
1.773
0.0
333.0
38.1623
38.0977
39.1114
2.661
0.0
375.5
44.5805
44.5246
45.8281
2.928
0.0
423.3
52.3711
52.3226
54.0374
3.277
0.0
472.3
60.4504
60.4076
63.0125
4.312
0.0
Number of points (Ref.79) 5
AAD-%
AAD
2.990
1.447
BIAS-%
BIAS
2.990
1.447
RMS-
RMS
0.828
0.685
mW-m"i -K"!
Data from Sokolova and Golubev [80]
T A , exp Aq , exp Aq , cal
K mW-m'i-K"i mW-m'^-K"^ mW-m'^-K'^
118.8 12.71 12.48
Number of points (Ref.80) 11
12.04
Dev
-3.556
AAD-%
1.261
BIAS-%
-0.061
RMS-%
1.536
AAD
0.235
BIAS
0.049
RMS
0.256
Wt
238.7
26.08
25.98
26.30
1.245
0.0
231.8
25.25
25.15
25.46
1.244
0.0
224.8
24.45
24.34
24.61
1.102
0.0
216.4
23.47
23.35
23.60
1.048
0.0
210.0
22.71
22.59
22.83
1.093
0.0
183.2
19.68
19.53
19.66
0.662
0.0
176.8
19.01
18.86
18.90
0.206
0.0
165.3
17.75
17.60
17.54
-0.343
0.0
152.6
16.39
16.24
16.04
-1.213
0.0
140.3
15.07
14.90
14.58
-2.160
0.0
0.0
mW-m'i -K'l
208
Data from Le Neindre et al. [81]
T A.exp Ap.exp Aq ,cal
K mW-m'i-K'i mW-m'^-K'^ mW-m'^-K'^
Dev
Wt
307.35
35.6
35.53
35.35
-0.498
0.0
298.65
34.5
34.40
34.13
-0.791
0.0
368.85
45.1
45.04
44.74
-0.678
1.0
407.95
51.4
51.35
51.33
-0.031
1.0
420.25
53.9
53.83
53.50
-0.628
1.0
465.55
62.3
62.24
61.75
-0.789
1.0
523.35
73.2
73.15
72.77
-0.520
1.0
571.85
82.8
82.77
82.25
-0.618
1.0
575.75
84.6
84.57
83.02
-1.826
1.0
621.45
94.0
93.96
92.05
-2.031
1.0
Number of points (Ref.81) 10
AAD-%
AAD
0.841
0.594
BIAS-%
BIAS
-0.841
-0.594
RMS-%
RMS
0.582
0.588
mW-m
-1
K"
Data from
Yorizane et al,
. [82]
T
A.exp
Aq , exp
Xq ,cal
Dev
Wt
K
mW-m"i -R-i
mW-m-i-K-i
mW-m-i-K-i
%
323.35
37.7
37.63
37.67
0.098
0.0
319.95
37.5
37.43
37.17
-0.700
0.0
316.75
37.3
37.23
36.70
-1.418
0.0
312.85
36.7
36.63
36.14
-1.342
0.0
309.35
36.3
36.23
35.64
-1.635
0.0
308.25
35.7
35.63
35.48
-0.419
0.0
303.15
35.1
35.03
34.76
-0.771
0.0
297.75
34.4
34.33
34.00
-0.943
0.0
303.15
35.1
35.03
34.76
-0.771
0.0
309.85
36.6
36.53
35.71
-2.248
0.0
316.75
37.2
37.13
36.70
-1.153
0.0
317.75
37.2
37.13
36.85
-0.762
0.0
323.45
37.7
37.63
37.69
-0.138
0.0
Number of points (Ref.82) 13
AAD-%
0.954
BIAS-%
-0.917
RMS-%
0.637
AAD
0.347
BIAS
-0.333
RMS
0.234
mW-m"i -K'l
209
Data from Tanaka et al. [83]
T
A.exp
Aq ,exp
Aq ,cal
Dev
Wt
K
mW-m"i -K-i
mW-m-i-K-i
mW-m-i-K-i
%
298.15
33.9
33.83
34.06
0.685
0.0
323.15
37.4
37.33
37.64
0.824
0.0
348.15
41.4
41.34
41.44
0.236
0.0
Number of points (Ref.83) 3
AAD-% 0.582 BIAS-% 0.582 RMS-% 0.251
AAD 0.212 BIAS 0.212 RMS 0.087 mW-m'^-K"^
Number of Points Total with positive weight 21
AAD-%
0.839
BIAS-%
-0.112
AAD
0.389
BIAS
-0.176
RMS-% 1.025
RMS 0.586 mW-m'i-K'^
Number of Points Total referenced in Ref . [1] 74
RMS-% 1.456
-%
1.076
BIAS-%
-0.449
0.315
BIAS
-0.135
RMS 0.413 mW-m"i-K
-I .v-i
Number of Points Total 91
AAD-%
1.241
BIAS-%
-0.084
AAD
0.424
BIAS
0.028
RMS-% 1.705
RMS 0.639 mW-m"^-K"^
210
TABLE A13
COMPARISONS FOR VISCOSITY AT ELEVATED PRESSURES
Notes for Table A13. The quantities T, P, and r?,exp refer to experimental
quantities; the density was evaluated from the SWEOS . For the data along the
saturated liquid boundary of Boon [85] and Haynes [87], however, both the
pressure and density were calculated from the ancillary equations for the
phase boundary. The tabulated densities were then used as input to calculate
the viscosity.
Data from Barua et al
84'
T
P
P
r?,exp
r?,cal
Dev
Wt
K
MPa
mol •dm"''
/iPa-s
/iPa- s
%
223.15
2.0265
1.2092
8.820
9.0509
2.618
0.0
223.15
6.0795
4.8458
10.875
11.3032
3.938
0.0
223.15
8.1065
7.8446
13.528
14.1882
4.880
0.0
223.15
12.1590
13.2838
21.641
22.5027
3.982
0.0
223.15
14.1855
14.6807
25.013
25.5006
1.949
0.0
223.15
16.2120
15.6757
27.310
27.9289
2.266
0.0
248.15
1.0133
0.5081
9.555
9.6414
0.904
0.0
248.15
3.0398
1.6405
9.980
10.1550
1.754
0.0
248.15
6.0795
3.7125
11.117
11.3922
2.476
0.0
248.15
8.1060
5.3936
12.390
12.6976
2.483
0.0
248.15
10.1325
7.2752
14.144
14.5088
2.579
0.0
248.15
14.1855
10.8636
18.692
19.1512
2.456
0.0
248.15
16.2120
12.2398
20.865
21.4262
2.690
0.0
273.15
1.4196
0.6469
10.410
10.5567
1.409
0.0
273.15
2.6223
1.2312
10.644
10.8216
1.669
0.0
273.15
4.9426
2.4619
11.264
11.4766
1.888
0.0
273.15
7.0137
3.6802
12.010
12.2591
2.074
0.0
273.15
9.8903
5.5360
13.454
13.7217
1.989
0.0
273.15
13.3516
7.8639
15.799
16.0592
1.647
0.0
273.15
16.8899
10.0448
18.487
18.8258
1.832
0.0
298.15
2.8999
1.2307
11.479
11.6574
1.554
0.0
298.15
5.5455
2.4624
12.123
12.3235
1.654
0.0
298.15
7.9804
3.6810
12.923
13.1148
1.484
0.0
298.15
11.5004
5.5387
14.384
14.5871
1.412
0.0
298.15
15.9404
7.8691
16.731
16.9271
1.172
0.0
298.15
17.7552
8.7601
17.709
17.9814
1.538
0.0
348.15
2.8989
1.0281
13.037
13.1487
0.857
0.0
348.15
5.5648
2.0165
13.504
13.6689
1.221
0.0
348.15
8.1384
3.0010
14.119
14.2697
1.067
0.0
348.15
12.1185
4.5508
15.222
15.3883
1.092
0.0
211
Data from Barua et al. [84] (continued)
T
P
P
»7,exp
f7,cal
Dev
Wt
K
MPa
mol-dm"^
/iPa-s
/iPa-s
%
348.15
14.6800
5.5415
16.066
16.2187
0.950
0.0
348.15
17.6539
6.6599
17.100
17.2700
0.994
0.0
423.15
1.1703
0.3339
15.063
15.0284
-0.230
0.0
423.15
2.8513
0.8172
15.233
15.2521
0.125
0.0
423.15
5.6793
1.6377
15.620
15.6752
0.354
0.0
423.15
8.5052
2.4615
16.055
16.1555
0.626
0.0
423.15
12.7163
3.6816
16.831
16.9709
0.831
0.0
423.15
15.7844
4.5531
17.496
17.6313
0.773
0.0
423.15
17.2253
4.9545
17.827
17.9579
0.734
0.0
Number of points (Ref.84) 39
AAD-%
AAD
1.696
0.255
BIAS-%
BIAS
1.684
0.253
RMS-%
RMS
1.026
0.182 AiPa-s
Data from Boon et al. [85]
T
P
P
i/,exp
»;,cal
Dev
Wt
K
MPa
mol-dm"^
/iPa-s
/iPa-s
%
91.01
0.0122
28.1199
199.50
200.3647
0.433
0.0
93.77
0.0172
27.8858
182.50
185.5583
1.676
0.0
97.34
0.0259
27.5809
162.40
168.4102
3.701
0.0
100.88
0.0377
ll.llbS
146.70
153.4119
4.575
0.0
103.84
0.0505
n .0115
138.40
142.2355
2.771
0.0
107.05
0.0681
IS.ThMi
127.20
131.3626
3.272
0.0
109.86
0.0872
26.4835
120.10
122.7949
2.244
0.0
114.15
0.1238
26.0937
112.30
111.2087
-0.972
0.0
Number of points (Ref.85) 8
AAD-%
AAD
2.456
3.554
BIAS-%
BIAS
2.213
3.281
RMS-%
RMS
1.689
2.389 /iPa-s
212
Data from Carmichael et al. [71]
T
P
P
»7.exp
»7,cal
Dev
Wt
K
MPa
mol • dm" ^
/iPa-s
/iPa-s
%
111 .59h
0.1117
0.0485
10.530
10.4640
-0.627
1.0
277.594
6.9685
3.5515
12.447
12.3242
-0.986
1.0
277.594
14.1301
8.0623
16.990
16.4423
-3.223
1.0
277.594
14.1473
8.0730
17.008
16.4547
-3.253
1.0
277.594
14.1632
8.0828
16.881
16.4661
-2.458
1.0
277.594
27.7051
14.0602
26.417
25.9290
-1.847
1.0
111 ,59i^
27.7361
14.0691
26.438
25.9478
-1.854
1.0
277.594
27.7430
14.0711
26.436
25.9519
-1.831
1.0
277.594
35.6368
15.9423
30.814
30.3397
-1.539
1.0
277.594
35.6547
15.9458
30.770
30.3489
-1.368
1.0
277.594
35.6713
15.9491
30.833
30.3575
-1.542
1.0
310.928
0.1207
0.0468
11.685
11.5508
-1.148
1.0
310.928
0.1227
0.0476
11.602
11.5511
-0.439
1.0
310.928
0.1241
0.0481
11.615
11.5513
-0.548
1.0
310.928
0.1262
0.0489
11.684
11.5516
-1.133
1.0
310.928
0.1317
0.0510
11.609
11.5525
-0.487
1.0
310.928
6.2839
2.6594
12.829
12.8643
0.275
1.0
310.928
10.2077
4.5153
14.318
14.1618
-1.091
1.0
310.928
10.2070
4.5149
14.328
14.1615
-1.162
1.0
310.928
13.4034
6.0653
15.587
15.4942
-0.595
1.0
310.928
27.4438
11.7304
22.952
22.6524
-1.305
1.0
310.928
27.4652
11.7370
22.924
22.6632
-1.138
1.0
310.928
27.4679
11.7378
22.741
22.6645
-0.336
1.0
310.928
27.5127
11.7515
22.697
22.6871
-0.044
1.0
310.928
34.5757
13.6235
26.489
26.0815
-1.538
1.0
310.928
34.6129
13.6320
26.454
26.0985
-1.344
1.0
310.928
34.6447
13.6393
26.414
26.1130
-1.139
1.0
310.928
35.1866
13.7622
26.436
26.3598
-0.288
1.0
310.928
35.2107
13.7676
26.439
26.3708
-0.258
1.0
377.594
0.1269
0.0405
13.631
13.5932
-0.277
1.0
377.594
7.0540
2.3327
14.639
14.7501
0.759
1.0
377.594
7.0547
2.3329
14.657
14.7503
0.636
1.0
377.594
13.8770
4.6575
16.389
16.3790
-0.061
1.0
377.594
14.0611
4.7195
16.368
16.4290
0.373
1.0
377.594
14.0694
4.7223
16.363
16.4312
0.417
1.0
213
Data from Carmichael [71] (continued)
T
P
P
r/,exp
T? ,cal
Dev
Wt
K
MPa
mol • dm" ^
/iPa-s
^Pa- s
%
377.594
27.6741
8.8847
20.850
20.6467
-0.975
1.0
377.594
27.6844
8.8874
20.940
20.6501
-1.385
1.0
377.594
27.6913
8.8893
20.658
20.6523
-0.027
1.0
377.594
27.9085
8.9471
20.743
20.7239
-0.092
1.0
377.594
27.9340
8.9539
20.849
20.7323
-0.560
1.0
377.594
27.9954
8.9702
20.776
20.7525
-0.113
1.0
377.594
35.0494
10.6868
23.350
23.0703
-1.198
1.0
444.261
0.1338
0.0362
15.597
15.4845
-0.721
1.0
444.261
6.9913
1.9112
16.377
16.4191
0.257
1.0
444.261
6.9933
1.9118
16.357
16.4194
0.381
1.0
444.261
6.9961
1.9126
16.358
16.4198
0.378
1.0
444.261
14.0446
3.8254
17.589
17.6695
0.458
1.0
444.261
14.0466
3.8259
17.573
17.6699
0.552
1.0
444.261
28.6221
7.4148
20.976
20.8781
-0.467
1.0
444.261
28.6621
7.4236
20.918
20.8876
-0.145
1.0
444.261
28.6704
7.4255
20.915
20.8895
-0.122
1.0
444.261
34.8177
8.7200
22.208
22.3553
0.663
1.0
444.261
34.8212
8.7207
22.172
22.3561
0.830
1.0
444.261
35.2997
8.8158
22.513
22.4709
-0.187
1.0
444.261
35.3259
8.8210
22.499
22.4771
-0.097
1.0
444.261
35.3438
8.8245
22.581
22.4814
-0.441
1.0
477.594
0.2158
0.0544
16.543
16.3896
-0.927
1.0
477.594
7.0795
1.7857
17.242
17.2527
0.062
1.0
477.594
7.0823
1.7864
17.253
17.2531
0.001
1.0
477.594
7.0857
1.7873
17.214
17.2536
0.230
1.0
477.594
14.0639
3.5158
18.338
18.3564
0.100
1.0
477.594
14.0666
3.5165
18.372
18.3569
-0.082
1.0
477.594
27.8368
6.6392
20.909
20.9922
0.398
1.0
477.594
27.8464
6.6412
20.921
20.9942
0.350
1.0
477.594
27.9616
6.6651
21.023
21.0178
-0.025
1.0
477.594
34.9349
8.0423
22.285
22.4699
0.830
1.0
477.594
34.9549
8.0461
22.296
22.4741
0.799
1.0
Number of points (Ref.71) 67
AAD-%
AAD
0.764
0.156
BIAS-%
BIAS
■0.503
■0.108
RMS-
RMS
0.905
0.193 /iPa-s
214
Data from Diller [9]
T
P
P
f7,exp
rj.cal
Dev
Wt
K
MPa
mol-dm"^
/iPa- s
/xPa-s
%
300.0
27.5171
12.4236
23.08
23.4859
1.759
0.0
300.0
24.6130
11.4741
21.63
21.8836
1.172
0.0
300.0
21.9816
10.4929
20.11
20.3771
1.328
0.0
300.0
19.8617
9.6115
18.89
19.1409
1.328
0.0
300.0
17.5856
8.5754
17.60
17.8172
1.234
0.0
300.0
14.2203
6.9008
16.17
15.9469
-1.380
0.0
300.0
10.6642
5.0361
14.10
14.2183
0.839
0.0
300.0
8.5932
3.9579
13.43
13.3756
-0.405
0.0
300.0
6.5757
2.9418
12.57
12.6805
0.879
0.0
300.0
4.4641
1.9307
12.13
12.0809
-0.404
0.0
300.0
2.3501
0.9808
11.67
11.5988
-0.610
0.0
250.0
33.1075
17.4623
33.91
33.8731
-0.109
0.0
250.0
30.2114
16.8947
32.12
32.1340
0.043
0.0
250.0
26.2641
15.9738
29.56
29.5642
0.014
0.0
250.0
23.4267
15.1618
27.44
27.5203
0.293
0.0
250.0
19.9095
13.8848
24.55
24.6567
0.435
0.0
250.0
15.6382
11.6497
20.33
20.4779
0.727
0.0
250.0
14.2168
10.6548
19.30
18.8990
-2.078
0.0
250.0
12.8282
9.5433
17.24
17.3106
0.410
0.0
250.0
11.4851
8.3599
15.87
15.8044
-0.413
0.0
250.0
10.0994
7.0840
14.56
14.3750
-1.270
0.0
250.0
8.6876
5.8009
13.12
13.1252
0.040
0.0
250.0
7.2482
4.5728
12.31
12.0926
-1.766
0.0
250.0
5.8005
3.4501
11.36
11.2803
-0.701
0.0
250.0
4.5051
2 . 5444
10.84
10.7125
-1.177
0.0
250.0
3.0433
1.6256
10.57
10.2130
-3.378
0.0
212.0
25.9756
19.4383
40.14
40.0453
-0.236
1.0
212.0
24.0602
19.1042
39.18
38.6561
-1.337
1.0
212.0
22.0279
18.7101
37.20
37.1058
-0.253
1.0
212.0
19.8848
18.2372
35.20
35.3592
0.452
1.0
212.0
18.0669
17.7740
33.66
33.7563
0.286
0.0
212.0
17.8173
17.7049
33.45
33.5253
0.225
0.0
212.0
15.8212
17.0886
31.53
31.5564
0.084
0.0
212.0
15.1417
16.8471
30.36
30.8256
1.534
0.0
212.0
12.5149
15.6714
27.22
27.5556
1.233
0.0
215
Data from Diller [9] (continued)
T
P
P
Tj.exp
f7,cal
Dev
Wt
K
MPa
mol-dm"^
/iPa-s
/iPa-s
%
212.0
12.3572
15.5834
26.86
27.3283
1.743
0.0
212.0
10.7324
14.4780
24.30
24.6547
1.460
0.0
212.0
9.8615
13.6563
22.68
22.8642
0.812
0.0
212.0
9.2284
12.8844
20.78
21.3169
2.584
0.0
212.0
8.6517
11.9841
19.32
19.6613
1.767
0.0
212.0
8.2518
11.2078
18.35
18.3512
0.006
0.0
212.0
7.6827
9.8580
15.71
16.3074
3.803
0.0
212.0
7.3221
8.9005
14.48
15.0219
3.742
0.0
212.0
6.9239
7.8512
13.38
13.7564
2.813
0.0
212.0
6.5161
6.8677
12.19
12.6967
4.156
0.0
212.0
6.0626
5.9185
11.59
11.7826
1.662
0.0
212.0
5.2844
4.6049
10.31
10.6825
3.613
0.0
212.0
4.7580
3.8854
9.69
10.1567
4.816
0.0
212.0
3.8811
2.8909
9.41
9.5148
1.114
0.0
212.0
2.6830
1.8045
9.07
8.9211
-1.642
0.0
212.0
1.3573
0.8328
8.69
8.4809
-2.406
0.0
200.0
26.0666
20.5452
45.55
44.9282
-1.365
1.0
200.0
22.7861
20.0554
43.26
42.5112
-1.731
1.0
200.0
17.1539
18.9907
38.47
37.8847
-1.522
1.0
200.0
13.4880
18.0190
34.49
34.2569
-0.676
1.0
200.0
10.7512
16.9746
31.18
30.8498
-1.059
0.0
200.0
8.9805
15.9606
28.11
27.9351
-0.622
0.0
200.0
7.9300
15.0569
26.03
25.6097
-1.615
0.0
200.0
7.0972
13.9399
23.25
23.0368
-0.917
0.0
200.0
6.0940
10.7792
17.73
17.1987
-2.997
0.0
200.0
5.7235
8.3884
13.97
13.9010
-0.494
0.0
200.0
5.3374
6.5189
12.28
11.8645
-3.383
0.0
200.0
5.0575
5.6154
11.44
11.0312
-3.573
0.0
200.0
4.6874
4.7241
10.71
10.2986
-3.841
0.0
200.0
4.1792
3.8062
10.06
9.6321
-4.253
0.0
200.0
3.5092
2.8863
9.58
9.0494
-5.538
0.0
200.0
2.5405
1.8678
9.05
8.4990
-6.088
0.0
180.0
29.6172
22.6414
58.06
57.9165
-0.247
1.0
180.0
26.0926
22.2956
55.35
55.2777
-0.131
1.0
180.0
22.5630
21.9099
52.91
52.5713
-0.640
1.0
216
Data from Diller [9] (continued)
T
P
P
i/,exp
ij.cal
Dev
Wt
K
MPa
mol'dm"^
/iPa-s
/iPa-s
%
180.0
18.9364
21.4591
50.00
49.6796
-0.641
1.0
180.0
18.0006
21.3314
49.05
48.9073
-0.291
1.0
180.0
15.5309
20.9659
47.34
46.7988
-1.143
1.0
180.0
14.3643
20.7761
46.07
45.7585
-0.676
1.0
180.0
10.9669
20.1355
42.77
42.4934
-0.647
1.0
180.0
6.6784
18.9933
37.64
37.4444
-0.520
1.0
180.0
4.7313
18.1821
34.47
34.3347
-0.392
1.0
180.0
3.5334
17.4191
31.78
31.7013
-0.248
0.0
170.0
31.3603
23.5728
65.87
66.1360
0.404
1.0
170.0
28.0109
23.2992
63.50
63.4795
-0.032
1.0
170.0
24.6337
22.9996
61.26
60.7878
-0.771
1.0
170.0
21.4364
22.6889
58.20
58.2058
0.010
1.0
170.0
17.7783
22.2923
55.66
55.1763
-0.869
1.0
170.0
14.7678
21.9226
53.31
52.5838
-1.362
1.0
170.0
14.6458
21.9066
53.26
52.4762
-1.472
1.0
170.0
11.6174
21.4778
50.26
49.7178
-1.079
1.0
170.0
8.5905
20.9691
47.07
46.7281
-0.726
1.0
170.0
5.9150
20.4137
43.65
43.7607
0.254
1.0
170.0
3.2114
19.6654
40.24
40.1690
-0.176
1.0
170.0
2.3339
19.3469
38.78
38.7617
-0.047
1.0
170.0
2.3338
19.3468
38.72
38.7616
0.107
1.0
140.0
32.1731
25.8442
97.32
99.9805
2.734
1.0
140.0
28.6862
25.6534
93.95
96.0911
2.279
1.0
140.0
25.5140
25.4705
91.10
92.6413
1.692
1.0
140.0
21.9776
25.2547
88.47
88.8758
0.459
1.0
140.0
18.3655
25.0192
85.03
85.0952
0.077
1.0
140.0
16.7132
24.9056
82.61
83.3812
0.934
1.0
140.0
14.8198
24.7704
81.70
81.4242
-0.338
1.0
140.0
14.3898
24.7389
81.05
80.9804
-0.086
1.0
140.0
11.6975
24.5340
78.46
78.2020
-0.329
1.0
140.0
11.5486
24.5223
78.50
78.0482
-0.576
1.0
140.0
8.7964
24.2966
75.33
75.1958
-0.178
1.0
140.0
8.1090
24.2375
75.22
74.4791
-0.985
1.0
140.0
5.9313
24.0417
71.93
72.1916
0.364
1.0
140.0
4.6192
23.9169
71.39
70.7963
-0.832
1.0
217
Data from Diller [9] (continued)
T
p
P
»?.exp
n.cal
Dev
Wt
K
MPa
mol-dm"-'
/iPa-s
^Fa- s
%
140.0
3.6012
23.8159
69.54
69.7021
0.233
1.0
140.0
3.5782
23.8136
69.59
69.6772
0.125
1.0
140.0
1.0162
23.5408
67.74
66.8629
-1.295
1.0
140.0
0.6435
23.4986
66.18
66.4447
0.400
1.0
120.0
29.6804
27.1490
135.66
139.1141
2.546
1.0
120.0
26.0938
26.9908
132.02
133.5790
1.181
1.0
120.0
22.8894
26.8433
126.93
128.8088
1.480
1.0
120.0
18.5450
26.6331
121.87
122.5704
0.575
1.0
120.0
14.9691
26.4501
117.36
117.6036
0.208
1.0
120.0
11.8634
26.2826
112.56
113.3914
0.739
1.0
120.0
10.0661
26.1816
110.98
110.9899
0.009
1.0
120.0
8.2936
26.0789
109.04
108.6433
-0.364
1.0
120.0
6.4887
25.9707
105.48
106.2723
0.751
1.0
120.0
4.7333
25.8617
103.04
103.9804
0.913
1.0
120.0
3.0145
25.7511
101.69
101.7460
0.055
1.0
120.0
1.1885
25.6289
99.49
99.3782
-0.112
1.0
100.0
31.3341
28.6020
218.49
220.8303
1.071
1.0
100.0
29.1106
28.5266
215.48
215.6186
0.064
1.0
100.0
27.6657
28.4768
212.13
212.3065
0.083
1.0
100.0
26.8786
28.4494
210.75
210.5254
-0.107
1.0
100.0
25.2648
28.3926
206.80
206.9247
0.060
1.0
100.0
24.0528
28.3494
205.58
204.2630
-0.641
1.0
100.0
23.3380
28.3236
203.68
202.7097
-0.476
1.0
100.0
22.0477
28.2767
201.56
199.9366
-0.805
1.0
100.0
20.4257
28.2169
198.40
196.5039
-0.956
1.0
100.0
18.5381
28.1460
193.94
192.5810
-0.701
1.0
100.0
16.5683
28.0705
190.05
188.5651
-0.781
1.0
100.0
12.5966
27.9134
181.94
180.6900
-0.687
1.0
100.0
9.8678
27.8011
174.37
175.4359
0.611
1.0
100.0
9.4111
27.7820
175.95
174.5682
-0.785
1.0
100.0
7.3829
27.6956
169.50
170.7511
0.738
1.0
100.0
5.8976
27.6310
169.32
167.9918
-0.784
1.0
100.0
4.5249
27.5700
164.74
165.4672
0.441
1.0
100.0
3 . 3040
27.5149
161.63
163.2414
0.997
1.0
100.0
2.3281
27.4701
162.62
161.4742
-0.705
1.0
100.0
1.7964
27.4455
159.99
160.5160
0.329
1.0
218
Data from Diller et al. [9] (continued)
Number of points (Ref. 9) 141
AAD-%
1.101
BIAS-%
-0.089
RMS-%
1.598
AAD
0.489
BIAS
0.014
RMS
0.749 n?a
Data from Giddings et al. [70]
T
P
P
f/.exp
rj.cal
Dev
Wt
K
MPa
mol • dm" "^
/iPa- s
/iPa- s
%
283.15
0.1013
0.0431
10.67
10.6464
-0.221
4.0
283.15
0.6890
0.2969
10.74
10.7460
0.056
4.0
283.15
1.3790
0.6031
10.86
10.8733
0.123
4.0
283.15
2.0680
0.9180
10.90
11.0126
1.033
4.0
283.15
2.7581
1.2427
11.14
11.1650
0.224
4.0
283.15
3.4471
1.5766
11.31
11.3312
0.188
4.0
283.15
4.1371
1.9208
11.48
11.5127
0.285
4.0
283.15
5.5161
2.6383
11.93
11.9244
-0.047
4.0
283.15
6.8952
3.3941
12.37
12.4083
0.309
4.0
283.15
8.6187
4.3867
13.12
13.1240
0.031
4.0
283.15
10.3220
5.4071
14.08
13.9584
-0.864
4.0
283.15
12.0658
6.4699
14.96
14.9390
-0.141
4.0
283.15
13.7893
7.5111
16.00
16.0161
0.100
4.0
283.15
17.3377
9.5126
18.32
18.4396
0.653
4.0
283.15
20.6804
11.1214
20.70
20.7672
0.324
4.0
283.15
27.5786
13.6062
25.05
25.1734
0.493
4.0
283.15
34.4738
15.3290
28.80
28.9703
0.591
4.0
283.15
41.3680
16.6170
32.25
32.3405
0.281
4.0
283.15
48.2631
17.6396
35.50
35.4399
-0.169
4.0
283.15
55.1583
18.4868
38.50
38.3703
-0.337
0.0
310.93
0.1013
0.0392
11.62
11.5479
-0.620
4.0
310.93
0.6890
0.2693
11.68
11.6402
-0.340
4.0
310.93
1.3790
0.5445
11.79
11.7565
-0.284
4.0
310.93
2.0680
0.8249
11.90
11.8814
-0.156
4.0
310.93
2.7581
1.1113
12.00
12.0159
0.133
4.0
310.93
3.4471
1.4029
12.16
12.1599
-0.001
4.0
310.93
4.1371
1.7004
12.31
12.3144
0.035
4.0
310.93
5.5161
2.3108
12.65
12.6551
0.041
4.0
310.93
6.8952
2.9409
13.03
13.0411
0.085
4.0
310.93
8.6187
3.7515
13.68
13.5898
-0.659
4.0
219
Data from Giddings et al. [70] (continued)
T
P
P
r/.exp
i^.cal
Dev
Wt
K
MPa
mol • dm" ^
/iPa-s
AiPa-s
%
310.93
10.3422
4.5803
14.22
14.2131
-0.048
4.0
310.93
12.0658
5.4174
14.94
14.9087
-0.210
4.0
310.93
13.7893
6.2509
15.71
15.6699
-0.256
4.0
310.93
17.3377
7.9075
17.52
17.3976
-0.699
4.0
310.93
20.6804
9.3362
19.30
19.1372
-0.844
4.0
310.93
27.5786
11.7715
22.80
22.7201
-0.350
4.0
310.93
34.4738
13.5999
26.10
26.0347
-0.250
4.0
310.93
41.3680
15.0082
29.20
29.0564
-0.492
4.0
310.93
48.2631
16.1369
31.80
31.8533
0.168
4.0
310.93
55.1583
17.0733
34.20
34.4918
0.853
4.0
344.26
0.1013
0.0354
12.69
12.5893
-0.794
4.0
344.26
0.6890
0.2423
12.75
12.6742
-0.595
4.0
344.26
1.3790
0.4883
12.84
12.7796
-0.470
4.0
344.26
2.0680
0.7370
12.94
12.8914
-0.375
4.0
344.26
2.7581
0.9893
13.05
13.0100
-0.307
4.0
344.26
3.4471
1.2442
13.15
13.1352
-0.113
4.0
344.26
4.1371
1.5023
13.28
13.2675
-0.094
4.0
344.26
5.5161
2.0262
13.55
13.5535
0.026
4.0
344.26
6.8952
2.5595
13.86
13.8686
0.062
4.0
344.26
8.6187
3.2362
14.29
14.3039
0.097
4.0
344.26
10.3422
3.9200
14.79
14.7849
-0.035
4.0
344.26
12.0658
4.6059
15.33
15.3097
-0.133
4.0
344.26
13.7893
5.2881
15.89
15.8749
-0.095
4.0
344.26
17.3377
6.6588
17.12
17.1463
0.154
4.0
344.26
20.6804
7.8789
18.42
18.4396
0.106
4.0
344.26
27.5786
10.0969
21.23
21.2238
-0.029
4.0
344.26
34.4738
11.8972
23.94
23.9618
0.091
4.0
344.26
41.3680
13.3519
26.50
26.5568
0.214
4.0
344.26
48.2631
14.5478
29.10
29.0044
-0.328
4.0
344.26
55.1583
15.5526
31.30
31.3296
0.095
4.0
377.59
0.1013
0.0323
13.70
13.5897
-0.805
4.0
377.59
0.6890
0.2204
13.76
13.6683
-0.667
4.0
377.59
1.3790
0.4430
13.84
13.7649
-0.542
4.0
377.59
2.0680
0.6671
13.93
13.8663
-0.457
4.0
377.59
2.7581
0.8933
14.03
13.9729
-0.407
4.0
220
Data from Giddings et al. [70] (continued)
T
P
P
»7,exp
»/,cal
Dev
Wt
K
MPa
mol'dm"^
/iPa-s
/iPa-s
%
377.59
3.4471
1.1207
14.12
14.0842
-0.254
4.0
377.59
4.1371
1.3500
14.23
14.2008
-0.205
4.0
377.59
5.5161
1.8122
14.45
14.4490
-0.007
4.0
377.59
6.8952
2.2788
14.71
14.7178
0.053
4.0
377.59
8.6187
2.8661
15.07
15.0822
0.081
4.0
377.59
10.3422
3.4554
15.47
15.4777
0.050
4.0
377.59
12.0658
4.0438
15.80
15.9027
0.650
4.0
377.59
13.7893
4.6280
16.36
16.3552
-0.029
4.0
377.59
17.3377
5.8055
17.34
17.3621
0.127
4.0
377.59
20.6804
6.8670
18.39
18.3834
-0.036
4.0
377.59
27.5786
8.8593
20.62
20.6153
-0.023
4.0
377.59
34.4738
10.5579
22.86
22.8828
0.100
4.0
377.59
41.3680
11.9874
25.10
25.0967
-0.013
4.0
377.59
48.2631
13.1961
27.20
27.2273
0.100
4.0
377.59
55.1583
14.2300
29.40
29.2743
-0.428
4.0
410.93
0.1013
0.0297
14.65
14.5527
-0.664
4.0
410.93
0.6890
0.2022
14.70
14.6258
-0.505
4.0
410.93
1.3790
0.4057
14.78
14.7151
-0.439
4.0
410.93
2.0680
0.6099
14.86
14.8081
-0.349
4.0
410.93
2.7581
0.8154
14.94
14.9050
-0.234
4.0
410.93
3.4471
1.0213
15.03
15.0056
-0.162
4.0
410.93
4.1371
1.2282
15.12
15.1102
-0.065
4.0
410.93
5.5161
1.6436
15.32
15.3307
0.070
4.0
410.93
6.8952
2.0607
15.54
15.5663
0.170
4.0
410.93
8.6187
2.5829
15.84
15.8818
0.264
4.0
410.93
10.3422
3.1046
16.17
16.2197
0.308
4.0
410.93
12.0658
3.6239
16.33
16.5790
1.525
4.0
410.93
13.7893
4.1387
16.91
16.9582
0.285
4.0
410.93
17.3377
5.1773
17.74
17.7943
0.306
4.0
410.93
20.6804
6.1195
18.61
18.6377
0.149
4.0
410.93
27.5786
7.9189
20.49
20.4876
-0.012
4.0
410.93
34.4738
9.5003
22.40
22.3977
-0.010
4.0
410.93
41.3680
10.8712
24.30
24.2988
-0.005
4.0
410.93
48.2631
12.0584
26.10
26.1577
0.221
4.0
410.93
55.1583
13.0925
28.00
27.9639
-0.129
4.0
Number of points (Ref.70) 100
AAD-%
AAD
0.281
0.049
BIAS-%
BIAS
-0.055
-0.006
RMS-%
RMS
0.386
0.071 AiPa-s
221
Data from Gonzalez et al. [86]
T
P
P
»j,exp
»7,cal
Dev
Wt
K
MPa
mol-dm"^
AiPa-s
/iPa-s
%
310.928
1.3789
. 5444
12.01
11.7564
-2.112
0.0
310.928
2.7579
1.1112
12.10
12.0158
-0.696
0.0
310.928
4.1368
1.7002
12.54
12.3142
-1.800
0.0
310.928
5.5158
2.3107
12.76
12.6550
-0.823
0.0
310.928
6.8947
2.9407
13.16
13.0409
-0.905
0.0
310.928
10.3421
4.5803
14.46
14.2131
-1.708
0.0
310.928
13.7895
6.2511
15.95
15.6699
-1.756
0.0
310.928
20.6842
9.3378
19.56
19.1393
-2.151
0.0
310.928
27.5789
11.7717
23.14
22.7204
-1.813
0.0
310.928
34.4737
13.6000
26.65
26.0348
-2.309
0.0
310.928
41.3684
15.0083
29.90
29.0567
-2.820
0.0
310.928
55.1579
17.0733
35.47
34.4919
-2.758
0.0
344.261
1.3789
0.4882
13.08
12.7797
-2.296
0.0
344.261
2.7579
0.9892
13.28
13.0100
-2.033
0.0
344.261
4.1368
1.5022
13.46
13.2675
-1.430
0.0
344.261
5.5158
2.0260
13.73
13.5534
-1.286
0.0
344.261
6.8947
2.5593
14.08
13.8685
-1.502
0.0
344.261
10.3421
3.9200
14.90
14.7849
-0.773
0.0
344.261
13.7895
5.2882
15.95
15.8750
-0.470
0.0
344.261
20.6842
7.8802
18.68
18.4411
-1.279
0.0
344.261
27.5789
10.0969
21.63
21.2239
-1.878
0.0
344.261
34.4737
11.8971
24.46
23.9617
-2.037
0.0
344.261
41.3684
13.3519
27.50
26.5569
-3.430
0.0
344.261
55.1579
15.5525
32.22
31.3294
-2.764
0.0
377.594
1.3789
0.4430
14.05
13.7650
-2.028
0.0
377.594
2.7579
0.8932
14.22
13.9729
-1.737
0.0
377.594
4.1368
1.3499
14.40
14.2008
-1.383
0.0
377.594
5.5158
1.8120
14.63
14.4491
-1.237
0.0
377.594
6.8947
2.2786
14.81
14.7178
-0.623
0.0
377.594
13.7895
4.6280
16.46
16.3553
-0.636
0.0
377.594
20.6842
6.8680
18.60
18.3846
-1.158
0.0
377.594
27.5789
8.8593
20.64
20.6153
-0.120
0.0
377.594
34.4737
10.5577
23.27
22.8827
-1.665
0.0
377.594
41.3684
11.9874
25.56
25.0967
-1.812
0.0
377.594
55.1579
14.2298
30.03
29.2740
-2.517
0.0
222
Data from Gonzalez et al. [86] (continued)
T
P
P
»?,exp
»7,cal
Dev
Wt
K
MPa
mol-dra"^
/iPa-s
/iPa'S
%
410.928
1.3789
0.4057
15.09
14.7150
-2.485
0.0
410.928
2.7579
0.8153
15.26
14.9049
-2.327
0.0
410.928
4.1368
1.2281
15.34
15.1101
-1.499
0.0
410.928
5.5158
1.6435
15.50
15.3306
-1.093
0.0
410.928
6.8947
2.0605
15.66
15.5662
-0.599
0.0
410.928
10.3421
3.1046
16.33
16.2197
-0.676
0.0
410.928
13.7895
4.1388
17.02
16.9582
-0.363
0.0
410.928
20.6842
6.1206
18.82
18.6386
-0.964
0.0
410.928
34.4737
9.5003
22.83
22.3976
-1.894
0.0
410.928
41.3684
10.8713
24.86
24.2989
-2.257
0.0
410.928
55.1579
13.0925
29.08
27.9638
-3.838
0.0
444.261
1.3789
0.3744
16.00
15.6322
-2.299
0.0
444.261
4.1368
1.1280
16.37
15.9943
-2.295
0.0
444.261
6.8947
1.8847
16.72
16.4039
-1.891
0.0
444.261
13.7895
3.7574
17.85
17.6198
-1.289
0.0
444.261
20.6842
5.5417
19.33
19.0567
-1.414
0.0
444.261
27.5789
7.1813
20.92
20.6325
-1.374
0.0
444.261
34.4737
8.6512
22.63
22.2728
-1.579
0.0
Number of points (Ref.86) 53
AAD-%
AAD
1.658
0.335
BIAS-%
BIAS
•1.658
■0.335
RMS-%
RMS
0.768
0.248 /iPa-s
Data from
Haynes [87]
T
P
P
fy.exp
r/,cal
Dev
Wt
K
MPa
mol • dm' ^
|iPa-s
/iPa-s
%
95.0
0.01983
27.78109
178.44724
179.40555
0.5370
2.0
100.0
0.03441
27.35180
156.97692
156.96669
-0.0065
2.0
105.0
0.05643
26.91566
138.38713
138.16422
-0.1611
2.0
110.0
0.08820
26.47086
122.58596
122.38943
-0.1603
2.0
115.0
0.13232
26.01545
109.07683
109.10539
0.0262
2.0
223
Data from Haynes [87] (continued)
T
P
P
»7,exp
ly.cal
Dev
Wt
K
MPa
mol • dm" ^
/iPa-s
/iPa- s
%
120.0
0,
.19158
25.54730
97.56533
97.85224
0.2941
2.0
125.0
.26896
25.06409
88.35418
88.24503
-0.1235
2.0
130.0
0,
.36760
24.56319
81.04580
79.96689
-1.3312
2.0
135.0
0,
.49072
24.04154
73.34020
72.75987
-0.7913
2.0
140.0
0,
.64165
23.49559
67.33754
66.41512
-1.3699
2.0
145.0
0,
.82379
22.92098
61.23474
60.76358
-0.7694
2.0
150.0
1,
.04065
22.31228
55.73642
55.66745
-0.1238
2.0
155.0
1,
.29580
21.66242
51.43842
51.01256
-0.8279
2.0
160.0
1,
,59296
20.96180
46.54146
46.70134
0.3435
2.0
165.0
1,
,93607
20.19664
41.94595
42.64546
1.6677
2.0
170.0
2,
,32936
19.34572
37.64927
38.75676
2.9416
2.0
175.0
2,
,77762
18.37296
34.35499
34.93156
1.6783
2.0
180.0
3,
,28655
17.20702
30.95908
31.01327
0.1750
2.0
185.0
3.
,86361
15.66142
26.15027
26.65399
1.9263
2.0
190.0
4.
,52082
12.49998
19.76671
19.75384
-0.0651
2.0
Number of points (Ref.87) 20
AAD-%
AAD
0.766
0.424
BIAS-%
BIAS
0.193
0.014
RMS-%
RMS
1.081
0.556 /iPa-s
Data from Hellemans et al. [88]
T P p
K MPa mol • dm' ^
r/.exp
/iPa-s
»?,cal
/iPa-s
Dev
Wt
96.8
0.0405
27.6352
169.0
171.2001
1.302
0.0
96.8
0.2837
27.6462
170.0
171.6593
0.976
0.0
96.8
1.9657
27.7211
173.0
174.8539
1.072
0.0
96.8
1.8238
27.7149
180.0
174.5834
-3.009
0.0
96.8
5.8262
27.8869
180.0
182.3155
1.286
0.0
96.8
7.8122
27.9690
191.0
186.2324
-2.496
0.0
96.8
9.3523
28.0314
188.0
189.3108
0.697
0.0
106.0
0.0808
26.8426
133.0
135.2417
1.685
0.0
106.0
1.9252
26.9391
135.0
138.2104
2.378
0.0
106.0
4.0327
27.0458
138.0
141.6371
2.636
0.0
224
Data from Hellemans et al. [88] (continued)
T
P
P
f/.exp
Tj.cal
Dev
Wt
K
MPa
mol'dm"^
/iPa-s
|iPa-s
%
106.0
5.8465
27.1349
141.0
144.6196
2.567
0.0
106.0
7.9439
27.2349
145.0
148.1123
2.146
0.0
106.0
9.5448
27.3093
149.0
150.8128
1.217
0.0
115.3
0.1517
26.0031
107.0
108.7093
1.597
0.0
115.3
2.1380
26.1265
110.0
111.4579
1.325
0.0
115.3
4.0023
26.2380
112.0
114.0509
1.831
0.0
115.3
6.0592
26.3565
117.0
116.9325
-0.058
0.0
115.3
7.8122
26.4540
119.0
119.4099
0.344
0.0
115.3
0.1224
26.5783
123.0
122.7114
-0.235
0.0
125.0
0.2736
25.0747
90.0
88.4116
-1.765
0.0
125.0
3.8098
25.3383
93.6
92.7271
-0.933
0.0
125.0
6.1504
25.5004
95.8
95.5786
-0.231
0.0
125.0
7.7108
25.6039
100.7
97.4845
-3.193
0.0
125.0
9.8083
25.7378
98.3
100.0576
1.788
0.0
138.7
0.6181
23.6455
69.5
68.0467
-2.091
0.0
138.7
1.9252
23.7854
71.2
69.5065
-2.378
0.0
138.7
3.9415
23.9875
73.6
71.7128
-2.564
0.0
138.7
5.8465
24.1657
76.5
73.7595
-3.582
0.0
138.7
7.9540
24.3504
78.8
75.9945
-3.560
0.0
138.7
9.4435
24.4743
80.2
77.5619
-3.289
0.0
145.6
0.8613
22.8527
63.5
60.1486
-5.278
0.0
145.6
1.1146
22.8866
63.7
60.4347
-5.126
0.0
145.6
1.9961
23.0012
66.0
61.4168
-6.944
0.0
145.6
3.9821
23.2416
68.3
63.5643
-6.934
0.0
145.6
5.8465
23.4487
71.3
65.5170
-8.111
0.0
145.6
7.7919
23.6491
72.5
67.5067
-6.887
0.0
145.6
9.5955
23.8230
75.8
69.3193
-8.550
0.0
156.3
1.3780
21.4872
48.8
49.8724
2.198
0.0
156.3
2.5129
21.7009
49.1
51.2355
4.349
0.0
156.3
4.0530
21.9621
51.5
52.9799
2.874
0.0
156.3
6.0187
22.2588
52.1
55.0765
5.713
0.0
156.3
8.0959
22.5388
51.5
57.1789
11.027
0.0
156.3
9.7069
22.7374
53.3
58.7506
10.226
0.0
171.4
2.4619
19.0923
35.5
37.7034
6.207
0.0
171.4
3.9314
19.6399
36.8
40.0699
8.886
0.0
225
Data from Hellemans et al. [88] (continued)
T
P
P
r/,exp
r;,cal
Dev
Wt
K
MPa
mol • dm" ^
/iPa-s
/iPa- s
%
171.4
5.9072
20.1983
38.1
42.6942
12.058
0.0
171.4
7.6906
20.6046
39.6
44.7578
13.025
0.0
171.4
9.6360
20.9816
40.2
46.8052
16.431
0.0
183.0
3.6477
16.3848
27.0
28.5960
5.911
0.0
183.0
5.5222
17.8916
28.4
33.3737
17.513
0.0
183.0
7.7716
18.8385
29.9
36.8849
23.361
0.0
183.0
9.9602
19.4847
30.7
39.5636
28.872
0.0
187.3
4.1645
14.7229
22.5
24.3686
8.305
0.0
187.3
5.8870
17.0254
23.7
30.6393
29.280
0.0
187.3
7.8628
18.0876
23.9
34.1682
42.963
0.0
187.3
9.7069
18.7569
25.3
36.6581
44.894
0.0
mber of p
oints (Ref,
,88) 56
AAD-%
7.074
BIAS-%
4.317
RMS-% 11.
,118
AAD
3.405
BIAS
1.160
RMS 4,
.006 /xPa-s
Data from Huang et al. [89]
T
P
P
»?,exp
r/,cal
Dev
Wt
K
MPa
mol- dm" ^
/iPa-s
/iPa-s
%
173.15
2.6067
18.7496
38.5
36.3444
-5.599
0.0
173.15
4.0279
19.3416
40.5
38.7816
-4.243
0.0
173.15
6.7132
20.1296
43.8
42.3765
-3.250
0.0
173.15
10.0699
20.8403
47.7
46.0341
-3.492
0.0
173.15
13.4265
21.3968
51.2
49.2358
-3.836
0.0
173.15
20.1397
22.2632
57.3
54.9746
-4.058
0.0
173.15
26.8529
22.9416
62.7
60.3075
-3.816
0.0
173.15
33.5662
23.5072
67.6
65.5140
-3.086
0.0
153.15
1.1975
21.9082
54.2
52.6900
-2.786
0.0
153.15
4.0279
22.3571
57.0
55.8884
-1.950
0.0
153.15
6.7132
22.7182
59.9
58.6908
-2.019
0.0
153.15
10.0699
23.1097
63.1
62.0007
-1.742
0.0
153.15
13.4265
23.4536
66.4
65.1794
-1.838
0.0
153.15
20.1397
24.0428
72.7
71.3503
-1.857
0.0
153.15
26.8529
24.5415
78.8
77.4837
-1.670
0.0
226
Data from Huang et al. [89] (continued)
T
P
P
i7,exp
»7,cal
Dev
Wt
K
MPa
mol • dm" ^
/iPa- s
/iPa-s
%
153.15
33.5662
Ik.^llk
84.7
83.7509
-1.121
0.0
133.15
0.4426
lU.lkZl
76.7
75.3883
-1.710
0.0
133.15
4.0279
24.5639
81.0
79.4553
-1.907
0.0
133.15
6.7132
24.7821
84.0
82.4523
-1.842
0.0
133.15
10.0699
25.0340
87.8
86.1768
-1.849
0.0
133.15
13.4265
25.2667
91.7
89.9079
-1.954
0.0
133.15
20.1397
25.6872
99.0
97.4929
-1.522
0.0
133.15
26.8529
26.0613
106.0
105.3840
-0.581
0.0
133.15
33.5662
26.4001
114.0
113.7365
-0.231
0.0
123.15
0.2384
25.2560
94.0
91.8162
-2.323
0.0
123.15
4.0279
25.5268
99.0
96.5397
-2.485
0.0
123.15
6.7132
25.7047
102.0
99.8924
-2.066
0.0
123.15
10.0699
25.9135
107.0
104.1160
-2.695
0.0
123.15
13.4265
26.1094
111.0
108.3998
-2.342
0.0
123.15
20.1397
26.4698
120.0
117.2396
-2.300
0.0
123.15
26.8529
26.7963
129.0
126.5817
-1.875
0.0
123.15
33.5662
27.0959
137.0
136.5954
-0.295
0.0
113.15
0.1151
26.2001
114.0
114.1058
0.093
0.0
113.15
4.0279
26.4292
119.0
119.7182
0.604
0.0
113.15
6.7132
26.5772
123.0
123.6223
0.506
0.0
113.15
10.0699
26.7530
128.0
128.5843
0.456
0.0
113.15
13.4265
26.9200
133.0
133.6591
0.496
0.0
113.15
20.1397
27.2312
142.0
144.2348
1.574
0.0
113.15
26.8529
27.5175
152.0
155.5272
2.321
0.0
113.15
33.5662
27.7832
162.0
167.7264
3.535
0.0
103.15
0.0479
27.0909
144.0
145.1668
0.810
0.0
103.15
4.0279
27.2857
151.0
151.9432
0.625
0.0
103.15
6.7132
27.4107
156.0
156.6087
0.390
0.0
103.15
10.0699
27.5607
162.0
162.5659
0.349
0.0
103.15
13.4265
27.7043
168.0
168.6842
0.407
0.0
103.15
20.1397
27.9751
181.0
181.4927
0.272
0.0
103.15
26.8529
28.2271
193.0
195.2203
1.150
0.0
103.15
33.5662
28.4633
206.0
210.0740
1.978
0.0
Number of points (Ref.89) 48
AAD-%
AAD
1.873
1.635
BIAS-%
BIAS
■1.225
■0.596
RMS-%
RMS
1.885
1.843 /iPa-s
227
Data from Kestin and Yata [65]
T
P
P
'7,exp
r/,cal
Dev
Wt
K
MPa
mol-dm"''
/xPa-s
^Pa-s
%
293.15
2.5524
1.0984
11.321
11.4289
0.953
0.0
293.15
2.0255
0.8631
11.217
11.3196
0.914
0.0
293.15
1.5219
0.6424
11.137
11.2213
0.757
0.0
293.15
1.0153
0.4245
11.054
11.1283
0.672
0.0
293.15
0.5087
0.2107
10.986
11.0409
0.500
0.0
293.15
0.1064
0.0437
10.936
10.9754
0.360
0.0
293.15
0.0500
0.0205
10.924
10.9664
0.388
0.0
303.15
2.2443
0.9238
11.590
11.6751
0.734
0.0
303.15
1.9221
0.7870
11.526
11.6125
0.750
0.0
303.15
1.5280
0.6216
11.462
11.5389
0.671
0.0
303.15
1.0072
0.4063
11.387
11.4466
0.524
0.0
303.15
0.5147
0.2059
11.318
11.3642
0.408
0.0
303.15
0.5137
0.2055
11.318
11.3641
0.407
0.0
303.15
0.5066
0.2027
11.322
11.3629
0.361
0.0
303.15
0.1155
0.0459
11.276
11.3008
0.220
0.0
303.15
0.1125
0.0447
11.268
11.3003
0.287
0.0
303.15
0.1054
0.0419
11.267
11.2992
0.286
0.0
303.15
0.0500
0.0199
11.258
11.2907
0.290
0.0
Number of points (Ref.65) 18
AAD-%
AAD
0.527
0.059
BIAS-%
BIAS
0.527
0.059
RMS-%
RMS
0.222
0.025 /iPa-s
Number of Points Total with positive weight 267
AAD-%
AAD
0.559
0.292
BIAS-%
BIAS
-0.161
-0.025
RMS-%
RMS
0.791
0.559 /iPa-s
Number of Points Total referenced in Ref. [1] 532
AAD-%
AAD
1.710
0.786
BIAS-%
BIAS
0.246
0.092
RMS-%
RMS
4.122
1.613 ^Pa-s
Number of Points Total
550
AAD-%
AAD
1.672
0.762
BIAS-%
BIAS
0.255
0.092
RMS-%
RMS
4.055
1.586 /iPa-s
228
TABLE A14
COMPARISONS FOR THERMAL CONDUCTIVITY AT ELEVATED PRESSURES
Notes for Table Al4. The quantities T, P, and A,exp refer to experimental
quantities; the density was evaluated from the SWEOS. The tabulated densities
were then used as input to calculate the thermal conductivity.
Data from Assael and Wakeham [73]
T P p
K MPa mol-dm"3
A , exp A , cal
Number of Points (Ref. 73) 13
Dev
AAD-%
AAD
0.630
0.266
BIAS-%
BIAS
-0.428 RMS-% 0.706
-0.191 RMS 0.303 mW-m'^ -K'l
Wt
307.48
1.84
0.741
36.45
36.60
0.412
0.0
307.27
2.60
1.060
37.01
37.14
0.351
0.0
307.16
3.31
1.364
37.62
37.68
0.159
0.0
307.03
3.93
1.636
38.09
38.19
0.263
0.0
306.96
4.49
1.885
38.62
38.67
0.129
0.0
306.82
5.06
2.144
39.22
39.19
-0.076
0.0
306.73
5.79
2.480
39.99
39.90
-0.225
0.0
306.62
6.48
2.804
40.78
40.61
-0.417
0.0
306.58
7.12
3.109
41.53
41.31
-0.530
0.0
306.87
7.81
3.436
42.71
42.15
-1.311
0.0
306.73
8.36
3.706
43.39
42.81
-1.337
0.0
306.66
8.79
3.918
43.99
43.35
-1.455
0.0
306.52
9.27
4.157
44.65
43.97
-1.523
0.0
Data from
CI:
Lfford et
al. [72]
T
P
P
A, exp
A, cal
Dev
Wt
K
MPa
mol •dm""'
mW • m~ ^
•K-i
%
301.10
1.61
0.661
35.85
35.57
-0.781
0.0
300.98
2.10
0.869
36.06
35.91
-0.416
0.0
300.90
2.36
0.982
36.35
36.10
-0.688
0.0
300.89
3.06
1.288
36.98
36.66
-0.865
0.0
300.64
3.60
1.531
37.29
37.09
-0.536
0.0
229
Data from Clifford et al. [72] (continued)
T P p A.exp A.cal
K MPa mol-dm"3 mW-m'^-K'^
Dev
Wt
300.54
4.08
1.749
37.72
37.50
-0.583
0.0
300.35
4.56
1.972
38.22
37.93
-0.759
0.0
300.30
5.04
2.198
38.73
38.39
-0.878
0.0
300.15
5.87
2.595
39.67
39.24
-1.084
0.0
300.05
6.58
2.943
40.39
40.03
-0.891
0.0
299.95
7.42
3.363
41.57
41.02
-1.323
0.0
299.85
8.11
3.714
42.90
41.89
-2.354
0.0
299.73
9.18
4.267
44.00
43.35
-1.477
0.0
299.61
10.18
4.793
45.58
44.82
-1.667
0.0
299.49
11.15
5.308
47.04
46.33
-1.509
0.0
299.40
12.13
5.830
48.68
47.94
-1.520
0.0
299.32
13.08
6.334
50.26
49.55
-1.413
0.0
299.16
14.12
6.886
51.84
51.38
-0.887
0.0
299.09
15.15
7.421
53.68
53.21
-0.876
0.0
299.05
15.72
7.712
54.55
54.23
-0.587
0.0
298.93
18.14
8.897
58.83
58.51
-0.544
0.0
298.88
19.60
9.564
61.32
61.01
-0.506
0.0
298.80
21.17
10.240
63.53
63.60
0.110
0.0
298.78
22.81
10.893
66.30
66.17
-0.196
0.0
298.77
24.20
11.408
68.31
68.26
-0.073
0.0
298.73
25.48
11.854
70.68
70.12
-0.792
0.0
298.73
27.17
12.399
72.69
72.47
-0.303
0.0
298.65
28.64
12.844
74.64
74.45
-0.255
0.0
298.66
30.09
13.249
76.69
76.33
-0.469
0.0
298.65
31.41
13.597
78.35
77.99
-0.459
0.0
298.65
32.85
13.953
79.91
79.75
-0.200
0.0
298.65
33.90
14.200
81.48
81.01
-0.577
0.0
298.67
35.35
14.522
82.76
82.70
-0.072
0.0
Number of Points (Ref. 72) 33
AAD-%
AAD
0.777
0.378
BIAS-%
BIAS
■0.771
■0.374
RMS-%
RMS
0.531
0.233 mW-m"^
K
-1
230
Data from Ikenberry and. Rice [90]
T
P
P
A.exp
A.cal
Dev
Wt
K
MPa
mol-dni''^
mW • m" ^
•K-^
%
98.90
39.82
28.949
287.36
234.92
-18.249
0.0
98.93
30.44
28.645
267.61
227.58
-14.958
0.0
98.99
20.31
28.286
225.48
219.25
-2.763
0.0
99.01
10.13
27.890
216.52
210.41
-2.822
0.0
99.02
5.12
11 .(ill
211.71
205.82
-2.782
0.0
99.02
2.56
21 .561
209.16
203.41
-2.749
0.0
99.03
0.16
27.451
206.90
201.09
-2.808
0.0
125.47
50.67
27.624
218.99
215.69
-1.507
0.0
125.49
40.68
27.235
210.12
206.97
-1.499
0.0
125.55
30.41
26.788
200.33
197.43
-1.448
0.0
125.53
20.41
26.300
189.91
187.57
-1.232
0.0
125.54
10.15
25.712
178.24
176.45
-1.004
0.0
125.61
5.08
25.371
171.38
170.35
-0.601
0.0
125.62
2.43
25.178
168.03
167.02
-0.601
0.0
150.23
50.74
26.087
192.38
189.73
-1.377
0.0
150.25
40.54
25.577
182.84
179.88
-1.619
0.0
150.28
30.44
24.995
171.67
169.34
-1.357
0.0
150.28
20.48
24.312
159.54
157.91
-1.022
0.0
150.28
10.13
23.409
145.60
144.17
-0.982
0.0
150.29
5.04
22.834
137.40
136.18
-0.888
0.0
150.30
2.62
22.510
132.88
131.91
-0.730
0.0
175.13
50.67
24.523
166.52
165.89
-0.378
0.0
175.14
40.58
23.879
156.19
155.42
-0.493
0.0
175.17
30.41
23.095
144.43
143.74
-0.478
0.0
175.15
20.41
22.107
130.92
130.56
-0.275
0.0
175.16
10.13
20.596
114.06
113.25
-0.710
0.0
175.15
5.13
19.345
102.76
101.19
-1.528
0.0
200.20
50.67
22.946
145.31
145.38
0.048
0.0
200.20
40.41
22.115
134.22
134.22
0.000
0.0
200.21
30.41
21.084
122.05
121.89
-0.131
0.0
200.22
20.28
19.601
106.86
106.75
-0.103
0.0
200.18
13.01
17.837
92.80
92.23
-0.614
0.0
200.18
10.17
16.652
85.73
84.40
-1.551
0.0
200.18
7.63
14.653
78.28
74.66
-4.624
0.0
200.10
5.11
5.735
41.92
42.01
0.215
0.0
231
Data from Ikenberry and Rice [90] (continued)
T P p A.exp A.cal
K MPa mol-dm'3 mW-m'^-K"^
200.08
200.08
235.01
235.00
235.00
234.99
235.00
234.98
234.96
234.95
2.48
0.28
50.74
40.54
30.68
20.28
13.06
10.10
5.07
2.49
1.813
0.174
20.786
19.681
18.228
15.717
11.882
8.769
3.294
1.419
Number of Points (Ref. 90) 45
AAD-%
AAD
1.847
3.683
BIAS-%
BIAS
25.02
21.59
123.34
112.13
99.50
82.30
64.89
53.18
32.89
27.91
•1.585
■3.614
25.46
22.00
123.08
111.74
99.03
81.92
64.29
52.69
32.91
28.44
Dev
%
1.759
1.899
-0.211
-0.348
-0.472
-0.462
■0.925
-0.921
0.061
1.899
Wt
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
RMS-%
RMS
3.472
9.466 mW-m"i
K'
Data from
Le Neindre
et al. [81]
T
P
P
A.exp
A.cal
Dev
Wt
K
MPa
mol-dm"^
mW • m" ^
•K-i
%
307.35
0.10
0.039
35.60
35.42
-0.506
0.0
298.65
0.14
0.057
34.50
34.23
-0.783
0.0
304.45
1.00
0.401
35.80
35.60
-0.559
0.0
298.55
1.00
0.410
35.00
34.79
-0.600
0.0
303.85
4.40
1.870
38.80
38.21
-1.521
0.0
298.45
5.00
2.197
38.40
38.14
-0.677
0.0
306.35
5.80
2.489
40.70
39.86
-2.064
0.0
302.85
7.30
3.254
41.90
41.15
-1.790
0.0
298.85
10.10
k.lll
45.50
44.66
-1.846
0.0
304.75
10.50
k.ZYl
46.80
45.57
-2.628
0.0
301.45
10.50
4.908
46.30
45.39
-1.965
0.0
304.15
13.70
6.462
51.30
50.58
-1.404
0.0
299.35
14.70
7.178
53.20
52.40
-1.504
0.0
303.45
16.30
7.780
55.70
55.01
-1.239
0.0
302.75
18.50
8.847
59.30
58.79
-0.860
0.0
232
Data from Le Neindre et al. [81] (continued)
T P p A,exp A.cal Dev Wt
K MPa mol-dm"3 mW-m'^-K'^ %
298.75
20.40
9.920
62.60
62.35
-0.399
0.0
302.05
21.60
10.214
64.30
63.88
-0.653
0.0
303.25
22.30
10.417
65.40
64.82
-0.887
0.0
302.75
26.90
12.057
71.60
71.48
-0.168
0.0
298.45
30.60
13.399
77.00
77.01
0.013
0.0
302.55
32.30
13.577
78.70
78.39
-0.394
0.0
302.35
38.60
14.970
86.30
85.64
-0.765
0.0
298.65
40.70
15.577
89.00
88.66
-0.382
0.0
302.35
45.40
16.155
93.80
92.73
-1.141
0.0
298.75
50.90
17.140
99.70
98.92
-0.782
0.0
302.25
51.40
17.024
99.90
98.57
-1.331
0.0
302.05
58.20
17.868
106.60
104.83
-1.660
0.0
298.65
60.90
18.329
108.80
108.07
-0.671
0.0
301.75
69.00
18.982
115.90
114.12
-1.536
0.0
298.65
71.50
19.345
118.40
117.02
-1.166
0.0
301.65
78.50
19.793
123.20
121.75
-1.177
0.0
298.65
82.10
20.196
126.80
125.41
-1.096
0.0
301.45
87.00
20.431
129.50
128.30
-0.927
0.0
298.55
93.90
21.008
134.40
134.28
-0.089
0.0
301.25
95.90
21.027
136.40
134.89
-1.107
0.0
298.45
101.70
21.485
141.10
139.92
-0.836
0.0
301.15
103.60
21.491
141.90
140.40
-1.057
0.0
301.15
106.90
21.677
143.50
142.70
-0.557
0.0
301.35
116.20
22.161
150.60
148.98
-1.076
0.0
368.85
0.10
0.033
45.10
44.79
-0.687
0.0
368.75
1.10
0.362
45.60
45.30
-0.658
0.0
368.75
4.80
1.615
47.50
47.51
0.021
0.0
369.05
10.20
3.511
52.00
51.64
-0.692
0.0
369.25
20.60
7.065
61.90
61.85
-0.081
0.0
368.85
31.00
10.047
72.00
72.49
0.681
0.0
368.65
41.80
12.409
81.90
82.34
0.537
0.0
368.55
51.40
14.028
90.00
90.18
0.200
0.0
368.75
60.90
15.311
97.20
97.36
0.165
0.0
368.75
71.60
16.509
105.10
104.96
-0.133
0.0
368.75
81.50
17.442
112.00
111.63
-0.330
0.0
233
Data from Le Neindre et al. [81] (continued)
T P p A.exp A,cal Dev Wt
K MPa mol-dm'3 mW-m'^-K'^ %
368.55
92.10
18.311
119.20
118.50
-0.587
0.0
368.35
102.30
19.045
125.20
124.87
-0.264
0.0
407.95
0.10
0.029
51.40
51.38
-0.039
0.0
407.65
3.30
0.986
53.00
52.90
-0.189
0.0
406.85
10.50
3.191
58.00
57.21
-1.362
0.0
406.25
17.60
5.332
63.30
62.60
-1.106
0.0
405.85
24.30
7.207
68.70
68.28
-0.611
0.0
405.65
30.80
8.828
74.00
73.84
-0.216
0.0
406.65
38.50
10.453
80.70
80.18
-0.644
0.0
406.15
45.40
11.736
86.00
85.43
-0.663
0.0
405.65
52.50
12.879
91.30
90.53
-0.843
0.0
405.15
59.50
13.862
96.30
95.33
-1.007
0.0
404.35
67.20
14.820
101.80
100.38
-1.395
0.0
403.75
77.30
15.895
108.20
106.75
-1.340
0.0
402.85
83.30
16.479
112.00
110.43
-1.402
0.0
404.25
95.90
17.468
119.50
117.78
-1.439
0.0
404.25
104.50
18.088
124.30
122.66
-1.319
0.0
404.35
114.70
18.749
130.20
128.30
-1.459
0.0
420.25
0.14
0.040
53.90
53.56
-0.631
0.0
420.25
1.00
0.287
54.40
53.95
-0.827
0.0
420.45
5.00
1.450
56.30
55.99
-0.551
0.0
420.55
10.20
2.977
59.60
59.11
-0.822
0.0
420.45
20.60
5.918
67.10
66.76
-0.507
0.0
420.35
31.00
8.487
75.10
75.12
0.027
0.0
420.25
40.80
10.492
82.50
82.65
0.182
0.0
420.25
51.30
12.245
90.00
90.09
0.100
0.0
420.25
60.90
13.569
96.60
96.42
-0.186
0.0
420.15
71.40
14.791
104.00
102.95
-1.010
0.0
420.05
81.60
15.804
110.00
109.00
-0.909
0.0
419.95
92.10
16.710
116.50
115.00
-1.288
0.0
419.85
101.70
17.442
121.40
120.31
-0.898
0.0
465.55
0.14
0.036
62.30
61.81
-0.787
0.0
465.55
1.00
0.259
62.80
62.16
-1.019
0.0
465.55
5.00
1.297
64.20
63.91
-0.452
0.0
466.05
10.20
2.638
67.00
66.64
-0.537
0.0
234
Data from Le Neindre et al, [81] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm'^ mW-ra'^-K"^ %
465.85 20.80 5.257 73.20 73.02 -0.246 0.0
465.65 30.80 7.460 79.60 79.68 0.101 0.0
465.55 40.80 9.350 86.10 86.29 0.221 0.0
465.45 51.10 10.996 92.30 92.74 0.477 0.0
465.35 60.80 12.312 98.20 98.45 0.255 0.0
465.25 71.00 13.501 104.20 104.14 -0.058 0.0
465.15 81.70 14.578 110.20 109.85 -0.318 0.0
465.15 92.20 15.500 116.10 115.25 -0.732 0.0
464.95 102.50 16.305 121.30 120.39 -0.750 0.0
483.25 0.55 0.137 65.20 65.29 0.138 0.0
486.85 1.20 0.297 66.40 66.23 -0.256 0.0
483.15 3.40 0.848 66.60 66.43 -0.255 0.0
486.55 6.80 1.681 69.10 68.57 -0.767 0.0
482.85 7.30 1.819 68.60 68.13 -0.685 0.0
482.65 11.80 2.927 70.80 70.37 -0.607 0.0
487.05 15.10 3.682 73.50 72.92 -0.789 0.0
486.65 21.60 5.169 77.20 76.66 -0.699 0.0
485.25 28.40 6.632 81.10 80.67 -0.530 0.0
484.85 35.90 8.083 85.60 85.33 -0.315 0.0
484.55 42.70 9.264 89.80 89.48 -0.356 0.0
484.35 54.10 10.980 96.30 96.16 -0.145 0.0
484.35 55.10 11.116 96.80 96.73 -0.072 0.0
484.05 65.70 12.449 102.50 102.53 0.029 0.0
483.95 70.60 12.999 105.20 105.12 -0.076 0.0
483.95 72.60 13.213 106.30 106.17 -0.122 0.0
483.75 75.50 13.517 107.80 107.65 -0.139 0.0
483.65 79.40 13.905 109.90 109.64 -0.237 0.0
483.55 84.30 14.365 112.50 112.09 -0.364 0.0
483.55 87.30 14.633 114.20 113.58 -0.543 0.0
483.45 95.10 15.288 118.30 117.38 -0.778 0.0
483.45 104.90 16.033 122.90 122.05 -0.692 0.0
483.45 109.80 16.378 125.10 124.34 -0.608 0.0
483.65 112.80 16.577 125.40 125.74 0.271 0.0
523.35 0.14 0.032 73.20 72.82 -0.519 0.0
523.35 1.00 0.230 73.70 73.13 -0.773 0.0
235
Data from Le Neindre et al. [81] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol.dm'3 mW-m'^-K'^ %
523.25
5.00
1.145
74.70
74.63
-0.094
0.0
523.25
10.40
2.363
76.80
76.94
0.182
0.0
523.15
20.40
4.512
81.60
81.87
0.331
0.0
523.05
30.70
6.515
87.00
87.48
0.552
0.0
522.95
40.80
8.242
92.20
93.08
0.954
0.0
522.85
50.90
9.745
97.70
98.52
0.839
0.0
522.65
60.70
11.019
102.90
103.56
0.641
0.0
522.65
71.40
12.228
108.30
108.83
0.489
0.0
522.55
82.40
13.316
114.00
114.00
0.000
0.0
522.45
94.90
14.397
120.20
119.66
-0.449
0.0
571.85
0.10
0.021
82.80
82.29
-0.616
0.0
571.65
5.30
1.106
85.30
84.02
-1.501
0.0
571.45
10.50
2.168
87.30
85.96
-1.535
0.0
571.35
20.70
4.147
91.60
90.35
-1.365
0.0
571.15
30.30
5.850
95.90
94.85
-1.095
0.0
570.85
40.50
7.472
100.60
99.77
-0.825
0.0
570.85
50.90
8.928
105.40
104.77
-0.598
0.0
570.65
60.50
10.120
109.80
109.21
-0.537
0.0
570.55
72.60
11.438
115.20
114.59
-0.530
0.0
570.45
83.70
12.499
120.00
119.33
-0.558
0.0
570.35
95.40
13.490
125.20
124.15
-0.839
0.0
570.25
107.90
14.431
130.40
129.14
-0.966
0.0
570.15
117.40
15.078
134.30
132.84
-1.087
0.0
570.05
124.70
15.542
137.50
135.63
-1.360
0.0
575.75
0.10
0.021
84.60
83.06
-1.820
0.0
575.75
1.00
0.209
85.20
83.35
-2.171
0.0
575.75
5.10
1.057
86.10
84.74
-1.580
0.0
575.35
10.10
2.072
87.40
86.54
-0.984
0.0
575.65
20.50
4.077
91.80
91.02
-0.850
0.0
575.55
30.60
5.852
96.20
95.72
-0.499
0.0
575.45
40.80
7.455
100.70
100.61
-0.089
0.0
575.35
50.70
8.833
105.50
105.30
-0.190
0.0
575.35
60.60
10.054
110.30
109.86
-0.399
0.0
575.25
69.20
11.005
114.20
113.68
-0.455
0.0
575.25
80.60
12.130
119.10
118.57
-0.445
0.0
236
Data from Le Neindre et al. [81] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm'3 mW-m'^-K'^ %
575.15
91.60
13.094
123.80
123.10
-0.565
0.0
575.05
103.50
14.024
129.00
127.86
-0.884
0.0
621.45
0.14
0.027
94.00
92.09
-2.032
0.0
621.45
1.00
0.193
94.50
92.35
-2.275
0.0
621.45
5.00
0.958
95.40
93.59
-1.897
0.0
621.45
10.20
1.929
96.80
95.36
-1.488
0.0
621.25
20.30
3.722
100.20
99.15
-1.048
0.0
621.25
30.50
5.382
104.00
103.38
-0.596
0.0
621.15
40.50
6.852
108.40
107.66
-0.683
0.0
621.05
50.70
8.195
112.30
112.02
-0.249
0.0
620.95
60.90
9.395
116.70
116.28
-0.360
0.0
620.95
68.40
10.196
119.90
119.34
-0.467
0.0
620.95
81.40
11.442
125.40
124.48
-0.734
0.0
620.95
92.10
12.354
129.40
128.55
-0.657
0.0
620.75
102.20
13.139
133.10
132.27
-0.624
0.0
648.65
0.50
0.093
98.70
97.57
-1.145
0.0
648.55
3.40
0.626
100.50
98.39
-2.100
0.0
648.45
7.00
1.277
101.80
99.49
-2.269
0.0
648.45
11.20
2.021
103.10
100.87
-2.163
0.0
648.25
21.10
3.689
106.20
104.40
-1.695
0.0
648.15
30.50
5.150
109.70
108.05
-1.504
0.0
647.95
40.70
6.592
113.40
112.13
-1.120
0.0
647.95
50.30
7.816
117.30
116.02
-1.091
0.0
647.85
59.40
8.868
120.60
119.64
-0.796
0.0
647.75
71.60
10.132
125.10
124.35
-0.600
0.0
647.65
83.20
11.200
129.30
128.68
-0.480
0.0
647.65
95.10
12.179
134.30
132.99
-0.975
0.0
647.75
117.10
13.741
141.50
140.64
-0.608
0.0
647.85
119.40
13.887
142.30
141.43
-0.611
0.0
648.05
121.10
13.992
142.50
142.03
-0.330
0.0
726.55
1.00
0.165
114.50
113.00
-1.310
0.0
726.45
3.60
0.590
115.30
113.65
-1.431
0.0
725.15
40.10
5.822
126.10
125.00
-0.872
0.0
725.05
50.70
7.060
128.90
128.67
-0.178
0.0
725.15
60.80
8.131
131.30
132.18
0.670
0.0
725.25
72.00
9.207
134.80
136.00
0.890
0.0
725.45
81.00
9.996
137.90
139.01
0.805
0.0
725.75
89.00
10.646
141.70
141.65
-0.035
0.0
237
Data from Le Neindre et al. [81] (continued)
Number of Points (Ref. 81) 193
AAD-% 0.778 BIAS-% -0.677 RMS-% 0.664
AAD 0.735 BIAS -0.632 RMS 0. 657 mW-m'^ -K" ^
Data from Mardolcar and de Castro [91]
T P p A.exp A.cal Dev Wt
K MPa mol-dra"3 mW-m'^-K'^ %
110.868
0.204
26.414
184.60
185.17
0.309
9.7
111.002
1.100
26.453
185.59
185.97
0.205
9.7
110.971
2.236
26.521
187.00
187.26
0.139
9.7
111.202
3.270
26.558
188.06
188.07
0.005
9.7
111.024
4.269
26.628
189.03
189.37
0.180
9.6
110.897
5.269
26.692
190.10
190.60
0.263
9.6
111.038
6.337
26.737
191.04
191.53
0.256
9.6
110.718
7.404
26.819
192.55
193.06
0.265
9.6
110.952
8.645
26.862
194.09
194.02
-0.036
9.5
124.806
0.721
25.129
164.41
165.97
0.949
10.1
124.985
1.755
25.190
166.20
167.05
0.511
10.1
125.059
2.719
25.254
167.39
168.18
0.472
10.1
125.034
3.822
25.336
168.97
169.60
0.373
10.0
124.867
4.924
25.429
170.41
171.18
0.452
10.0
125.196
5.957
25.469
172.13
171.99
-0.081
10.0
124.728
7.060
25.586
173.44
173.94
0.288
9.9
124.784
8.369
25.666
175.10
175.40
0.171
9.9
155.480
1.514
21.634
122.11
121.93
-0.147
11.3
155.251
2.306
21.810
122.85
123.98
0.920
11.3
154.953
2.891
21.950
125.47
125.62
0.120
11.2
155.192
3.374
21.997
125.94
126.23
0.230
11.2
154.969
4.132
22.145
127.52
128.01
0.384
11.1
155.034
4.924
22.255
129.08
129.40
0.248
11.1
155.285
5.648
22.328
130.18
130.36
0.138
11.0
154.726
6.302
22.484
131.09
132.28
0.908
11.0
154.995
7.129
22.562
132.64
133.33
0.520
11.0
154.598
7.887
22.702
134.03
135.11
0.806
10.9
155.167
8.576
22.724
135.51
135.50
-0.007
10.9
180.336
3.753
17.485
89.69
87.39
-2.564
12.5
180.509
4.132
17.703
91.15
88.90
-2.468
12.5
238
Data from Mardolcar and de Castro [91] (continued)
T P p A , exp A , cal
K MPa mol-dni"3 mW-m'^-K'^
180.132
180.172
180.255
180.139
180.058
179.989
179.905
4,
.580
18,
.070
5,
.027
18,
.290
5,
.578
18,
.523
6,
.095
18,
.756
6,
.784
19,
.019
7,
.335
19,
.211
8.
.231
19,
.487
Number of Points (Ref. 91) 37
AAD-%
AAD
0.485
0.602
BIAS-%
BIAS
93.03
93.96
95.12
97.01
99.01
100.49
102.61
0.045
0.192
91.49
93.16
94.98
96.84
99.03
100.67
103.12
RMS-% 0.763
RMS 0.801 mW-m'^ -K'^
Dev
Wt
%
1.655
12.4
0.851
12.4
0.147
12.4
0.175
12.3
0.020
12.2
0.179
12.2
0.497
12.1
Data from
Prasad et al
. [92]
T
P
P
A, exp
A, cal
Dev
Wt
K
MPa
mol-dm"^
mW • ra" ^
•K-i
%
139.920
59.998
27.104
204.88
208.52
1.777
0.0
140.070
59.998
27.095
204.70
208.36
1.788
0.0
139.950
50.001
26.696
196.45
199.67
1.639
0.0
139.970
50.001
26.694
195.83
199.65
1.951
0.0
140.000
40.004
26.240
187.30
190.31
1.607
0.0
140.010
40.004
26.239
187.37
190.30
1.564
0.0
140.090
30.006
25.720
176.87
180.25
1.911
0.0
140.000
30.006
15.111
177.60
180.35
1.548
0.0
120.080
10.004
26.171
179.56
183.48
2.183
0.0
120.010
10.004
26.177
179.65
183.57
2.182
0.0
120.080
10.004
26.171
179.74
183.48
2.081
0.0
119.900
20.002
26.713
190.16
194.09
2.067
0.0
119.890
20.002
26.713
190.80
194.10
1.730
0.0
120.040
29.999
27.160
199.96
203.48
1.760
0.0
119.910
29.999
27.169
200.32
203.63
1.652
0.0
119.940
40.004
27.575
208.87
212.56
1.767
0.0
119.860
40.004
27.580
209.33
212.65
1.586
0.0
121.010
50.001
11 .Zll
212.99
219.91
3.249
0.0
139.900
20.002
25.136
166.86
169.61
1.648
0.0
139.930
20.002
25.134
166.32
169.58
1.960
0.0
239
Data from Prasad et al. [92] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm'3 mW-mx'^-K"^ %
139.890
10.004
24.408
154.05
157.42
2.188
0.0
139.890
10.004
24.408
154.20
157.42
2.088
0.0
139.890
10.004
24.408
153.85
157.42
2.320
0.0
139.920
4.999
23.962
147.09
150.46
2.291
0.0
139.900
4.999
23.964
147.19
150.49
2.242
0.0
139.950
2.496
23.707
143.24
146.66
2.388
0.0
139.950
2.496
23.707
143.39
146.66
2.280
0.0
159.930
2.496
21.172
115.33
117.32
1.725
0.0
159.940
2.496
21.170
115.08
117.30
1.929
0.0
159.900
20.002
23.447
143.77
146.36
1.801
0.0
159.890
20.002
23.448
143.74
146.37
1.830
0.0
159.960
29.999
24.237
156.17
158.49
1.486
0.0
159.980
29.999
24.236
155.82
158.47
1.701
0.0
159.980
10.004
22.375
129.31
131.69
1.841
0.0
159.980
10.004
22.375
129.16
131.69
1.959
0.0
159.980
4.999
21.638
120.29
122.64
1.954
0.0
160.010
4.999
21.634
119.94
122.60
2.218
0.0
160.040
2.496
21.155
115.18
117.15
1.710
0.0
160.000
2.496
21.161
114.93
117.21
1.984
0.0
160.000
40.004
24.884
166.74
169.33
1.553
0.0
160.000
40 . 004
24.884
166.64
169.33
1.614
0.0
160.000
49.994
25.438
176.81
179.32
1.420
0.0
159.950
49.994
25.441
176.98
179.37
1.350
0.0
159.980
59.998
25.925
185.53
188.69
1.703
0.0
159.970
59.998
25.926
185.80
188.70
1.561
0.0
160.050
69.996
26.357
193.60
197.48
2.004
0.0
159.940
69.996
26.363
194.17
197.59
1.761
0.0
179.960
69.996
25.262
176.98
179.87
1.633
0.0
180.000
69.996
25.260
177.06
179.84
1.570
0.0
179.910
59.998
24.758
168.28
170.76
1.474
0.0
179.960
50.001
24.178
158.37
160.98
1.648
0.0
179.920
40.004
23.506
148.17
150.48
1.559
0.0
179.950
29.999
22.681
136.53
138.74
1.619
0.0
180.000
20.002
21.598
122.91
125.06
1.749
0.0
179.980
20.002
21.600
122.79
125.08
1.865
0.0
240
Data from Prasad et al. [92] (continued)
T P ^ A,exp A.cal Dev Wt
K MPa mol-dm'3 mW-m'^-K"^ %
179.980
9.997
19.923
106.00
107.18
1.113
0.0
179.980
9.997
19.923
105.83
107.18
1.276
0.0
179.980
4.999
18.320
93.92
93.36
-0.596
0.0
179.990
4.999
18.318
94.16
93.34
-0.871
0.0
199.990
69.996
24.174
161.18
164.15
1.843
0.0
200.010
59.998
23.588
152.39
154.82
1.595
0.0
200.010
59.998
23.588
152.44
154.82
1.561
0.0
200.010
50.001
22.909
142.54
144.83
1.607
0.0
200.000
40.004
22.093
131.59
133.90
1.755
0.0
199.990
29.999
21.054
119.76
121.52
1.470
0.0
199.990
20.002
19.575
104.91
106.48
1.497
0.0
200.000
10.004
16.597
84.95
84.07
-1.036
0.0
199.990
10.004
16.599
84.65
84.08
-0.673
0.0
199.990
4.999
5.458
40.15
40.35
0.498
0.0
220.020
69.996
23.105
147.79
150.52
1.847
0.0
220.000
69.996
23.106
147.89
150.53
1.785
0.0
220.050
59.998
22.436
139.11
141.15
1.466
0.0
220.010
50.001
21.648
128.97
131.08
1.636
0.0
220.050
40.004
20.670
118.07
119.89
1.541
0.0
220.110
29.999
19.367
105.42
106.96
1.461
0.0
220.000
20.002
17.358
89.67
90.80
1.260
0.0
220.030
9.997
11.685
66.15
63.42
-4.127
0.0
240.020
69.996
22.063
137.42
138.98
1.135
0.0
240.060
59.998
21.308
128.56
129.68
0.871
0.0
240.000
50.001
20.407
118.30
119.66
1.150
0.0
240.000
40.004
19.264
106.96
108.47
1.412
0.0
240.000
29.999
17.684
94.38
95.42
1.102
0.0
240.060
20.002
15.039
78.35
78.67
0.408
0.0
260.030
69.996
21.051
128.14
129.39
0.975
0.0
260.000
59.998
20.217
119.20
120.31
0.931
0.0
260.000
50.001
19.200
109.25
110.44
1.089
0.0
260.030
40.004
17.889
98.59
99.43
0.852
0.0
260.050
30.006
16.034
86.20
86.59
0.452
0.0
300.180
69.996
19.143
114.95
115.36
0.357
0.0
299.330
69.996
19.182
115.72
115.60
-0.104
0.0
241
Data from Prasad et al. [92] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm'3 mW-m'^-K'^ %
300.070
69.996
19.148
114.75
115.39
0.558
0.0
300.080
69.996
19.148
114.55
115.39
0.733
0.0
300.000
59.998
18.167
106.00
106.93
0.877
0.0
300.010
59.998
18.167
106.39
106.93
0.508
0.0
300.000
49.994
16.952
97.09
97.76
0.690
0.0
300.030
49.994
16.950
97.22
97.75
0.545
0.0
300.030
40.004
15.370
86.59
87.62
1.190
0.0
300.050
40.004
15.369
86.64
87.62
1.131
0.0
299.970
29.999
13.141
74.99
75.98
1.320
0.0
299.970
29.999
13.141
75.09
75.98
1.185
0.0
299.960
20.002
9.675
60.81
61.56
1.233
0.0
300.040
20.002
9.670
61.01
61.55
0.885
0.0
300.000
9.997
4.686
43.04
44.56
3.532
0.0
299.930
9.997
4.688
43.14
44.56
3.292
0.0
300.240
4.999
2.179
35.13
38.35
9.166
0.0
299.660
4.999
2.184
35.33
38.28
8.350
0.0
299.870
4.999
2.182
35.73
38.30
7.193
0.0
300.000
4.999
2.181
35.81
38.32
7.009
0.0
320.020
69.996
18.271
110.32
110.64
0.290
0.0
320.070
69.996
18.269
110.47
110.63
0.145
0.0
320.000
59.998
17.227
101.51
102.54
1.015
0.0
319.950
59.998
17.229
101.96
102.55
0.579
0.0
319.950
50.001
15.941
92.80
93.83
1.110
0.0
319.940
50.001
15.941
92.60
93.83
1.328
0.0
319.980
40.004
14.271
83.05
84.24
1.433
0.0
319.980
40.004
14.271
82.90
84.24
1.616
0.0
319.960
29.999
11.964
72.75
73.30
0.756
0.0
319.980
29.999
11.963
71.86
73.30
2.004
0.0
320.060
20.002
8.610
59.19
60.10
1.537
0.0
320.040
20.002
8.611
59.19
60.11
1.554
0.0
319.980
10.004
4.220
44.92
46.00
2.404
0.0
320.000
10.004
4.219
44.79
46.00
2.701
0.0
339.800
69.996
17.451
106.60
107.14
0.507
0.0
339.960
10.004
3.854
47.18
47.96
1.653
0.0
339.980
10.004
3.854
47.67
47.97
0.629
0.0
242
Data from Prasad et al. [92] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm'3 mW-m'^-K'^ %
340.000
10.004
3.853
47.67
47.97
0.629
0.0
340.050
69.996
17.441
106.05
107.10
0.990
0.0
340.020
69.996
17.442
105.66
107.11
1.372
0.0
340.000
59.998
16.349
98.53
99.40
0.883
0.0
340.020
59.998
16.348
98.39
99.40
1.027
0.0
339.980
50.001
15.006
90.13
91.14
1.121
0.0
339.960
40.004
13.284
81.33
82.11
0.959
0.0
339.950
29.999
10.967
71.26
71.87
0.856
0.0
340.230
20.002
7.782
58.67
59.93
2.148
0.0
400.150
69.996
15.264
102.24
102.25
0.010
0.0
400.070
59.998
14.092
95.35
95.67
0.336
0.0
399.990
50.001
12.685
87.89
88.67
0.887
0.0
399.950
40.004
10.956
79.47
81.10
2.051
0.0
399.920
29.999
8.799
71.29
72.78
2.090
0.0
399.880
20.002
6.150
63.87
63.93
0.094
0.0
399.890
10.004
3.105
54.03
55.81
3.294
0.0
379.920
69.996
15.945
102.25
103.07
0.802
0.0
379.970
59.998
14.786
95.98
96.13
0.156
0.0
379.980
50.001
13.383
88.08
88.74
0.749
0.0
380.030
40.004
11.635
79.98
80.71
0.913
0.0
379.970
40.004
11.637
79.93
80.71
0.976
0.0
379.990
30.006
9.410
71.16
71.80
0.899
0.0
380.090
20.002
6.594
61.76
62.06
0.486
0.0
379.910
10.004
3.313
52.97
52.94
-0.057
0.0
359.900
69.996
16.670
104.39
104.65
0.249
0.0
357.900
69.996
16.746
104.54
104.85
0.297
0.0
359.890
59.998
15.540
96.62
97.33
0.735
0.0
359.890
50.001
14.159
89.34
89.52
0.201
0.0
359.900
40.004
12.412
80.52
81.00
0.596
0.0
359.890
30.006
10.129
70.68
71.44
1.075
0.0
359.910
20.002
7.136
60.69
60.65
-0.066
0.0
359.940
20.002
7.135
60.69
60.65
-0.066
0.0
359.940
10.011
3.561
50.07
50.31
0.479
0.0
260.580
69.996
21.024
129.47
129.15
-0.247
0.0
260.510
59.998
20.190
119.32
120.09
0.645
0.0
243
Data from Prasad et al. [92] (continued)
T ? p A.exp A.cal
K MPa inol-dm"3 mW-m'^-K'^
260.480
260.530
260.570
260.710
260.900
261.150
261.170
261.690
261.930
277.150
277.310
277.430
277.720
277.980
278.280
278.520
279.190
279.510
279.630
279.990
Number of Points (Ref.92) 180
50
.001
19,
.171
40
.004
17,
.855
29
.999
15,
.991
20
.009
12,
.803
15
.003
10,
.005
20
.009
12,
.759
9
.997
6,
.215
4,
.999
2,
.666
4,
.999
2.
.662
69
.996
20,
.216
59,
.998
19,
.305
49,
.994
18,
.188
40.
.004
16,
,729
29,
.999
14,
,651
20,
.002
11.
,202
15,
.003
8,
,531
9,
.997
5,
,358
5,
.006
2.
,413
5,
.013
2,
.416
9,
.997
5.
,327
109.35
98.79
86.61
71.73
60.45
70.62
46.18
32.65
32.45
122.16
113.22
103.41
93.36
81.06
65.16
55.87
44.47
35.72
35.72
44.61
110.24
99.23
86.38
70.01
58.81
69.86
44.83
34.40
34.43
122.61
113.69
104 . 04
93.27
80.80
65.11
54.89
43.97
36.08
36.10
43.97
Dev
%
0.814
0.445
-0.266
-2.398
-2.713
-1.076
-2.923
5.360
6.102
0.368
0.415
0.609
-0.096
-0.321
-0.077
-1.754
-1.124
1.008
1.064
-1.435
Wt
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
AAD-%
AAD
1.525
1.633
BIAS-%
BIAS
1.280
1.474
RMS-%
RMS
1.547
1.383 mW-m"i
K
-1
Data from
Roder [8]
T
P
P
A ,exp
A.cal
Dev
Wt
K
MPa
mol'dm""'
mW • m" ^
•K-i
%
111.827
0.561
26.348
184.27
184.23
-0.022
9.7
111.655
0.556
26.363
184.76
184.46
-0.162
9.7
111.255
0.551
26.399
184.75
185.02
0.146
9.7
110.983
0.546
26.423
185.12
185.39
0.146
9.7
111.762
11.644
26.945
196.81
195.99
-0.417
9.5
244
Data from Roder [8] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-din'3
111.363
111.215
110.985
111.768
111.688
111.301
111.173
111.613
111.472
111.231
110.997
111.508
111.347
111.101
110.863
111.433
111.181
110.963
110.745
111.218
111.104
110.894
110.631
134.645
134.119
133.606
133.127
135.369
135.054
134.663
134.383
135.395
135.072
134.724
134.433
11
.641
26
.976
11
.635
26
.988
11
.630
27
.006
22
.698
27
.445
22
.693
27
.450
22
.688
27
.479
22
682
27
.488
34
119
27
.909
34
117
27
.918
34
112
27
935
34
109
27
950
44
939
28
301
44
932
28
311
44
926
28
326
44
920
28
341
56
744
28
687
56
740
28
702
56
735
28
715
56
726
28
728
68
635
29
052
68
639
29
058
68
647
29
070
68
659
29
086
316
303
316
304
315
305
314
305
778
24
035
772
24
069
761
24
110
745
24
139
11
718
24
951
11.
715
24
980
11.
709
25
010
11.
694
25
035
X,i
-xp
A,<
:al
mW • m" ^
•K-i
196
.79
196
.50
197
.54
196
.68
197
.58
196
.97
207
.04
206
.53
207
.62
206
.62
207
.75
207
.07
208
.46
207
.22
216
.81
216
.80
217
.79
216
.96
217
61
217
.22
217
96
217
.48
225
69
225
92
226
02
226
09
226
24
226
.34
226
67
226
.59
234
94
235
35
235
17
235
60
235
42
235
81
235
54
236
03
243
25
244
57
243
68
244
68
243
81
244
88
244
05
245
15
14
83
14
60
14
75
14
54
14
75
14
49
14
71
14
44
151
36
150
68
151
81
151
13
152
03
151
69
152
45
152
07
166
43
165
43
166
87
165
84
167
08
166
28
167.
55
166.
64
0.147
9.5
0.435
9.5
0.309
9.5
0.246
9.3
0.482
9.3
0.327
9.3
0.595
9.3
0.005
9.2
0.381
9.2
0.179
9.2
0.220
9.2
0.102
9.1
0.031
9.0
0.044
9.0
0.035
9.0
0.175
8.9
0.183
8.9
0.166
8.9
0.208
8.9
0.543
8.8
0.410
8.8
0.439
8.8
0.451
8.8
1.551
14.7
1.424
14.9
1.763
14.4
1.835
14.3
0.449
10.4
0.448
10.4
0.224
10.4
0.249
10.4
0.601
10.1
0.617
10.1
0.479
10.1
0.543
10.1
245
Data from Roder [8] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm'3 mW-m'^-K'^ %
135.255 22.964 25.687 179.51 178.46
134.855 22.963 25.718 180.09 178.94
134.596 22.961 25.738 179.96 179.24
134.300 22.959 25.760 180.38 179.60
135.304 34.181 26.279 190.82 189.87
134.983 34.180 26.302 191.06 190.24
134.717 34.177 26.320 191.53 190.53
134.482 34.172 26.336 191.75 190.79
135.055 45.585 26.817 201.44 200.89
134.801 45.577 26.833 201.70 201.15
134.607 45.574 26.846 202.24 201.36
134.390 45.564 26.859 202.25 201.59
135.242 56.761 27.257 210.85 210.56
134.920 56.753 27.276 211.14 210.89
134.722 56.743 27.288 211.86 211.08
134.408 56.735 27.306 211.76 211.41
135.053 67.925 27.675 219.96 220.11
134.764 67.926 27.692 220.06 220.41
134.496 67.926 27.707 220.36 220.68
134.259 67.928 27.720 220.67 220.92
145.151 0.357 0.315 15.97 15.80
144.549 0.357 0.317 15.90 15.74
144.034 0.357 0.318 15.84 15.68
143.587 0.357 0.319 15.84 15.64
144.746 0.650 0.612 16.58 16.58
144.258 0.650 0.615 16.59 16.54
143.690 0.650 0.619 16.60 16.50
143.403 0.650 0.620 16.52 16.48
154.710 0.429 0.355 17.08 16.99
154.129 0.429 0.357 17.17 16.93
153.687 0.429 0.358 16.97 16.88
153.161 0.429 0.359 16.91 16.82
155.000 0.731 0.635 17.81 17.70
154.460 0.731 0.638 17.73 17.66
153.983 0.731 0.641 17.71 17.61
0.585
9.8
0.639
9.8
0.400
9.8
0.432
9.8
0.498
9.6
0.429
9.6
0.522
9.6
0.501
9.6
0.273
9.4
0.273
9.4
0.435
9.4
0.326
9.4
0.138
9.3
0.118
9.3
0.368
9.3
0.165
9.3
0.068
9.1
0.159
9.1
0.145
9.1
0.113
9.1
1.064
16.1
1.006
16.1
1.010
16.1
1.263
15.6
0.000
16.7
0.301
16.3
0.602
15.9
0.242
16.2
0.527
17.5
1.398
15.9
0.530
17.5
0.532
17.5
0.618
17.0
0.395
17.1
0.565
17.0
246
Data from Roder [8] (continued)
T
P
P
A.exp
A.cal
Dev
Wt
K
MPa
mol -dm" •'
mW • m" -^
•K-i
%
153.493
0.731
0.644
17.62
17.57
-0.284
17.2
154.611
1.082
1.014
18.76
18.80
0.213
16.6
154.165
1.082
1.019
18.66
18.78
0.643
16.9
153.622
1.082
1.025
18.64
18.76
0.644
16.8
153.277
1.082
1.029
18.52
18.75
1.242
17.1
155.515
1.600
21.645
121.79
122.07
0.230
11.3
155.080
1.599
21.707
122.60
122.73
0.106
11.3
154.711
1.598
21.759
123.06
123.30
0.195
11.3
154.339
1.595
21.811
123.44
123.86
0.340
11.2
155.315
6.757
22.476
131.93
132.27
0.258
11.0
154.878
6.755
22.527
132.63
132.85
0.166
11.0
154.565
6.754
22.562
132.94
133.27
0.248
11.0
154.223
6.757
22.602
133.18
133.73
0.413
11.0
155.484
14.577
23.343
143.99
144.11
0.083
10.7
155.132
14.576
23.376
144.44
144.53
0.062
10.6
154.797
14.575
23.408
144.87
144.92
0.035
10.6
154.491
14.579
23.437
145.20
145.30
0.069
10.6
155.595
25.316
24.239
157.93
157.73
-0.127
10.3
155.239
25.314
24.267
158.29
158.11
-0.114
10.3
154.966
25.310
24.289
158.67
158.41
-0.164
10.3
154.586
25.318
24.319
158.89
158.84
-0.031
10.3
155.724
36.001
24.941
169.52
169.51
-0.006
10.1
155.402
36.001
24.964
169.96
169.84
-0.071
10.0
154.976
35.997
24.994
170.56
170.28
-0.164
10.0
154.755
35.978
25.009
170.93
170.49
-0.257
10.0
155.563
46.637
25.547
180.80
180.44
-0.199
9.8
155.228
46.631
25.568
180.94
180.77
-0.094
9.8
154.890
46.626
25.589
181.48
181.11
-0.204
9.8
154.570
46.626
25.610
181.85
181.43
-0.231
9.8
155.419
56.930
26.055
190.60
190.28
-0.168
9.6
154.980
56.927
26.081
190.79
190.71
-0.042
9.6
154.681
56.921
26.099
191.18
190.99
-0.099
9.6
154.420
56.919
26.115
191.54
191.25
-0.151
9.6
155.151
67.027
26.508
199.46
199.53
0.035
9.5
154.884
67.028
26.523
199.42
199.78
0.181
9.5
247
Data from Roder [8] (continued)
T
P
P
A,exp
A.cal
Dev
Wt
K
MPa
mol -dm"^
mW • m' ^
•K-i
%
154.564
67.035
26.541
200.13
200.10
-0.015
9.5
154.234
67.043
26.560
200.37
200.42
0.025
9.5
165.249
0.446
0.342
18.21
18.19
-0.110
19.0
164.627
0.446
0.344
18.11
18.12
0.055
19.5
164.008
0.446
0.345
18.07
18.05
-0.111
19.0
163.654
0.446
0.346
18.03
18.01
-0.111
19.0
164.789
0.935
0.771
19.12
19.11
-0.052
18.1
164.336
0.935
0.774
19.12
19.07
-0.262
17.8
163.737
0.935
0.778
19.03
19.02
-0.053
18.0
163.372
0.935
0.781
18.91
18.98
0.370
18.5
164.151
1.657
1.578
21.41
21.53
0.560
16.7
163.770
1.657
1.587
21.44
21.53
0.420
16.5
163.435
1.657
1.594
21.47
21.54
0.326
16.4
163.111
1.657
1.601
21.41
21.54
0.607
16.5
175.467
0.406
0.290
19.22
19.30
0.416
21.8
174.780
0.406
0.291
19.09
19.22
0.681
23.3
174.244
0.406
0.292
19.11
19.16
0.262
20.9
173.672
0.406
0.293
19.08
19.09
0.052
20.0
174.946
1.015
0.778
20.29
20.26
-0.148
18.7
174.370
1.015
0.782
20.15
20.21
0.298
19.2
173.887
1.015
0.785
20.15
20.16
0.050
18.8
173.424
1.015
0.788
20.10
20.11
0.050
18.8
174.393
1.751
1.500
22.07
22.12
0.227
17.8
173.984
1.751
1.507
22.03
22.10
0.318
17.8
173.504
1.751
1.515
22.16
22.08
-0.361
17.3
173.135
1.752
1.523
21.94
22.07
0.593
17.8
173.762
2.459
2.478
25.67
25.67
0.000
16.2
173.415
2.460
2.497
25.79
25.74
-0.194
16.1
173.064
2.461
2.516
25.85
25.82
-0.116
16.1
172.766
2.462
2.533
25.28
25.89
2.413
16.9
175.226
4.616
19.151
99.77
99.49
-0.281
12.1
174.785
4.616
19.236
100.43
100.18
-0.249
12.1
174.407
4.615
19.308
101.07
100.76
-0.307
12.1
174.021
4.616
19.381
101.29
101.35
0.059
12.1
175.360
12.710
21.033
117.36
117.96
0.511
11.5
248
Data from Roder [8] (continued)
T
P
P
A.exp
A,cal
Dev
Wt
K
MPa
mol-dm'^
mW • m" ^
•K-i
%
175.020
12.708
21.072
117.69
118.34
0.552
11.5
174.534
12.705
21.128
118.18
118.89
0.601
11.5
174.088
12.712
21.180
118.62
119.41
0.666
11.5
175.653
19.724
21.980
128.32
129.05
0.569
11.2
175.178
19.722
22.025
129.01
129.53
0.403
11.1
174.793
19.720
22.061
129.57
129.93
0.278
11.1
174.357
19.724
22.103
129.80
130.38
0.447
11.1
175.719
26.457
22.692
137.72
138.26
0.392
10.9
175.380
26.455
22.720
138.11
138.58
0.340
10.9
174.924
26.450
22.757
138.61
139.02
0.296
10.9
174.570
26.446
22.787
138.79
139.36
0.411
10.9
175.558
33.801
23.346
147.01
147.42
0.279
10.6
175.163
33.796
23.375
147.43
147.78
0.237
10.6
174.813
33.792
23.401
147.73
148.11
0.257
10.6
174.483
33.794
23.425
148.27
148.42
0.101
10.6
175.820
41.291
23.881
155.22
155.57
0.225
10.4
175.338
41.288
23.914
155.73
156.00
0.173
10.4
175.061
41.285
23.933
156.08
156.25
0.109
10.4
174.654
41.276
23.960
156.53
156.61
0.051
10.4
175.705
48.148
24.335
162.60
162.84
0.148
10.3
175.305
48.149
24.361
162.91
163.20
0.178
10.2
174.788
48.142
24.393
163.32
163.65
0.202
10.2
174.596
48.145
24.406
163.48
163.83
0.214
10.2
175.547
55.061
24.748
169.59
169.82
0.136
10.1
175.051
55.062
24.778
169.93
170.26
0.194
10.1
174.704
55.058
24.799
170.64
170.56
-0.047
10.1
174.439
55.051
24.815
170.91
170.79
-0.070
10.1
175.386
61.637
25.107
175.83
176.18
0.199
10.0
175.017
61.642
25.128
176.36
176.51
0.085
9.9
174.659
61.637
25.149
176.57
176.81
0.136
9.9
174.273
61.641
25.171
177.02
177.15
0.073
9.9
175.485
68.363
25.431
181.95
182.21
0.143
9.8
175.204
68.360
25.446
182.24
182.45
0.115
9.8
174.804
68.375
25.469
182.35
182.81
0.252
9.8
174.506
68.379
25.486
182.64
183.07
0.235
9.8
249
Data from Roder [8] (continued)
T P p A,exp A.cal Dev Wt
K MPa mol-dm"3 mW-m'^-K'^ %
185.421
0.752
0.520
20.72
20.96
1.158
23.4
184.903
0.752
0.522
20.77
20.90
0.626
21.4
184.371
0.752
0.524
20.79
20.84
0.241
20.3
183.963
0.752
0.525
20.11
20.79
3.381
44.7
185.602
1.507
1.124
22.16
22.33
0.767
20.0
185.087
1.508
1.130
22.09
22.28
0.860
20.0
184.516
1.508
1.135
22.06
22.23
0.771
19.8
184.171
1.508
1.138
21.51
22.19
3.161
23.4
185.078
2.252
1.856
24.16
24.28
0.497
18.6
184.541
2.251
1.866
23.97
24.25
1.168
19.0
184.292
2.252
1.872
23.74
24.25
2.148
19.6
183.844
2.252
1.882
24.07
24.23
0.665
18.5
184.688
2.884
2.664
26.94
27.11
0.631
17.7
184.300
2.884
2.681
26.99
27.14
0.556
17.6
183.918
2.884
2.697
26.92
27.18
0.966
17.7
183.674
2.885
2.710
27.23
27.21
-0.073
17.2
184.243
3.449
3.735
32.46
32.48
0.062
16.5
183.964
3.449
3.766
32.51
32.67
0.492
16.6
183.733
3.450
3.795
33.64
32.86
-2.319
15.7
183.486
3.450
3.825
34.04
33.06
-2.879
15.5
199.676
1.013
0.654
22.71
22.86
0.661
21.5
199.006
1.013
0.657
22.69
22.79
0.441
20.9
199.033
1.014
0.658
22.60
22.79
0.841
22.1
198.544
1.014
0.660
22.58
22.74
0.709
21.7
199.330
1.531
1.032
23.44
23.58
0.597
20.6
198.735
1.531
1.036
23.44
23.53
0.384
20.2
198.347
1.532
1.040
23.24
23.49
1.076
21.4
198.016
1.531
1.042
22.90
23.46
2.445
24.2
199.379
2.669
2.000
25.82
25.88
0.232
19.3
198.893
2.670
2.011
25.92
25.87
-0.193
18.9
198.471
2.671
2.020
25.86
25.86
0.000
19.1
198.055
2.669
2.026
25.89
25.84
-0.193
18.9
198.901
3.520
2.942
28.76
28.69
-0.243
18.4
198.535
3.520
2.956
28.94
28.72
-0.760
18.2
198.178
3.520
2.971
28.84
28.75
-0.312
18.4
250
Data from Roder [8] (continued)
T P /? A.exp A.cal Dev Wt
K MPa mol-dm'3 mW-m'^-K'^ %
197.847
3.519
2.983
28.74
28.79
0.174
18.6
198.920
4.156
3.845
32.41
32.16
-0.771
17.8
198.545
4.156
3.872
32.46
32.29
-0.524
17.8
198.129
4.156
3.904
32.35
32.44
0.278
18.1
197.856
4.156
3.925
32.71
32.55
-0.489
17.8
198.576
4.568
4.642
36.11
36.01
-0.277
17.6
198.243
4.568
4.683
36.40
36.28
-0.330
17.5
197.957
4.569
4.721
36.66
36.53
-0.355
17.5
197.623
4.568
4.763
36.88
36.83
-0.136
17.5
198.546
4.860
5.348
40.13
40.08
-0.125
17.3
198.321
4.860
5.390
40.52
40.41
-0.271
17.2
197.947
4.861
5.467
40.67
41.03
0.885
17.5
197.737
4.861
5.510
40.65
41.39
1.820
17.8
198.059
5.049
6.048
44.89
44.97
0.178
17.0
197.769
5.049
6.133
44.98
45.76
1.734
17.5
197.600
5.049
6.185
45.24
46.26
2.255
17.6
197.361
5.049
6.264
45.18
47.03
4.095
18.2
197.928
5.172
6.580
48.44
49.04
1.239
17.1
197.711
5.172
6.667
49.06
49.90
1.712
17.2
197.542
5.172
6.739
49.72
50.64
1.850
17.2
197.323
5.172
6.839
49.96
51.67
3.423
17.6
197.897
5.229
6.858
50.60
51.24
1.265
17.0
197.733
5.229
6.934
51.05
52.01
1.881
17.1
197.549
5.230
7.031
51.94
52.99
2.022
17.1
197.367
5.229
7.122
52.49
53.96
2.801
17.3
197.769
5.328
7.467
53.77
56.24
4.594
0.0
197.637
5.328
7.553
54.38
57.10
5.002
0.0
197.424
5.329
7.709
55.10
58.67
6.479
0.0
197.318
5.328
7.782
55.35
59.43
7.371
0.0
197.894
5.407
7.894
57.20
59.34
3.741
0.0
197.711
5.408
8.046
57.96
60.76
4.831
0.0
197.560
5.408
8.176
58.54
61.97
5.859
0.0
197.396
5.407
8.320
59.71
63.31
6.029
0.0
198.115
5.500
8.384
61.27
62.37
1.795
0.0
197.914
5.500
8.573
61.86
63.92
3.330
0.0
251
Data from Roder [8] (continued)
T
P
P
A.exp
A.cal
Dev
Wt
K
MPa
mol 'dm"^
mW-m'i
•K-i
%
197.829
5.500
8.659
62.56
64.59
3.245
0.0
197.597
5.499
8.901
63.01
66.41
5.396
0.0
198.226
5.692
9.855
68.75
68.57
-0.262
15.4
198.053
5.692
10.068
69.21
69.31
0.144
15.4
197.882
5.692
10.286
69.19
69.92
1.055
15.5
197.678
5.693
10.559
70.18
70.51
0.470
15.2
198.474
5.965
11.521
71.59
69.54
-2.864
14.4
198.275
5.966
11.722
71.75
69.80
-2.718
14.3
198.070
5.966
11.919
72.03
70.05
-2.749
14.3
197.904
5.967
12.079
72.53
70.24
-3.157
14.2
198.471
6.571
13.638
74.06
71.86
-2.971
13.7
198.290
6.571
13.733
73.72
72.13
-2.157
13.8
198.023
6.572
13.872
74.24
72.54
-2.290
13.7
197.943
6.571
13.910
74.35
72.66
-2.273
13.7
198.650
7.445
14.955
77.03
75.94
-1.415
13.5
198.306
7.446
15.073
77.59
76.44
-1.482
13.4
197.917
7.447
15.202
77.58
77.00
-0.748
13.5
197.672
7.447
15.282
78.22
77.35
-1.112
13.4
198.998
8.899
16.143
82.02
81.47
-0.671
13.2
198.586
8.899
16.239
82.43
81.98
-0.546
13.1
198.134
8.900
16.345
82.95
82.55
-0.482
13.1
197.859
8.900
16.408
83.31
82.89
-0.504
13.1
199.382
11.180
17.276
88.43
88.28
-0.170
12.8
198.850
11.180
17.369
88.94
88.86
-0.090
12.8
198.640
11.180
17.405
89.21
89.08
-0.146
12.8
198.159
11.180
17.487
89.73
89.61
-0.134
12.7
199.233
14.451
18.412
96.32
96.48
0.166
12.4
198.829
14.449
18.466
96.69
96.87
0.186
12.4
198.513
14.449
18.508
97.01
97.17
0.165
12.4
197.985
14.452
18.580
97.36
97.69
0.339
12.4
199.647
19.223
19.463
105.59
105.42
-0.161
12.0
199.171
19.221
19.515
105.73
105.84
0.104
12.0
198.766
19.217
19.558
105.77
106.19
0.397
12.0
198.521
19.214
19.584
106.75
106.40
-0.328
12.0
200.860
26.073
20.469
114.55
115.34
0.690
11.7
252
Data from Roder [8] (continued)
T
P
P
A.exp
A.cal
Dev
Wt
K
MPa
mol •dm""'
mW • m" ^
•K-i
%
200.358
26.073
20.514
115.03
115.74
0.617
11.7
199.942
26.070
20.551
115.46
116.08
0.537
11.7
199.516
26.067
20.589
115.52
116.42
0.779
11.7
201.141
35.267
21.550
126.69
127.38
0.545
11.3
200.642
35.265
21.588
127.33
127.76
0.338
11.3
200.211
35.263
21.620
127.63
128.09
0.360
11.3
199.725
35.263
21.657
127.79
128.47
0.532
11.3
200.885
47.247
22.643
140.78
141.27
0.348
10.9
200.367
47.244
22.677
141.41
141.65
0.170
10.8
199.989
47.240
22.701
141.38
141.93
0.389
10.9
199.680
47.238
22.721
141.74
142.16
0.296
10.8
201.164
62.619
23.684
156.25
156.47
0.141
10.5
200.687
62.619
23.711
156.68
156.82
0.089
10.4
200.378
62.620
23.729
156.87
157.05
0.115
10.4
200.002
62.621
23.750
157.19
157.32
0.083
10.4
201.156
69.413
24.079
163.11
162.77
-0.208
10.3
200.706
69.417
24.104
163.28
163.10
-0.110
10.3
200.328
69.421
24.125
163.56
163.38
-0.110
10.3
200.030
69.426
24.141
163.91
163.60
-0.189
10.3
215.053
1.068
0.633
24.40
24.58
0.738
22.1
214.489
1.068
0.635
24.27
24.52
1.030
23.0
213.947
1.068
0.637
24.32
24.46
0.576
21.5
213.426
1.068
0.639
24.11
24.40
1.203
23.7
215.328
1.747
1.076
25.39
25.46
0.276
20.1
214.790
1.747
1.080
25.34
25.41
0.276
20.1
214.260
1.747
1.083
25.27
25.35
0.317
20.1
213.806
1.748
1.087
25.12
25.31
0.756
20.8
214.864
3.035
2.049
27.64
27.54
-0.362
18.8
214.326
3.036
2.059
27.49
27.51
0.073
19.1
213.846
3.036
2.067
27.86
27.48
-1.364
18.1
213.566
3.038
2.074
27.61
27.46
-0.543
18.7
214.431
4.165
3.103
30.69
30.34
-1.140
17.9
214.021
4.165
3.117
30.68
30.34
-1.108
17.9
213.625
4.165
3.131
30.67
30.35
-1.043
18.0
213.296
4.165
3.143
30.69
30.35
-1.108
17.9
253
Data from Roder [8] (continued)
T
P
P
A.exp
A.cal
Dev
Wt
K
MPa
mol-dm""'
mW • m' ^
•K-i
%
215.344
5.021
4.028
33.84
33.41
-1.271
17.5
214.428
5.021
4.080
33.98
33.53
-1.324
17.5
213.774
5.021
4.119
34.21
33.63
-1.695
17.3
213.072
5.021
4.162
34.39
33.75
-1.861
17.2
214.675
5.810
5.168
38.44
37.76
-1.769
16.9
214.439
5.811
5.192
38.21
37.86
-0.916
17.1
214.014
5.813
5.238
38.06
38.05
-0.026
17.4
213.567
5.810
5.279
39.16
38.22
-2.400
16.6
214.369
6.372
6.164
42.81
42.14
-1.565
16.5
214.079
6.373
6.209
42.83
42.36
-1.097
16.6
213.712
6.370
6.259
42.67
42.61
-0.141
16.9
213.474
6.371
6.298
43.09
42.81
-0.650
16.7
213.934
6.928
7.386
47.97
47.87
-0.208
16.4
213.759
6.929
7.428
48.31
48.09
-0.455
16.3
213.375
6.929
7.516
48.62
48.56
-0.123
16.3
213.185
6.930
7.563
49.03
48.81
-0.449
16.2
213.566
7.356
8.495
52.95
52.91
-0.076
15.9
213.304
7.357
8.575
53.01
53.30
0.547
16.0
213.126
7.358
8.631
53.68
53.58
-0.186
15.9
212.961
7.356
8.677
53.66
53.80
0.261
15.9
213.712
7.759
9.444
56.44
56.66
0.390
15.6
213.375
7.759
9.558
57.37
57.15
-0.383
15.5
213.200
7.760
9.620
57.56
57.41
-0.261
15.5
213.080
7.759
9.660
57.26
57.58
0.559
15.6
213.798
8.254
10.564
60.38
60.44
0.099
15.2
213.577
8.255
10.643
60.79
60.73
-0.099
15.1
213.415
8.255
10.700
61.04
60.94
-0.164
15.1
213.191
8.255
10.780
61.31
61.22
-0.147
15.1
213.742
8.697
11.473
63.46
63.22
-0.378
14.8
213.550
8.697
11.537
63.92
63.44
-0.751
14.7
213.349
8.698
11.607
64.11
63.67
-0.686
14.7
213.104
8.696
11.686
64.49
63.93
-0.868
14.6
213.965
9.310
12.406
66.72
66.07
-0.974
14.4
213.642
9.311
12.504
67.07
66.41
-0.984
14.3
213.475
9.312
12.556
67.04
66.58
-0.686
14.4
254
Data from Roder [8] (continued)
T P p A.exp A.cal Dev Wt
K MPa niol-dm"3 mW-m'^-K'^ %
213.336
9.309
12.593
67.24
66.71
-0.788
14.3
214.655
10.068
13.183
69.21
68.69
-0.751
14.1
214.386
10.069
13.255
69.76
68.96
-1.147
14.1
214.165
10.069
13.313
69.79
69.17
-0.888
14.1
213.890
10.070
13.386
70.16
69.44
-1.026
14.0
214.865
11.106
14.143
73.03
72.46
-0.781
13.8
214.535
11.106
14.216
73.33
72.76
-0.777
13.8
214.277
11.106
14.274
73.71
72.99
-0.977
13.8
213.865
11.107
14.365
74.08
73.38
-0.945
13.7
215.388
12.417
14.987
76.99
76.33
-0.857
13.5
214.771
12.418
15.104
77.41
76.86
-0.711
13.5
214.164
12.420
15.219
78.00
77.40
-0.769
13.5
213.575
12.422
15.330
78.22
77.93
-0.371
13.5
215.850
14.257
15.899
81.17
81.16
-0.012
13.3
215.227
14.257
15.997
81.80
81.67
-0.159
13.3
214.710
14.257
16.079
82.21
82.09
-0.146
13.2
214.290
14.256
16.144
82.28
82.44
0.194
13.2
216.298
16.764
16.828
86.64
86.84
0.231
13.0
215.635
16.766
16.917
87.24
87.35
0.126
13.0
215.026
16.764
16.997
87.62
87.82
0.228
12.9
214.509
16.767
17.067
87.84
88.23
0.444
12.9
215.935
20.275
17.890
93.75
94.22
0.501
12.6
215.396
20.274
17.950
94.22
94.62
0.425
12.6
214.891
20.273
18.007
94.76
94.99
0.243
12.6
214.387
20.270
18.062
94.91
95.36
0.474
12.6
216.265
24.891
18.846
101.43
101.91
0.473
12.3
215.719
24.888
18.898
101.99
102.29
0.294
12.3
215.148
24.888
18.952
102.20
102.69
0.479
12.3
214.700
24.886
18.995
102.68
103.01
0.321
12.2
215.940
31.251
19.899
111.15
111.47
0.288
11.9
215.396
31.251
19.944
111.37
111.84
0.422
11.9
214.911
31.248
19.983
111.76
112.17
0.367
11.9
214.518
31.245
20.015
111.99
112.44
0.402
11.9
215.647
39.620
20.942
121.78
122.29
0.419
11.5
215.127
39.618
20.979
122.24
122.63
0.319
11.5
255
Data from Roder [8] (continued)
T
P
P
A,exp
A,cal
Dev
Wt
K
MPa
mol • dm' ^
mW • m" ^
•K-i
%
214.645
39.614
21.013
122.54
122.95
0.335
11.5
214.236
39.613
21.042
122.71
123.23
0.424
11.5
215.862
48.553
21.785
131.78
132.20
0.319
11.2
215.441
48.554
21.812
132.02
132.47
0.341
11.2
214.911
48.549
21.845
132.38
132.82
0.332
11.2
214.480
48.547
21.873
132.96
133.10
0.105
11.1
216.114
57.652
22.492
141.03
141.36
0.234
10.9
215.631
57.648
22.520
141.39
141.67
0.198
10.9
215.140
57.648
22.549
141.70
141.99
0.205
10.9
214.778
57.645
22.570
141.82
142.23
0.289
10.9
215.841
66.100
23.084
149.35
149.62
0.181
10.7
215.368
66.103
23.110
149.75
149.93
0.120
10.7
214.932
66.101
23.134
150.16
150.21
0.033
10.6
214.525
66.103
23.157
150.37
150.48
0.073
10.6
215.706
69.263
23.289
152.59
152.61
0.013
10.6
215.349
69.269
23.309
153.09
152.85
-0.157
10.6
214.975
69.277
23.329
153.29
153.10
-0.124
10.6
214.553
69.276
23.352
153.48
153.38
-0.065
10.6
234.956
0.977
0.520
26.53
26.75
0.829
23.5
234.383
0.978
0.522
26.45
26.68
0.870
23.7
233.637
0.978
0.524
26.34
26.60
0.987
24.2
233.152
0.979
0.526
26.32
26.54
0.836
23.4
236.032
3.145
1.834
29.45
29.44
-0.034
19.2
235.316
3.146
1.843
29.45
29.38
-0.238
19.0
234.753
3.147
1.851
29.35
29.33
-0.068
19.1
234.261
3.148
1.857
29.36
29.28
-0.272
19.0
235.158
5.135
3.346
33.53
33.08
-1.342
17.7
234.655
5.135
3.361
33.61
33.07
-1.607
17.6
234.220
5.135
3.374
33.61
33.06
-1.636
17.6
233.740
5.135
3.389
33.61
33.05
-1.666
17.5
236.400
7.129
5.155
38.39
38.91
1.355
17.8
235.396
7.129
5.218
39.46
39.05
-1.039
17.1
234.339
7.131
5.290
39.52
39.23
-0.734
17.1
233.533
7.132
5.347
40.43
39.37
-2.622
16.5
235.044
9.424
7.925
49.71
49.39
-0.644
16.0
256
Data from Roder [8] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm'3
234.249
233.554
232.938
235.259
234.432
233.788
233.227
235.523
234.841
234.078
233.513
235.351
234.621
234.028
233.472
235.036
234.425
233.812
233.349
234.799
234.255
233.698
233.233
235.343
234.724
234.109
233.639
235.025
234.553
234.168
233.546
235.148
234.592
234.248
233.560
9
.425
8
.033
9
.426
8
.130
9
.427
8
.220
11
.469
10
.306
11
.470
10
.447
11
.471
10
.560
11
472
10
.660
13
600
12
.235
13
600
12
.346
13
601
12
.471
13
602
12
564
15
750
13
694
15
750
13
799
15
751
13
885
15
751
13
965
17
692
14
709
17
692
14
788
17
693
14
868
17
693
14
928
20
536
15
827
20
535
15
888
20
535
15
951
20
535
16
004
23
411
16
625
23
411
16
688
23
411
16
750
23
410
16
798
26
932
17
496
26
932
17
539
26
932
17
575
26
931
17
631
30
368
18
160
30
366
18
206
30
361
18
234
30
360
18
292
A.exp
A.cal
mW • m" ^
•K-i
51.04
49.80
50.41
50.17
50.29
50.51
58.58
58.47
59.03
58.98
59.74
59.38
59.26
59.73
65.54
65.67
66.03
66.07
66.42
66.51
66.70
66.85
71.73
71.70
72.19
72.11
72.38
72.45
72.82
72.78
76.44
76.49
76.87
76.83
77.12
77.18
77.40
77.45
81.88
82.54
82.72
82.84
83.18
83.15
83.48
83.42
87.34
87.51
87.68
87.85
87.84
88.19
88.45
88.46
93.32
93.46
93.11
93.72
93.83
93.93
93.95
94.28
98.44
98.51
98.94
98.81
99.22
98.99
99.35
99.37
2
.429
15
.6
.476
16
.0
.437
16
1
.188
15
.2
.085
15
2
603
15
1
793
15
3
198
14
6
061
14
5
136
14
5
225
14
5
042
14
1
111
14
097
14
055
14
065
13
7
052
13
7
078
13
7
065
13
6
806
13
4
145
13
3
036
13
3
072
13
3
195
13
1
194
13
398
13
Oil
13
150
12
8
655
12
8
107
12
7
351
12
7
071
12
5
131
12
5
232
12
5
020
12
5
257
Data from Roder [8] (continued)
T
P
P
A.exp
A ,cal
Dev
Wt
K
MPa
mol • dm' ^
mW • m' ^
•K-i
%
234.964
34.092
18.795
103.31
103.71
0.387
12.3
234.389
34.091
18.839
103.59
104.02
0.415
12.3
233.804
34.090
18.885
103.95
104.34
0.375
12.3
233.473
34.089
18.910
103.56
104.52
0.927
12.3
235.426
37.551
19.262
107.55
107.89
0.316
12.1
234.763
37.547
19.310
107.94
108.24
0.278
12.1
234.319
37.547
19.342
108.24
108.48
0.222
12.1
233.849
37.543
19.376
108.25
108.73
0.443
12.1
235.318
41.022
19.718
111.89
112.14
0.223
11.9
234.701
41.021
19.761
112.12
112.47
0.312
11.9
234.205
41.021
19.795
112.39
112.74
0.311
11.9
233.707
41.018
19.829
112.63
113.01
0.337
11.9
235.189
44.354
20.116
116.37
116.05
-0.275
11.8
234.641
44.354
20.152
115.99
116.34
0.302
11.8
234. 13C
44.351
20.186
116.43
116.62
0.163
11.8
233.731
44.350
20.212
116.93
116.84
-0.077
11.7
235.016
47.931
20.508
120.00
120.09
0.075
11.6
234.521
47.932
20.540
120.28
120.36
0.067
11.6
234.030
47.927
20.570
120.52
120.62
0.083
11.6
233.633
47.928
20.595
120.49
120.84
0.290
11.6
234.971
51.244
20.836
123.41
123.63
0.178
11.5
234.454
51.246
20.867
123.89
123.91
0.016
11.5
234.029
51.243
20.893
124.23
124.14
-0.072
11.5
233.650
51.240
20.916
124.65
124.34
-0.249
11.5
235.440
55.105
21.158
127.30
127.32
0.016
11.4
234.914
55.104
21.189
127.66
127.61
-0.039
11.4
234.391
55.102
21.219
128.01
127.89
-0.094
11.4
233.958
55.098
21.244
128.22
128.13
-0.070
11.3
235.316
58.418
21.445
130.73
130.68
-0.038
11.3
234.894
58.416
21.469
130.80
130.90
0.076
11.3
234.436
58.416
21.495
131.20
131.15
-0.038
11.3
233.899
58.413
21.525
131.57
131.45
-0.091
11.2
235.308
61.887
21.721
134.15
134.02
-0.097
11.2
234.767
61.887
21.751
134.48
134.32
-0.119
11.2
234.277
61.885
21.778
134.61
134.59
-0.015
11.1
258
Data from Roder [8] (continued)
T
P
P
A ,exp
A.cal
Dev
Wt
K
MPa
mol-dm"^
mW • m" ^
•K-i
%
233.911
61.882
21.798
134.51
134.79
0.208
11.2
235.226
65.387
21.987
137.52
137.36
-0.116
11.1
234.756
65.384
22.012
137.80
137.61
-0.138
11.1
234.141
65.382
22.045
138.34
137.95
-0.282
11.0
233.842
65.381
22.061
138.07
138.11
0.029
11.0
235.239
68.761
22.225
140.80
140.44
-0.256
11.0
234.730
68.761
22.252
141.04
140.72
-0.227
11.0
234.268
68.757
22.276
141.56
140.97
-0.417
10.9
233.731
68.757
22.304
141.60
141.27
-0.233
10.9
255.835
1.020
0.495
29.06
29.29
0.791
23.8
255.177
1.020
0.496
29.00
29.20
0.690
23.4
254.645
1.019
0.497
28.87
29.14
0.935
24.8
253.943
1.019
0.498
28.81
29.05
0.833
24.2
256.518
2.714
1.384
30.98
31.00
0.065
19.6
255.864
2.714
1.389
30.81
30.93
0.389
20.0
255.237
2.716
1.394
30.80
30.86
0.195
19.7
254.735
2.717
1.399
30.76
30.81
0.163
19.7
255.777
4.718
2.587
33.81
33.50
-0.917
18.2
255.276
4.721
2.597
33.67
33.46
-0.624
18.3
254.679
4.726
2.610
33.65
33.42
-0.684
18.3
254.209
4.732
2.622
33.50
33.39
-0.328
18.5
256.067
6.551
3.825
37.09
36.72
-0.998
17.6
255.011
6.552
3.858
37.07
36.69
-1.025
17.6
254.140
6.555
3.886
36.97
36.68
-0.784
17.7
253.452
6.558
3.910
37.16
36.67
-1.319
17.5
256.771
6.788
3.975
37.63
37.23
-1.063
17.5
255.562
6.788
4.013
37.65
37.20
-1.195
17.5
254.504
6.789
4.048
37.68
37.18
-1.327
17.4
256.308
8.785
5.525
42.54
41.99
-1.293
16.8
255.358
8.785
5.576
42.74
42.07
-1.568
16.7
254.477
8.785
5.624
42.76
42.14
-1.450
16.8
253.831
8.786
5.660
43.15
42.21
-2.178
16.5
256.639
11.182
7.487
49.11
49.00
-0.224
16.3
255.633
11.183
7.570
49.34
49.23
-0.223
16.3
254.824
11.183
7.639
49.49
49.42
-0.141
16.3
259
Data from Roder [8] (continued)
T
P
P
A.exp
A,cal
Dev
Wt
K
MPa
mol • dm" ^
mW • m" ^
•K-i
%
254.114
11.187
7.704
49.73
49.60
-0.261
16.2
256.101
13.268
9.233
55.38
55.51
0.235
15.7
255.217
13.269
9.325
55.49
55.80
0.559
15.7
254.473
13.270
9.405
55.59
56.04
0.809
15.7
253.901
13.273
9.469
55.89
56.24
0.626
15.7
256.416
15.396
10.740
60.85
61.27
0.690
15.2
255.651
15.397
10.825
61.12
61.54
0.687
15.2
254.967
15.399
10.904
61.34
61.79
0.734
15.2
254.357
15.401
10.975
61.67
62.02
0.568
15.1
256.151
17.518
12.052
65.96
66.43
0.713
14.7
255.415
17.519
12.134
66.19
66.70
0.771
14.7
254.730
17.521
12.212
66.43
66.96
0.798
14.7
254.159
17.522
12.276
66.67
67.18
0.765
14.7
255.901
20.351
13.442
71.95
72.38
0.598
14.2
255.130
20.352
13.522
72.27
72.68
0.567
14.2
254.542
20.353
13.584
72.66
72.90
0.330
14.1
254.029
20.351
13.637
72.60
73.10
0.689
14.2
256.273
23.422
14.554
77.46
77.82
0.465
13.8
255.560
23.422
14.622
77.81
78.09
0.360
13.8
254.902
23.423
14.686
77.92
78.35
0.552
13.8
254.313
23.423
14.742
78.09
78.58
0.627
13.8
255.901
26.850
15.604
83.05
83.53
0.578
13.5
255.234
26.850
15.662
83.38
83.79
0.492
13.4
254.549
26.851
15.722
83.45
84.07
0.743
13.4
254.205
26.849
15.752
83.91
84.20
0.346
13.4
255.776
30.401
16.465
88.33
88.81
0.543
13.2
255.193
30.399
16.512
88.52
89.04
0.587
13.1
254.584
30.400
16.561
89.07
89.29
0.247
13.1
254.087
30.397
16.601
89.15
89.50
0.393
13.1
255.663
33.905
17.178
93.23
93.62
0.418
12.9
255.054
33.907
17.224
93.61
93.88
0.288
12.9
254.579
33.909
17.260
93.88
94.08
0.213
12.8
254.064
33.909
17.299
93.94
94.29
0.373
12.8
255.663
37.376
17.778
97.80
98.03
0.235
12.7
255.091
37.374
17.818
98.11
98.27
0.163
12.6
260
Data from Roder [8] (continued)
T
P
P
A.exp
A.cal
Dev
Wt
K
MPa
mol-dm'-'
mW • m" ^
•K-i
%
254.512
37.373
17.859
98.20
98.51
0.316
12.6
254.068
37.374
17.891
98.38
98.70
0,325
12.6
256.199
40.731
18.254
101.93
101.83
-0.098
12.5
255.692
40.729
18.288
102.18
102.04
-0.137
12.4
255.244
40.727
18.317
102.49
102.23
-0.254
12.4
256.203
44.631
18.784
105.93
106.27
0.321
12.3
255.607
44.631
18.822
106.28
106.52
0.226
12.3
254.993
44.631
18.861
106.34
106.78
0.414
12.3
254.544
44.632
18.890
106.82
106.98
0.150
12.2
256.097
48.090
19.214
109.70
110.07
0.337
12.1
255.479
48.089
19.252
110.07
110.33
0.236
12.1
254.909
48.089
19.287
110.33
110.58
0.227
12.1
254.428
48.087
19.316
110.59
110.78
0.172
12.1
255.939
51.674
19.624
113.61
113.87
0.229
12.0
255.358
51.673
19.658
113.79
114.12
0.290
12.0
254.925
51.672
19.683
113.97
114.31
0.298
12.0
254.412
51.673
19.713
114.22
114.53
0.271
11.9
256.371
56.210
20.060
117.93
118.22
0.246
11.8
255.786
56.209
20.093
118.19
118.48
0.245
11.8
255.239
56.207
20.123
118.43
118.71
0.236
11.8
254.711
56.208
20.153
118.39
118.95
0.473
11.8
254.267
56.203
20.177
119.12
119.14
0.017
11.8
255.471
59.687
20.434
121.84
121.97
0.107
11.7
255.429
59.690
20.436
121.89
121.99
0.082
11.7
254.396
59.684
20.492
122.09
122.45
0.295
11.7
254.078
59.683
20.509
122.46
122.59
0.106
11.6
255.957
63.260
20.719
125.86
125.11
-0.596
11.5
255.379
63.260
20.749
126.59
125.36
-0.972
11.5
254.993
63.255
20.769
124.68
125.53
0.682
11.6
254.436
63.252
20.798
125.37
125.78
0.327
11.5
255.922
66.477
20.984
128.80
128.06
-0.575
11.4
255.361
66.480
21.013
128.65
128.32
-0.257
11.4
254.827
66.474
21.040
128.88
128.55
-0.256
11.4
254.429
66.473
21.060
128.52
128.73
0.163
11.4
275.820
1.015
0.453
31.52
31.79
0.857
25.6
261
Data from Roder [8] (continued)
T P p A.exp A.cal Dev Wt
K MPa inol-dm"3 mW-m'^-K"^ %
275.218
1.015
0.454
31.44
31.71
0.859
25.6
274.623
1.015
0.455
31.34
31.64
0.957
26.4
274.083
1.016
0.457
31.34
31.57
0.734
24.4
276.019
2.495
1.153
32.88
33.05
0.517
20.6
275.382
2.495
1.156
32.89
32.98
0.274
20.1
274.765
2.496
1.160
32.77
32.90
0.397
20.3
274.285
2.497
1.163
32.74
32.84
0.305
20.2
275.546
4.446
2.159
35.09
35.01
-0.228
18.8
275.066
4.447
2.165
34.95
34.96
0.029
19.0
274.433
4.448
2.173
34.99
34.90
-0.257
18.8
274.021
4.449
2.178
34.89
34.85
-0.115
18.9
275.252
6.508
3.329
38.04
37.71
-0.868
17.9
274.818
6.508
3.338
38.09
37.68
-1.076
17.8
274.354
6.507
3.347
38.07
37.64
-1.129
17.7
274.121
6.507
3.352
38.16
37.63
-1.389
17.6
277.314
8.401
4.425
41.35
40.93
-1.016
17.4
276.746
8.402
4.443
41.34
40.92
-1.016
17.3
276.190
8.405
4.462
41.26
40.90
-0.873
17.4
275.541
8.407
4.483
41.20
40.89
-0.752
17.4
276.595
10.552
5.821
45.51
45.15
-0.791
16.9
276.054
10.553
5.846
45.48
45.17
-0.682
16.9
275.617
10.555
5.867
45.43
45.19
-0.528
16.9
275.127
10.559
5.892
45.47
45.22
-0.550
16.9
276.632
12.673
7.199
50.04
49.87
-0.340
16.4
276.126
12.674
7.230
50.12
49.92
-0.399
16.4
275.640
12.675
7.260
50.08
49.98
-0.200
16.4
275.203
12.678
7.288
50.07
50.03
-0.080
16.4
276.728
14.652
8.444
54.39
54.39
0.000
16.0
276.201
14.653
8.481
54.43
54.47
0.073
16.0
275.829
14.655
8.509
54.49
54.54
0.092
16.0
275.408
14.656
8.540
54.52
54.61
0.165
16.0
276.345
16.954
9.820
59.29
59.52
0.388
15.5
275.929
16.954
9.853
59.45
59.60
0.252
15.5
275.539
16.956
9.885
59.41
59.69
0.471
15.5
275.111
16.957
9.920
59.39
59.78
0.657
15.5
262
Data from Roder [8] (continued)
T
P
P
A.exp
A.cal
Dev
Wt
K
MPa
rnol'dm" ^
mW • m" ^
•K-i
%
276.052
19.153
10.986
63.56
64.02
0.724
15.1
275.714
19.154
11.014
63.73
64.10
0.581
15.1
275.280
19.155
11.051
63.82
64.20
0.595
15.1
275.004
19.155
11.075
63.83
64.27
0.689
15.1
276.700
21.322
11.913
67.46
67.85
0.578
14.8
275.909
21.323
11.979
67.57
68.05
0.710
14.8
275.069
21.324
12.051
67.82
68.26
0.649
14.7
274.513
21.325
12.098
67.84
68.40
0.825
14.7
276.428
23.529
12.802
71.33
71.64
0.435
14.4
275.693
23.529
12.862
71.46
71.83
0.518
14.4
274.982
23.531
12.921
71.68
72.02
0.474
14.4
274.401
23.535
12.971
71.55
72.18
0.881
14.4
276.181
26.983
13.959
76.78
77.03
0.326
14.0
275.483
26.984
14.014
76.96
77.23
0.351
14.0
274.770
26.986
14.070
77.18
77.43
0.324
14.0
274.248
26.988
14.112
77.28
77.57
0.375
14.0
276.033
30.486
14.917
81.88
82.01
0.159
13.7
275.358
30.487
14.967
81.86
82.20
0.415
13.7
274.715
30.488
15.015
82.31
82.39
0.097
13.6
274.239
30.490
15.051
82.32
82.53
0.255
13.6
276.647
33.987
15.671
86.53
86.39
-0.162
13.4
276.018
33.989
15.715
86.78
86.58
-0.230
13.3
275.248
33.987
15.768
86.84
86.81
-0.035
13.3
274.869
33.991
15.796
87.10
86.93
-0.195
13.3
276.150
37.531
16.399
90.67
90.87
0.221
13.1
275.502
37.530
16.441
89.76
91.07
1.459
13.3
274.848
37.529
16.485
91.82
91.27
-0.599
13.0
274.390
37.528
16.515
88.26
91.41
3.569
13.4
276.052
41.154
17.024
94.92
95.08
0.169
12.9
275.385
41.153
17.066
95.86
95.29
-0.595
12.8
274.737
41.151
17.107
95.28
95.50
0.231
12.9
274.280
41.151
17.136
95.76
95.65
-0.115
12.9
275.921
44.660
17.563
99.29
98.98
-0.312
12.7
275.284
44.660
17.602
100.15
99.18
-0.969
12.6
274.679
44.660
17.639
99.36
99.38
0.020
12.7
263
Data from Roder [8] (continued)
T
P
P
A.exp
A,cal
Dev
Wt
K
MPa
mol-dm"^
mW • m" ^
•K-i
%
274.171
44.660
17.670
99.27
99.55
0.282
12.7
llb.lie
48.079
18.039
102.77
102.63
-0.136
12.5
275.237
48.080
18.071
102.90
102.81
-0.087
12.5
274.656
48.078
18.104
102.84
103.00
0.156
12.5
274.170
48.078
18.132
103.64
103.16
-0.463
12.5
276.282
51.734
18.464
106.45
106.16
-0.272
12.4
275.668
51.733
18.499
106.52
106.36
-0.150
12.4
275.120
51.733
18.529
106.82
106.55
-0.253
12.3
llh.591
51.732
18.559
106.77
106.73
-0.037
12.3
iie.zei
55.237
18.859
109.87
109.54
-0.300
12.2
275.610
55.235
18.899
110.00
109.80
-0.182
12.2
275.048
55.235
18.930
110.26
109.99
-0.245
12.2
274.537
55.233
18.957
110.59
110.17
-0.380
12.2
276.173
58.748
19.239
113.29
112.93
-0.318
12.1
275.531
58.747
19.272
113.47
113.15
-0.282
12.1
274.999
58.748
19.300
113.61
113.34
-0.238
12.1
llk.klY
58.749
19.328
113.93
113.52
-0.360
12.0
276.101
62.502
19.608
116.94
116.40
-0.462
11.9
215A11
62.503
19.640
117.10
116.62
-0.410
11.9
274.905
62.499
19.669
117.22
116.82
-0.341
11.9
274.457
62.497
19.692
117.44
116.98
-0.392
11.9
275.948
65.832
19.919
120.04
119.42
-0.516
11.8
275.385
65.838
19.948
120.10
119.63
-0.391
11.8
274.943
65.840
19.970
120.14
119.79
-0.291
11.8
llU.klZ
65.839
19.996
120.16
119.98
-0.150
11.8
lieA99
69.251
20.186
122.80
122.21
-0.480
11.7
275.940
69.252
20.213
123.06
122.41
-0.528
11.7
275.379
69.254
20.240
123.27
122.62
-0.527
11.7
274.798
69.256
20.268
123.33
122.83
-0.405
11.7
296.783
0.988
0.407
34.02
34.54
1.529
49.1
296.042
0.988
0.409
33.89
34.44
1.623
57.3
295.352
0.988
0.410
33.83
34.35
1.537
47.6
294.797
0.989
0.411
33.57
34.27
2.085
59.8
296.430
1.949
0.819
34.77
35.19
1.208
24.2
295.783
1.949
0.821
34.65
35.11
1.328
24.7
264
Data from Roder [8] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm'3
295.177 1.950 0.823
294.638 1.950 0.825
296.023 3.911 1.705
295.413 3.912 1.710
294.915 3.913 1.714
294.458 3.914 1.718
296.320 5.976 2.696
295.741 5.978 2.705
295.153 5.981 2.714
294.671 5.974 2.717
295.849 8.077 3.778
295.213 8.079 3.792
294.626 8.082 3.806
294.135 8.087 3.819
295.366 10.365 5.016
294.726 10.367 5.037
294.274 10.369 5.052
293.791 10.373 5.069
294.991 12.169 6.017
294.453 12.171 6.039
293.987 12.173 6.058
293.540 12.176 6.078
296.186 14.295 7.114
295.091 14.297 7.168
294.119 14.297 7.215
293.367 14.299 7.254
295.764 16.379 8.219
294.721 16.379 8.277
293.904 16.381 8.324
293.091 16.382 8.372
295.420 18.657 9.348
294.415 18.658 9.411
293.588 18.659 9.464
292.903 18.662 9.509
295.068 21.429 10.589
A.exp
A.cal
mW • m" ^
.K-i
34.65
35.03
34.51
34.96
36.48
36.79
36.51
36.72
36.40
36.66
36.38
36.61
38.82
38.95
38.79
38.89
38.66
38.83
38.62
38.77
41.52
41.53
41.59
41.48
41.52
41.44
41.46
41.41
44.99
44.92
45.03
44.90
44.96
44.89
44.98
44.88
48.08
47.98
47.98
47.98
48.22
47.99
48.13
48.00
51.70
51.80
51.78
51.85
51.74
51.90
51.59
51.94
55.29
55.65
55.35
55.74
55.34
55.82
55.32
55.90
59.17
59.79
59.36
59.91
59.36
60.02
59.52
60.11
63.90
64.52
1
097
23
6
1
304
24
5
850
20
4
575
20
714
20
2
632
20
1
335
19
258
18
9
440
19
388
19
024
18
1
264
18
193
18
121
18
156
17
4
289
17
4
156
17
4
222
17
4
208
16
9
000
17
477
16
8
270
16
9
193
16
6
135
16
5
309
16
6
678
16
6
651
16
2
705
16
2
867
16
2
1
048
16
2
1
048
15
8
927
15
8
1
112
15
8
991
15
8
970
15
3
265
Data from Roder [8] (continued)
T P p A,exp A.cal Dev Wt
K MPa mol-dm'3
294.252
293.482
292.793
295.659
294.864
294.012
293.449
295.578
294.771
294.080
293.601
296.573
295.711
295.042
294.303
296.404
295.521
294.862
294.272
296.324
295.531
294.765
294.155
296.156
295.472
294.753
294.259
296.097
295.347
294.739
294.112
296.086
295.349
294.672
294.162
21
.432
10
.644
21
.432
10
.696
21
.434
10
.744
25,
.128
11,
.939
25
.127
11
.992
25,
.128
12,
.050
25,
.126
12,
.088
28,
.719
13,
.068
28,
.716
13,
.121
28,
.712
13,
.166
28,
.713
13,
.199
32,
.484
13,
.996
32,
,483
14,
,051
32,
,484
14,
,094
32,
,485
14,
,142
36,
,134
14,
,828
36,
,135
14,
,883
36.
,136
14.
,924
36,
,136
14.
,960
39,
,442
15.
,484
39,
,442
15.
,531
39,
,444
15.
,577
39,
,444
15.
,614
42,
,826
16.
,086
42,
,826
16.
,126
42.
,827
16.
,167
42.
,827
16.
,196
46.
,333
16.
,640
46.
,333
16.
,682
46.
,333
16.
.716
46.
,334
16.
,751
49.
,998
17.
,160
50.
,000
17.
,200
50.
,000
17.
236
50.
,001
17.
,264
A,exp
A.cal
mW • m" ^
•K-i
64.09
64.65
64.09
64.77
64.31
64.88
69.21
70,11
69.71
70.24
69.69
70.39
69.76
70.48
74.60
75.10
74.85
75.24
74.95
75.37
74.84
75.46
79.14
79.70
79.27
79.87
79.26
80.01
79.89
80.16
83.42
84.07
83.66
84.25
83.84
84.40
83.98
84.52
87.33
87.80
87.43
87.97
87.56
88.15
87.86
88.29
91.03
91.46
91.27
91.62
91.25
91.79
91.36
91.91
94.70
95.08
94.92
95.26
94.97
95.41
95.24
95.56
98.47
98.70
98.67
98.89
98.83
99.06
99.14
99.19
.874
15
.3
1
.061
15
.3
.886
15
.3
1
.300
14,
.9
.760
14
.8
1
.004
14
.8
1
.032
14
.8
0,
.670
14,
.4
0,
.521
14,
.3
0,
.560
14,
.3
0,
.828
14,
.4
0,
.708
14,
.1
0,
.757
14,
.0
0,
,946
14,
.1
0,
.338
14,
.0
0.
.779
13,
.8
0.
,705
13.
,7
0.
,668
13.
,7
0.
,643
13.
.7
0.
,538
13.
,5
0.
,618
13.
,5
0.
,674
13.
,5
0.
,489
13.
,5
0.
,472
13.
,3
0.
,383
13.
3
0.
,592
13.
3
0.
602
13.
3
0.
,401
13.
1
0.
358
13.
1
0.
463
13.
1
0.
336
13.
0.
234
12.
9
0.
223
12.
9
0.
233
12.
8
0.
050
12.
8
266
Data from Roder [8] (continued)
T
P
P
A.exp
A.cal
Dev
Wt
K
MPa
mol-dm" ^
mW • m" ^
•K-i
%
295.878
53.680
17.645
102.13
102.26
0.127
12.7
295.267
53.681
11 .eii
102.20
102.42
0.215
12.7
294.552
53.682
17.714
102.37
102.60
0.225
12.7
294.003
53.685
17.743
102.49
102.75
0.254
12.7
295.330
57.061
18.072
105.41
105.52
0.104
12.5
294.706
57.060
18.104
105.58
105.68
0.095
12.5
294.110
57.061
18.134
105.84
105.85
0.009
12.5
293.609
57.062
18.159
105.74
105.98
0.227
12.5
295.232
60.576
18.461
108.65
108.70
0.046
12.4
294.648
60.576
18.490
108.85
108.86
0.009
12.4
294.036
60.578
18.520
108.97
109.03
0.055
12.4
293.630
60.577
18.540
109.09
109.14
0.046
12.4
295.187
63.953
18.807
111.77
111.66
-0.098
12.2
294.555
63.958
18.838
112.04
111.84
-0.179
12.2
294.012
63.952
18.864
111.93
111.99
0.054
12.2
293.475
63.951
18.889
112.41
112.14
-0.240
12.2
295.776
67.319
19.101
114.71
114.36
-0.305
12.1
295.118
67.321
19.132
114.91
114.55
-0.313
12.1
294.631
67.320
19.155
115.10
114.69
-0.356
12.1
294.106
67.323
19.180
115.21
114.84
-0.321
12.1
309.085
1.076
0.426
35.91
36.30
1.086
31.5
308.341
1.076
0.427
36.10
36.20
0.277
21.7
307.755
1.077
0.428
35.81
36.11
0.838
27.3
307.128
1.077
0.429
35.58
36.03
1.265
35.3
309.214
2.675
1.083
37.42
37.46
0.107
19.9
308.624
2.675
1.086
37.33
37.38
0.134
19.9
308.033
2.676
1.089
37.01
37.30
0.784
21.5
307.414
2.678
1.092
36.93
37.22
0.785
21.5
309.391
4.743
1.979
39.36
39.21
-0.381
18.7
308.849
4.743
1.983
39.10
39.14
0.102
19.2
308.250
4.743
1.988
39.15
39.07
-0.204
18.9
307.648
4.744
1.994
39.01
38.99
-0.051
19.1
309.635
6.732
2.883
41.48
41.21
-0.651
18.1
309.040
6.732
2.891
41.53
41.15
-0.915
17.9
308.464
6.733
2.899
41.46
41.08
-0.917
17.9
267
Data from Roder [8] (continued)
T
P
P
A.exp
A,cal
Dev
Wt
K
MPa
mol-dm"'*
mW • in' ^
•K-i
%
307.941
6.733
2.906
41.27
41.03
-0.582
18.2
309.267
8.876
3.907
44.26
43.68
-1.310
17.4
308.712
8.876
3.918
43.95
43.63
-0.728
17.7
308.170
8.877
3.930
44.02
43.59
-0.977
17.5
307.710
8.877
3.939
44.03
43.55
-1.090
17.5
310.021
11.038
4.942
47.19
46.64
-1.166
17.0
308.898
11.039
4.973
47.15
46.58
-1.209
17.0
307.879
11.039
5.001
46.83
46.52
-0.662
17.2
307.031
11.039
5.025
46.95
46.48
-1.001
17.1
309.673
13.147
5.984
50.09
49.76
-0.659
16.8
308.603
13.147
6.021
49.96
49.73
-0.460
16.9
307.642
13.148
6.056
50.23
49.72
-1.015
16.7
306.841
13.148
6.084
50.33
49.70
-1.252
16.6
309.353
15.185
6.980
53.20
52.98
-0.414
16.5
308.309
15.186
7.024
53.23
53.00
-0.432
16.4
307.523
15.186
7.057
53.23
53.01
-0.413
16.4
306.746
15.186
7.090
53.25
53.02
-0.432
16.4
310.102
17.278
7.919
56.39
56.33
-0.106
16.2
308.975
17.278
7.972
56.47
56.38
-0.159
16.1
308.110
17.277
8.013
56.44
56.42
-0.035
16.1
307.320
17.276
8.051
56.46
56.45
-0.018
16.1
309.770
19.464
8.894
59.73
59.82
0.151
15.8
308.761
19.463
8.946
59.86
59.89
0.050
15.8
307.944
19.463
8.990
59.83
59.95
0.201
15.8
307.225
19.462
9.028
60.00
60.00
0.000
15.7
309.480
22.418
10.097
64.11
64.34
0.359
15.4
308.591
22.418
10.147
64.22
64.42
0.311
15.4
307.806
22.418
10.192
64.22
64.50
0.436
15.4
307.109
22.418
10.233
64.11
64.57
0.718
15.4
309.260
26.028
11.381
69.20
69.44
0.347
14.9
308.444
26.028
11.429
69.41
69.54
0.187
14.9
307.756
26.028
11.470
69.41
69.63
0.317
14.9
307.136
26.028
11.508
69.52
69.70
0.259
14.9
310.093
29.477
12.376
73.93
73.80
-0.176
14.5
309.235
29.477
12.427
73.95
73.92
-0.041
14.5
268
Data from Roder [8] (continued)
T
P
P
A.exp
A.cal
Dev
Wt
K
MPa
mol-dm''^
mW • m" ^
•K-i
%
308.527
29.476
12.469
74.17
74.01
-0.216
14.5
307.869
29.475
12.508
74.30
74.10
-0.269
14.4
309.694
33.098
13.346
78.15
78.21
0.077
14.2
308.929
33.097
13.390
78.27
78.32
0.064
14.2
308.143
33.098
13.436
78.33
78.44
0.140
14.2
307.480
33.098
13.475
78.50
78.54
0.051
14.2
309.498
36.518
14.135
81.99
82.10
0.134
13.9
308.688
36.519
14.181
82.22
82.23
0.012
13.9
308.056
36.520
14.218
82.15
82.34
0.231
13.9
307.447
36.521
14.253
82.16
82.44
0.341
13.9
309.222
39.909
14.831
85.88
85.79
-0.105
13.7
308.550
39.909
14.869
86.03
85.90
-0.151
13.6
307.881
39.911
14.906
86.21
86.02
-0.220
13.6
307.206
39.914
14.945
86.23
86.15
-0.093
13.6
309.943
43.084
15.364
89.13
88.92
-0.236
13.5
309.132
43.083
15.408
89.28
89.07
-0.235
13.4
308.403
43.081
15.447
89.18
89.20
0.022
13.5
307.807
43.079
15.479
89.70
89.31
-0.435
13.4
309.716
46.727
15.968
93.03
92.56
-0.505
13.2
309.019
46.727
16.004
93.12
92.69
-0.462
13.2
308.324
46.726
16.040
93.05
92.82
-0.247
13.2
307.749
46.725
16.071
93.25
92.94
-0.332
13.2
309.703
50.127
16.468
96.30
95.79
-0.530
13.0
308.899
50.126
16.509
96.44
95.95
-0.508
13.0
308.226
50.126
16.543
96.38
96.09
-0.301
13.0
307.650
50.126
16.573
96.65
96.21
-0.455
13.0
309.618
53.476
16.924
99.50
98.89
-0.613
12.9
308.897
53.476
16.960
99.60
99.04
-0.562
12.9
308.209
53.476
16.994
99.74
99.19
-0.551
12.9
307.616
53.475
17.023
99.82
99.31
-0.511
12.9
309.416
57.009
17.372
102.83
102.09
-0.720
12.7
308.753
57.009
17.404
103.06
102.24
-0.796
12.7
308.134
57.009
17.434
103.01
102.37
-0.621
12.7
307.513
57.008
17.464
103.21
102.51
-0.678
12.7
309.315
60.531
17.781
106.01
105.17
-0.792
12.6
269
Data from Roder [8] (continued)
T
P
P
A.exp
A.cal
Dev
Wt
K
MPa
mol • dm" •^
mW • m" ^
•K-i
%
308.655
60.530
17.812
106.23
105.32
-0.857
12.5
308.072
60.531
17.839
106.53
105.45
-1.014
12.5
307.537
60.531
17.864
106.47
105.57
-0.845
12.5
309.320
64.078
18.159
109.19
108.17
-0.934
12.4
308.648
64.078
18.189
109.26
108.33
-0.851
12.4
308.025
64.075
18.218
109.42
108.47
-0.868
12.4
307.462
64.077
18.244
109.48
108.61
-0.795
12.4
313.129
66.672
18.248
110.38
109.46
-0.833
12.4
312.494
66.678
18.277
110.55
109.60
-0.859
12.4
311.828
66.670
18.306
110.76
109.74
-0.921
12.3
311.372
66.685
18.328
110.71
109.86
-0.768
12.4
309.358
67.415
18.490
112.15
110.92
-1.097
12.3
308.758
67.414
18.516
112.44
111.06
-1.227
12.2
308.136
67.414
18.544
112.59
111.21
-1.226
12.2
307.614
67.416
18.568
112.78
111.34
-1.277
12.2
Number of Points (Ref. 8) 895
AAD-%
AAD
0.577
0.387
BIAS-%
BIAS
0.069
0.032
RMS-%
RMS
0.942
0.584 mW-m"i
K"
Data from
Sokolova and
Golubev [80]
T
P
P
A.exp
A.cal
Dev
Wt
K
MPa
mol- dm' ^
mW • m" ^
•K-i
%
238.70
0.10
0.051
26.08
26.40
1.227
0.0
238.80
0.20
0.101
26.13
26.50
1.416
0.0
238.80
0.26
0.132
26.16
26.55
1.491
0.0
238.50
0.69
0.357
26.22
26.90
2.593
0.0
238.50
1.06
0.557
26.80
27.24
1.642
0.0
238.80
2.09
1.143
27.71
28.36
2.346
0.0
239.00
2.09
1.142
27.90
28.38
1.720
0.0
238.80
3.04
1.734
29.17
29.55
1.303
0.0
239.00
3.19
1.829
29.12
29.78
2.266
0.0
238.80
4.02
2.400
30.52
31.05
1.737
0.0
270
Data from Sokolova and Golubev [80] (continued)
T P p A.exp A,cal Dev Wt
K MPa mol-dm'3 mW-m'^-K'^ %
238.80 4.02 2.400 30.48 31.05 1.870 0.0
239.00 4.33 2.621 31.19 31.60 1.315 0.0
239.00 4.33 2.621 30.73 31.60 2.831 0.0
238.80 5.04 3.167 32.28 32.98 2.169 0.0
239.20 5.36 3.412 32.99 33.70 2.152 0.0
239.20 6.49 4.387 35.76 36.60 2.349 0.0
238.50 6.86 4.767 37.18 37.77 1.587 0.0
238.30 8.53 6.515 43.50 44.04 1.241 0.0
239.00 8.72 6.661 50.45 44.64 -11.516 0.0
238.50 10.01 8.175 51.61 50.48 -2.189 0.0
238.50 12.41 10.729 62.05 60.14 -3.078 0.0
238.50 12.41 10.729 61.67 60.14 -2.481 0.0
238.50 14.62 12.525 67.78 66.99 -1.166 0.0
238.50 14.81 12.654 69.04 67.51 -2.216 0.0
238.50 19.72 15.113 79.13 78.91 -0.278 0.0
238.50 19.72 15.113 78.42 78.91 0.625 0.0
238.50 29.42 17.698 93.99 95.36 1.458 0.0
238.80 29.53 17.694 93.66 95.36 1.815 0.0
239.00 40.22 19.362 106.60 109.25 2.486 0.0
239.00 50.13 20.481 116.90 120.32 2.926 0.0
239.00 50.23 20.491 117.20 120.42 2.747 0.0
231.80 0.10 0.052 25.25 25.56 1.228 0.0
231.80 0.43 0.227 25.39 25.86 1.851 0.0
231.80 1.08 0.586 26.00 26.48 1.846 0.0
231.60 2.07 1.178 26.69 27.56 3.260 0.0
231.80 2.07 1.176 26.77 27.58 3.026 0.0
231.80 3.04 1.813 28.24 28.90 2.337 0.0
231.80 4.12 2.606 30.45 30.76 1.018 0.0
231.60 5.20 3.515 32.66 33.19 1.623 0.0
231.60 5.20 3.515 32.57 33.19 1.904 0.0
231.80 5.99 4.252 34.96 35.47 1.459 0.0
231.80 5.99 4.252 35.29 35.47 0.510 0.0
231.80 6.58 4.860 37.22 37.51 0.779 0.0
232.10 7.16 5.482 39.82 39.76 -0.151 0.0
231.80 7.16 5.504 39.90 39.83 -0.175 0.0
271
Data from Sokolova and Golubev [80] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dni'3 mW-ra'^-K'^ %
231.80
7.99
6.505
45.13
43.67
-3.235
0.0
231.80
7.99
6.505
44.84
43.67
-2.609
0.0
231.80
8.34
6.952
49.61
45.44
-8.406
0.0
231.80
8.84
7.608
50.58
48.06
-4.982
0.0
231.80
9.96
9.095
57.32
53.91
-5.949
0.0
231.80
9.96
9.095
57.15
53.91
-5.669
0.0
231.60
10.89
10.294
61.55
58.38
-5.150
0.0
231.60
10.89
10.294
62.13
58.38
-6.036
0.0
231.80
11.88
11.346
64.64
62.20
-3.775
0.0
231.80
11.88
11.346
65.69
62.20
-5.313
0.0
231.80
13.49
12.765
70.46
67.55
-4.130
0.0
231.80
15.30
13.958
74.40
72.62
-2.392
0.0
231.60
19.72
15.921
83.69
82.76
-1.111
0.0
231.60
19.72
15.921
83.44
82.76
-0.815
0.0
231.80
23.79
17.080
90.39
90.16
-0.254
0.0
231.60
29.53
18.309
98.56
99.28
0.731
0.0
224.80
0.10
0.054
24.45
24.72
1.104
0.0
224.80
0.30
0.163
24.62
24.91
1.178
0.0
224.90
0.30
0.163
24.48
24.92
1.797
0.0
224.80
0.61
0.336
24.80
25.20
1.613
0.0
225.00
0.69
0.381
24.77
25.31
2.180
0.0
224.90
1.06
0.596
25.00
25.67
2.680
0.0
224.80
1.08
0.608
25.21
25.68
1.864
0.0
224.10
2.11
1.258
26.26
26.84
2.209
0.0
224.10
2.11
1.258
26.39
26.84
1.705
0.0
224.60
3.04
1.905
27.77
28.28
1.837
0.0
224.80
3.04
1.903
27.83
28.30
1.689
0.0
224.80
4.00
2.661
30.20
30.13
-0.232
0.0
224.90
4.02
2.675
30.17
30.18
0.033
0.0
224.60
4.74
3.327
32.18
31.95
-0.715
0.0
224.80
5.01
3.581
32.70
32.72
0.061
0.0
224.80
5.01
3.581
32.62
32.72
0.307
0.0
224.80
5.01
3.581
32.82
32.72
-0.305
0.0
224.90
6.02
4.658
37.14
36.28
-2.316
0.0
224.90
6.02
4.658
36.68
36.28
-1.091
0.0
272
Data from Sokolova and Golubev [80] (continued)
T P /? A.exp A,cal Dev Wt
K MPa mol-dm'3 mW-m'^-K"^ %
224.90
6.86
5.712
42.50
40.25
-5.294
0.0
224.80
6.97
5.872
43.08
40.88
-5.107
0.0
225.40
7.75
6.927
53.67
45.23
-15.726
0.0
225.60
7.85
7.050
54.14
45.74
-15.515
0.0
224.80
8.83
8.734
61.63
52.65
-14.571
0.0
224.10
9.91
10.562
66.57
59.45
-10.696
0.0
224.80
9.91
10.402
65.82
58.86
-10.574
0.0
223.80
11.43
12.479
71.89
66.16
-7.971
0.0
223.80
11.43
12.479
70.51
66.16
-6.169
0.0
223.30
12.36
13.420
73.27
69.77
-4.777
0.0
223.30
12.36
13.420
72.72
69.77
-4.057
0.0
224.10
14.71
14.818
78.84
76.10
-3.475
0.0
223.30
14.81
14.996
79.09
76.93
-2.731
0.0
224.80
16.38
15.515
82.15
79.80
-2.861
0.0
224.10
20.20
16.944
89.72
88.40
-1.471
0.0
224.10
20.20
16.944
89.39
88.40
-1.108
0.0
224.10
25.21
18.157
96.84
97.19
0.361
0.0
224.40
29.53
18.926
102.50
103.56
1.034
0.0
223.40
38.94
20.310
113.80
116.52
2.390
0.0
224.90
39.14
20.226
112.70
115.85
2.795
0.0
223.40
48.36
21.287
123.00
127.23
3.439
0.0
223.40
48.66
21.315
122.90
127.55
3.784
0.0
223.40
48.85
21.332
123.70
127.76
3.282
0.0
216.40
0.10
0.056
23.47
23.71
1.023
0.0
216.30
0.42
0.239
23.61
24.02
1.737
0.0
216.10
1.09
0.643
24.14
24.72
2.403
0.0
216.10
1.97
1.225
25.30
25.85
2.174
0.0
216.10
3.06
2.049
27.52
27.68
0.581
0.0
216.30
4.07
2.948
30.41
30.05
-1.184
0.0
216.30
5.01
3.962
33.97
33.24
-2.149
0.0
216.30
5.50
4.584
37.43
35.49
-5.183
0.0
216.30
5.50
4.584
37.51
35.49
-5.385
0.0
216.10
6.18
5.608
44.00
39.64
-9.909
0.0
216.30
6.58
6.267
51.00
42.53
-16.608
0.0
216.30
6.58
6.267
50.07
42.53
-15.059
0.0
273
Data from Sokolova and Golubev [80] (continued)
T P p A,exp A.cal Dev Wt
K MPa mol-dm'3 mW-m'^-K'^ %
216.60
6.97
6.948
57.40
45.59
-20.575
0.0
216.60
6.97
6.948
57.99
45.59
-21.383
0.0
216.30
7.16
7.385
60.16
47.59
-20.894
0.0
216.30
7.16
7.385
59.41
47.59
-19.896
0.0
216.30
7.46
8.017
63.68
50.40
-20.854
0.0
216.30
7.94
9.067
66.78
54.75
-18.014
0.0
216.30
7.99
9.176
67.28
55.17
-17.999
0.0
216.30
8.93
11.074
71.26
61.70
-13.416
0.0
216.60
11.28
13.907
77.67
71.52
-7.918
0.0
216.60
12.85
15.030
81.27
76.61
-5.734
0.0
216.60
15.79
16.434
88.05
84.38
-4.168
0.0
216.60
19.52
17.620
94.16
92.30
-1.975
0.0
216.60
19.72
17.673
93.70
92.69
-1.078
0.0
216.30
25.41
18.938
102.50
102.71
0.205
0.0
210.00
0.10
0.058
22.71
22.96
1.101
0.0
209.80
1.10
0.673
23.36
24.04
2.911
0.0
208.40
1.41
0.887
23.63
24.30
2.835
0.0
209.30
1.77
1.135
24.13
24.89
3.150
0.0
210.30
2.08
1.355
24.65
25.47
3.327
0.0
209.80
2.41
1.615
25.52
25.98
1.803
0.0
209.80
2.41
1.615
25.27
25.98
2.810
0.0
207.50
2.91
2.071
26.65
26.83
0.675
0.0
210.30
3.07
2.161
27.27
27.34
0.257
0.0
210.30
3.07
2.161
27.14
27.34
0.737
0.0
209.00
3.54
2.634
29.10
28.48
-2.131
0.0
209.00
3.54
2.634
28.48
28.48
0.000
0.0
210.30
3.95
3.019
31.02
29.72
-4.191
0.0
210.30
3.95
3.019
30.86
29.72
-3.694
0.0
207.50
4.30
3.541
32.95
31.21
-5.281
0.0
207.50
4.30
3.541
32.74
31.21
-4.673
0.0
210.10
5.01
4.348
38.64
34.33
-11.154
0.0
210.10
5.01
4.348
38.98
34.33
-11.929
0.0
210.60
5.24
4.653
42.96
35.56
-17.225
0.0
210.60
5.24
4.653
42.62
35.56
-16.565
0.0
210.10
5.48
5.090
49.19
37.43
-23.907
0.0
274
Data from Sokolova and Golubev [80] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm"3 mW-m'^-K'^ %
210.10
5.48
5.090
50.66
37.43
-26.115
0.0
210.10
5.48
5.090
49.07
37.43
-23.721
0.0
209.50
5.72
5.602
55.98
39.79
-28.921
0.0
210.10
5.99
6.061
63.76
41.95
-34.206
0.0
209.60
6.00
6.166
68.16
42.52
-37.617
0.0
210.10
6.10
6.299
69.58
43.12
-38.028
0.0
210.10
6.10
6.299
70.80
43.12
-39.096
0.0
210.10
6.20
6.524
72.35
44.24
-38.853
0.0
210.10
6.20
6.524
75.45
44.24
-41.365
0.0
209.80
6.94
8.586
77.50
54.26
-29.987
0.0
209.80
6.94
8.586
78.21
54.26
-30.623
0.0
206.60
7.32
11.237
72.85
64.12
-11.984
0.0
209.60
7.32
9.815
73.60
59.08
-19.728
0.0
209.60
7.32
9.815
73.10
59.08
-19.179
0.0
209.50
7.35
9.947
72.35
59.55
-17.692
0.0
209.60
7.35
9.903
71.05
59.37
-16.439
0.0
209.60
7.66
10.773
72.39
62.00
-14.353
0.0
210.70
8.24
11.672
74.02
64.24
-13.213
0.0
210.80
8.24
11.634
74.90
64.11
-14.406
0.0
210.80
9.91
14.023
78.92
71.89
-8.908
0.0
210.10
12.46
15.983
83.86
81.19
-3.184
0.0
209.80
14.71
17.007
89.18
87.39
-2.007
0.0
210.30
14.92
17.011
90.02
87.46
-2.844
0.0
209.80
16.78
17.684
93.91
92.05
-1.981
0.0
209.80
16.78
17.684
93.03
92.05
-1.053
0.0
210.00
19.72
18.423
98.14
97.70
-0.448
0.0
210.00
30.50
20.287
112.50
114.61
1.876
0.0
210.00
31.20
20.380
113.50
115.56
1.815
0.0
209.60
39.73
21.385
122.50
126.55
3.306
0.0
209.60
39.73
21.385
122.80
126.55
3.054
0.0
209.60
48.95
22.218
131.10
136.83
4.371
0.0
209.60
48.95
22.218
131.80
136.83
3.816
0.0
209.60
50.52
22.344
133.40
138.48
3.808
0.0
195.90
2.19
1.611
25.53
24.57
-3.760
0.0
195.90
2.19
1.611
25.23
24.57
-2.616
0.0
275
Data from Sokolova and Golubev [80] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm'3 mW-m'^-K"^ %
195.60
2.19
1.616
25.13
24.56
-2.268
0.0
195.90
3.14
2.587
28.35
27.37
-3.457
0.0
195.40
3.14
2.604
28.52
27.40
-3.927
0.0
195.60
3.14
2.597
27.92
27.39
-1.898
0.0
195.60
4.13
4.068
33.23
33.43
0.602
0.0
195.40
4.13
4.087
32.53
33.55
3.136
0.0
195.90
4.15
4.079
34.59
33.45
-3.296
0.0
194.90
4.15
4.175
33.90
34.10
0.590
0.0
195.40
4.18
4.185
34.23
34.07
-0.467
0.0
195.60
4.18
4.166
33.79
33.93
0.414
0.0
195.30
4.51
4.966
41.27
38.71
-6.203
0.0
195.90
4.66
5.284
43.71
40.62
-7.069
0.0
195.90
4.81
5.783
54.09
44.31
-18.081
0.0
194.90
4.81
6.102
54.34
47.84
-11.962
0.0
195.50
4.92
6.387
62.51
49.76
-20.397
0.0
195.90
4.93
6.274
68.54
48.34
-29.472
0.0
194.90
4.93
6.735
67.37
53.93
-19.950
0.0
194.90
4.93
6.735
67.83
53.93
-20.492
0.0
195.90
5.04
6.840
80.30
53.42
-33.474
0.0
195.60
5.04
7.014
84.20
55.54
-34.038
0.0
195.90
5.05
6.899
84.87
53.97
-36.409
0.0
195.90
5.06
6.959
86.25
54.53
-36.777
0.0
195.90
5.07
7.021
91.40
55.12
-39.694
0.0
195.90
5.08
7.085
97.89
55.72
-43.079
0.0
194.90
5.09
8.054
112.80
67.81
-39.885
0.0
195.90
5.10
7.218
114.60
56.98
-50.279
0.0
194.90
5.10
8.168
123.80
68.89
-44.354
0.0
194.90
5.11
8.288
143.00
70.00
-51.049
0.0
194.90
5.11
8.288
147.00
70.00
-52.381
0.0
194.90
5.11
8.288
143.90
70.00
-51.355
0.0
194.90
5.12
8.414
149.80
71.10
-52.537
0.0
194.90
5.12
8.414
148.70
71.10
-52.186
0.0
194.90
5.16
8.969
163.10
75.29
-53.838
0.0
194.90
5.16
8.969
174.00
75.29
-56.730
0.0
194.90
5.16
8.969
168.10
75.29
-55.211
0.0
276
Data from Sokolova and Golubev [80] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm'3 mW-m'^-K"^ %
194.90
5.16
8.969
171.60
75.29
-56.125
0.0
194.90
5.16
8.969
165.30
75.29
-54.453
0.0
194.90
5.17
9.121
171.10
76.18
-55.476
0.0
194.90
5.26
10.535
156.50
78.46
-49.866
0.0
194.90
5.28
10.817
153.30
77.95
-49.152
0.0
194.90
5.28
10.817
151.40
77.95
-48.514
0.0
194.90
5.28
10.817
148.70
77.95
-47.579
0.0
194.90
5.35
11.627
124.30
75.71
-39.091
0.0
194.90
5.35
11.627
125.80
75.71
-39.817
0.0
194.90
5.35
11.627
123.10
75.71
-38.497
0.0
194.90
5.40
12.064
117.30
74.57
-36.428
0.0
194.90
5.47
12.540
95.79
73.67
-23.092
0.0
194.90
5.48
12.599
98.89
73.59
-25.584
0.0
194.90
5.50
12.710
102.30
73.30
-28.348
0.0
194.90
5.50
12.710
99.44
73.30
-26.287
0.0
194.90
5.50
12.710
101.40
73.30
-27.712
0.0
194.90
5.50
12.710
100.20
73.30
-26.846
0.0
194.90
5.50
12.710
100.90
73.30
-27.354
0.0
194.90
5.51
12.764
100.80
73.25
-27.331
0.0
194.90
5.52
12.815
95.79
73.22
-23.562
0.0
194.90
5.52
12.815
95.42
73.22
-23.266
0.0
194.90
5.52
12.815
95.96
73.22
-23.697
0.0
194.90
5.62
13.258
88.97
73.15
-17.781
0.0
194.90
5.62
13.258
89.56
73.15
-18.323
0.0
194.90
5.62
13.258
98.64
73.15
-25.841
0.0
194.90
6.09
14.497
83.53
75.04
-10.164
0.0
194.90
6.09
14.497
83.78
75.04
-10.432
0.0
195.40
7.05
15.601
84.87
78.89
-7.046
0.0
195.40
7.05
15.601
84.20
78.89
-6.306
0.0
195.90
7.06
15.448
86.42
78.18
-9.535
0.0
194.90
7.09
15.798
84.57
79.82
-5.617
0.0
194.90
7.10
15.807
85.79
79.86
-6.912
0.0
194.90
7.10
15.807
85.96
79.86
-7.096
0.0
195.90
8.15
16.375
87.71
82.69
-5.723
0.0
195.40
8.15
16.497
87.00
83.36
-4.184
0.0
277
Data from Sokolova and Golubev [80] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dni"3 mW-m'^-K'^ %
195.90
9.13
16.967
90.02
86.11
-4.343
0.0
195.40
9.13
17.070
87.71
86.73
-1.117
0.0
195.40
9.13
17.070
88.47
86.73
-1.967
0.0
195.90
10.01
17.393
91.40
88.83
-2.812
0.0
195.40
10.10
17.524
90.81
89.68
-1.244
0.0
194.90
10.10
17.614
92.57
90.26
-2.495
0.0
195.90
12.41
18.281
96.30
95.17
-1.173
0.0
195.40
12.41
18.355
94.91
95.69
0.822
0.0
195.90
12.46
18.297
95.88
95.28
-0.626
0.0
195.60
12.46
18.341
94.91
95.60
0.727
0.0
195.60
14.81
18.983
102.30
100.78
-1.486
0.0
195.40
14.81
19.009
103.40
100.98
-2.340
0.0
195.40
14.81
19.009
101.40
100.98
-0.414
0.0
195.90
19.37
19.894
111.30
109.02
-2.049
0.0
195.40
19.37
19.947
109.90
109.47
-0.391
0.0
195.40
22.66
20.481
113.50
114.80
1.145
0.0
194.50
22.66
20.568
114.70
115.59
0.776
0.0
195.90
22.66
20.433
116.20
114.36
-1.583
0.0
188.40
2.00
1.542
23.14
23.77
2.723
0.0
188.40
2.00
1.542
22.55
23.77
5.410
0.0
188.60
3.04
2.724
25.87
27.80
7.460
0.0
188.90
3.04
2.712
25.41
27.80
9.406
0.0
188.60
3.74
3.948
36.35
34.12
-6.135
0.0
188.90
3.74
3.916
35.13
33.97
-3.302
0.0
188.90
4.18
5.269
70.88
45.67
-35.567
0.0
188.90
4.20
5.365
76.91
46.81
-39.137
0.0
188.60
4.26
5.859
87.17
53.87
-38.201
0.0
188.60
4.28
6.019
94.87
56.64
-40.297
0.0
188.60
4.28
6.019
95.12
56.64
-40.454
0.0
188.60
4.28
6.019
93.45
56.64
-39.390
0.0
188.60
4.29
6.109
100.70
58.34
-42.066
0.0
188.60
4.32
6.439
106.40
65.72
-38.233
0.0
188.60
4.55
14.843
91.10
77.11
-15.357
0.0
188.60
4.56
14.870
93.70
77.15
-17.663
0.0
188.60
4.57
14.897
98.98
77.20
-22.004
0.0
278
Data from Sokolova and Golubev [80] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm'3 mW-m'^-K'^ %
188.60
5.99
16.736
94.12
84.36
-10.370
0.0
188.40
5.99
16.793
93.24
84.62
-9.245
0.0
188.40
5.99
16.793
94.58
84.62
-10.531
0.0
188.40
5.99
16.793
93.95
84.62
-9.931
0.0
188.40
7.94
17.907
94.79
91.69
-3.270
0.0
188.40
7.94
17.907
94.62
91.69
-3.097
0.0
188.20
10.10
18.737
97.43
97.93
0.513
0.0
188.20
10.10
18.737
97.13
97.93
0.824
0.0
188.20
10.10
18.737
98.14
97.93
-0.214
0.0
187.90
11.08
19.069
100.30
100.63
0.329
0.0
187.90
11.08
19.069
99.06
100.63
1.585
0.0
188.60
14.92
19.874
106.00
107.96
1.849
0.0
188.60
14.92
19.874
104.00
107.96
3.808
0.0
188.60
19.53
20.680
113.60
116.02
2.130
0.0
188.60
19.53
20.680
111.80
116.02
3.775
0.0
188.90
19.62
20.664
112.60
115.89
2.922
0.0
188.90
19.62
20.664
111.30
115.89
4.124
0.0
187.90
20.70
20.924
115.50
118.52
2.615
0.0
187.90
20.89
20.951
114.50
118.82
3.773
0.0
187.90
20.89
20.951
113.80
118.82
4.411
0.0
188.40
29.63
21.964
127.50
130.69
2.502
0.0
188.40
29.73
21.975
126.70
130.82
3.252
0.0
188.40
29.73
21.975
127.50
130.82
2.604
0.0
188.20
39.33
22.871
138.20
142.58
3.169
0.0
188.20
39.54
22.888
138.00
142.82
3.493
0.0
187.90
47.19
23.484
147.40
151.39
2.707
0.0
187.90
47.19
23.484
145.50
151.39
4.048
0.0
187.90
49.14
23.618
149.10
153.42
2.897
0.0
183.20
0.10
0.066
19.68
19.81
0.661
0.0
183.20
0.26
0.174
19.68
20.01
1.677
0.0
183.70
0.26
0.174
19.95
20.07
0.602
0.0
182.90
1.57
1.207
21.77
22.21
2.021
0.0
183.20
1.57
1.204
21.65
22.24
2.725
0.0
183.20
2.58
2.296
25.75
25.56
-0.738
0.0
183.20
2.58
2.296
25.46
25.56
0.393
0.0
279
Data from Sokolova and Golubev [80] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-din'^ mW-m'^-K'^ %
183.20
3.07
3.039
28.63
28.65
0.070
0.0
182.90
3.69
16.486
87.47
81.78
-6.505
0.0
182.90
3.69
16.486
88.56
81.78
-7.656
0.0
182.90
7.46
18.748
96.66
97.18
0.538
0.0
183.20
7.46
18.694
98.62
96.78
-1.866
0.0
183.50
10.01
19.425
105.10
103.06
-1.941
0.0
183.50
10.01
19.425
102.30
103.06
0.743
0.0
183.50
14.92
20.472
112.50
113.12
0.551
0.0
183.50
14.92
20.472
111.80
113.12
1.181
0.0
183.70
19.72
21.200
118.90
120.98
1.749
0.0
183.70
19.72
21.200
120.10
120.98
0.733
0.0
183.50
29.53
22.352
131.70
134.90
2.430
0.0
183.50
29.53
22.352
133.30
134.90
1.200
0.0
183.50
39.73
23.234
142.70
147.03
3.034
0.0
183.20
49.14
23.918
152.70
157.33
3.032
0.0
183.20
49.14
23.918
151.50
157.33
3.848
0.0
176.80
0.10
0.069
19.01
19.05
0.210
0.0
177.00
0.30
0.210
19.32
19.33
0.052
0.0
177.00
0.30
0.210
19.22
19.33
0.572
0.0
175.70
0.91
0.685
20.23
20.14
-0.445
0.0
176.80
1.67
1.377
22.58
22.00
-2.569
0.0
176.50
2.61
2.605
28.53
26.33
-7.711
0.0
176.50
2.61
2.605
28.24
26.33
-6.763
0.0
176.40
3.83
18.574
100.40
94.85
-5.528
0.0
176.40
3.83
18.574
99.40
94.85
-4.577
0.0
176.70
5.01
19.010
102.60
98.49
-4.006
0.0
176.70
5.01
19.010
102.00
98.49
-3.441
0.0
177.00
6.24
19.377
105.40
101.72
-3.491
0.0
177.50
7.95
19.782
108.90
105.50
-3.122
0.0
176.70
7.95
19.902
108.00
106.54
-1.352
0.0
177.00
10.06
20.341
112.60
110.89
-1.519
0.0
177.50
11.68
20.596
116.40
113.58
-2.423
0.0
177.50
11.68
20.596
115.30
113.58
-1.492
0.0
176.50
19.72
21.899
127.30
128.17
0.683
0.0
176.50
19.72
21.899
129.00
128.17
-0.643
0.0
280
Data from Sokolova and Golubev [80] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm'^ mW-m'^-K"^ %
176.50
29.53
22.913
140.60
141.39
0.562
0.0
176.70
39.19
23.672
150.10
152.47
1.579
0.0
176.70
39.19
23.672
149.10
152.47
2.260
0.0
177.00
48.80
24.292
158.00
162.35
2.753
0.0
177.00
48.80
24.292
159.00
162.35
2.107
0.0
165.30
0.10
0.074
17.75
17.69
-0.338
0.0
166.00
0.75
0.596
18.48
18.83
1.894
0.0
164.20
1.54
1.427
22.88
20.99
-8.260
0.0
164.20
1.54
1.427
22.65
20.99
-7.329
0.0
165.00
3.59
20.635
124.70
112.25
-9.984
0.0
165.50
3.59
20.555
125.00
111.49
-10.808
0.0
164.20
5.20
21.102
126.10
117.15
-7.098
0.0
165.00
5.40
21.029
126.80
116.46
-8.155
0.0
165.30
7.95
21.454
131.30
121.28
-7.631
0.0
164.70
9.71
21.803
134.20
125.29
-6.639
0.0
166.00
14.81
22.338
141.70
132.13
-6.754
0.0
164.70
20.36
23.055
147.40
141.54
-3.976
0.0
164.70
20.36
23.055
148.50
141.54
-4.687
0.0
166.20
29.33
23.707
157.20
151.28
-3.766
0.0
164.70
29.53
23.839
157.20
153.05
-2.640
0.0
164.20
39.14
24.541
167.30
164.26
-1.817
0.0
164.20
49.14
25.127
175.30
174.45
-0.485
0.0
164.20
49.14
25.127
175.70
174.45
-0.711
0.0
152.60
0.10
0.080
16.39
16.19
-1.220
0.0
151.50
0.36
0.302
16.93
16.50
-2.540
0.0
151.50
0.36
0.302
17.58
16.50
-6.143
0.0
152.70
1.60
22.039
144.70
126.36
-12.674
0.0
152.70
3.07
22.272
148.20
129.26
-12.780
0.0
152.20
7.36
22.903
153.50
137.42
-10.476
0.0
152.20
7.36
22.903
156.70
137.42
-12.304
0.0
152.70
9.91
23.139
156.90
140.75
-10.293
0.0
151.80
10.60
23.304
158.60
142.92
-9.887
0.0
152.90
14.81
23.608
164.10
147.53
-10.098
0.0
153.20
14.81
23.580
164.00
147.17
-10.262
0.0
152.70
19.72
24.048
171.10
154.17
-9.895
0.0
281
Data from Sokolova and Golubev [80] (continued)
T P p A.exp A.cal Dev Wt
K MPa mol-dm'^ mW-m'^K'^ %
152.90
29.13
24.714
180.60
165.05
-8.610
0.0
152.70
29.33
24.743
178.20
165.49
-7.132
0.0
152.90
39.14
25.321
185.00
175.70
-5.027
0.0
152.90
39.14
25.321
187.90
175.70
-6.493
0.0
152.70
39.24
25.340
184.80
176.01
-4.756
0.0
152.70
49.14
25.855
194.30
185.73
-4.411
0.0
140.30
0.10
0.087
15.07
14.75
-2.123
0.0
140.30
0.30
0.272
16.26
15.15
-6.827
0.0
140.00
0.30
0.273
16.36
15.12
-7.579
0.0
141.00
1.47
23.477
168.10
143.50
-14.634
0.0
141.00
3.36
23.683
170.10
146 . 50
-13.874
0.0
141.00
3.36
23.683
170.50
146.50
-14.076
0.0
141.00
5.10
23.859
172.90
149.12
-13.754
0.0
140.80
5.99
23.966
173.50
150.69
-13.147
0.0
139.90
7.94
24.233
177.40
154.63
-12.835
0.0
139.30
7.94
24.291
174.00
155.44
-10.667
0.0
139.50
9.32
24.388
177.40
157.02
-11.488
0.0
139.50
12.07
24.609
180.80
160.59
-11.178
0.0
139.50
14.81
24.813
183.20
163.99
-10.486
0.0
140.30
19.62
25.078
188.40
168.69
-10.462
0.0
140.00
19.72
25.109
187.10
169.17
-9.583
0.0
140.00
29.72
25.711
196.70
180.06
-8.460
0.0
140.00
39.73
26.227
201.20
190.05
-5.542
0.0
140.00
49.14
26.656
210.40
198.84
-5.494
0.0
118.80
0.10
0.104
12.71
12.27
-3.462
0.0
117.80
0.46
25.788
196.80
175.69
-10.727
0.0
119.00
6.97
26.087
201.00
181.57
-9.667
0.0
119.70
11.48
26.286
200.30
185.57
-7.354
0.0
119.70
11.48
26.286
205.40
185.57
-9.654
0.0
119.50
14.92
26.488
206.80
189.45
-8.390
0.0
118.00
19.72
26.844
211.80
196.15
-7.389
0.0
117.60
29.53
27.312
217.20
205.89
-5.207
0.0
117.60
39.24
27.700
223.40
214.50
-3.984
0.0
119.90
39.43
27.555
223.40
212.10
-5.058
0.0
119.90
48.75
27.902
229.10
220.06
-3.946
0.0
282
Data from Sokolova and Golubev [80] (continued)
T P p A,exp A,cal
K MPa mol-dm"3 mW-m'^-K"^
Dev
Wt
119.90
48.95
27.909
226.50
220.22
-2.773
0.0
108.90
2.95
26.741
208.80
190.84
-8.602
0.0
108.90
2.95
26.741
209.80
190.84
-9.037
0.0
109.40
4.70
26.790
209.00
192.00
-8.134
0.0
109.40
4.70
26.790
211.20
192.00
-9.091
0.0
109.20
9.81
27.063
213.50
197.45
-7.518
0.0
109.90
14.81
27.241
215.30
201.43
-6.442
0.0
109.90
14.81
27.241
216.80
201.43
-7.089
0.0
109.20
19.72
27.509
220.30
206.87
-6.096
0.0
109.20
19.72
27.509
220.00
206.87
-5.968
0.0
109.40
29.53
27.888
225.60
215.36
-4.539
0.0
109.40
38.94
28.231
230.00
223.28
-2.922
0.0
109.40
39.14
28.238
230.00
223.45
-2.848
0.0
109.40
49.73
28.591
237.80
231.96
-2.456
0.0
109.40
49.93
28.597
235.00
232.11
-1.230
0.0
Number of Points (Ref. 80) 445
AAD-%
AAD
9.654
10.265
BIAS-%
BIAS
-8.376 RMS-% 13.781
-9.301 RMS 17.521 mW-m'^ -K"^
Data from
Yorizane et
al. [82]
T
P
P
A , exp
A.cal
Dev
Wt
K
MPa
mol -dm" ^
mW • m" ^
•K-i
%
323.35
0.10
0.037
37.70
37.74
0.106
0.0
319.95
0.10
0.038
37.50
37.24
-0.693
0.0
316.75
0.10
0.038
37.30
36.77
-1.421
0.0
312.85
0.10
0.038
36.70
36.21
-1.335
0.0
309.35
0.10
0.039
36.30
35.71
-1.625
0.0
308.25
0.10
0.039
35.70
35.55
-0.420
0.0
303.15
0.10
0.040
35.10
34.83
-0.769
0.0
297.75
0.10
0.040
34.40
34.08
-0.930
0.0
297.75
2.55
1.077
36.30
35.84
-1.267
0.0
297.75
5.10
2.252
38.90
38.16
-1.902
0.0
283
Data from Yorizane et al. [82] (continued)
T P p A,exp A.cal
K mPa mol-dra"^ mW-m'-^-K'^
Number of Points (Ref. 82) 32
Dev
AAD-%
AAD
2.024
0.923
BIAS-%
BIAS
■2.009
•0.918
RMS-%
RMS
1.182
0.640 mW-m"i
Wt
297.75
7.50
3.442
42.40
40.92
-3.491
0.0
303.15
0.10
0.040
35.10
34.83
-0.769
0.0
303.15
5.30
2.291
39.90
38.99
-2.281
0.0
303.25
10.01
4.607
46.30
44.77
-3.305
0.0
303.25
14.73
7.017
55.30
52.33
-5.371
0.0
309.85
0.10
0.039
36.60
35.78
-2.240
0.0
312.95
5.07
2.093
41.10
39.95
-2.798
0.0
312.85
9.88
4.314
46.60
45.26
-2.876
0.0
316.75
0.10
0.038
37.20
36.77
-1.156
0.0
316.75
2.58
1.015
39.00
38.41
-1.513
0.0
316.75
7.60
3.182
44.30
42.92
-3.115
0.0
316.85
9.93
4.251
47.10
45.64
-3.100
0.0
316.65
12.31
5.366
50.10
48.79
-2.615
0.0
316.75
17.36
7.658
57.90
56.28
-2.798
0.0
317.75
0.10
0.038
37.20
36.92
-0.753
0.0
317.75
5.15
2.087
41.60
40.62
-2.356
0.0
317.75
10.00
4.264
47.20
45.81
-2.945
0.0
317.75
14.82
6.489
53.80
52.46
-2.491
0.0
317.75
19.71
8.601
61.20
59.77
-2.337
0.0
323.45
0.10
0.037
37.70
37.75
0.133
0.0
323.45
9.96
4.130
47.70
46.26
-3.019
0.0
323.45
14.80
6.285
54.10
52.58
-2.810
0.0
K
- 1
Data from Zheng et al. [75]
T P p
K mPa mol • dm" ^
A , exp X , cal
mW-m-l-K"i
Dev
Wt
299.45
0.10
0.040
34.74
34.31
-1.238
0.0
299.45
1.07
0.438
34.92
34.96
0.115
0.0
299.45
2.04
0.849
35.99
35.67
-0.889
0.0
299.45
3.00
1.269
36.56
36.43
-0.356
0.0
299.45
3.97
1.707
37.68
37.27
-1.088
0.0
284
Data from Zheng et al. [75] (continued)
T P p A.exp A.cal
K mPa mol-dm"^ mW-m"^-K"^
Dev
Wt
299.45
4.94
2.159
38.43
38.20
-0.598
0.0
299.45
5.91
2.624
39.86
39.21
-1.631
0.0
299.45
6.88
3.101
40.78
40.32
-1.128
0.0
299.45
7.79
3.559
42.32
41.44
-2.079
0.0
299.45
7.84
3.584
42.56
41.51
-2.467
0.0
299.45
8.81
4.082
43.35
42.81
-1.246
0.0
299.45
9.78
4.587
44.89
44.21
-1.515
0.0
299.45
10.75
5.098
46.30
45.69
-1.317
0.0
299.45
11.71
5.606
47.93
47.24
-1.440
0.0
299.45
12.68
6.119
49.95
48.87
-2.162
0.0
299.45
13.65
6.628
51.14
50.54
-1.173
0.0
299.45
14.62
7.132
52.90
52.25
-1.229
0.0
299.45
15.54
7.601
54.51
53.89
-1.137
0.0
299.45
15.59
7.626
54.65
53.98
-1.226
0.0
Number of Points (Ref. 75) 19
AAD-%
AAD
1.265
0.565
BIAS-%
BIAS
■1.253
■0.561
RMS-%
RMS
0.586
0.275 mW-m'i
Number of Points Total with positive weight 920
AAD-%
AAD
0.518
0.364
BIAS-%
BIAS
0.003
-0.002
RMS-%
RMS
0.749
0.500 mW-m"i -K'^
Number of Points Total excluding Ref. [80] (Sokolova and Golubev) 1447
AAD-% 0.805 BIAS-% -0.022 RMS-% 1.346
AAD 0.709 BIAS -0.030 RMS 2 .020 mW-m' ^ -K" ^
Number of Points Total
1892
AAD-%
AAD
2.886
2.957
BIAS-%
BIAS
■1.985
■2.208
RMS-%
RMS
7.656
9.528 mW-m'i -K'^
285
APPENDIX B
TABLES FOR THE THEBIMOPHYSICAL PROPERTIES OF METHANE
Bl. PROPERTIES OF IDEAL GAS AT 0.1 MPA AND
DILUTE GAS TRANSPORT PROPERTIES 288
B2 . PROPERTIES ALONG SATURATION BOUNDARY 298
B3. PROPERTIES IN THE SINGLE-PHASE REGION ALONG ISOBARS 301
B4. PROPERTIES IN THE SINGLE-PHASE REGION ALONG ISOTHERMS 412
The tables in this Appendix give the values of several thermophysical
properties at specified values of the independent state variables as
evaluated from the correlating equations given in the main text of this
report. The uncertainties in the dependent thermophysical properties are
discussed in Section 4. Notes included at the head of each table should
also be consulted.
287
TABLE Bl
PROPERTIES OF IDEAL GAS AT . 1 MPa AND
DILUTE GAS TRANSPORT PROPERTIES
Notes for Table Bl . The ideal gas values of the Helmholtz energy, enthalpy,
entropy and isobaric specific heat capacity are evaluated from eq (5). The
conversion from atmospheric pressure to 0. 1 MPa affects the values of A^"^ and
S^''. The dilute gas viscosity is from eq (9) and the dilute gas thermal
conductivity is from eq (11).
T
A'^
jjid
gid
Cid
•^o
^0
K
kJ-mol"^
kJ-mol*i
J -mol'
i.K-i
^Pa- s
mW-m'^ -K'l
90.6854
-11.023
3.001
146.33
33.276
3.61
8.75
91.
-11.072
3.012
146.45
33.276
3.62
8.78
92.
-11.226
3.045
146.81
33.276
3.66
8.90
93.
-11.382
3.078
147.17
33.276
3.69
9.01
94.
-11.537
3.111
147.52
33.276
3.73
9.13
95.
-11.693
3.145
147.88
33.276
3.77
9.25
96.
-11.850
3.178
148.23
33.277
3.80
9.36
97.
-12.007
3.211
148.57
33.277
3.84
9.48
98.
-12.164
3.245
148.91
33.277
3.88
9.59
99.
-12.321
3.278
149.25
33.277
3.92
9.71
100.
-12.479
3.311
149.58
33.277
3.95
9.83
101.
-12.637
3.344
149.91
33.277
3.99
9.94
102.
-12.795
3.378
150.24
33.277
4.03
10.06
103.
-12.954
3.411
150.57
33.277
4.07
10.18
104.
-13.113
3.444
150.89
33.277
4.10
10.29
105.
-13.272
3.477
151.21
33.277
4.14
10.41
106.
-13.432
3.511
151.52
33.277
4.18
10.53
107.
-13.592
3.544
151.83
33.277
4.22
10.65
108.
-13.752
3.577
152.14
33.277
4.25
10.76
109.
-13.913
3.611
152.45
33.277
4.29
10.88
110.
-14.074
3.644
152.76
33.277
4.33
11.00
111.
-14.235
3.677
153.06
33.278
4.37
11.12
112.
-14.397
3.710
153.35
33.278
4.41
11.23
113.
-14.558
3.744
153.65
33.278
4.44
11.35
114.
-14.720
3.777
153.94
33.278
4.48
11.47
115.
-14.883
3.810
154.23
33.278
4.52
11.59
116.
-15.046
3.843
154.52
33.278
4.56
11.70
117.
-15.209
3.877
154.81
33.279
4.60
11.82
118.
-15.372
3.910
155.09
33.279
4.63
11.94
119.
-15.535
3.943
155.37
33.279
4.67
12.06
288
Table Bl (continued)
T
Aid
Hid
gid
Cid
no
^0
K
kJ-mol-i
kJ-mol"i
J-mol'
i.K-i
fiPa- s
mW • m" ^
120.
-15.699
3.977
155.65
33.279
4.71
12.18
121.
-15.863
4.010
155.93
33.280
4.75
12.30
122.
-16.028
4.043
156.20
33.280
4.79
12.41
123.
-16.192
4.076
156.47
33.280
4.82
12.53
124.
-16.357
4.110
156.74
33.281
4.86
12.65
125.
-16.522
4.143
157.01
33.281
4.90
12.77
126.
-16.688
4.176
157.27
33.281
4.94
12.89
127.
-16.854
4.210
157.54
33.282
4.98
13.01
128.
-17.020
4.243
157.80
33.282
5.02
13.12
129.
-17.186
4.276
158.06
33.283
5.05
13.24
130.
-17.352
4.309
158.31
33.283
5.09
13.36
131.
-17.519
4.343
158.57
33.284
5.13
13.48
132.
-17.686
4.376
158.82
33.284
5.17
13.60
133.
-17.853
4.409
159.07
33.285
5.21
13.72
134.
-18.021
4.443
159.32
33.285
5.25
13.84
135.
-18.189
4.476
159.57
33.286
5.28
13.95
136.
-18.357
4.509
159.82
33.287
5.32
14.07
137.
-18.525
4.542
160.06
33.287
5.36
14.19
138.
-18.693
4.576
160.30
33.288
5.40
14.31
139.
-18.862
4.609
160.54
33.289
5.44
14.43
140.
-19.031
4.642
160.78
33.290
5.48
14.55
141.
-19.200
4.676
161.02
33.291
5.51
14.67
142.
-19.370
4.709
161.25
33.292
5.55
14.78
143.
-19.539
4.742
161.49
33.293
5.59
14.90
144.
-19.709
4.775
161.72
33.294
5.63
15.02
145.
-19.880
4.809
161.95
33.295
5.67
15.14
146.
-20.050
4.842
162.18
33.296
5.71
15.26
147.
-20.221
4.875
162.41
33.297
5.74
15.38
148.
-20.391
4.909
162.63
33.299
5.78
15.50
149.
-20.562
4.942
162.86
33.300
5.82
15.61
150.
-20.734
4.975
163.08
33.302
5.86
15.73
151.
-20.905
5.009
163.30
33.303
5.90
15.85
152.
-21.077
5.042
163.52
33.305
5.93
15.97
153.
-21.249
5.075
163.74
33.306
5.97
16.09
154.
-21.421
5.108
163.95
33.308
6.01
16.21
155.
-21.593
5.142
164.17
33.310
6.05
16.32
156.
-21.766
5.175
164.38
33.312
6.09
16.44
157.
-21.939
5.208
164.60
33.314
6.13
16.56
158.
-22.112
5.242
164.81
33.316
6.16
16.68
159.
-22.285
5.275
165.02
33.318
6.20
16.80
289
Table Bl
(continued)
T
^id
Hid
Sid
r'id
flQ
>o
K
kJ-mol-i
kJ-mol"^
J -mol"
i.K-1
/iPa-s
mW • m" ^
160.
-22.459
5.308
165.23
33.320
6.24
16.92
161.
-22.632
5.342
165.44
33.322
6.28
17.03
162.
-22.806
5.375
165.64
33.325
6.32
17.15
163.
-22.980
5.408
165.85
33.327
6.35
17.27
164.
-23.154
5.442
166.05
33.330
6.39
17.39
165.
-23.329
5.475
166.25
33.332
6.43
17.51
166.
-23.503
5.508
166.46
33.335
6.47
17.63
167.
-23.678
5.542
166.66
33.338
6.50
17.74
168.
-23.853
5.575
166.85
33.341
6.54
17.86
169.
-24.029
5.608
167.05
33.344
6.58
17.98
170.
-24.204
5.642
167.25
33.348
6.62
18.10
171.
-24.380
5.675
167.44
33.351
6.66
18.22
172.
-24.556
5.708
167.64
33.355
6.69
18.33
173.
-24.732
5.742
167.83
33.358
6.73
18.45
174.
-24.908
5.775
168.02
33.362
6.77
18.57
175.
-25.084
5.808
168.22
33.366
6.81
18.69
176.
-25.261
5.842
168.41
33.370
6.84
18.81
177.
-25.438
5.875
168.60
33.374
6.88
18.92
178.
-25.615
5.909
168.78
33.379
6.92
19.04
179.
-25.792
5.942
168.97
33.383
6.96
19.16
180.
-25.969
5.975
169.16
33.388
6.99
19.28
181.
-26.147
6.009
169.34
33.393
7.03
19.40
182.
-26.325
6.042
169.53
33.397
7.07
19.52
183.
-26.503
6.076
169.71
33.403
7.10
19.63
184.
-26.681
6.109
169.89
33.408
7.14
19.75
185.
-26.859
6.142
170.07
33.413
7.18
19.87
186.
-27.038
6.176
170.25
33.419
7.22
19.99
187.
-27.216
6.209
170.43
33.425
7.25
20.11
188.
-27.395
6.243
170.61
33.431
7.29
20.22
189.
-27.574
6.276
170.79
33.437
7.33
20.34
190.
-27.753
6.309
170.96
33.443
7.36
20.46
190.551
-27.852
6.328
171.06
33.447
7.38
20.52
191.
-27.933
6.343
171.14
33.450
7.40
20.58
192.
-28.112
6.376
171.31
33.457
7.44
20.70
193.
-28.292
6.410
171.49
33.463
7.48
20.81
194.
-28.472
6.443
171.66
33.471
7.51
20.93
195.
-28.652
6.477
171.83
33.478
7.55
21.05
196.
-28.832
6.510
172.00
33.485
7.59
21.17
197.
-29.012
6.544
172.17
33.493
7.62
21.29
198.
-29.193
6.577
172.34
33.501
7.66
21.41
290
Table Bl (continued)
T
A'^
Hid
gid
Cid
'70
^0
K
kJ-mol"i
kJ-mol'i
J 'mol'
i.K-i
/iPa-s
mW • m" ^
199.
-29.374
6.611
172.51
33.509
7.70
21.52
200.
-29.555
6.644
172.68
33.518
7.73
21.64
201.
-29.736
6.678
172.85
33.526
7.77
21.76
202.
-29.917
6.711
173.01
33.535
7.81
21.88
203.
-30.098
6.745
173.18
33.544
7.84
22.00
204.
-30.280
6.778
173.34
33.553
7.88
22.12
205.
-30.462
6.812
173.51
33.563
7.92
22.24
206.
-30.644
6.846
173.67
33.573
7.95
22.36
207.
-30.826
6.879
173.83
33.583
7.99
22.47
208.
-31.008
6.913
174.00
33.593
8.02
22.59
209.
-31.190
6.946
174.16
33.603
8.06
22.71
210.
-31.373
6.980
174.32
33.614
8.10
22.83
211.
-31.556
7.014
174.48
33.625
8.13
22.95
212.
-31.738
7.047
174.64
33.636
8.17
23.07
213.
-31.921
7.081
174.79
33.648
8.21
23.19
214.
-32.105
7.114
174.95
33.659
8.24
23.31
215.
-32.288
7.148
175.11
33.671
8.28
23.43
216.
-32.471
7.182
175.27
33.683
8.31
23.55
217.
-32.655
7.215
175.42
33.696
8.35
23.67
218.
-32.839
7.249
175.58
33.709
8.38
23.79
219.
-33.023
7.283
175.73
33.722
8.42
23.91
220.
-33.207
7.317
175.88
33.735
8.46
24.03
221.
-33.391
7.350
176.04
33.749
8.49
24.15
222.
-33.576
7.384
176.19
33.762
8.53
24.27
223.
-33.760
7.418
176.34
33.777
8.56
24.39
224.
-33.945
7.452
176.49
33.791
8.60
24.51
225.
-34.130
7.485
176.64
33.806
8.63
24.63
226.
-34.315
7.519
176.79
33.821
8.67
24.75
227.
-34.500
7.553
176.94
33.836
8.71
24.87
228.
-34.685
7.587
177.09
33.851
8.74
25.00
229.
-34.871
7.621
177.24
33.867
8.78
25.12
230.
-35.057
7.655
177.39
33.883
8.81
25.24
231.
-35.242
7.689
177.53
33.900
8.85
25.36
232.
-35.428
7.722
177.68
33.916
8.88
25.48
233.
-35.614
7.756
177.83
33.933
8.92
25.60
234.
-35.801
7.790
177.97
33.951
8.95
25.73
235.
-35.987
7.824
178.12
33.968
8.99
25.85
236.
-36.173
7.858
178.26
33.986
9.02
25.97
237.
-36.360
7.892
178.40
34.004
9.06
26.09
238.
-36.547
7.926
178.55
34.023
9.09
26.22
291
Table Bl
(continued)
T
Aid
Hid
gid
Cid
'70
^0
K
kJ-mol"i
kJ-mol'i
J-mol"
i.K-i
/iPa- s
mW • m' ^
239.
-36.734
7.960
178.69
34.041
9.13
26.34
240.
-36.921
7.994
178.83
34.061
9.16
26.46
241.
-37.108
8.028
178.97
34.080
9.20
26.59
242.
-37.295
8.063
179.12
34.100
9.23
26.71
243.
-37.483
8.097
179.26
34.120
9.27
26.84
244.
-37.671
8.131
179.40
34.140
9.30
26.96
245.
-37.858
8.165
179.54
34.161
9.34
27.08
246.
-38.046
8.199
179.67
34.181
9.37
27.21
Ikl .
-38.234
8.233
179.81
34.203
9.41
27.33
248.
-38.423
8.268
179.95
34.224
9.44
27.46
249.
-38.611
8.302
180.09
34.246
9.48
27.58
250.
-38.799
8.336
180.23
34.268
9.51
27.71
251.
-38.988
8.370
180.36
34.291
9.54
27.83
252.
-39.177
8.405
180.50
34.313
9.58
27.96
253.
-39.366
8.439
180.64
34.337
9.61
28.09
254.
-39.555
8.473
180.77
34.360
9.65
28.21
255.
-39.744
8.508
180.91
34.384
9.68
28.34
256.
-39.933
8.542
181.04
34.408
9.72
28.47
257.
-40.122
8.576
181.18
34.432
9.75
28.59
258.
-40.312
8.611
181.31
34.457
9.79
28.72
259.
-40.502
8.645
181.44
34.482
9.82
28.85
260.
-40.692
8.680
181.58
34.507
9.85
28.97
261.
-40.882
8.714
181.71
34.533
9.89
29.10
262.
-41.072
8.749
181.84
34.559
9.92
29.23
263.
-41.262
8.783
181.97
34.585
9.96
29.36
264.
-41.452
8.818
182.10
34.612
9.99
29.49
265.
-41.643
8.853
182.23
34.638
10.02
29.62
266.
-41.833
8.887
182.36
34.666
10.06
29.75
267.
-42.024
8.922
182.49
34.693
10.09
29.88
268.
-42.215
8.957
182.62
34.721
10.12
30.01
269.
-42.406
8.991
182.75
34.749
10.16
30.14
270.
-42.597
9.026
182.88
34.778
10.19
30.27
271.
-42.788
9.061
183.01
34.806
10.23
30.40
272.
-42.980
9.096
183.14
34.835
10.26
30.53
273.
-43.171
9.131
183.27
34.865
10.29
30.66
273.15
-43.200
9.136
183.29
34.869
10.30
30.68
274.
-43.363
9.166
183.40
34.894
10.33
30.79
275.
-43.555
9.201
183.52
34.924
10.36
30.92
276.
-43.747
9.235
183.65
34.955
10.39
31.05
277.
-43.939
9.270
183.78
34.985
10.43
31.19
1 .v-l
292
Table Bl
(continued)
T
Aid
Hid
gid
Cid
no
^0
K
kJ-mol-i
kJ-mol"i
J -mol'
L.K-i
^iPa'S
mW-m"i -K-i
278.
-44.131
9.305
183.90
35.016
10.46
31.32
279.
-44.323
9.340
184.03
35.048
10.49
31.45
280.
-44.515
9.376
184.15
35.079
10.53
31.59
281.
-44.708
9.411
184.28
35.111
10.56
31.72
282.
-44.901
9.446
184.40
35.143
10.59
31.85
283.
-45.093
9.481
184.53
35.176
10.63
31.99
284.
-45.286
9.516
184.65
35.208
10.66
32.12
285.
-45.479
9.551
184.78
35.241
10.69
32.26
286.
-45.672
9.587
184.90
35.275
10.72
32.39
287.
-45.866
9.622
185.02
35.308
10.76
32.53
288.
-46.059
9.657
185.14
35.342
10.79
32.66
289.
-46.253
9.693
185.27
35.377
10.82
32.80
290.
-46.446
9.728
185.39
35.411
10.86
32.94
291.
-46.640
9.763
185.51
35.446
10.89
33.07
292.
-46.834
9.799
185.63
35.481
10.92
33.21
293.
-47.028
9.834
185.75
35.517
10.95
33.35
294.
-47.222
9.870
185.88
35.552
10.99
33.48
295.
-47.416
9.905
186.00
35.588
11.02
33.62
296.
-47.611
9.941
186.12
35.625
11.05
33.76
297.
-47.805
9.977
186.24
35.661
11.08
33.90
298.
-48.000
10.012
186.36
35.698
11.12
34.04
298.15
-48.029
10.018
186.38
35.704
11.12
34.06
299.
-48.195
10.048
186.48
35.735
11.15
34.18
300.
-48.389
10.084
186.60
35.773
11.18
34.32
301.
-48.584
10.120
186.72
35.811
11.21
34.46
302.
-48.779
10.155
186.83
35.848
11.25
34.60
303.
-48.975
10.191
186.95
35.887
11.28
34.74
304.
-49.170
10.227
187.07
35.925
11.31
34.88
305.
-49.365
10.263
187.19
35.964
11.34
35.02
306.
-49.561
10.299
187.31
36.003
11.37
35.16
307.
-49.757
10.335
187.42
36.043
11.41
35.30
308.
-49.952
10.371
187.54
36.082
11.44
35.44
309.
-50.148
10.407
187.66
36.122
11.47
35.59
310.
-50.344
10.443
187.78
36.162
11.50
35.73
311.
-50.541
10.480
187.89
36.203
11.53
35.87
312.
-50.737
10.516
188.01
36.243
11.57
36.02
313.
-50.933
10.552
188.12
36.284
11.60
36.16
314.
-51.130
10.588
188.24
36.326
11.63
36.31
315.
-51.326
10.625
188.36
36.367
11.66
36.45
316.
-51.523
10.661
188.47
36.409
11.69
36.59
293
Table Bl (continued)
T
^id
Hid
gid
Cid
•^o
^0
K
kJ-mol"^
kJ-mol'i
J -mol"
i.K-i
/iPa- s
mW • m" ^
317.
-51.720
10.698
188.59
36.451
11.73
36.74
318.
-51.917
10.734
188.70
36.493
11.76
36.89
319.
-52.114
10.771
188.82
36.535
11.79
37.03
320.
-52.311
10.807
188.93
36.578
11.82
37.18
321.
-52.508
10.844
189.04
36.621
11.85
37.32
322.
-52.706
10.880
189.16
36.664
11.88
37.47
323.
-52.903
10.917
189.27
36.708
11.92
37.62
324.
-53.101
10.954
189.39
36.751
11.95
37.77
325.
-53.299
10.991
189.50
36.795
11.98
37.91
326.
-53.497
11.027
189.61
36.840
12.01
38.06
327.
-53.695
11.064
189.72
36.884
12.04
38.21
328.
-53.893
11.101
189.84
36.929
12.07
38.36
329.
-54.091
11.138
189.95
36.973
12.10
38.51
330.
-54.289
11.175
190.06
37.018
12.13
38.66
331.
-54.488
11.212
190.17
37.064
12.17
38.81
332.
-54.686
11.249
190.29
37.109
12.20
38.96
333.
-54.885
11.286
190.40
37.155
12.23
39.11
334.
-55.084
11.324
190.51
37.201
12.26
39.26
335.
-55.282
11.361
190.62
37.247
12.29
39.41
336.
-55.481
11.398
190.73
37.294
12.32
39.57
337.
-55.681
11.435
190.84
37.340
12.35
39.72
338.
-55.880
11.473
190.95
37.387
12.38
39.87
339.
-56.079
11.510
191.06
37.434
12.41
40.02
340.
-56.279
11.548
191.17
37.481
12.44
40.18
341.
-56.478
11.585
191.28
37.529
12.48
40.33
342.
-56.678
11.623
191.39
37.576
12.51
40.48
343.
-56.878
11.660
191.50
37.624
12.54
40.64
344.
-57.077
11.698
191.61
37.672
12.57
40.79
345.
-57.277
11.736
191.72
37.720
12.60
40.95
346.
-57.477
11.773
191.83
37.769
12.63
41.10
347.
-57.678
11.811
191.94
37.817
12.66
41.26
348.
-57.878
11.849
192.05
37.866
12.69
41.41
349.
-58.078
11.887
192.16
37.915
12.72
41.57
350.
-58.279
11.925
192.27
37.964
12.75
41.73
351.
-58.480
11.963
192.38
38.014
12.78
41.88
352.
-58.680
12.001
192.48
38.063
12.81
42.04
353.
-58.881
12.039
192.59
38.113
12.84
42.20
354.
-59.082
12.077
192.70
38.163
12.87
42.36
355.
-59.283
12.115
192.81
38.213
12.90
42.51
356.
-59.484
12.154
192.92
38.263
12.93
42.67
1 .v-l
294
Table Bl (continued)
T
k'^
Hid
gid
/^id
»?o
^0
K
kJ-mol-i
kJ-mol'i
J -mol"
i.K-1
/iPa-s
mW-m-i -K-i
357.
-59.686
12.192
193.02
38.314
12.96
42.83
358.
-59.887
12.230
193.13
38.364
12.99
42.99
359.
-60.089
12.269
193.24
38.415
13.02
43.15
360.
-60.290
12.307
193.34
38.466
13.05
43.31
361.
-60.492
12.345
193.45
38.517
13.08
43.47
362.
-60.694
12.384
193.56
38.568
13.11
43.63
363.
-60.896
12.423
193.66
38.620
13.14
43.79
364.
-61.098
12.461
193.77
38.671
13.17
43.95
365.
-61.300
12.500
193.88
38.723
13.20
44.11
366.
-61.502
12.539
193.98
38.775
13.23
44.28
367.
-61.704
12.577
194.09
38.827
13.26
44.44
368.
-61.907
12.616
194.19
38.879
13.29
44.60
369.
-62.109
12.655
194.30
38.931
13.32
44.76
370.
-62.312
12.694
194.41
38.984
13.35
44.93
371.
-62.515
12.733
194.51
39.036
13.38
45.09
372.
-62.718
12.772
194.62
39.089
13.41
45.25
373.
-62.921
12.811
194.72
39.142
13.44
45.42
374.
-63.124
12.851
194.83
39.195
13.47
45.58
375.
-63.327
12.890
194.93
39.248
13.50
45.75
376.
-63.530
12.929
195.03
39.301
13.53
45.91
377.
-63.734
12.968
195.14
39.354
13.56
46.08
378.
-63.937
13.008
195.24
39.408
13.59
46.24
379.
-64.141
13.047
195.35
39.462
13.62
46.41
380.
-64.344
13.087
195.45
39.515
13.65
46.57
381.
-64.548
13.126
195.56
39.569
13.68
46.74
382.
-64.752
13.166
195.66
39.623
13.71
46.91
383.
-64.956
13.205
195.76
39.677
13.74
47.07
384.
-65.160
13.245
195.87
39.732
13.76
47.24
385.
-65.365
13.285
195.97
39.786
13.79
47.41
386.
-65.569
13.325
196.07
39.840
13.82
47.58
387.
-65.773
13.365
196.18
39.895
13.85
47.74
388.
-65.978
13.405
196.28
39.950
13.88
47.91
389.
-66.183
13.445
196.38
40.004
13.91
48.08
390.
-66.387
13.485
196.49
40.059
13.94
48.25
391.
-66.592
13.525
196.59
40.114
13.97
48.42
392.
-66.797
13.565
196.69
40.169
14.00
48.59
393.
-67.002
13.605
196.79
40.224
14.03
48.76
394.
-67.207
13.645
196.90
40.280
14.06
48.93
395.
-67.413
13.686
197.00
40.335
14.08
49.10
396.
-67.618
13.726
197.10
40.391
14.11
49.27
295
Table Bl (continued)
T
Aid
Hid
gid
Cid
Vo ^0
K
kJ-mol"i
kJ-mol"^
J -mol"
^•K"i /iPa-s mW-m-i
397.
-67.823
13.766
197.20
40.446 14
.14 49.44
398.
-68.029
13.807
197.30
40.502 14
.17 49.61
399.
-68.235
13.847
197.40
40.558 14
.20 49.79
400.
-68.440
13.888
197.51
40.613 14
.23 49.96
405.
-69.471
14.092
198.01
40.894
50.82
410.
-70.504
14.297
198.52
41.176
51.69
415.
-71.539
14.503
199.02
41.460
52.57
420.
-72.577
14.711
199.52
41.745
53.45
425.
-73.617
14.921
200.01
42.031
54.34
430.
-74.660
15.132
200.50
42.319
55.23
435.
-75.706
15.344
201.00
42.608
56.14
440.
-76.753
15.558
201.48
42.897
57.04
445.
-77.804
15.773
201.97
43.187
57.95
450.
-78.856
15.990
202.45
43.477
58.87
455.
-79.911
16.208
202.94
43.767
59.79
460.
-80.969
16.427
203.42
44.057
60.72
465.
-82.029
16.648
203.89
44.348
61.65
470.
-83.091
16.871
204.37
44.638
62.58
475.
-84.155
17.095
204.84
44.928
63.52
480.
-85.222
17.320
205.32
45.217
64.46
485.
-86.292
17.547
205.79
45.506
65.41
490.
-87.363
17.775
206.25
45.794
66.36
495.
-88.437
18.005
206.72
46.082
67.31
500.
-89.514
18.236
207.18
46.368
68.27
505.
-90.592
18.469
207.65
46.654
69.23
510.
-91.673
18.703
208.11
46.938
70.19
515.
-92.757
18.938
208.57
47.222
71.15
520.
-93.842
19.175
209.03
47.504
72.12
525.
-94.930
19.413
209.48
47.785
73.09
530.
-96.020
19.653
209.94
48.065
74.06
535.
-97.112
19.894
210.39
48.343
75.03
540.
-98.207
20.136
210.84
48.620
76.01
545.
-99.304
20.380
211.29
48.895
76.98
550.
-100.403
20.625
211.74
49.169
77.96
555.
-101.505
20.872
212.18
49.441
78.94
560.
-102.608
21.119
212.63
49.712
79.92
565.
-103.714
21.369
213.07
49.981
80.91
570.
-104.822
21.619
213.51
50.248
81.89
575.
-105.932
21.871
213.95
50.514
82.87
580.
-107.045
22.124
214.39
50.778
83.86
296
Table Bl (continued)
T
Ai'i
Hid
gid
Cid
'/o
Ao
K
kJ-mol"i
kJ-mol"i
J-mol"i
•K-i
/iPa-s
mW-m-i -K-i
585.
-108.159
22.379
214.83
51.040
84.85
590.
-109.276
22.635
215.26
51.300
85.83
595.
-110.395
22.892
215.70
51.558
86.82
600.
-111.516
23.150
216.13
51.815
87.81
297
TABLE B2
PROPERTIES ALONG SATURATION BOUNDARY
Notes for Table B2 . Values of the pressure, density of the saturated liquid,
density of the saturated vapor, specific heat capacity, sound speed, viscosity,
and thermal conductivity along the two phase liquid-vapor coexistence curve.
The quantities P^^l , P^l i and p^-^ are from the ancillary equations, eqs (3-5).
The specific heat capacity along the saturated boundary is from the equation in
Table 7; the sound speed is also taken from Table 7 but the density argument is
for the saturated liquid and is taken from column 3 of this table. The
viscosity and thermal conductivity at saturation are from eqs (8) and (9)
[with the terms evaluated from eqs (10-25)]; again the density input is from
column 3 of this table.
T
K
Po\.
P«rV
VL
w.
crL
MPa
mol-dm'^ mol-dm"'' J-mol"^-K~^ m-s'^
/iPa- s mW-m' -^ -K" ^
90.6854 0.011694
28.147
0.01564
52.98
1549.3
202.20
211.3
91.
0.012
28.12
0.016
53.08
1545.2
200.42
210.9
92.
0.014
28.04
0.018
53.37
1532.7
194.89
209.7
93.
0.016
27.95
0.020
53.63
1520.7
189.55
208.5
94.
0.018
27.87
0.023
53.85
1509.0
184.39
207.2
95.
0.020
27.78
0.025
54.05
1497.7
179.41
206.0
96.
0.022
27.70
0.028
54.24
1486.6
174.60
204.7
97.
0.025
27.61
0.031
54.40
1475.8
169.95
203.4
98.
0.028
27.52
0.035
54.54
1465.1
165.47
202.1
99.
0.031
27.44
0.038
54.68
1454.6
161.14
200.8
100.
0.034
27.35
0.042
54.80
1444 . 3
156.97
199.5
101.
0.038
27.27
0.046
54.91
1434.1
152.94
198.2
102.
0.042
27.18
0.051
55.02
1424.0
149.04
196.8
103.
0.047
27.09
0.056
55.12
1413.9
145.29
195.5
104.
0.051
27.00
0.061
55.21
1403.9
141.66
194.2
105.
0.056
26.92
0.066
55.30
1394.0
138.16
192.8
106.
0.062
26.83
0.072
55.39
1384.1
134.79
191.4
107.
0.068
26.74
0.078
55.47
1374.2
131.52
190.1
108.
0.074
26.65
0.085
55.56
1364.4
128.37
188.7
109.
0.081
26.56
0.092
55.64
1354.5
125.33
187.3
110.
0.088
26.47
0.100
55.72
1344.7
122.39
186.0
111.
0.096
26.38
0.108
55.81
1334.8
119.55
184.6
112.
0.104
26.29
0.116
55.89
1325.0
116.80
183.2
113.
0.113
26.20
0.125
55.98
1315.1
114.15
181.8
114.
0.122
26.11
0.135
56.07
1305.2
111.59
180.4
298
Table B2
(continue
d)
T
Pa
PaL
PaV
C.L
W.L
V^L
^.L
K
MPa
mol • dm" ^
mol -dra"^
J-mor^-K'i
m- s" ■'^
/iPa- s
raw • m" 1 • K" ^
115.
0.132
26.02
0.145
56.16
1295.3
109.11
179.0
116.
0.143
25.92
0.155
56.26
1285.4
106.71
177.6
117.
0.154
25.83
0.167
56.36
1275.4
104.38
176.2
118.
0.166
25.74
0.178
56.46
1265.4
102.14
174.8
119.
0.178
25.64
0.191
56.57
1255.4
99.96
173.4
120.
0.192
25.55
0.204
56.68
1245.3
97.85
172.0
121.
0.206
25.45
0.217
56.79
1235.2
95.81
170.6
122.
0.220
25.36
0.231
56.91
1225.1
93.83
169.2
123.
0.236
25.26
0.246
57.03
1214.9
91.91
167.8
124.
0.252
25.16
0.262
57.16
1204.7
90.05
166.3
125.
0.269
25.06
0.279
57.29
1194.4
88.25
164.9
126.
0.287
24.97
0.296
57.43
1184.0
86.49
163.5
127.
0.306
24.87
0.314
57.58
1173.7
84.79
162.1
128.
0.325
24.77
0.333
57.73
1163.2
83.14
160.7
129.
0.346
24.66
0.352
57.88
1152.7
81.53
159.2
130.
0.368
24.56
0.373
58.05
1142.2
79.97
157.8
131.
0.390
24.46
0.394
58.21
1131.6
78.45
156.4
132.
0.414
24.36
0.417
58.39
1120.9
76.97
155.0
133.
0.438
24.25
0.440
58.57
1110.2
75.53
153.6
134.
0.464
24.15
0.464
58.76
1099.4
74.13
152.1
135.
0.491
24.04
0.490
58.96
1088.6
72.76
150.7
136.
0.519
23.93
0.516
59.16
1077.7
71.43
149.3
137.
0.548
23.83
0.544
59.37
1066.7
70.13
147.9
138.
0.578
23.72
0.572
59.59
1055.6
68.86
146.4
139.
0.609
23.61
0.602
59.82
1044.5
67.62
145.0
140.
0.642
23.50
0.633
60.05
1033.3
66.42
143.6
141.
0.675
23.38
0.665
60.30
1022.1
65.23
142.2
142.
0.711
23.27
0.699
60.55
1010.7
64.08
140.7
143.
0.747
23.15
0.733
60.82
999.3
62.95
139.3
144.
0.785
23.04
0.770
61.09
987.8
61.85
137.9
145.
0.824
22.92
0.807
61.37
976.3
60.76
136.5
146.
0.864
22.80
0.846
61.67
964.6
59.70
135.0
147.
0.906
22.68
0.887
61.98
952.9
58.67
133.6
148.
0.950
22.56
0.929
62.30
941.1
57.65
132.2
149.
0.994
22.44
0.973
62.63
929.2
56.65
130.8
150.
1.041
22.31
1.018
62.98
917.2
55.67
129.3
151.
1.088
22.19
1.066
63.34
905.1
54.70
127.9
152.
1.138
22.06
1.115
63.72
892.9
53.76
126.5
153.
1.189
21.93
1.166
64.11
880.6
52.83
125.1
154.
1.242
21.80
1.219
64.52
868.2
51.91
123.6
299
Table B2 (continued)
T
P.
PcL
PaV
C.L
W.L
'?aL
Ki.
K
MPa
mol • dm" ^
mol • dm" ^
J-nor^-K'i
m- s" ^
/iPa- s
mW-m-i -K"!
155.
1.296
21.66
1.274
64.95
855.7
51.01
122.2
156.
1.352
21.53
1.331
65.40
843.1
50.13
120.8
157.
1.409
21.39
1.391
65.87
830.4
49.25
119.3
158.
1.469
21.25
1.452
66.36
817.6
48.39
117.9
159.
1.530
21.11
1.517
66.88
804.6
47.54
116.5
160.
1.593
20.96
1.584
67.42
791.5
46.70
115.0
161.
1.658
20.81
1.654
68.00
778.3
45.87
113.6
162.
1.724
20.66
1.726
68.60
765.0
45.05
112.1
163.
1.793
20.51
1.802
69.24
751.6
44.24
110.7
164.
1.864
20.36
1.880
69.92
738.0
43.44
109.3
165.
1.936
20.20
1.963
70.64
724.2
42.65
107.8
166.
2.011
20.03
2.048
71.40
710.3
41.86
106.4
167.
2.087
19.87
2.138
72.22
696.3
41.08
104.9
168.
2.166
19.70
2.232
73.10
682.1
40.30
103.4
169.
2.246
19.52
2.330
74.03
667.7
39.53
102.0
170.
2.329
19.35
2.432
75.04
653.2
38.76
100.5
171.
2.414
19.16
2.540
76.14
638.5
37.99
99.0
172.
2.502
18.97
2.653
77.33
623.6
37.23
97.5
173.
2.591
18.78
2.772
78.62
608.5
36.46
96.1
174.
2.683
18.58
2.897
80.05
593.2
35.70
94.6
175.
2.778
18.37
3.030
81.62
577.7
34.93
93.1
176.
2.874
18.16
3.170
83.36
562.0
34.16
91.6
177.
2.974
17.94
3.318
85.32
546.0
33.39
90.1
178.
3.075
17.70
3.477
87.53
529.8
32.61
88.5
179.
3.180
17.46
3.646
90.05
513.2
31.82
87.0
180.
3.287
17.21
3.827
92.96
496.4
31.01
85.5
181.
3.396
16.94
4.023
96.37
479.1
30.20
84.0
182.
3.509
16.65
4.236
100.42
461.3
29.36
82.5
183.
3.624
16.35
4.469
105.34
443.0
28.49
81.1
184.
3.742
16.02
4.726
111.46
423.8
27.60
79.7
185.
3.864
15.66
5.015
119.33
403.7
26.65
78.4
186.
3.988
15.26
5.344
129.94
382.2
25.65
77.3
187.
4.116
14.81
5.729
145.23
358.8
24.56
76.7
188.
4.247
14.27
6.200
169.79
332.7
23.33
76.9
189.
4.382
13.58
6.821
218.36
302.4
21.86
79.8
190.
4.521
12.50
7.827
389.90
264.3
19.75
100.3
190.551
4.5992
10.139
10.139
300
TABLE B3
PROPERTIES IN THE SINGLE- PHASE REGION ALONG ISOBARS
Notes for Table B3. Values of the density, compressibility factor, enthalpy,
entropy, isochoric and isobaric heat capacities, speed of sound, viscosity, and
thermal conductivity in the single-phase region of the methane fluid. The
independent variables were chosen to be temperature and pressure. The density
was evaluated by inverting the pressure equation in Table 7; the quantities H,
S, C^ , C , and W were then evaluated directly from the expressions in Table 7.
The viscosity and thermal conductivity are from eqs (7) and (8) [with the
terms evaluated from eqs (10-23)]; the density input is from column 3 of this
table .
METHANE ISOBAR AT P = 0.012 MPa
K mol-dm'-^
H
W
'p - »7 A
kJ/mol J/(mDl-K) J/(nol-K) J/(iiol-K) m-s^^ /xPa-s mW/(m-K)
90.685
28.145
0.001
-5.745
67
80
33
40
52
57
1548
8
202.08
211
2
90.685
0.0157
0.991
2.969
163
88
28
31
37
53
247
1
3.61
8
8
95.
0.0149
0.993
3.124
165
56
26
11
34
85
254
5
3.77
9
3
100.
0.0141
0.994
3.295
167
32
25
36
33
92
261
7
3.95
9
9
105.
0.0135
0.995
3.464
168
96
25
14
33
64
268
5
4.14
10
4
110.
0.0128
0.996
3.632
170
52
25
07
33
54
274
9
4.33
11
115.
0.0123
0.996
3.799
172
01
25
04
33
48
281
2
4.52
11
6
120.
0.0118
0.997
3.967
173
44
25
03
33
45
287
4
4.71
12
2
125.
0.0113
0.997
4.134
174
80
25
02
33
43
293
3
4.90
12
8
130.
0.0108
0.997
4.301
176
11
25
02
33
41
299
2
5.10
13
4
135.
0.0104
0.998
4.468
177
38
25
01
33
40
305
5.29
14
lAO.
0.0101
0.998
4.635
178
59
25
01
33
39
310
6
5.48
14
6
145.
0.0097
0.998
4.802
179
76
25
01
33
39
316
1
5.67
15
2
150.
0.0094
0.998
4.969
180
89
25
01
33
38
321
5
5.86
15
8
155.
0.0091
0.998
5.136
181
99
25
02
33
38
326
9
6.05
16
3
160.
0.0088
0.999
5.303
183
05
25
03
33
38
332
1
6.24
16
9
165.
0.0085
0.999
5.470
184
08
25
04
33
39
337
3
6.43
17
5
170.
0.0083
0.999
5.637
185
07
25
05
33
40
342
3
6.62
18
1
175.
0.0080
0.999
5.804
186
04
25
06
33
41
347
3
6.81
18
7
180.
0.0078
0.999
5.971
186
98
25
09
33
43
352
2
7.00
19
3
185.
0.0076
0.999
6.138
187
90
25
11
33
45
357
1
7.18
19
9
190.
0.0074
0.999
6.305
188
79
25
14
33
48
361
8
7.37
20
5
195.
0.0072
0.999
6.473
189
66
25
17
33
51
366
5
7.55
21
1
200.
0.0070
0.999
6.641
190
51
25
21
33
55
371
1
7.73
21
7
205.
0.0069
0.999
6.808
191
34
25
26
33
59
375
7
7.92
22
3
301
METHANE ISOBAR AT P = 0.012 MPa (continued)
T
P
z
H
S
Cv
Cp
W
»?
A
K
mol-dm"''
kJ/mol
J/(mol.K) J/(nol-K) J/(mol-K)
m- s' ^
/iPa
,-s
mW/(m-
210.
0.0067
.999
6.977
192.15
25.31
33.64
380.1
8
.10
22.9
215.
0.0065
.999
7.145
192.94
25.36
33.70
384.5
8
.28
23.5
220.
0.0064
.999
7.314
193.72
25.43
33.76
388.9
8
.46
24.1
225.
0.0063
.999
7.482
194.48
25.50
33.83
393.1
8
.64
24.7
230.
0.0061
1,
.000
7.652
195.22
25.57
33.90
397.3
8
.81
25.3
235.
0.0060
1,
.000
7.822
195.95
25.66
33.99
401.5
8,
.99
25.9
240.
0.0059
1,
.000
7.992
196.67
25.75
34.08
405.6
9,
.17
26.5
245.
0.0057
1,
.000
8.162
197.37
25.85
34.18
409.6
9,
.34
27.1
250.
0.0056
1,
,000
8.334
198.06
25.96
34.29
413.5
9,
.51
27.7
255.
0.0055
1,
.000
8.505
198.74
26.07
34.40
417.4
9,
.68
28.4
260.
0.0054
1,
,000
8.678
199.41
26.20
34.52
421.3
9,
.86
29.0
265.
0.0053
1.
,000
8.850
200.07
26.33
34.65
425.0
10,
.02
29.6
270.
0.0052
1,
,000
9.024
200.72
26.47
34.79
428.8
10,
.19
30.3
275.
0.0051
1,
,000
9.198
201.36
26.61
34.94
432.4
10,
.36
30.9
280.
0.0050
1.
,000
9.373
201.99
26.77
35.09
436.1
10,
,53
31.6
285.
0.0049
1,
,000
9.549
202.61
26.93
35.25
439.6
10,
.69
32.3
290.
0.0049
1,
.000
9.726
203.23
27.10
35.42
443.1
10,
,86
32.9
295.
0.0048
1,
,000
9.904
203.83
27.28
35.60
446.6
11,
,02
33.6
300.
0.0047
1,
.000
10.082
204.43
27.46
35.78
450.0
11,
,18
34.3
310.
0.0045
1,
,000
10.442
205.61
27.85
36.17
456.7
11.
,50
35.7
320.
0.0044
1,
,000
10.806
206.77
28.27
36.59
463.3
11.
82
37.2
330.
0.0043
1,
,000
11.174
207.90
28.71
37.03
469.6
12.
,14
38.7
340.
0.0041
1,
,000
11.546
209.01
29.17
37.49
475.8
12.
,45
40.2
350.
0.0040
1,
,000
11.923
210.11
29.65
37.97
481.9
12.
,75
41.7
360.
0.0039
1,
,000
12.306
211.18
30.15
38.47
487.9
13.
05
43.3
370.
0.0038
1,
.000
12.693
212.24
30.67
38.99
493.7
13.
,35
44.9
380.
0.0037
1,
.000
13.085
213.29
31.20
39.52
499.4
13.
65
46.6
390.
0.0036
1
,000
13.483
214.33
31.75
40.06
505.0
13.
,94
48.3
400.
0.0035
1
.000
13.887
215.35
32.30
40.62
510.6
14.
,23
50.0
410.
0.0034
1,
,000
14.296
216.36
32.86
41.18
516.0
51.7
420.
0.0033
1,
,000
14.710
217.36
33.43
41.75
521.4
53.5
430.
0.0033
1
,000
15.131
218.34
34.01
42.32
526.6
55.2
440.
0.0032
1,
,000
15.557
219.32
34.58
42.90
531.9
57.0
450.
0.0031
1
,000
15.989
220.29
35.16
43.48
537.0
58.9
460.
0.0031
1,
,000
16.427
221.26
35.74
44.06
542.1
60.7
470.
0.0030
1,
,000
16.870
222.21
36.32
44.64
547.1
62.6
480.
0.0029
1,
.000
17.319
223.16
36.90
45.22
552.1
64.5
490.
0.0029
1,
.000
17.774
224.09
37.48
45.80
557.0
66.4
500.
0.0028
1,
,000
18.235
225.03
38.05
46.37
561.9
68.3
520.
0.0027
1,
,000
19.174
226.87
39.19
47.51
571.6
72.1
302
METHANE ISOBAR AT P = 0.012 MPa (continued)
T pZHSC^CpWry A
K mol-dm'3 kJ/mol J/(mol-K) J/(mol-K) J/Cnol-K) m-s'^ /iPa-s mW/(m-K)
540. 0.0026 1.000
560. 0.0025 1.000
580. 0.0024 1.000
600. 0.0023 1.000
20
135
228.68
40.31
48.62
581.0
76
21
119
230.47
41.40
49.71
590.4
79
9
22
124
232.23
42.46
50.78
599.6
83
9
23
150
233.97
43.50
51.82
608.6
87
8
METHANE ISOBAR AT P = 0.025 MPa
H
W
mol • dm' ^
'p " »7 A
kJ/mol J/(niol-K) J/(nol-K) J/(nol-K) m-s'^ /zPa-s mW/(m-K)
95.
27.786
0.001
-5.515
70
28
33
99
53
76
1498.6
179.63
206
1
97.034
27.607
0.001
-5.403
71
44
34
07
54
18
1475.4
169.80
203
4
97.034
0.0314
0.986
3.166
159
75
28
02
37
36
254.9
3.85
9
6
LOO.
0.0305
0.987
3.273
160
84
26
53
35
53
259.9
3.96
9
9
105.
0.0289
0.989
3.448
162
54
25
56
34
32
267.3
4.15
10
5
110.
0.0276
0.991
3.618
164
12
25
26
33
91
274.1
4.33
11
1
115.
0.0264
0.992
3.787
165
63
25
16
33
75
280.5
4.53
11
6
120.
0.0252
0.993
3.956
167
06
25
11
33
67
286.7
4.72
12
2
125.
0.0242
0.994
4.124
168
43
25
09
33
61
292.7
4.91
12
8
130.
0.0233
0.994
4.292
169
75
25
07
33
57
298.7
5.10
13
4
135.
0.0224
0.995
4.459
171
02
25
06
33
53
304.5
5.29
14
140.
0.0216
0.996
4.627
172
24
25
05
33
51
310.1
5.48
14
6
145.
0.0208
0.996
4.795
173
41
25
04
33
49
315.7
5.67
15
2
150.
0.0201
0.996
4.962
174
55
25
04
33
47
321.2
5.86
15
8
155.
0.0195
0.997
5.129
175
64
25
04
33
46
326.5
6.05
16
4
160.
0.0188
0.997
5.297
176
71
25
05
33
46
331.8
6.24
17
165.
0.0183
0.997
5.464
177
74
25
05
33
46
337.0
6.43
17
6
170.
0.0177
0.997
5.631
178
73
25
07
33
46
342.1
6.62
18
1
175.
0.0172
0.998
5.799
179
70
25
08
33
47
347.1
6.81
18
7
180.
0.0167
0.998
5.966
180
65
25
10
33
48
352.0
7.00
19
3
185.
0.0163
0.998
6.133
181
57
25
12
33
50
356.9
7.18
19
9
190.
0.0159
0.998
6.301
182
46
25
15
33
52
361.6
7.37
20
5
195.
0.0154
0.998
6.469
183
33
25
18
33
55
366.3
7.55
21
1
200.
0.0151
0.998
6.636
184
18
25
22
33
59
370.9
7.74
21
7
205.
0.0147
0.999
6.804
185
01
25
26
33
63
375.5
7.92
22
3
210.
0.0143
0.999
6.973
185
82
25
31
33
67
380.0
8.10
22
9
215.
0.0140
0.999
7.141
186
61
25
37
33
73
384.4
8.28
23
5
220.
0.0137
0.999
7.310
187
39
25
43
33
79
388.7
8.46
24
1
225.
0.0134
0.999
7.479
188
15
25
50
33
85
393.0
8.64
24
7
230.
0.0131
0.999
7.649
188
89
25
58
33
.93
397.2
8.82
25
3
303
METHANE ISOBAR AT P = 0.025 MPa (continued)
T
K
235.
240.
245.
250.
255.
260.
265.
270.
275.
280.
285.
290.
295.
300.
310.
320.
330.
340.
350.
360.
370.
380.
390.
400.
410.
420.
430.
440.
450.
460.
470.
480.
490.
500.
520.
540.
560.
580.
600.
pZHSC^CpWr/ A
niol-dm'3 kJ/mol J/(mDl-K) J/(rtol-K) J/(nol-K) m-s"^ /iPa-s mW/(in-K)
0.0128
0.999
7,
.818
189
.63
25
.66
34
.01
401
.4
8,
.99
25
.9
0.0125
0.999
7,
.989
190
.34
25
.75
34
.10
405
.5
9,
.17
26
.5
0.0123
0.999
8
.159
191,
.05
25
.85
34
.20
409
.5
9
.34
27
.1
0.0120
0.999
8,
.331
191,
.74
25,
.96
34
.30
413
.4
9,
.51
27
.7
0.0118
0.999
8,
.502
192
.42
26,
.08
34
.42
417
.3
9,
.69
28
.4
0.0116
0.999
8,
.675
193,
.09
26,
.20
34,
.54
421
.2
9,
.86
29
.0
0.0114
0.999
8,
.848
193,
.75
26
.33
34,
.67
425
.0
10,
.03
29
.6
0.0111
0.999
9.
.022
194,
.40
26,
.47
34,
.81
428
.7
10,
.20
30
.3
0.0109
0.999
9,
.196
195,
.04
26,
.62
34,
.95
432
.4
10,
.36
30,
.9
0.0107
0.999
9,
.371
195,
.67
26,
.77
35,
.11
436
.0
10,
.53
31,
.6
0.0106
0.999
9,
.547
196,
.29
26,
.93
35,
.27
439
.6
10,
.70
32,
.3
0.0104
1.000
9,
.724
196,
.91
27,
.10
35,
.44
443
.1
10,
.86
33
.0
0.0102
1.000
9.
.901
197,
.51
27,
.28
35,
.61
446
.6
11,
.02
33
.6
0.0100
1.000
10.
.080
198,
.11
27,
.46
35,
.80
450
.0
11,
.19
34
.3
0.0097
1.000
10,
.440
199,
.29
27,
.85
36,
.18
456
.7
11,
.51
35
.8
0.0094
1.000
10,
.804
200,
.45
28,
.27
36,
.60
463,
.2
11,
.82
37,
.2
0.0091
1.000
11,
.172
201,
.58
28,
.71
37,
.04
469
.6
12,
,14
38,
.7
0.0088
1.000
11,
.544
202,
.69
29,
.17
37,
.50
475,
.8
12,
.45
40,
.2
0.0086
1.000
11,
.922
203,
.79
29,
.65
37,
.98
481
.9
12,
.75
41,
.7
0.0084
1.000
12,
.304
204,
.86
30,
.15
38,
.48
487,
.9
13,
,06
43,
.3
0.0081
1.000
12,
.692
205,
.93
30,
.67
39,
.00
493,
.7
13.
.36
44,
.9
0.0079
1.000
13,
.084
206,
.97
31,
.20
39,
.53
499,
.4
13.
.65
46,
.6
0.0077
1.000
13,
.482
208,
.01
31,
.75
40,
.07
505,
.0
13,
.94
48,
.3
0.0075
1.000
13,
.886
209,
.03
32,
.30
40,
.62
510.
.6
14.
.23
50,
.0
0.0073
1.000
14,
.295
210,
.04
32,
.86
41,
.19
516,
.0
51,
.7
0.0072
1.000
14,
.709
211,
.04
33,
.43
41,
.76
521,
.4
53,
.5
0.0070
1.000
15,
.130
212,
.03
34,
.01
42,
,33
526,
.6
55,
.2
0.0068
1.000
15,
.556
213,
.01
34,
.58
42.
.91
531,
.9
57,
.1
0.0067
1.000
15,
.988
213,
.98
35.
.16
43,
.49
537,
.0
58,
.9
0.0065
1.000
16,
.426
214,
.94
35,
,74
44,
,07
542,
.1
60,
.7
0.0064
1.000
16,
.869
215,
.89
36,
,32
44,
.65
547,
.1
62,
.6
0.0063
1.000
17,
.319
216,
.84
36,
,90
45.
.22
552,
,1
64.
,5
0.0061
1.000
17,
.774
217,
.78
37.
,48
45,
.80
557.
,1
66,
,4
0.0060
1.000
18,
.235
218,
.71
38,
,05
46.
.37
561,
,9
68.
3
0.0058
1.000
19,
.173
220,
.55
39.
,19
47.
.51
571.
.6
72.
1
0.0056
1.000
20,
.135
222,
,36
40,
.31
48.
,63
581,
.1
76.
0.0054
1.000
21,
.118
224,
,15
41.
.40
49.
,72
590,
.4
79.
9
0.0052
1.000
22,
.123
225,
.92
42.
.46
50.
78
599.
.6
83.
9
0.0050
1.000
23,
.149
227,
,65
43.
.50
51.
82
608.
.6
87.
8
304
METHANE ISOBAR AT P - 0.050 MPa
T
P
Z
H
S
Cv
Cp
W
V
A
K
mol • dm" ^
kJ/mol
J/(nDl-K) J/(nDl-K) J/(mDl-K)
m-s" ^
/iPa-s
mW/Cm-
95.
11 .IZl
0.002
-5.514
70.27
33.99
53.75
1498.8
179.68
206.1
100.
27.363
0.002
-5.243
73.05
34.08
54.64
1446 . 4
157.39
199.7
103.729
21 .021
0.002
-5.035
75.10
33.92
55.17
1406.6
142.63
194.5
103.729
0.0593
0.977
3.367
156.09
27.52
37.02
262.5
4.10
10.4
105.
0.0586
0.978
3.413
156.54
26.94
36.29
264.7
4.15
10.6
110.
0.0557
0.981
3.590
158.19
25.80
34.84
272.2
4.34
11.1
115.
0.0532
0.984
3.763
159.72
25.43
34.33
279.0
4.53
11.7
120.
0.0508
0.986
3.934
161.18
25.29
34.09
285.4
4.72
12.3
125.
0.0487
0.987
4.104
162.57
25.22
33.96
291.6
4.91
12.9
130.
0.0468
0.989
4.274
163.90
25.18
33.86
291 .e
5.10
13.5
135.
0.0450
0.990
4.443
165.17
25.15
33.79
303.5
5.30
14.0
140.
0.0433
0.991
4.612
166.40
25.13
33.73
309.3
5.49
14.6
145.
0.0418
0.992
4.780
167.58
25.11
33.69
314.9
5.68
15.2
150.
0.0404
0.993
4.949
168.72
25.10
33.65
320.5
5.87
15.8
155.
0.0391
0.993
5.117
169.83
25.09
33.62
325.9
6.06
16.4
160.
0.0378
0.994
5.285
170.89
25.09
33.60
331.2
6.25
17.0
165.
0.0367
0.994
5.453
171.93
25.09
33.59
336.4
6.44
17.6
170.
0.0356
0.995
5.621
172.93
25.10
33.58
341.6
6.63
18.2
175.
0.0345
0.995
5.789
173.90
25.11
33.57
346.6
6.82
18.8
180.
0.0336
0.996
5.956
174.85
25.12
33.58
351.6
7.00
19.4
185.
0.0326
0.996
6.124
175.77
25.14
33.59
356.4
7.19
20.0
190.
0.0318
0.996
6.292
176.67
25.17
33.60
361.2
7.37
20.6
195.
0.0309
0.997
6.460
177.54
25.20
33.63
366.0
7.56
21.1
200.
0.0302
0.997
6.629
178.39
25.24
33.66
370.6
7.74
21.7
205.
0.0294
0.997
6.797
179.22
25.28
33.69
375.2
7.92
22.3
210.
0.0287
0.997
6.965
180.03
25.33
33.73
379.7
8.11
22.9
215.
0.0280
0.997
7.134
180.83
25.38
33.78
384.1
8.29
23.5
220.
0.0274
0.998
7.303
181.61
25.44
33.84
388.5
8.47
24.1
225.
0.0268
0.998
7.473
182.37
25.51
33.90
392.8
8.64
24.7
230.
0.0262
0.998
7.642
183.11
25.59
33.98
397.0
8.82
25.3
235.
0.0256
0.998
7.812
183.85
25.67
34.05
401.2
9.00
25.9
240.
0.0251
0.998
7.983
184.56
25.76
34.14
405.3
9.17
26.5
245.
0.0246
0.998
8.154
185.27
25.86
34.24
409.3
9.35
27.1
250.
0.0241
0.998
8.325
185.96
25.97
34.34
413.3
9.52
27.8
255.
0.0236
0.999
8.497
186.64
26.08
34.45
417.2
9.69
28.4
260.
0.0232
0.999
8.670
187.31
26.20
34.57
421.0
9.86
29.0
265.
0.0227
0.999
8.843
187.97
26.34
34.70
424.8
10.03
29.7
270.
0.0223
0.999
9.017
188.62
26.47
34.84
428.6
10.20
30.3
275.
0.0219
0.999
9.191
189.26
26.62
34.98
432.3
10.37
31.0
280.
0.0215
0.999
9.367
189.89
26.77
35.13
435.9
10.53
31.6
305
METHANE ISOBAR AT P = 0.050 MPa (continued)
K
P Z H S C^ Cp W
mol-dm'2 kJ/mol J/(nol-K) J/(nDl-K) J/(ito1-K) m-s'^
r, A
/xPa-s mW/(m-K)
285.
0.0211
0.999
9
.543
190
.52
26
.94
35
.29
439
.5
10,
.70
32
.3
290.
0.0208
0.999
9
.720
191
.13
27
.11
35
.46
443
.0
10,
.86
33
.0
295.
0.0204
0.999
9
.897
191
.74
27
.28
35
.64
446
.5
11,
.03
33
.7
300.
0.0201
0.999
10
.076
192
.34
27
.47
35
.82
449
.9
11,
.19
34
.4
310.
0.0194
0.999
10
.436
193
.52
27
.85
36
.20
456,
.6
11,
.51
35
.8
320.
0.0188
0.999
10,
.800
194,
.68
28
.27
36
.62
463
.2
11,
.83
37
.2
330.
0.0182
0.999
11,
,169
195,
.81
28
.71
37,
.05
469,
.6
12.
.14
38
.7
340.
0.0177
0.999
11,
,541
196,
.92
29
.17
37
.51
475
.8
12.
.45
40,
.2
350.
0.0172
1.000
11,
,919
198,
,02
29,
.66
38
.00
481,
.9
12.
.76
41,
.8
360.
0.0167
1.000
12,
.301
199,
,10
30,
.16
38
.50
487,
,8
13.
,06
43,
.3
370.
0.0163
1.000
12,
.689
200,
,16
30
.67
39,
.01
493,
,7
13.
.36
45,
,0
380.
0.0158
1.000
13.
,082
201,
.20
31,
.20
39
.54
499,
,4
13.
,65
46,
,6
390.
0.0154
1.000
13,
.480
202,
.24
31,
.75
40
.08
505,
,0
13,
.95
48,
.3
400.
0.0150
1.000
13,
,883
203,
,26
32,
,30
40,
.64
510,
.6
14.
.23
50,
.0
410.
0.0147
1.000
14.
.292
204.
,27
32,
.86
41,
.20
516,
.0
51.
.7
420.
0.0143
1.000
14.
.707
205.
,27
33
.43
41.
.77
521,
,4
53.
.5
430.
0.0140
1.000
15.
.128
206.
.26
34,
.01
42,
.34
526.
,7
55.
.3
440.
0.0137
1.000
15.
.554
207.
.24
34,
,59
42,
.91
531.
,9
57.
,1
450.
0.0134
1.000
15.
.986
208.
.21
35,
,16
43,
.49
537.
.0
58.
.9
460.
0.0131
1.000
16.
.424
209.
.17
35.
.75
44.
,07
542.
,1
60.
.7
470.
0.0128
1.000
16.
,868
210.
.13
36.
.33
44.
.65
547.
.2
62.
.6
480.
0.0125
1.000
17.
.317
211,
.07
36.
.91
45,
.23
552.
.2
64,
.5
490.
0.0123
1.000
17.
,772
212,
,01
37,
.48
45,
.81
557.
.1
66,
,4
500.
0.0120
1.000
18,
,233
212,
,94
38.
.06
46,
.38
562,
.0
68,
,3
520.
0.0116
1.000
19,
,172
214,
,78
39,
.19
47,
,52
571,
,6
72.
,1
540.
0.0111
1.000
20.
,134
216,
,60
40,
.31
48,
,63
581.
,1
76.
560.
0.0107
1.000
21.
,117
218,
,39
41.
,40
49.
,72
590.
,4
79.
9
580.
0.0104
1.000
22.
,122
220,
,15
42,
,46
50.
,79
599.
,6
83.
9
600.
0.0100
1.000
23.
,149
221,
,89
43,
,50
51.
82
608.
7
87.
8
METHANE !
[SOBAR AT
P =
= 0.075 MPa
T
P
Z
H
S
Cv
K
mol • dm" ^
kJ/mol
J/(ito1-K) J/(nol-l
95.
27.788
0,
.003
-5.513
70.27
33.99
100.
27.364
0,
.003
-5.242
73.05
34.08
105.
26.930
0,
.003
-4.967
75.73
33.86
108.
127
26.639
.003
-4.790
77.39
33.63
108.
127
0.0860
0,
.970
3.493
154.00
27.19
w
53.75 1499.0
54.64 1446.6
55.28 1396.6
55.68 1363.1
36.85 267.1
179.73 206.1
157.43 199.7
138.62 193.1
127.98 188.5
4.28 11.0
306
METHANE ISOBAR AT P = 0.075 MPa (continued)
T
K
110.
115.
120.
125.
130.
135.
140.
145.
150.
155.
160.
165.
170.
175.
180.
185.
190.
195.
200.
205.
210.
215.
220.
225.
230.
235.
240.
245.
250.
255.
260.
265.
270.
275.
280.
285.
290.
295.
300.
310.
H
W
mol • dm
-3
kJ/mol J/(mol-K) J/(inDl-K) J/(nol-K) m-s'^ /zPa-s niW/(m-K)
.0844
971
3
.561
154
.63
26
.56
36
.04
270
.1
4
.35
11
.2
.0804
975
3
.739
156
.20
25
.76
34
.98
277
.4
4
.54
11
.8
.0768
978
3
.912
157
.68
25
.48
34
.55
284
.1
4
.73
12
.3
.0736
981
4
.084
159
.09
25
.36
34
.32
290
.4
4
.92
12
.9
.0706
983
4
.256
160
.43
25
.29
34
.17
296
.6
5
.11
13
5
.0678
985
4
.426
161
.72
25
.24
34
.06
302
.6
5
.30
14
1
0653
986
4
596
162
96
25
.20
33
97
308
.4
5
.49
14
7
0630
988
4
766
164
.15
25
.18
33
89
314
.1
5
.68
15
3
0608
989
4
935
165
29
25
.16
33
83
319
.7
5
.88
15
8
0588
990
5
104
166
40
25
.14
33
78
325
2
6
.07
16
4
0569
991
5
273
167
47
25
13
33
74
330
6
6
26
17
0551
992
5
442
168
51
25
13
33
71
335
9
6
45
17
6
0535
992
5
610
169
52
25
13
33
69
341
6
63
18
2
0519
993
5
778
170
50
25
14
33
68
346
1
6
82
18
8
0504
993
5
947
171
44
25
15
33
68
351
1
7
01
19
4
0491
994
6
115
172
37
25
17
33
68
356
7
19
20
0477
994
6
284
173
26
25
19
33
69
360
9
7
38
20
6
0465
995
6
452
174
14
25
22
33
70
365
6
7
56
21
2
0453
995
6
621
174
99
25
25
33
72
370
3
7
75
21
8
0442
996
6
789
175
83
25
29
33
76
374
9
7
93
22
3
0431
996
6
958
176
64
25
34
33
79
379
4
8
11
22
9
0421
996
7
127
177
44
25
39
33
84
383
9
8
29
23
5
0411
996
7
297
178
21
25
45
33
89
388
2
8
47
24
1
0402
997
7
466
178
98
25
52
33
95
392
6
8
65
24
7
0393
997
7
636
179
72
25
60
34
02
396
8
8
83
25
3
0385
997
7
806
180
46
25
68
34
10
401
9
00
25
9
0377
997
7
977
181
18
25
77
34
18
405
1
9
18
26
5
0369
997
8
148
181
88
25
87
34
28
409
1
9
35
27
2
0362
998
8
320
182
57
25
97
34
38
413
1
9
52
27
8
0355
998
8
492
183
26
26
09
34
49
417
9
70
28
4
0348
998
8
665
183
93
26
21
34
61
420
9
9
87
29
0341
998
8
838
184
59
26
34
34
73
424
7
10
04
29
7
0335
998
9
012
185
24
26
48
34
87
428
5
10
20
30
3
0329
998
9
187
185
88
26
63
35
01
432
2
10
37
31
0323
998
9
362
186
51
26
78
35
16
435
8
10
54
31
6
0317
998
9
539
187
14
26
94
35
32
439
4
10
70
32
3
0311
999
9
716
187
75
27
11
35
49
442
9
10
87
33
0306
999
9
893
188
36
27
29
35
66
446
4
11
03
33
7
0301
999
10
072
188
96
27
47
35
84
449
8
11
19
34
4
0291
999
10
432
190
14
27
86
36
23
456
6
11
51
35
8
307
METHANE ISOBAR AT P = 0.075 MPa (continued)
T
P
Z
H
S
Cv
Cp
W
ri
A
K
mol • dm" ^
kJ/mol
J/(nol-K) J/(mDl-K) J/(nDl-K)
m-s" ^
/iPa
•s
mW/(m-K)
320.
0.0282
0.999
10.797
191.30
28.27
36.64
463.1
11.
,83
37.2
330.
0.0274
0.999
11.165
192.43
28.71
37.07
469.5
12.
,15
38.7
340.
0.0266
0.999
11.538
193.55
29.17
37.53
475.7
12,
,45
40.2
350.
0.0258
0.999
11.916
194.64
29.66
38.01
481.8
12.
,76
41.8
360.
0.0251
0.999
12.299
195.72
30.16
38.51
487.8
13.
,06
43.4
370.
0.0244
0.999
12.686
196.78
30.68
39.02
493.6
13.
36
45.0
380.
0.0237
1.000
13.079
197.83
31.21
39.55
499.4
13.
66
46.6
390.
0.0231
1.000
13.477
198.86
31.75
40.10
505.0
13.
95
48.3
400.
0.0226
1.000
13.881
199.88
32.30
40.65
510.6
14.
24
50.0
410.
0.0220
1.000
14.290
200.89
32.87
41.21
516.0
51.7
420.
0.0215
1.000
14.705
201.89
33.44
41.78
521.4
53.5
430.
0.0210
1.000
15.126
202.88
34.01
42.35
526.7
55.3
440.
0.0205
1.000
15.552
203.86
34.59
42.92
531.9
57.1
450.
0.0200
1.000
15.984
204.84
35.17
43.50
537.0
58.9
460.
0.0196
1.000
16.422
205.80
35.75
44.08
542.1
60.7
470.
0.0192
1.000
16.866
206.75
36.33
44.66
547.2
62.6
480.
0.0188
1.000
17.315
207.70
36.91
45.24
552.2
64.5
490.
0.0184
1.000
17.771
208.64
37.48
45.82
557.1
66.4
500.
0.0180
1.000
18.232
209.57
38.06
46.39
562.0
68.3
520.
0.0173
1.000
19.171
211.41
39.19
47.52
571.7
72.1
540.
0.0167
1.000
20.133
213.22
40.31
48.64
581.1
76.0
560.
0.0161
1.000
21.116
215.01
41.40
49.73
590.5
79.9
580.
0.0156
1.000
22.121
216.78
42.47
50.79
599.7
83.9
600.
0.0150
1.000
23.148
218.52
43.50
51.83
608.7
87.8
METHANE '.
[SOBAR AT
P = 0.100 MPa
T
P
Z
H
S
Cv
Cp
W
ri
A
K
mol -dm" ^
kJ/mol
J/(nol-K) J/(mol-K) J/(mDl-K)
m- s
- 1
H?a- s
mW/(m'
95.
27.789
0.005
-5.513
70.27
33.99
53.75
1499.
.2
179.78
206.1
100.
27.366
0.004
-5.242
73.05
34.08
54.64
1446,
,8
157.48
199.8
105.
26.932
0.004
-4.967
75.73
33.86
55.28
1396.
,9
138.67
193.1
110.
26.486
0.004
-4.689
78.32
33.49
55.84
1347,
.4
122.80
186.3
111.
498
26.336
0.004
-4.601
79.10
33.36
56.06
1329,
.9
118.17
183.9
111.
498
0.1120
0.963
3.587
152.54
26.97
36.80
270.
,3
4.41
11.5
115.
0.1082
0.967
3.713
153.66
26.15
35.72
275.
,7
4.54
11.8
120.
0.1032
0.971
3.890
155.17
25.68
35.03
282.
,7
4.73
12.4
125.
0.0987
0.974
4.064
156.59
25.49
34.69
289.
2
4.92
13.0
130.
0.0947
0.977
4.237
157.95
25.39
34.48
295.
5
5.12
13.5
308
METHANE ISOBAR AT P = 0.100 MPa (continued)
T
P
z
H
S
Cv
Cp
W
»/
A
K
mol -dm" ^
kJ/mol
J/(nol-K) J/(iiol-K) J/Cnol-K)
m- s" ^
^Pa- s
mW/(m
135.
0.0909
980
4.409
159.24
25.33
34.33
301.6
5.31
14.1
140.
0.0875
982
4.580
160.49
25.28
34.20
307.5
5.50
14.7
145.
0.0843
984
4.751
161.69
25.24
34.10
313.3
5.69
15.3
150.
0.0814
985
4.921
162.84
25.21
34.01
319.0
5.88
15.9
155.
0.0787
987
5.091
163.96
25.19
33.95
324.5
6.07
16.5
160.
0.0761
988
5.261
165.03
25.18
33.89
330.0
6.26
17.1
165.
0.0737
989
5.430
166.08
25.17
33.85
335.3
6.45
17.7
170.
0.0715
990
5.599
167.09
25.16
33.81
340.5
6.64
18.2
175.
0.0694
991
5.768
168.07
25.17
33.79
345.6
6.83
18.8
180.
0.0674
991
5.937
169.02
25.18
33.77
350.7
7.01
19.4
185.
0.0655
992
6.106
169.94
25.19
33.77
355.6
7.20
20.0
190.
0.0638
993
6.275
170.84
25.21
33.77
360.5
7.39
20.6
195.
0.0621
993
6.444
171.72
25.24
33.78
365.3
7.57
21.2
200.
0.0605
994
6.613
172.58
25.27
33.80
370.0
7.75
21.8
205.
0.0590
994
6.782
173.41
25.31
33.82
374.6
7.93
22.4
210.
0.0576
995
6.951
174.23
25.35
33.85
379.1
8.12
23.0
215.
0.0562
995
7.120
175.02
25.41
33.90
383.6
8.30
23.5
220.
0.0549
995
7.290
175.80
25.47
33.94
388.0
8.48
24.1
225.
0.0537
996
7.460
176.57
25.53
34.00
392.3
8.65
24.7
230.
0.0525
996
7.630
177.31
25.61
34.07
396.6
8.83
25.3
235.
0.0514
996
7.801
178.05
25.69
34.14
400.8
9.01
26.0
240.
0.0503
996
7.971
178.77
25.78
34.22
404.9
9.18
26.6
245.
0.0493
997
8.143
179.47
25.88
34.32
409.0
9.36
27.2
250.
0.0483
997
8.315
180.17
25.98
34.42
413.0
9.53
27.8
255.
0.0473
997
8.487
180.85
26.10
34.52
416.9
9.70
28.4
260.
0.0464
997
8.660
181.52
26.22
34.64
420.8
9.87
29.1
265.
0.0455
997
8.833
182.18
26.35
34.76
424.6
10.04
29.7
270.
0.0447
998
9.008
182.83
26.48
34.90
428.3
10.21
30.3
275.
0.0438
998
9.182
183.48
26.63
35.04
432.0
10.38
31.0
280.
0.0430
998
9.358
184.11
26.78
35.19
435.7
10.54
31.7
285.
0.0423
998
9.534
184.73
26.95
35.35
439.3
10.71
32.3
290.
0.0416
998
9.711
185.35
27.11
35.51
442.8
10.87
33.0
295.
0.0408
998
9.889
185.96
27.29
35.68
446.3
11.03
33.7
300.
0.0402
998
10.068
186.56
27.47
35.86
449.7
11.20
34.4
310.
0.0389
998
10.429
187.74
27.86
36.25
456.5
11.52
35.8
320.
0.0376
999
10.793
188.90
28.28
36.66
463.1
11.84
37.2
330.
0.0365
999
11.162
190.03
28.72
37.09
469.5
12.15
38.7
340.
0.0354
999
11.535
191.15
29.18
37.55
475.7
12.46
40.2
350.
0.0344
999
11.913
192.24
29.66
38.03
481.8
12.76
41.8
360.
0.0334
999
12.296
193.32
30.16
38.52
487.8
13.07
43.4
309
METHANE ISOBAR AT P = 0.100 MPa (continued)
T
P
Z
H
S
Cv
Cp
W
ri
A
K
mol -dm'^
kJ/mol
J/(nDl-K) J/(inol-K) J/(nK)l-K)
m- s" ^
/iPa
• s
mW/(m
370.
0.0325
0.999
12.684
194.38
30.68
39.04
493.6
13.
37
45.0
380.
0.0317
0.999
13.077
195.43
31.21
39.57
499.4
13.
66
46.6
390.
0.0309
0.999
13.475
196.46
31.75
40.11
505.0
13.
95
48.3
400.
0.0301
1.000
13.879
197.49
32.31
40.66
510.5
14.
24
50.0
410.
0.0293
1.000
14.288
198.50
32.87
41.22
516.0
51.7
420.
0.0286
1.000
14.703
199.50
33.44
41.79
521.4
53.5
430.
0.0280
1.000
15.124
200.49
34.01
42.36
526.7
55.3
440.
0.0273
1.000
15.550
201.47
34.59
42.93
531.9
57.1
450.
0.0267
1.000
15.983
202.44
35.17
43.51
537.1
58.9
460.
0.0262
1.000
16.421
203.40
35.75
44.09
542.2
60.8
470.
0.0256
1.000
16.864
204.36
36.33
44.67
547.2
62.6
480.
0.0251
1.000
17.314
205.30
36.91
45.25
552.2
64.5
490.
0.0245
1.000
17.769
206.24
37.48
45.82
557.1
66.4
500.
0.0241
1.000
18.230
207.17
38.06
46.39
562.0
68.3
520.
0.0231
1.000
19.170
209.02
39.19
47.53
571,7
72.2
540.
0.0223
1.000
20.131
210.83
40.31
48.64
581.2
76.0
560.
0.0215
1.000
21.115
212.62
41.40
49.73
590.5
80.0
580.
0.0207
1.000
22.120
214.38
42.47
50.80
599.7
83.9
600.
0.0200
1.000
23.147
216.12
43.50
51.83
608.8
87.8
METHANE "
[SOBAR AT
P = 0.150 MPa
T
P
Z
H
S
Cv
Cp
W
V
A
K
mol • dm" ^
kJ/mol
J/Cnol-K) J/(irDl-K) J/(nol-K)
m- s
- 1
/LtPa- s
mW/(m
95.
27.792
0.007
-5.511
70.26
33.99
53.74
1499
6
179.88
206.2
100.
27.368
0.007
-5.240
73.04
34.08
54.63
1447
2
157.57
199.8
105.
26.934
0.006
-4.966
75.72
33.86
55.27
1397
3
138.75
193.2
110.
26.489
0.006
-4.688
78.31
33.49
55.83
1347
9
122.87
186.3
115.
26.031
0.006
-4.407
80.80
33.07
56.40
1298
109.44
179.3
116.
645
25.863
0.006
-4.311
81.64
32.92
56.66
1279
105.20
176.7
116.
645
0.1625
0.952
3.723
150.51
26.74
36.94
274
7
4.62
12.2
120.
0.1573
0.956
3.845
151.54
26.14
36.08
279
8
4.75
12.6
125.
0.1502
0.961
4.023
153.00
25.77
35.46
286
8
4.94
13.1
130.
0.1437
0.966
4.200
154.38
25.61
35.12
293
3
5.13
13.7
135.
0.1379
0.969
4.375
155.70
25.51
34.88
299
7
5.32
14.2
140.
0.1325
0.972
4.549
156.97
25.44
34.68
305
8
5.51
14.8
145.
0.1276
0.975
4.722
158.18
25.38
34.52
311
7
5.70
15.4
150.
0.1230
0.978
4.894
159.35
25.33
34.39
317
5
5.89
16.0
155.
0.1188
0.980
5.066
160.48
25.29
34.28
323
2
6.08
16.5
310
METHANE ISOBAR AT P = 0.150 MPa (continued)
T
P
z
H
S
Cv
Cp
W
n
A
K
mol -dm" ^
kJ/mol
J/(nol-K) J/(nol-K) J/(nK)l-K)
in- s" ^
H?a
• s
mW/(m
160.
0.1149
981
5.237
161.56
25.26
34.19
328.7
6
27
17.1
165.
0.1112
983
5.408
162.61
25.24
34.11
334.2
6
46
17.7
170.
0.1078
985
5.578
163.63
25.23
34.05
339.5
6
65
18.3
175.
0.1046
986
5.748
164.62
25.23
34.01
344.7
6
84
18.9
180.
0.1016
987
5.918
165.58
25.23
33.97
349.8
7
02
19.5
185.
0.0987
988
6.088
166.51
25.24
33.95
354.8
7
21
20.1
190.
0.0960
989
6.258
167.41
25.25
33.94
359.7
7
40
20.7
195.
0.0935
990
6.427
168.29
25.27
33.93
364.5
7
58
21.3
200.
0.0911
990
6.597
169.15
25.30
33.94
369.3
7
76
21.8
205.
0.0888
991
6.767
169.99
25.34
33.95
374.0
7
95
22.4
210.
0.0866
992
6.936
170.81
25.38
33.98
378.5
8
13
23.0
215.
0.0846
992
7.106
171.61
25.43
34.01
383.1
8
31
23.6
220.
0.0826
993
7.277
172.39
25.49
34.05
387.5
8
49
24.2
225.
0.0807
993
7.447
173.16
25.55
34.10
391.9
8
66
24.8
230.
0.0789
994
7.618
173.91
25.63
34.16
396.1
8
84
25.4
235.
0.0772
994
7.789
174.64
25.71
34.23
400.4
9
02
26.0
240.
0.0756
995
7.960
175.36
25.79
34.31
404.5
9
19
26.6
245.
0.0740
995
8.132
176.07
25.89
34.39
408.6
9
36
27.2
250.
0.0725
995
8.304
176.77
26.00
34.49
412.6
9
54
27.8
255.
0.0711
996
8.477
177.45
26.11
34.59
416.6
9
71
28.5
260.
0.0697
996
8.650
178.12
26.23
34.71
420.5
9
88
29.1
265.
0.0683
996
8.824
178.79
26.36
34.83
424.3
10
05
29.7
270.
0.0671
996
8.998
179.44
26.50
34.96
428.1
10
22
30.4
275.
0.0658
997
9.173
180.08
26.64
35.10
431.8
10
38
31.0
280.
0.0646
997
9.349
180.71
26.79
35.24
435.5
10
55
31.7
285.
0.0635
997
9.526
181.34
26.95
35.40
439.1
10
72
32.4
290.
0.0624
997
9.703
181.96
27.12
35.56
442.6
10
88
33.0
295.
0.0613
997
9.881
182.57
27.30
35.73
446.1
11
04
33.7
300.
0.0603
997
10.060
183.17
27.48
35.91
449.6
11
20
34.4
310.
0.0583
998
10.421
184.35
27.87
36.29
456.4
11
53
35.8
320.
0.0565
998
10.786
185.51
28.28
36.70
462.9
11
84
37.3
330.
0.0548
998
11.155
186.65
28.72
37.13
469.4
12
16
38.8
340.
0.0531
998
11.529
187.76
29.18
37.58
475.6
12
47
40.3
350.
0.0516
999
11.907
188.86
29.67
38.06
481.7
12
77
41.8
360.
0.0502
999
12.290
189.94
30.17
38.55
487.7
13
07
43.4
370.
0.0488
999
12.678
191.00
30.68
39.07
493.6
13
37
45.0
380.
0.0475
999
13.072
192.05
31.21
39.59
499.3
13
67
46.7
390.
0.0463
999
13.470
193.08
31.76
40.13
505.0
13
96
48.3
400.
0.0451
999
13.874
194.11
32.31
40.68
510.5
14
25
50.0
410.
0.0440
999
14.284
195.12
32.87
41.24
516.0
51.8
311
METHANE ISOBAR AT P = 0.150 MPa (continued)
K
420.
430.
440.
450.
460.
pZHSCyCpWr; A
mol-dm"3 kJ/mol J/(inol-K) J/(nDl-K) J/(nol-K) in-s"^ /iPa-s mW/(m-K)
0.0430 0.999 14.699 196.12 33.44 41.81 521.4
0.0420 1.000 15.120 197.11 34.01 42.38 526.7
0.0410 1.000 15.547 198.09 34.59 42.95 531.9
0.0401 1.000 15.979 199.06 35.17 43.53 537.1
0.0392 1.000 16.417 200.02 35.75 44.11 542.2
53.5
55.3
57.1
58.9
60.8
470. 0.0384 1.000
480. 0.0376 1.000
490. 0.0368 1.000
500. 0.0361 1.000
520. 0.0347 1.000
16.861 200.98 36.33 44.68 547.3
17.311 201.93 36.91 45.26 552.2
17.766 202.87 37.49 45.84 557.2
18.228 203.80 38.06 46.41 562.1
19.167 205.64 39.20 47.54 571.8
62.6
64.5
66.4
68
72
540. 0.0334 1.000
560. 0.0322 1.000
580. 0.0311 1.000
600. 0.0301 1.000
20.129 207.45 40.31 48.65 581.2
21.113 209.24 41.40 49.74 590.6
22.119 211.01 42.47 50.81 599.8
23.145 212.75 43.50 51.84 608.9
76.1
80.0
83.9
87.9
METHANE ISOBAR AT P = . 200 MPa
W
K
mol •dm"''
kJ/mol
J/(nol-K) J/(nol-K) J/(nK>l-K)
m-s" ^
/iPa- s
mW/(m
95.
27.794
009
-5.510
70.26
33.99
53.74
1500.0
179.97
206.2
100.
27.370
009
-5.239
73.04
34.09
54.63
1447 . 7
157.66
199.9
105.
26.937
009
-4.964
75.72
33.86
55.27
1397.8
138.83
193.2
110.
26.492
008
-4.687
78.30
33.49
55.82
1348.4
122.95
186.4
115.
26.034
008
-4.406
80.80
33.07
56.39
1298.5
109.51
179.4
120.
25.561
008
-4.123
83.21
32.64
57.04
1247.6
98.10
172.2
120.611
25.489
008
-4.085
83.53
32.59
57.18
1239.2
96.60
171.1
120.611
0.2118
942
3.821
149.07
26.65
37.23
277.7
4.78
12.8
125.
0.2031
948
3.982
150.38
26.08
36.30
284.2
4.95
13.2
130.
0.1940
954
4.162
151.79
25.82
35.78
291.1
5.14
13.8
135.
0.1859
959
4.340
153.14
25.68
35.45
297.7
5.33
14.3
140.
0.1784
963
4.516
154.42
25.59
35.18
304.0
5.52
14.9
145.
0.1716
967
4.692
155.65
25.51
34.97
310.1
5.71
15.5
150.
0.1653
970
4.866
156.83
25.45
34.78
316.0
5.91
16.0
155.
0.1595
973
5.040
157.97
25.40
34.63
321.8
6.10
16.6
160.
0.1542
975
5.212
159.07
25.35
34.50
327.5
6.28
17.2
165.
0.1492
977
5.385
160.13
25.32
34.39
333.0
6.47
17.8
170.
0.1445
979
5.556
161.15
25.30
34.30
338.4
6.66
18.4
175.
0.1401
981
5.728
162.15
25.29
34.23
343.7
6.85
19.0
180.
0.1360
983
5.899
163.11
25.28
34.18
348.9
7.04
19.6
312
METHANE ISOBAR AT P = 0.200 MPa (continued)
T
K
185.
190.
195.
200.
205.
210.
215.
220.
225.
230.
235.
240.
245.
250.
255.
260.
265.
270.
275.
280.
285.
290.
295.
300.
310.
320.
330.
340.
350.
360.
370.
380.
390.
400.
410.
420.
430.
440.
450.
460.
mol • dm
-3
H S C^ Cp W i; A
kJ/mol J/(nol-K) J/Cmol-K) J/(mol-K) m-s"^ /xPa-s mW/(m-K)
.1322
984
6
.069
164
.05
25
.28
34
.14
354
.0
7
.22
20
.2
1285
985
6
.240
164
.96
25
.29
34
11
358
.9
7
.41
20
.8
1251
986
6
.411
165
.84
25
.31
34
09
363
.8
7
.59
21
.3
1218
987
6
.581
166
.71
25
.34
34
08
368
.6
7
.77
21
9
1187
988
6
.751
167
.55
25
.37
34
09
373
.3
7
.96
22
.5
1158
989
6
.922
168
.37
25
.41
34
10
378
.0
8
.14
23
.1
1130
990
7
.092
169
.17
25
.46
34
12
382
5
8
32
23
6
1104
990
7
.263
169
.96
25
.51
34
16
387
8
50
24
2
1079
991
7
.434
170
72
25
.57
34
20
391
4
8
67
24
8
1055
992
7
605
171
48
25
.64
34
26
395
7
8
85
25
4
1032
992
7
777
172
21
25
72
34
32
400
9
03
26
1010
993
7
948
172
94
25
81
34
39
404
1
9
20
26
6
0989
993
8
121
173
65
25
91
34
47
408
3
9
37
27
3
0968
994
8
293
174
35
26
01
34
56
412
3
9
55
27
9
0949
994
8
466
175
03
26
12
34
66
416
3
9
72
28
5
0930
994
8
640
175
70
26
24
34
77
420
2
9
89
29
1
0913
995
8
814
176
37
26
37
34
89
424
1
10
06
29
8
0895
995
8
989
177
02
26
51
35
02
427
8
10
23
30
4
0879
995
9
164
177
67
26
65
35
15
431
6
10
39
31
1
0863
996
9
340
178
30
26
80
35
30
435
3
10
56
31
7
0847
996
9
517
178
93
26
96
35
45
438
9
10
72
32
4
0833
996
9
695
179
54
27
13
35
61
442
4
10
89
33
1
0818
996
9
873
180
15
27
31
35
78
446
11
05
33
8
0805
997
10
053
180
76
27
49
35
96
449
4
11
21
34
5
0778
997
10
414
181
94
27
88
36
33
456
2
11
53
35
9
0754
997
10
779
183
10
28
29
36
73
462
8
11
85
37
3
0731
998
11
149
184
24
28
73
37
16
469
3
12
16
38
8
0709
998
11
523
185
35
29
19
37
62
475
5
12
47
40
3
0689
998
11
901
186
45
29
67
38
09
481
7
12
78
41
8
0669
998
12
285
187
53
30
17
38
58
487
7
13
08
43
4
0651
999
12
673
188
60
30
69
39
09
493
6
13
38
45
0634
999
13
066
189
65
31
22
39
62
499
3
13
67
46
7
0617
999
13
465
190
68
31
76
40
16
505
13
97
48
4
0602
999
13
870
191
71
32
31
40
70
510
5
14
25
50
1
0587
999
14
279
192
72
32
88
41
26
516
51
8
0573
999
14
695
193
72
33
44
41
83
521
4
53
5
0560
999
15
116
194
71
34
02
42
40
526
7
55
3
0547
1
000
15
543
195
69
34
59
42
97
532
57
1
0535
1
000
15
975
196
66
35
17
43
55
537
1
59
0523
1
000
16
414
197
63
35
75
44
12
542
2
60
8
313
METHANE ISOBAR AT P = 0.200 MPa (continued)
K
470.
480.
490.
500.
520.
540.
560.
580.
600.
mol • dm" ^
0.0512 1.000
0.0501 1.000
0.0491 1.000
0.0481 1.000
0.0463 1.000
0.0445 1.000
0.0429 1.000
0.0415 1.000
0.0401 1.000
H S C^ Cp W »7 A
kJ/mol J/(nol-K) J/(mol-K) J/(nol-K) m-s"! /xPa-s mW/(m-K)
16.858 198.58
17.308 199.53
17.763 200.47
18.225 201.40
19.164 203.24
20.127 205.06
21.111 206.85
22.117 208.61
23.143 210.35
36
33
44
70
547
3
36
91
45
28
552
3
37
49
45
85
557
3
38
06
46
42
562
2
39
20
47
55
571
8
40
31
48
66
581
3
41
40
49
75
590
7
42
47
50
82
599
9
43
51
51
85
609
62.7
64.5
66.4
68.3
72.2
76.1
80.0
83.9
87.9
METHANE ISOBAR AT P = 0.250 MPa
K
H
W
mol-dm"3 kJ/mol J/(inol-K) J/(iid1-K) J/(nol-K) m-s'^ ^Pa-s mW/(m-K)
95.
27
796
0.011
-5.509
70
25
33
.99
53.73
1500.4
180
.07
206
.3
100.
27
373
0.011
-5.238
73
03
34
.09
54.62
1448 . 1
157
.75
199
.9
105.
26
940
0.011
-4.963
75
71
33
.86
55.26
1398.3
138
.91
193
.3
110.
26
495
0.010
-4.685
78
30
33
.50
55.81
1348.9
123
.02
186
.4
115.
26
037
0.010
-4.405
80
79
33
.07
56.38
1299.0
109
.58
179
.4
120.
25
564
0.010
-4.121
83
20
32
65
57.03
1248.1
98
16
172
3
123.886
25
173
0.010
-3.896
85
05
32
32
57.66
1205.8
90
26
166
5
123.886
2603
0.932
3.897
147
96
26
.65
37.63
279.8
4
.92
13
3
125.
2576
0.934
3.939
148
29
26
47
37.32
281.5
4
.96
13
4
130.
2457
0.941
4.123
149
74
26
04
36.50
288.8
5
.15
13
.9
135.
2350
0.948
4.304
151
10
25
85
36.04
295.6
5
35
14
5
140.
2253
0.953
4.483
152
41
25
74
35.70
302.1
5
54
15
145.
2164
0.958
4.661
153
66
25
64
35.42
308.4
5
73
15
6
150.
2083
0.962
4.838
154
85
25
56
35.19
314.5
5
92
16
1
155.
2009
0.966
5.013
156
00
25
50
34.99
320.4
6
11
16
7
160.
1940
0.969
5.188
157
11
25
44
34.82
326.2
6
30
17
3
165.
1876
0.972
5.361
158
18
25
40
34.68
331.8
6
49
17
9
170.
1816
0.974
5.534
159
21
25
37
34.56
337.3
6
67
18
4
175.
1760
0.976
5.707
160
21
25
35
34.46
342.7
6
86
19
180.
1708
0.978
5.879
161
18
25
33
34.39
348.0
7
05
19
6
185.
1659
0.980
6.051
162
13
25
33
34.33
353.1
7
23
20
2
190.
1613
0.981
6.222
163
04
25
33
34.28
358.2
7
42
20
8
195.
1569
0.983
6.394
163
93
25
35
34.25
363.1
7
60
21
4
200.
1528
0.984
6.565
164
80
25
37
34.23
368.0
7
78
22
205.
1489
0.985
6.736
165
64
25
40
34.22
372.7
7
97
22
5
314
METHANE ISOBAR AT P = 0.250 MPa (continued)
T
P
z
H
S
Cv
Cp
W
r\
A
K
mol -dm" ^
kJ/mol
J/(niDl-K) J/(iiol-K) J/(nDl-K)
m- s
- 1
ii?a
•s
mW/(m
210.
0.1452
986
6.907
166.47
25.43
34.23
377
.4
8
.15
23.1
215.
0.1417
987
7.078
167.27
25.48
34.24
382
.0
8
33
23.7
220.
0.1383
988
7.250
168.06
25.53
34.27
386
.5
8
51
24.3
225.
0.1351
989
7.421
168.83
25.59
34.31
390
.9
8
68
24.9
230.
0.1321
990
7.593
169.58
25.66
34.35
395
3
8
86
25.5
235.
0.1292
990
7.765
170.32
25.74
34.41
399
6
9
03
26.1
240.
0.1264
991
7.937
171.05
25.83
34.48
403
8
9
21
26.7
245.
0.1238
991
8.109
171.76
25.92
34.55
407
9
9
38
27.3
250.
0.1212
992
8.282
172.46
26.02
34.64
412
9
56
27.9
255.
0.1188
993
8.456
173.15
26.13
34.74
416
9
73
28.5
260.
0.1165
993
8.630
173.82
26.25
34.84
419
9
9
90
29.2
265.
0.1142
993
8.804
174.49
26.38
34.96
423
8
10
07
29.8
270.
0.1121
994
8.979
175.14
26.52
35.08
427
6
10
23
30.5
275.
0.1100
994
9.155
175.79
26.66
35.21
431
4
10
40
31.1
280.
0.1080
995
9.331
176.42
26.81
35.35
435
10
57
31.8
285.
0.1060
995
9.509
177.05
26.97
35.50
438
7
10
73
32.4
290.
0.1042
995
9.686
177.67
27.14
35.66
442
3
10
90
33.1
295.
0.1024
995
9.865
178.28
27.31
35.83
445
8
11
06
33.8
300.
0.1007
996
10.045
178.88
27.50
36.00
449
3
11
22
34.5
310.
0.0974
996
10.407
180.07
27.88
36.37
456
1
11
54
35.9
320.
0.0943
997
10.772
181.23
28.30
36.77
462
7
11
86
37.3
330.
0.0914
997
11.142
182.37
28.73
37.20
469
2
12
17
38.8
340.
0.0887
997
11.516
183.49
29.19
37.65
475
5
12
48
40.3
350.
0.0861
998
11.895
184.58
29.68
38.12
481
6
12
79
41.9
360.
0.0837
998
12.279
185.66
30.18
38.61
487
6
13
09
43.4
370.
0.0814
998
12.668
186.73
30.69
39.12
493
5
13
39
45.1
380.
0.0792
998
13.061
187.78
31.22
39.64
499
3
13
68
46.7
390.
0.0772
999
13.461
188.82
31.76
40.18
505
13
97
48.4
400.
0.0753
999
13.865
189.84
32.32
40.73
510
5
14
26
50.1
410.
0.0734
999
14.275
190.85
32.88
41.28
516
51.8
420.
0.0717
999
14.691
191.85
33.45
41.85
521
4
53.6
430.
0.0700
999
15.112
192.85
34.02
42.41
526
7
55.3
440.
0.0684
999
15.539
193.83
34.60
42.99
532
57.2
450.
0.0668
1
000
15.972
194.80
35.18
43.56
537
2
59.0
460.
0.0654
1
000
16.410
195.76
35.76
44.14
542
3
60.8
470.
0.0640
1
000
16.855
196.72
36.34
44.72
547
3
62.7
480.
0.0627
1
000
17.305
197.67
36.91
45.29
552
4
64.6
490.
0.0614
1
000
17.760
198.61
37.49
45.86
557
3
66.5
500.
0.0601
1
000
18.222
199.54
38.06
46.43
562
2
68.4
520.
0.0578
1
000
19.162
201.38
39.20
47.56
571
9
72.2
315
METHANE ISOBAR AT P = 0.250 MPa (continued)
T pZHSC^CpWi; X
K moldm'3 kJ/mol J/(mol-K) J/(nDl-K) J/(iajl-K) m-s"^ /xPa-s inW/(m-K)
540. 0.0557 1.000
560. 0.0537 1.000
580. 0.0518 1.000
600. 0.0501 1.000
20.124
203.20
40.31
48.68
581.4
76.1
21.109
204.99
41.41
49.76
590.8
80.0
22.115
206.75
42.47
50.82
600.0
83.9
23.142
208.49
43.51
51.86
609.0
87.9
METHANE ISOBAR AT P = 0.300 MPa
H
W
moldm"3 kJ/mol J/(inol-K) J/(nol-K) J/(inol-K) m-s"^ /iPa-s mW/(m-K)
95.
27
798
0.014
-5.508
70
25
34.00
53.73
1500,8
180.17
206.3
100.
27
375
0.013
-5.237
73
03
34.09
54.61
1448 . 5
157.83
200.0
105.
26
942
0.013
-4.962
75
.71
33.87
55.25
1398.7
138.99
193.3
110.
26
498
0.012
-4.684
78
29
33.50
55.80
1349.4
123.10
186.5
115.
26
040
0.012
-4.404
80
78
33.08
56.37
1299.6
109.65
179.5
120.
25
568
0.012
-4.120
83
19
32.65
57.01
1248.7
98.23
172.3
125.
25
077
0.012
-3.833
85
54
32.24
57.78
1196.4
88.44
165.1
126.702
24
896
0.011
-3.732
86
34
32.10
58.12
1176.8
85.29
162.5
126.702
3084
0.923
3.960
147
05
26.70
38.07
281.4
5.04
13.8
130.
2988
0.929
4.083
148
01
26.30
37.31
286.4
5.17
14.1
135.
2853
0.937
4.268
149
41
26.03
36.67
293.5
5.36
14.6
140.
2732
0.943
4.450
150
73
25.88
36.24
300.3
5.55
15.1
145.
2621
0.949
4.630
152
00
25.77
35.90
306.7
5.74
15.7
150.
2521
0.954
4.809
153
21
25.68
35.61
313.0
5.93
16.2
155.
2428
0.959
4.986
154
37
25.60
35.36
319.0
6.12
16.8
160.
2343
0.962
5.163
155
49
25.53
35.15
324.9
6.31
17.4
165.
2264
0.966
5.338
156
57
25.48
34.97
330.7
6.50
17.9
170.
2191
0.969
5.512
157
61
25.44
34.82
336.3
6.69
18.5
175.
2123
0.971
5.686
158
62
25.41
34.70
341.7
6.87
19.1
180.
2059
0.974
5.859
159
60
25.39
34.60
347.1
7.06
19.7
185.
1999
0.976
6.032
160
54
25.38
34.52
352.3
7.24
20.3
190.
1943
0.978
6.205
161
46
25.38
34.46
357.4
7.43
20.9
195.
1890
0.979
6.377
162
36
25.39
34.41
362.4
7.61
21.4
200.
1839
0.981
6.549
163
23
25.40
34.38
367.3
7.79
22.0
205.
1792
0.982
6.721
164
08
25.43
34.36
372.1
7.98
22.6
210.
1747
0.983
6.892
164
90
25.46
34.35
376.8
8.16
23.2
215.
1704
0.985
7.064
165
71
25.51
34.36
381.5
8.34
23.8
220.
1664
0.986
7.236
166
50
25.56
34.38
386.0
8.52
24.3
225.
1625
0.987
7.408
167
28
25.62
34.41
390.5
8.69
24.9
230.
1589
0.988
7.580
168
03
25.68
34.45
394.8
8.87
25.5
316
METHANE ISOBAR AT P = 0.300 MPa (continued)
T
P
z
H
S
Cv
Cp
W
»?
A
K
mol-dm"^
kJ/mol
J/(nol-K) J/(mol-K) J/(nol-K)
m- s
- 1
/iPa
• s
mW/(m
235.
0.1554
988
7.753
168.77
25.76
34.50
399
2
9
04
26.1
240.
0.1520
989
7.925
169.50
25.84
34.56
403
4
9
22
26.7
245.
0.1488
990
8.098
170.21
25.94
34.63
407
6
9
39
27.3
250.
0.1457
990
8.272
170.91
26.04
34.72
411
6
9
56
28.0
255.
0.1428
991
8.445
171.60
26.15
34.81
415
7
9
74
28.6
260.
0.1400
992
8.620
172.28
26.27
34.91
419
6
9
91
29.2
265.
0.1372
992
8.794
172.95
26.39
35.02
423
5
10
07
29.9
270.
0.1346
993
8.970
173.60
26.53
35.14
427
4
10
24
30.5
275.
0.1321
993
9.146
174.25
26.67
35.27
431
1
10
41
31.1
280.
0.1297
993
9.323
174.88
26.82
35.41
434
8
10
58
31.8
285.
0.1274
994
9.500
175.51
26.98
35.56
438
5
10
74
32.5
290.
0.1251
994
9.678
176.13
27.15
35.71
442
1
10
90
33.1
295.
0.1230
995
9.857
176.74
27.32
35.88
445
6
11
07
33.8
300.
0.1209
995
10.037
177.35
27.51
36.05
449
1
11
23
34.5
310.
0.1169
995
10.399
178.54
27.89
36.42
456
11
55
35.9
320.
0.1132
996
10.765
179.70
28.30
36.81
462
6
11
87
37.4
330.
0.1097
996
11.136
180.84
28.74
37.24
469
1
12
18
38.8
340.
0.1065
997
11.510
181.96
29.20
37.68
475
4
12
49
40.4
350.
0.1034
997
11.889
183.05
29.68
38.15
481
6
12
79
41.9
360.
0.1005
998
12.273
184.14
30.18
38.64
487
6
13
09
43.5
370.
0.0977
998
12.662
185.20
30.70
39.15
493
5
13
39
45.1
380.
0.0951
998
13.056
186.25
31.23
39.67
499
3
13
69
46.7
390.
0.0927
998
13.456
187.29
31.77
40.20
505
13
98
48.4
400.
0.0903
999
13.860
188.31
32.32
40.75
510
5
14
27
50.1
410.
0.0881
999
14.271
189.33
32.88
41.30
516
51.8
420.
0.0860
999
14.687
190.33
33.45
41.87
521
4
53.6
430.
0.0840
999
15.108
191.32
34.02
42.43
526
8
55.4
440.
0.0821
999
15.535
192.30
34.60
43.01
532
57.2
450.
0.0802
999
15.968
193.28
35.18
43.58
537
2
59.0
460.
0.0785
1
000
16.407
194.24
35.76
44.16
542
3
60.8
470.
0.0768
1
000
16.851
195.20
36.34
44.73
547
4
62.7
480.
0.0752
1
000
17.301
196.14
36.92
45.31
552
4
64.6
490.
0.0736
1
000
17.757
197.08
37.49
45.88
557
4
66.5
500.
0.0722
1
000
18.219
198.02
38.07
46.45
562
3
68.4
520.
0.0694
1
000
19.159
199.86
39.20
47.58
572
72.2
540.
0.0668
1
000
20.122
201.68
40.32
48.69
581
5
76.1
560.
0.0644
1
000
21.107
203.47
41.41
49.77
590
8
80.0
580.
0.0622
1
000
22.113
205.23
42.47
50.83
600
1
84.0
600.
0.0601
1
000
23.140
206.97
43.51
51.87
609
1
87.9
317
METHANE ISOBAR AT P = 0.350 MPa
K
mol • dm
-3
H S C^ Cp W », A
kJ/mol J/(inol-K) J/(mol-K) J/(nDl-K) m-s"! ^Pa-s mW/(m-K)
95.
27
800
0.016
-5.506
70
24
34
00
53.72
1501.2
180
.27
206.4
100.
27
377
0.015
-5.235
73
02
34
09
54.61
1449.0
157
.92
200.0
105.
26
945
0.015
-4.961
75
70
33
87
55.24
1399.2
139
.07
193.4
110.
26
501
0.014
-4.683
78
28
33
50
55.80
1349.9
123
.17
186.5
115.
26
044
0.014
-4.403
80
78
33
08
56.36
1300.1
109
.72
179.5
120.
25
571
0.014
-4.119
83
19
32
.65
57.00
1249.3
98
.29
172.4
125.
25
081
0.013
-3.832
85
53
32
24
57.77
1197.1
88
.51
165.2
129.188
24
646
0.013
-3.587
87
46
31
92
58.57
1150.7
81
.23
159.0
129.188
3562
0.915
4.011
146
28
26
78
38.56
282.7
5
.15
14.2
130.
3535
0.916
4.042
146
51
26
65
38.32
283.9
5
.18
14.3
135.
3369
0.925
4.231
147
94
26
22
37.35
291.4
5
.37
14.7
140.
3221
0.933
4.416
149
28
26
03
36.80
298.3
5
56
15.2
145.
3087
0.940
4.599
150
57
25
90
36.39
305.0
5
75
15.8
150.
2966
0.946
4.780
151
80
25
80
36.04
311.4
5
94
16.3
155.
2855
0.951
4.959
152
97
25
71
35.74
317.6
6
13
16.9
160.
2752
0.956
5.137
154
10
25
63
35.49
323.6
6
32
17.4
165.
2658
0.960
5.314
155
19
25
56
35.27
329.5
6
51
18.0
170.
2571
0.963
5.490
156
24
25
51
35.09
335.2
6
.70
18.6
175.
2489
0.966
5.665
157
26
25
47
34.94
340.7
6
.88
19.2
180.
2413
0.969
5.840
158
24
25
44
34.82
346.1
7
.07
19.8
185.
2342
0.972
6.013
159
19
25
43
34.72
351.4
7
.26
20.3
190.
2275
0.974
6.187
160
12
25
42
34.64
356.6
7
.44
21.0
195.
2212
0.976
6.360
161
02
25
42
34.58
361.7
7
.62
21.5
200.
2153
0.978
6.533
161
89
25
44
34.53
366.6
7
.81
22.1
205.
2097
0.979
6.705
162
74
25
46
34.50
371.5
7
.99
22.6
210.
2044
0.981
6.878
163
57
25
49
34.48
376.2
8
17
23.2
215.
1994
0.982
7.050
164
39
25
53
34.48
380.9
8
35
23.8
220.
1946
0.983
7.222
165
18
25
58
34.49
385.5
8
53
24.4
225.
1901
0.984
7.395
165
95
25
64
34.51
390.0
8
70
25.0
230.
1857
0.985
7.568
166
71
25
70
34.55
394.4
8
88
25.6
235.
1816
0.986
7.740
167
46
25
78
34.59
398.8
9
05
26.2
240.
1777
0.987
7.914
168
19
25
86
34.65
403.0
9
23
26.8
245.
1739
0.988
8.087
168
90
25
95
34.71
407.2
9
40
27.4
250.
1703
0.989
8.261
169
60
26
05
34.79
411.3
9
57
28.0
255.
1668
0.990
8.435
170
29
26
16
34.88
415.4
9
74
28.6
260.
1635
0.990
8.610
170
97
26
28
34.98
419.3
9
91
29.3
265.
1603
0.991
8.785
171
64
26
40
35.09
423.3
10
08
29.9
270.
1573
0.991
8.960
172
29
26
54
35.20
427.1
10
25
30.5
275.
1543
0.992
9.137
172
94
26
68
35.33
430.9
10
42
31.2
280.
1515
0.992
9.314
173
58
26
83
35.47
434.6
10
58
31.8
318
METHANE ISOBAR AT P = 0.350 MPa (continued)
K
mol-dm'^
285.
0.1488
993
290.
0.1461
993
295.
0.1436
994
300.
0.1412
994
310.
0.1365
995
320.
0.1322
995
330.
0.1281
996
340.
0.1243
996
350.
0.1207
997
360.
0.1173
997
370.
0.1141
998
380.
0.1110
998
390.
0.1081
998
400.
0.1054
998
410.
0.1028
999
420.
0.1003
999
430.
0.0980
999
440.
0.0957
999
450.
0.0936
999
460.
0.0916
999
470.
0.0896
1
000
480.
0.0877
1
000
490.
0.0859
1
000
500.
0.0842
1
000
520.
0.0809
1
000
540.
0.0779
1
000
560.
0.0751
1
000
580.
0.0725
1
000
600.
0.0701
1
001
w
kJ/mol J/(mol-K) J/(mol-K) J/(niDl-K) m-s"^
ri X
/iPa-s niW/(m-K)
9.491 174.21
9.670 174.83
9.849 175.44
10.029 176.05
10.392 177.24
10.758 178.40
11.129 179.54
11.504 180.66
11.883 181.76
12.268 182.84
12.657 183.91
13.051 184.96
13.451 186.00
13.856 187.02
14.266 188.04
14.682 189.04
15.104 190.03
15.532 191.01
15.965 191.99
16.403 192.95
16.848
17.298
17.754
18.216
19.157
193.91
194.86
195.80
196.73
198.57
20.120 200.39
21.105 202.18
22.111 203.95
23.138 205.69
26.99
27.16
27.33
27.51
27.90
28.31
28.75
29.21
29.69
30.18
30.70
31.23
31.77
32.32
32.89
33.45
34.03
34.60
35.18
35.76
36.34
36.92
37.50
38.07
39.20
40.32
41.41
42.47
43.51
35.61
35.76
35.93
36.10
36.46
36.85
37.27
37.72
38.18
38.67
39.18
39.70
40.23
40.77
41.33
41.89
42.45
43.02
43.60
44.17
44.75
45.32
45.89
46.46
47.59
48.70
49.78
50.84
51.88
438.3
441.9
445.5
449.0
455.8
462.5
469.0
475.3
481.5
487.5
493.5
499.3
504.9
510.5
516.0
521.4
526.8
532.0
537.2
542.4
547.4
552.5
557.4
562.3
572.0
10.75
10.91
11.07
11.24
11.56
11.87
12.19
12.49
12.80
13.10
13.40
13.69
13.98
14.27
32.5
33.2
33.9
34.6
36.0
37.4
38.9
40.4
41.9
43.5
45.1
46.8
48.4
50.1
51.9
53.6
55.4
57.2
59.0
60.9
62,
64.
66.
68,
72.
581
590
600
609
76.1
80.0
84.0
87.9
METHANE ISOBAR AT P = 0.400 MPa
W
K
mol -dm' ^
kJ/mol
J/(m
3l-K)
J/(ni
Dll
95.
27.803
018
-5.505
70
24
34
00
100.
27.380
018
-5.234
73
01
34
09
105.
26.947
017
-4.959
75
69
33
87
110.
26.504
017
-4.682
78
28
33
50
115.
26.047
016
-4.402
80
77
33
08
J/(mol-K) m-s'^
53.72 1501.6
54.60 1449.4
55.24 1399.6
55.79 1350.4
56.35 1300.6
180.36 206.4
158.01 200.1
139.15 193.4
123.25 186.6
109.79 179.6
319
METHANE ISOBAR AT P = 0.400 MPa (continued)
H
W
P ^ " - -V -p
mol-dm'^ kJ/mol J/(mol-K) J/(inol-K) J/(iiol-K) m-s'^
/iPa-s mW/(m-K)
120.
25.
.575
0.016
-4.118
83
.18
32
.65
56.99
1249.9
98.36
172.5
125.
25,
.085
0.015
-3.831
85
.52
32
.24
57.75
1197.7
88.57
165.3
130.
24,
.574
0.015
-3.540
87
.80
31
.86
58.68
1143.9
80.11
158.0
131.423
24,
.417
0.015
-3.455
88
.46
31
.76
59.02
1127.1
77.82
155.8
131.423
.4037
0.907
4.055
145
.60
26
.88
39.07
283.6
5.25
14.6
135.
0,
.3900
0.914
4.192
146
.63
26
.45
38.14
289.1
5.39
14.9
140.
0,
.3722
0.923
4.381
148
.01
26
.18
37.41
296.4
5.58
15.4
145.
0,
.3563
0.931
4.567
149
.31
26
.03
36.90
303.2
5.77
15.9
150.
0,
,3419
0.938
4.750
150
.55
25
.91
36.49
309.8
5.96
16.4
155.
0.
.3288
0.944
4.932
151
.74
25
.81
36.14
316.2
6.15
17.0
160.
0.
.3167
0.949
5.112
152,
.89
25,
.72
35.84
322.3
6.33
17.5
165.
0,
.3057
0.954
5.290
153,
.98
25
.64
35.59
328.3
6.52
18.1
170.
0,
.2954
0.958
5.468
155,
.04
25
.58
35.37
334.1
6.71
18.7
175.
0,
.2859
0.961
5.644
156.
.07
25,
.53
35.19
339.7
6.90
19.2
180.
0,
,2771
0.965
5.820
157,
.06
25
.50
35.04
345.2
7.08
19.8
185.
0.
.2688
0.967
5.995
158,
.01
25,
.48
34.92
350.6
7.27
20.4
190.
0,
.2611
0.970
6.169
158,
.94
25,
.46
34.82
355.8
7.45
21.0
195.
0,
.2538
0.972
6.343
159,
.85
25,
.46
34.74
360.9
7.63
21.6
200.
0.
,2469
0.974
6.516
160,
.73
25,
.47
34.68
365.9
7.82
22.1
205.
0,
.2404
0.976
6.690
161,
.58
25,
.49
34.64
370.8
8.00
22.7
210.
0,
.2343
0.978
6.863
162,
.42
25,
.52
34.61
375.7
8.18
23.3
215.
0.
.2285
0.979
7.036
163,
.23
25,
.56
34.60
380.4
8.36
23.9
220.
0.
.2230
0.981
7.209
164,
.03
25,
.60
34.60
385.0
8.54
24.4
225.
0,
.2177
0.982
7.382
164,
.80
25,
,66
34.62
389.5
8.71
25.0
230.
0.
.2127
0.983
7.555
165,
.57
25,
,72
34.65
394.0
8.89
25.6
235.
0.
.2080
0.984
7.728
166,
,31
25,
.79
34.68
398.4
9.06
26.2
240.
0,
.2034
0.985
7.902
167,
.04
25,
.88
34.73
402.6
9.24
26.8
245.
0.
.1991
0.986
8.076
167,
,76
25,
.97
34.80
406.9
9.41
27.4
250.
0.
.1949
0.987
8.250
168,
.46
26,
.07
34.87
411.0
9.58
28.0
255.
0.
.1909
0.988
8.424
169,
.15
26,
.17
34.95
415.1
9.75
28.7
260.
0.
.1871
0.989
8.599
169.
.83
26,
.29
35.05
419.1
9.92
29.3
265.
0.
.1835
0.989
8.775
170,
.50
26.
.42
35.15
423.0
10.09
29.9
270.
0,
.1800
0.990
8.951
171,
.16
26.
.55
35.27
426.9
10.26
30.6
275.
0.
,1766
0.991
9.128
171.
.81
26.
69
35.39
430.7
10.43
31.2
280.
0,
.1733
0.991
9.305
172,
.45
26.
,84
35.52
434.4
10.59
31.9
285.
0,
.1702
0.992
9.483
173,
,08
27.
00
35.66
438.1
10.76
32.5
290.
0.
.1672
0.992
9.662
173.
,70
27.
,17
35.82
441.7
10.92
33.2
295.
0,
.1643
0.993
9.841
174.
,31
27.
34
35.98
445.3
11.08
33.9
300.
0.
,1615
0.993
10.021
174.
,92
27.
52
36.14
448.8
11.24
34.6
310.
0,
,1561
0.994
10.384
176.
,11
27.
90
36.50
455.7
11.56
36.0
320
METHANE ISOBAR AT P = 0.400 MPa (continued)
K
mol • dm" "^
320.
0.1511
0.995
330.
0.1465
0.995
340.
0.1421
0.996
350.
0.1380
0.996
360.
0.1341
0.997
370.
0.1304
0.997
380.
0.1269
0.998
390.
0.1236
0.998
400.
0.1205
0.998
410.
0.1175
0.998
420.
0.1147
0.999
430.
0.1120
0.999
440.
0.1094
0.999
450.
0.1070
0.999
460.
0.1046
0.999
470.
0.1024
1.000
480.
0.1003
1.000
490.
0.0982
1.000
500.
0.0962
1.000
520.
0.0925
1.000
540.
0.0891
1.000
560.
0.0859
1.000
580.
0.0829
1.001
600.
0.0801
1.001
w
kJ/mol J/(n»l-K) J/(nol-K) J/(nol-K) m-s
- 1
r, \
/iPa-s mW/(m-K)
10.751 177.27
11.122 178.42
11.498 179.54
11.878 180.64
12.262 181.72
12.652
13.046
13.446
13.851
14.262
14.678
15.100
15.528
15.961
16.400
182.79
183.84
184.88
185.90
186.92
187.92
188.91
189.90
190.87
191.84
16.845 192.79
17.295 193.74
17.751 194.68
18.213 195.61
19.154 197.46
20.117 199.28
21.102 201.07
22.109 202.83
23.136 204.57
28.32
28.75
29.21
29.69
30.19
30.70
31.23
31.78
32.33
32.89
33.46
34.03
34.61
35.18
35.76
36.34
36.92
37.50
38.07
39.21
40.32
41.41
42.48
43.51
36.89
37.31
37.75
38.22
38.70
39.20
39.72
40.25
40.80
41.35
41.91
42.47
43.04
43.61
44.19
44.76
45.33
45.91
46.47
47.60
48.71
49.79
50.85
51.88
462.4
468.9
475.2
481.4
487.5
493.4
499.2
504.9
510.5
516.0
521.5
526.8
532.1
537.3
542.4
547.5
552.5
557.5
562.4
572.1
581.6
591.0
600.2
609.3
11.88
12.19
12.50
12.81
13.11
13.41
13.70
13.99
14.28
37.4
38.9
40.4
42.0
43.5
45.1
46.8
48.5
50.2
51.9
53.6
55.4
57.2
59.0
60.9
62.7
64.6
66.5
68.4
72.3
76.1
80.1
84.0
87.9
METHANE ISOBAR AT P = 0.450 MPa
K
H
mol • dm
-3
W
kJ/mol J/(nol-K) J/(nol-K) J/(mDl-K) m-s'i /xPa-s mW/(mK)
95.
27
805
0.020
-5
504
70
23
34
00
53
71
1502
180
46
206
5
100.
27
382
0.020
-5
233
73
01
34
09
54
59
1449
8
158
10
200
1
105.
26
950
0.019
-4
958
75
69
33
87
55
23
1400
1
139
24
193
5
110.
26
506
0.019
-4
681
78
27
33
50
55
78
1350
9
123
32
186
6
115.
26
050
0.018
-4
400
80
76
33
08
56
34
1301
2
109
86
179
6
120.
25
578
0.018
-4
117
83
17
32
65
56
98
1250
5
98
42
172
5
125.
25
088
0.017
-3
830
85
51
32
24
57
73
1198
4
88
63
165
3
130.
24
578
0.017
-3
540
87
80
31
86
58
66
1144
6
80
17
158
1
133.
461
24
205
0.017
-3
334
89
36
31
62
59
46
1105
2
74
88
152
9
133.
461
4511
0.899
4
093
145
01
26
99
39
60
284
4
5
35
14
9
321
METHANE ISOBAR AT P = 0.450 MPa (continued)
T
P
z
H
S
Cv
Cp
W
ri
A
K
mol • dm" ^
kJ/mol
J/(nol-K) J/(mol-K) J/(inol-K)
m- s' ^
nVa- s
mW/(m-
135.
0.4445
0,
.902
4.153
145.45
26.75
39.10
286.8
5.40
15.1
140.
0.4235
0,
.913
4.345
146.85
26.35
38.07
294.4
5.59
15.5
145.
0.4048
.922
4.534
148.18
26.17
37.45
301.5
5.78
16.0
150.
0.3880
.930
4.720
149.44
26.03
36.96
308.2
5.97
16.5
155.
0.3728
0,
.937
4.904
150.64
25.91
36.55
314.7
6.16
17.1
160.
0.3589
0,
,943
5.086
151.80
25.81
36.20
321.0
6.35
17.6
165.
0.3461
0,
,948
5.266
152.91
25.73
35.91
327.1
6.54
18.2
170.
0.3343
0,
,952
5.445
153.97
25.65
35.66
333.0
6.72
18.7
175.
0.3234
0,
,956
5.623
155.00
25.60
35.45
338.7
6.91
19.3
180.
0.3132
0,
,960
5.799
156.00
25.55
35.27
344.3
7.09
19.9
185.
0.3037
0,
,963
5.975
156.97
25.52
35.13
349.7
7.28
20.5
190.
0.2949
0,
.966
6.151
157.90
25.51
35.01
355.0
7.46
21.1
195.
0.2865
0,
,969
6.326
158.81
25.50
34.92
360.2
7.65
21.6
200.
0.2787
0,
,971
6.500
159.69
25.51
34.84
365.3
7.83
22.2
205.
0.2713
0,
,973
6.674
160.55
25.52
34.79
370.2
8.01
22.8
210.
0.2643
0.
,975
6.848
161.39
25.55
34.75
375.1
8.19
23.3
215.
0.2577
0,
,977
7.022
162.21
25.58
34.73
379.8
8.37
23.9
220.
0.2514
0,
,978
7.195
163.00
25.63
34.72
384.5
8.55
24.5
225.
0.2455
0,
,980
7.369
163.78
25.68
34.72
389.1
8.72
25.1
230.
0.2398
0.
,981
7.542
164.55
25.74
34.74
393.6
8.90
25.7
235.
0.2344
0.
,982
7.716
165.30
25.81
34.78
398.0
9.07
26.3
240.
0.2293
0,
,984
7.890
166.03
25.89
34.82
402.3
9.25
26.9
245.
0.2243
0,
,985
8.064
166.75
25.98
34.88
406.5
9.42
27.5
250.
0.2196
0,
,986
8.239
167.45
26.08
34.95
410.7
9.59
28.1
255.
0.2151
0.
,987
8.414
168.15
26.19
35.03
414.8
9.76
28.7
260.
0.2108
0,
,987
8.589
168.83
26.30
35.12
418.8
9.93
29.3
265.
0.2067
0,
,988
8.765
169.50
26.43
35.22
422.7
10.10
30.0
270.
0.2027
0,
,989
8.941
170.16
26.56
35.33
426.6
10.27
30.6
275.
0.1989
0.
,990
9.118
170.80
26.70
35.45
430.4
10.44
31.3
280.
0.1952
0.
,990
9.296
171.44
26.85
35.58
434.2
10.60
31.9
285.
0.1917
0.
,991
9.474
172.08
27.01
35.72
437.9
10.77
32.6
290.
0.1883
0,
,991
9.653
172.70
27.17
35.87
441.5
10.93
33.3
295.
0.1850
0,
,992
9.833
173.31
27.35
36.02
445.1
11.09
33.9
300.
0.1818
0.
,992
10.013
173.92
27.53
36.19
448.7
11.25
34.6
310.
0.1758
0.
,993
10.377
175.11
27.91
36.55
455.6
11.57
36.0
320.
0.1701
0.
,994
10.744
176.28
28.32
36.93
462.3
11.89
37.5
330.
0.1649
0.
,995
11.116
177.42
28.76
37.35
468.8
12.20
38.9
340.
0.1599
0.
,995
11.491
178.54
29.22
37.79
475.2
12.51
40.4
350.
0.1553
0.
,996
11.872
179.64
29.70
38.25
481.4
12.81
42.0
360.
0.1509
0.
996
12.257
180.73
30.19
38.73
487.5
13.11
43.6
322
METHANE ISOBAR AT P = 0.450 MPa (continued)
H
W
K
mol • dm' ^
370.
0.1467
0,
.997
380.
0.1428
0.
.997
390.
0.1391
0,
,998
400.
0.1356
0,
.998
410.
0.1322
0.
.998
420.
0.1291
0,
,998
430.
0.1260
0,
,999
440.
0.1231
0,
,999
450.
0.1204
0.
,999
460.
0.1177
0,
,999
470.
0.1152
0.
,999
480.
0.1128
1,
,000
490.
0.1105
1,
,000
500.
0.1083
1,
,000
520.
0.1041
1.
,000
540.
0.1002
1.
,000
560.
0.0966
1.
,000
580.
0.0933
1.
.001
600.
0.0901
1.
,001
kJ/mol J/(nol-K) J/(iiol-K) J/(nol-K) ra-s"^
n A
/xPa-s mW/(m-K)
12.646 181.80
13.041 182.85
13.441 183.89
13.847 184.92
14.258 185.93
14.674 186.93
15.096 187.93
15.524 188.91
15.957 189.88
16.397 190.85
16.842 191.81
17.292 192.75
17.749 193.70
18.211 194.63
19.152 196.47
20.115 198.29
21.100 200.08
22.107 201.85
23.135 203.59
30.71
39.23
493.4
13,
.41
45.2
31.24
39.75
499.2
13,
.71
46.8
31.78
40.28
504.9
14,
,00
48.5
32.33
40.82
510.5
14,
,28
50.2
32.89
41.37
516.0
51.9
33.46
41.93
521.5
53.7
34.03
42.49
526.8
55.4
34.61
43.06
532.1
57.2
35.19
43.63
537.3
59.1
35.77
44.20
542.4
60.9
36.35
44.78
547.5
62.8
36.92
45.35
552.6
64.6
37.50
45.92
557.5
66.5
38.07
46.49
562.5
68.4
39.21
47.61
572.2
72.3
40.32
48.72
581.7
76.2
41.41
49.80
591.1
80.1
42.48
50.86
600.3
84.0
43.51
51.89
609.4
87.9
METHANE ISOBAR AT P = 0.500 MPa
pZHSC^CpWr? A
mol -dm" 2 kJ/mol J/(nol-K) J/(mol-K) J/(nol-K) m-s"^ /zPa-s mW/(m-K)
95.
27,
,807
0.
,023
-5,
,502
70.
,22
34,
.00
53.
.71
1502,
.4
180,
,56
206,
,5
100.
27,
,385
0,
,022
-5.
,232
73,
.00
34,
.10
54.
.59
1450,
.3
158.
.19
200.
,2
105.
26,
,953
0,
,021
-4.
,957
75,
.68
33,
.87
55.
.22
1400,
,6
139.
.32
193,
,5
110.
26,
.509
0.
,021
-4,
,679
78,
.26
33,
.50
55.
.77
1351,
.4
123.
.40
186,
,7
115.
26,
.053
0.
,020
-4,
,399
80,
.76
33,
.08
56.
.33
1301.
.7
109,
.93
179.
,7
120.
25,
.581
0,
,020
-4,
,116
83.
.17
32.
.66
56.
.96
1251.
.0
98.
.49
172.
,6
125.
25,
.092
0.
,019
-3,
,829
85,
.51
32.
.25
57,
,72
1199.
.0
88.
.69
165,
,4
130.
24,
.582
0,
,019
-3,
,539
87,
.79
31.
.87
58,
.64
1145,
.3
80.
.22
158,
,1
135.
24,
.047
0.
,019
-3.
,243
90,
.02
31.
.52
59,
.79
1089,
.5
72.
.83
150.
,8
135.338
24,
.005
0,
,019
-3,
,221
90,
.18
31,
.50
59,
.90
1084,
.9
72.
.31
150.
,2
135.338
0,
.4985
0,
,891
4,
,126
144,
.47
27.
.11
40,
.15
284,
.9
5.
.43
15.
,3
140.
0,
.4761
0,
,902
4,
,309
145,
.80
26,
.55
38,
.82
292,
.3
5.
.61
15,
,7
145.
0,
.4545
0.
,913
4.
,501
147,
.14
26,
.31
38.
.03
299,
.6
5,
.80
16.
,1
150.
0,
.4351
0,
,922
4.
,689
148,
.42
26,
.15
37.
.45
306,
.6
5,
.99
16,
,6
155.
0,
.4175
0,
.929
4.
.875
149,
.64
26.
.02
36.
.98
313.
.2
6,
.17
17.
,2
323
METHANE ISOBAR AT P = 0.500 MPa (continued)
T
P
Z
H
S
Cv
Cp
W
n
A
K
mol • dm" ^
kJ/mol
J/(nol-K) J/(nol-K) J/Cmol-K)
m- s" ^
/iPa-s
mW/(m'
160.
0.4016
0.936
5.059
150.81
25.91
36.58
319.6
6.36
17.7
165.
0.3870
0.942
5.241
151.93
25.81
36.24
325.8
6.55
18.3
170.
0.3736
0.947
5.422
153.01
25.73
35.95
331.8
6.74
18.8
175.
0.3612
0.951
5.601
154.05
25.66
35.71
337.7
6.92
19.4
180.
0.3497
0.955
5.779
155.05
25.61
35.51
343.3
7.11
20.0
185.
0.3390
0.959
5.956
156.02
25.58
35.34
348.8
7.29
20.5
190.
0.3289
0.962
6.133
156.96
25.55
35.20
354.2
1 Al
21.2
195.
0.3195
0.965
6.308
157.87
25.54
35.09
359.5
7.66
21.7
200.
0.3107
0.968
6.483
158.76
25.54
35.00
364.6
7.84
22.2
205.
0.3024
0.970
6.658
159.62
25.55
34.93
369.6
8.02
22.8
210.
0.2945
0.972
6.833
160.46
25.58
34.88
374.5
8.20
23.4
215.
0.2871
0.974
7.007
161.29
25.61
34.85
379.3
8.38
24.0
220.
0.2801
0.976
7.181
162.09
25.65
34.83
384.0
8.56
24.5
225.
0.2734
0.978
7.356
162.87
25.70
34.83
388.6
8.73
25.1
230.
0.2670
0.979
7.530
163.63
25.76
34.85
393.1
8.91
25.7
235.
0.2610
0.980
7.704
164.38
25.83
34.87
397.5
9.08
26.3
240.
0.2552
0.982
7.878
165.12
25.91
34.91
401.9
9.26
26.9
245.
0.2497
0.983
8.053
165.84
26.00
34.96
406.2
9.43
27.5
250.
0.2444
0.984
8.228
166.55
26.09
35.03
410.4
9.60
28.1
255.
0.2394
0.985
8.403
167.24
26.20
35.10
414.5
9.77
28.7
260.
0.2346
0.986
8.579
167.92
26.32
35.19
418.5
9.94
29.4
265.
0.2300
0.987
8.755
168.59
26.44
35.28
422.5
10.11
30.0
270.
0.2255
0.988
8.932
169.25
26.57
35.39
426.4
10.28
30.6
275.
0.2212
0.988
9.109
169.91
26.71
35.51
430.2
10.44
31.3
280.
0.2171
0.989
9.287
170.55
26.86
35.64
434.0
10.61
32.0
285.
0.2132
0.990
9.466
171.18
27.02
35.77
437.7
10.77
32.6
290.
0.2094
0.990
9.645
171.80
27.18
35.92
441.4
10.94
33.3
295.
0.2057
0.991
9.825
172.42
27.36
36.07
445.0
11.10
34.0
300.
0.2022
0.992
10.006
173.02
27.54
36.24
448.5
11.26
34.7
310.
0.1955
0.993
10.370
174.22
27.92
36.59
455.4
11.58
36.1
320.
0.1892
0.993
10.737
175.39
28.33
36.97
462.2
11.90
37.5
330.
0.1833
0.994
11.109
176.53
28.76
37.38
468.7
12.21
39.0
340.
0.1778
0.995
11.485
177.65
29.22
37.82
475.1
12.52
40.5
350.
0.1726
0.995
11.866
178.76
29.70
38.28
481.3
12.82
42.0
360.
0.1677
0.996
12.251
179.84
30.20
38.76
487.4
13.12
43.6
370.
0.1631
0.996
12.641
180.91
30.71
39.26
493.4
13.42
45.2
380.
0.1587
0.997
13.036
181.96
31.24
39.77
499.2
13.71
46.8
390.
0.1546
0.997
13.437
183.00
31.78
40.30
504.9
14.00
48.5
400.
0.1507
0.998
13.842
184.03
32.34
40.84
510.5
14.29
50.2
410.
0.1470
0.998
14.253
185.04
32.90
41.39
516.1
51.9
324
METHANE ISOBAR AT P = 0.500 MPa (continued)
K
420.
430.
440.
450.
460.
pZHSC^CpW»7 A
mol-dm"3 kJ/mol J/(nol-K) J/(itd1-K) J/(inol-K) m-s'^ /iPa-s inW/(m-K)
0.1434 0.998
0.1400 0.999
0.1368 0.999
0.1338 0.999
0.1308 0.999
14.670 186.05 33.46 41.95 521.5
15.092 187.04 34.04 42.51 526.8
15.520 188.03 34.61 43.08 532.1
15.954 189.00 35.19 43.65 537.3
16.393 189.97 35.77 44.22 542.5
53.7
55.5
57.3
59.1
60.9
470. 0.1280 0.999
480. 0.1253 1.000
490. 0.1228 1.000
500. 0.1203 1.000
520. 0.1156 1.000
540. 0.1113 1.000
560. 0.1073 1.001
580. 0.1036 1.001
600. 0.1001 1.001
16.838 190.92 36.35 44.79 547.6
17.289 191.87 36.93 45.36 552.6
17.746 192.81 37.50 45.93 557.6
18.208 193.75 38.08 46.50 562.5
19.149 195.59 39.21 47.63 572.2
20.113 197.41 40.32 48.73 581.8
21.098 199.20 41.41 49.81 591.2
22.105 200.97 42.48 50.87 600.4
23.133 202.71 43.52 51.90 609.5
62.8
64.7
66.6
68.5
72.3
76.2
80.1
84.0
88.0
METH^
lNE isobar at
P = 0.550 MPa
T
P
Z
H
S
Cv
Cp
W
ri
A
K
mol ■ dm" ^
kJ/mol
J/(nK)l-K) J/(mol-K) J/(nol-K:
) m-s'^
fiPa- s
mW/(m
95.
27.809
0.025
-5.501
70.22
34.00
53.70
1502.8
180.66
206.5
100.
27.387
0.024
-5.230
73.00
34.10
54.58
1450.7
158.28
200.2
105.
26.955
0.023
-4.956
75.68
33.87
55.21
1401.0
139.40
193.6
110.
26.512
0.023
-4.678
78.26
33.51
55.76
1351.9
123.47
186.8
115.
26.056
0.022
-4.398
80.75
33.08
56.32
1302.2
110.00
179.8
120.
25.585
0.022
-4.115
83.16
32.66
56.95
1251.6
98.55
172.7
125.
25.096
0.021
-3.828
85.50
32.25
57.70
1199.6
88.75
165.5
130.
24.587
0.021
-3.538
87.78
31.87
58.62
1145.9
80.28
158.2
135.
24.052
0.020
-3.242
90.01
31.52
59.76
1090.3
72.88
150.9
137.
082 23.817
0.020
-3.116
90.94
31.39
60.34
1065.8
70.02
147.7
137.
082 0.5459
0.884
4.155
143.98
27.23
40.71
285.4
5.52
15.6
140.
0.5302
0.891
4.271
144.82
26,80
39.69
290.1
5.62
15.9
145.
0.5052
0.903
4.467
146.19
26.46
38.66
191 .1
5.81
16.3
150.
0.4830
0.913
4.658
147.49
26.27
37.97
304.9
6.00
16.8
155.
0.4631
0.922
4.847
148.72
26.13
37.43
311.7
6.19
17.3
160.
0.4450
0.929
5.033
149.90
26.00
36.97
318.3
6.38
17.8
165.
0.4285
0.936
5.217
151.03
25.89
36.59
324.6
6.56
18.3
170.
0.4134
0.941
5.399
152.12
25.80
36.26
330.7
6.75
18.9
175.
0.3995
0.946
5.579
153.17
25.73
35.98
336.6
6.93
19.5
180.
0.3865
0.951
5.759
154.18
25.67
35.75
342.4
7.12
20.0
325
METHANE ISOBAR AT P = 0.550 MPa (continued)
T
P
z
H
S
Cv
%
W
»7
A
K
mol -dm"^
kJ/mol
J/(inol-K) J/(nol-K) J/(mol-K)
m-s" ^
/xPa-s
inW/(m'
185.
0.3745
.955
5.937
155.16
25.63
35.56
348.0
7.30
20.6
190.
0.3633
.958
6.114
156.10
25.60
35.40
353.4
7.49
21.2
195.
0.3528
.962
6.291
157.02
25.58
35.27
358.7
7.67
21.8
200.
0.3430
.964
6.467
157.91
25.58
35.16
363.9
7.85
22.3
205.
0.3337
.967
6.643
158.78
25.59
35.08
369.0
8.03
22.9
210.
0.3249
.969
6.818
159.62
25.60
35.02
373.9
8.21
23.4
215.
0.3167
.972
6.993
160.45
25.63
34.98
378.8
8.39
24.0
220.
0.3089
0,
.974
7.168
161.25
25.67
34.95
383.5
8.57
24.6
225.
0.3014
0,
.975
7.342
162.04
25.72
34.94
388.1
8.74
25.2
230.
0.2944
0,
.977
7.517
162.80
25.78
34.95
392.7
8.92
25.8
235.
0.2877
0,
.979
7.692
163.56
25.85
34.97
397.1
9.09
26.4
240.
0.2813
0,
,980
7.867
164.29
25.93
35.00
401.5
9.27
27.0
245.
0.2752
0,
.981
8.042
165.01
26.01
35.05
405.8
9.44
27.6
250.
0.2693
0,
.982
8.217
165.72
26.11
35.10
410.0
9.61
28.2
255.
0.2638
0,
.984
8.393
166.42
26.21
35.18
414.2
9.78
28.8
260.
0.2584
0.
,985
8.569
167.10
26.33
35.26
418.2
9.95
29.4
265.
0.2533
0.
,986
8.745
167.78
26.45
35.35
422.2
10.12
30.0
270.
0.2484
0.
,986
8.922
168.44
26.58
35.45
426.1
10.29
30.7
275.
0.2436
0.
,987
9.100
169.09
26.72
35.57
430.0
10.45
31.3
280.
0.2391
0.
,988
9.278
169.73
26.87
35.69
433.8
10.62
32.0
285.
0.2347
0,
,989
9.457
170.36
27.03
35.83
437.5
10.78
32.6
290.
0.2305
0,
,989
9.636
170.99
27.19
35.97
441.2
10.95
33.3
295.
0.2265
0,
,990
9.817
171.60
27.36
36.12
444.8
11.11
34.0
300.
0.2226
0,
,991
9.998
172.21
27.54
36.29
448.4
11.27
34.7
310.
0.2152
0.
,992
10.362
173.41
27.93
36.63
455.3
11.59
36.1
320.
0.2082
0,
,993
10.731
174.58
28.34
37.01
462.1
11.90
37.5
330.
0.2018
0,
,994
11.103
175.72
28.77
37.42
468.6
12.22
39.0
340.
0.1957
0,
,994
11.479
176.85
29.23
37.85
475.0
12.52
40.5
350.
0.1899
0,
,995
11.860
177.95
29.71
38.31
481.3
12.83
42.0
360.
0.1846
0.
,996
12.245
179.04
30.20
38.79
487.4
13.13
43.6
370.
0.1795
0.
,996
12.636
180.11
30.72
39.29
493.3
13.43
45.2
380.
0.1747
0.
,997
13.031
181.16
31.25
39.80
499.2
13.72
46.9
390.
0.1701
0.
,997
13.432
182.20
31.79
40.33
504.9
14.01
48.5
400.
0.1658
0,
,997
13.838
183.23
32.34
40.86
510.5
14.30
50.2
410.
0.1617
0,
,998
14.249
184.24
32.90
41.41
516.1
51.9
420.
0.1578
0,
,998
14.666
185.25
33.47
41.97
521.5
53.7
430.
0.1541
0.
,998
15.088
186.24
34.04
42.53
526.9
55.5
440.
0.1505
0,
.999
15.517
187.23
34.61
43.10
532.2
57.3
450.
0.1472
0.
,999
15.950
188.20
35.19
43.67
537.4
59.1
460.
0.1439
0,
,999
16.390
189.17
35.77
44.24
542.5
60.9
326
METHANE ISOBAR AT P = 0.550 MPa (continued)
W
K
mol -dm"^
kJ/mol
J/(mDl-K) J/(mDl-K) J/(nol-K)
m-s"^ /iPa-s
mW/(m
470.
0.1408
0.999
16.835
190.12
36.35
44.81
547.6
62.8
480.
0.1379
1.000
17.286
191.07
36.93
45.38
552.7
64.7
490.
0.1350
1.000
17.743
192.02
37.51
45.95
557.6
66.6
500.
0.1323
1.000
18.205
192.95
38.08
46.51
562.6
68.5
520.
0.1272
1.000
19.147
194.80
39.21
47.64
572.3
72.3
540.
0.1224
1.000
20.110
196.61
40.33
48.74
581.8
76.2
560.
0.1181
1.001
21.096
198.41
41.42
49.82
591.2
80.1
580.
0.1140
1.001
22.103
200.17
42.48
50.88
600.5
84.0
600.
0.1102
1.001
23.131
201.92
43.52
51.91
609.6
88.0
METHANE ISOBAR AT P = 0.600 MPa
H
W
K
mol -dm" ■^
kJ/mol
J/(mDl-K) J/(nol-K) J/(nol-K^
in- s' ^
/iPa
• s
mW/(m
95.
27.811
027
-5.500
70.21
34.01
53.70
1503.3
180
75
206.6
100.
27.389
026
-5.229
72.99
34.10
54.58
1451.1
158
37
200.3
105.
26.958
025
-4.955
75.67
33.87
55.21
1401.5
139
48
193.6
110.
26.515
025
-4.677
78.25
33.51
55.75
1352.4
123
55
186.8
115.
26.059
024
-4.397
80.74
33.09
56.31
1302.8
110
07
179.8
120.
25.588
024
-4.114
83.15
32.66
56.94
1252.2
98
62
172.7
125.
25.100
023
-3.827
85.49
32.25
57.69
1200.3
88
81
165.5
130.
24.591
023
-3.537
87.77
31.87
58.60
1146.6
80
34
158.3
135.
24.057
022
-3.241
90.00
31.52
59.73
1091.0
72
94
150.9
138.715
23.638
022
-3.016
91.64
31.29
60.78
1047.7
67
97
145.4
138.715
0.5933
877
4.181
143.53
27.36
41.28
285.7
5
59
15.9
140.
0.5858
880
4.232
143.90
27.12
40.73
287.9
5
64
16.0
145.
0.5572
893
4.432
145.30
26.63
39.35
295.8
5
83
16.4
150.
0.5320
904
4.626
146.62
26.40
38.52
303.2
6
02
16.9
155.
0.5094
914
4.817
147.87
26.23
37.90
310.2
6
20
17.4
160.
0.4891
922
5.006
149.06
26.10
37.38
316.9
6
39
17.9
165.
0.4706
929
5.191
150.21
25.98
36.94
323.4
6
58
18.4
170.
0.4537
936
5.375
151.30
25.88
36.57
329.6
6
76
19.0
175.
0.4381
941
5.557
152.36
25.79
36.26
335.6
6
95
19.5
180.
0.4238
946
5.738
153.38
25.73
36.00
341.4
7
13
20.1
185.
0.4104
950
5.917
154.36
25.68
35.78
347.1
7
32
20.7
190.
0.3980
954
6.096
155.31
25.64
35.60
352.6
7
50
21.3
195.
0.3863
958
6.273
156.24
25.62
35.45
358.0
7
68
21.8
200.
0.3754
961
6.450
157.13
25.61
35.33
363.2
7
86
22.4
205.
0.3652
964
6.627
158.00
25.62
35.23
368.3
8
04
22.9
327
METHANE ISOBAR AT P = 0.600 MPa (continued)
H
piiHSCyCpWi; A
K mol-dm'3 kJ/mol J/(inol-K) J/(inol-K) J/(nDl-K) m-s"i /xPa-s raW/(m-K)
210.
0.3555
0.967
6
803
158
85
25
63
35
16
373
3
8
22
23
5
215.
0.3464
0.969
6
978
159
68
25
66
35
11
378
2
8
40
24
1
220.
0.3378
0.971
7
154
160
48
25
70
35
07
383
8
58
24
6
225.
0.3296
0.973
7
329
161
27
25
74
35
05
387
7
8
75
25
2
230.
0.3218
0.975
7
504
162
04
25
80
35
05
392
3
8
93
25
8
235.
0.3145
0.977
7
680
162
80
25
87
35
06
396
7
9
10
26
4
240.
0.3074
0.978
7
855
163
54
25
94
35
09
401
1
9
28
27
245.
0.3007
0.980
8
030
164
26
26
03
35
13
405
5
9
45
27
6
250.
0.2943
0.981
8
206
164
97
26
12
35
18
409
7
9
62
28
2
255.
0.2882
0.982
8
382
165
67
26
23
35
25
413
9
9
79
28
8
260.
0.2823
0.983
8
559
166
35
26
34
35
33
417
9
9
96
29
5
265.
0.2767
0.984
8
736
167
03
26
46
35
42
422
10
13
30
1
270.
0.2713
0.985
8
913
167
69
26
59
35
52
425
9
10
30
30
7
275.
0.2661
0.986
9
091
168
34
26
73
35
63
429
8
10
46
31
4
280.
0.2611
0.987
9
269
168
98
26
88
35
75
433
6
10
63
32
285.
0.2563
0.988
9
448
169
62
27
04
35
88
437
3
10
79
32
7
290.
0.2517
0.988
9
628
170
24
27
20
36
02
441
10
95
33
4
295.
0.2473
0.989
9
809
170
86
27
37
36
17
444
6
11
12
34
300.
0.2430
0.990
9
990
171
47
27
55
36
33
448
2
11
28
34
7
310.
0.2349
0.991
10
355
172
67
27
93
36
68
455
2
11
60
36
1
320.
0.2273
0.992
10
724
173
84
28
34
37
05
462
11
91
37
6
330.
0.2202
0.993
11
096
174
98
28
78
37
46
468
5
12
22
39
340.
0.2136
0.994
11
473
176
11
29
23
37
89
475
12
53
40
5
350.
0.2073
0.995
11
854
177
21
29
71
38
34
481
2
12
84
42
1
360.
0.2014
0.995
12
240
178
30
30
21
38
82
487
3
13
14
43
6
370.
0.1959
0.996
12
630
179
37
30
72
39
31
493
3
13
43
45
2
380.
0.1906
0.996
13
026
180
43
31
25
39
83
499
2
13
73
46
9
390.
0.1856
0.997
13
427
181
47
31
79
40
35
504
9
14
02
48
5
400.
0.1809
0.997
13
833
182
49
32
34
40
89
510
5
14
30
50
2
410.
0.1764
0.998
14
245
183
51
32
90
41
43
516
1
52
420.
0.1722
0.998
14
662
184
52
33
47
41
99
521
5
53
7
430.
0.1681
0.998
15
084
185
51
34
04
42
55
526
9
55
5
440.
0.1642
0.999
15
513
186
50
34
62
43
11
532
2
57
3
450.
0.1605
0.999
15
947
187
47
35
20
43
68
537
4
59
1
460.
0.1570
0.999
16
386
188
44
35
77
44
25
542
6
61
470.
0.1536
0.999
16
832
189
39
36
35
44
82
547
7
62
8
480.
0.1504
1.000
17
283
190
34
36
93
45
39
552
7
64
7
490.
0.1473
1.000
17
740
191
29
37
51
45
96
557
7
66
6
500.
0.1443
1.000
18
202
192
22
38
08
46
53
562
6
68
5
520.
0.1387
1.000
19
144
194
07
39
21
47
65
572
4
72
3
328
METHANE ISOBAR AT P = 0.600 MPa (continued)
T p Z H S a
W
K
mol • dm" ^
540.
0.1336
1
000
560.
0.1288
1
001
580.
0.1243
1
001
600.
0.1202
1
001
kJ/mol J/(nol-K) J/(ik)1-K) J/(nDl-K) m-s'^ /iPa-s mW/(m-K)
20.108 195.89
21.094 197.68
22.101 199.45
23.129 201.19
40
33
48
75
581
9
41
42
49
83
591
3
42
48
50
89
600
6
43
52
51
92
609
7
76.2
80.1
84.1
88.0
METHANE "
[SOBAR AT
P = 0.650 MPa
T
P
Z
H
S
Cv
Cp
W
ri
\
K
mol • dm" ^
kJ/mol
J/(mol-K) J/(nDl-K) J/(mol-K:
m- s
-1
/iPa- s
mW/(m
95.
27.814
0.030
-5.499
70.21
34.01
53.69
1503
7
180.85
206.6
100.
27.392
0.029
-5.228
72.99
34.10
54.57
1451
6
158.46
200.3
105.
26.960
0.028
-4.953
75.66
33.88
55.20
1401
9
139.56
193.7
110.
26.518
0.027
-4.676
78.24
33.51
55.74
1352
8
123.62
186.9
115.
26.062
0.026
-4.396
80.73
33.09
56.30
1303
3
110.14
179.9
120.
25.592
0.025
-4.113
83.14
32.66
56.92
1252
8
98.68
172.8
125.
25.104
0.025
-3.826
85.48
32.25
57.67
1200
9
88.87
165.6
130.
24.595
0.024
-3.536
87.76
31.87
58.58
1147
3
80.40
158.3
135.
24.062
0.024
-3.240
89.99
31.53
59.71
1091
8
73.00
151.0
140.
23.499
0.024
-2.938
92.19
31.22
61.13
1033
9
66.45
143.6
140.251
23.468
0.024
-2.922
92.30
31.21
61.23
1030
5
66.12
143.2
140.251
0.6408
0.870
4.203
143.11
27.49
41.86
286
5.67
16.3
145.
0.6105
0.883
4.396
144.46
26.82
40.13
293
8
5.85
16.6
150.
0.5820
0.895
4.594
145.80
26.53
39.11
301
4
6.03
17.0
155.
0.5567
0.906
4.788
147.07
26.34
38.39
308
6
6.22
17.5
160.
0.5339
0.915
4.978
148.28
26.19
37.80
315
5
6.41
18.0
165.
0.5133
0.923
5.166
149.44
26.06
37.31
322
1
6.59
18.5
170.
0.4945
0.930
5.351
150.54
25.95
36.90
328
4
6.78
19.1
175.
0.4773
0.936
5.535
151.61
25.86
36.55
334
5
6.96
19.6
180.
0.4614
0.941
5.717
152.63
25.79
36.26
340
5
7.15
20.2
185.
0.4466
0.946
5.898
153.62
25.73
36.01
346
2
7.33
20.8
190.
0.4329
0.950
6.077
154.58
25.69
35.81
351
8
7.51
21.4
195.
0.4201
0.954
6.256
155.51
25.66
35.64
357
2
7.69
21.9
200.
0.4081
0.958
6.434
156.41
25.65
35.50
362
5
7.87
22.4
205.
0.3969
0.961
6.611
157.28
25.65
35.39
367
7
8.05
23.0
210.
0.3863
0.964
6.787
158.14
25.66
35.30
372
7
8.23
23.5
215.
0.3763
0.966
6.964
158.97
25.69
35.24
377
7
8.41
24.1
220.
0.3669
0.969
7.140
159.78
25.72
35.19
382
5
8.59
24.7
225.
0.3579
0.971
7.316
160.57
25.76
35.16
387
2
8.76
25.3
230.
0.3494
0.973
7.491
161.34
25.82
35.15
391
8
8.94
25.9
329
METHANE ISOBAR AT P = 0.650 MPa (continued)
T
K
235.
240.
245.
250.
255.
H
-3
mol • dm
0.3413
0.3337
0.3263
0.3193
0.3127
0.975
0.976
0.978
0.979
0.981
7.667
7.843
8.019
8.195
8.372
,-1
kJ/mol J/(inol-K) J/(inol-K) J/(mol-K) m-s"^ /zPa-s mW/(m-K)
162.10
162.84
163.56
164.27
164.97
25.88
25.96
26.04
26.14
26.24
35.16
35.18
35.22
35.26
35.33
396.3
400.8
405.1
409.4
413.6
9.11
9.29
9.46
9.63
9.80
26.4
27.0
27.6
28.3
28.9
260. 0.3063 0.982 8.549 165.66 26.35 35.40 417.7 9.97 29.5
265. 0.3001 0.983 8.726 166.33 26.47 35.49 421.7 10.14 30.1
270. 0.2943 0.984 8.903 167.00 26.60 35.58 425.7 10.30 30.8
275. 0.2886 0.985 9.082 167.65 26.74 35.69 429.6 10.47 31.4
280. 0.2832 0.986 9.260 168.30 26.89 35.81 433.4 10.64 32.1
285
290
295,
300,
310,
0.2780 0.987
0.2730 0.988
0.2681 0.988
0.2635 0.989
0.2547 0.990
9.440 168.93 27.05 35.94 437.1 10.80 32.7
9.620 169.56 27.21 36.08 440.8 10.96 33.4
9.801 170.18 27.38 36.22 444.5 11.12 34.1
9.982 170.79 27.56 36.38 448.1 11.29 34.8
10.348 171.98 27.94 36.72 455.1 11.60 36.1
320.
330,
340,
350.
360.
370.
380.
390.
400.
410,
420,
430,
440,
450,
460,
470
480
490
500
520,
540,
560,
580,
600
0.2464 0.991
0.2387 0.992
0.2315 0.993
0.2247 0.994
0.2183 0.995
0.2123 0.995
0.2065 0.996
0.2011 0.997
0.1960 0.997
0.1912 0.997
0.1865
0.1821
0.1779
0.1739
0.1701
0.1665
0.1629
0.1596
0.1564
0.1503
0.998
0.998
0.998
0.999
0.999
0.999
0.999
1.000
1.000
1.000
10.717 173.16
11.089 174.30
11.467 175.43
11.848 176.53
12.234 177.62
12.625 178.69
13.021 179.75
13.422 180.79
13.829 181.82
14.240 182.84
14.658
15.081
15.509
15.943
16.383
16.829
17.280
17.737
18.199
19.141
183.84
184.84
185.82
186.80
187.76
188.72
189.67
190.62
191.55
193.40
0.1447 1.000
0.1395 1.001
0.1347 1.001
0.1302 1.001
20.106 195.22
21.092 197.01
22.099 198.78
23.128 200.52
28.35
28.78
29.24
29.72
30.21
30.73
31.25
31.80
32.35
32.91
33.47
34.04
34.62
35.20
35.78
36.36
36.93
37.51
38.08
39.22
40.33
41.42
42.48
43.52
37.09
37.49
37.92
38.38
38.85
39.34
39.85
40.37
40.91
41.46
42.01
42.57
43.13
43.70
44.27
44.84
45.41
45.98
46.54
47.66
48.76
49.84
50.90
51.93
461.8
468.5
474.9
481.2
487.3
493.3
499.1
504.9
510.5
516.1
521.5
526.9
532.2
537.5
542.6
547.7
552.8
557.8
562.7
572.4
582.0
591.4
600.7
609.8
11.92
12.23
12.54
12.84
13.14
13.44
13.73
14.02
14.31
37.6
39.0
40.6
42.1
43.7
45.3
46.9
48.6
50.3
52.0
53.7
55.5
57.3
59.1
61.0
62.8
64
66,
68,
72.
76.
80,
84,
88.0
330
METHANE ISOBAR AT P = 0.700 MPa
T p Z H S C^ Cp W »; A
K mol-dm"3 kJ/mol J/(nol-K) J/(mDl-K) J/(nol-K) m-s"^ /xPa-s mW/(m-K)
95.
27.816
0.032
-5
.497
70
.20
34
.01
53
.69
1504
.1
180
.95
206
7
100.
27.394
0.031
-5
.227
72
.98
34
.10
54
.56
1452
.0
158
.55
200
4
105.
26.963
0.030
-4
.952
75
.66
33
88
55
.19
1402
4
139
.65
193
7
110.
26.521
0.029
-4
.675
78
.24
33
51
55
73
1353
3
123
.70
186
9
115.
26.065
0.028
-4
.395
80
73
33
09
56
.29
1303
8
110
.21
179
9
120.
25.595
0.027
-4
.112
83
14
32
66
56
.91
1253
3
98
.75
172
8
125. .
25.108
0.027
-3
825
85
47
32
25
57
65
1201
5
88
93
165
7
130.
24.600
0.026
-3
535
87
75
31
87
58
56
1148
80
46
158
4
135.
24.067
0.026
-3
239
89
98
31
53
59
68
1092
6
73
06
151
1
140.
23.505
0.026
-2
938
92
18
31
22
61
10
1034
8
66
51
143
7
141.703
23.303
0.025
-2
833
92
92
31
13
61
68
1014
1
64
42
141
2
141.703
0.6885
0.863
4
223
142
71
27
62
42
46
286
2
5
74
16
6
145.
0.6653
0.873
4
359
143
66
27
06
41
02
291
8
5
86
16
8
150.
0.6331
0.886
4
561
145
03
26
67
39
75
299
7
6
05
17
2
155.
0.6048
0.898
4
757
146
32
26
46
38
91
307
1
6
23
17
6
160.
0.5795
0.908
4
950
147
55
26
29
38
24
314
1
6
42
18
1
165.
0.5566
0.917
5
140
148
71
26
15
37
69
320
8
6
61
18
6
170.
0.5359
0.924
5
327
149
83
26
03
37
23
327
3
6
79
19
2
175.
0.5169
0.931
5
512
150
91
25
93
36
84
333
5
6
98
19
7
180.
0.4994
0.937
5
696
151
94
25
84
36
52
339
5
7
16
20
3
185.
0.4832
0.942
5
878
152
94
25
78
36
24
345
3
7
34
20
8
190.
0.4682
0.946
6
058
153
90
25
73
36
02
351
7
52
21
4
195.
0.4542
0.951
6
238
154
83
25
70
35
83
356
5
7
71
21
9
200.
0.4411
0.954
6
417
155
74
25
69
35
67
361
8
7
89
22
5
205.
0.4288
0.958
6
595
156
62
25
68
35
54
367
1
8
07
23
210.
0.4172
0.961
6
772
157
47
25
69
35
44
372
1
8
24
23
6
215.
0.4064
0.964
6
949
158
30
25
71
35
37
377
1
8
42
24
2
220.
0.3961
0.966
7
126
159
12
25
74
35
31
382
8
60
24
7
225.
0.3864
0.968
7
302
159
91
25
79
35
28
386
7
8
78
25
3
230.
0.3771
0.971
7
479
160
68
25
84
35
26
391
4
8
95
25
9
235.
0.3684
0.973
7
655
161
44
25
90
35
26
395
9
9
12
26
5
240.
0.3600
0.974
7
831
162
19
25
98
35
27
400
4
9
30
27
1
245.
0.3521
0.976
8
008
162
91
26
06
35
30
404
8
9
47
27
7
250.
0.3445
0.978
8
184
163
63
26
15
35
35
409
1
9
64
28
3
255.
0.3372
0.979
8
361
164
33
26
25
35
40
413
3
9
81
28
9
260.
0.3303
0.980
8
538
165
02
26
37
35
47
417
4
9
98
29
5
265.
0.3237
0.982
8
716
165
69
26
49
35
55
421
4
10
15
30
2
270.
0.3173
0.983
8
894
166
36
26
62
35
65
425
4
10
31
30
8
275.
0.3112
0.984
9
072
167
01
26
75
35
75
429
3
10
48
31
4
280.
0.3053
0.985
9
251
167
66
26
90
35
87
433
2
10
64
32
1
331
METHANE ISOBAR AT P = 0.700 MPa (continued)
T
P
Z
H
S
Cv
Cp
W
»7
A
K
mol -dni"^
kJ/mol
J/(nol.K) J/Cnol-K) J/(nK>l-K)
m-s-i
/xPa
•s
mW/(m-
285.
0.2997
0.986
9.431
168.29
27.05
35.99
436.9
10
81
32.8
290.
0.2943
0.987
9.611
168.92
27.22
36.13
440.7
10
97
33.4
295.
0.2890
0.987
9.792
169.54
27.39
36.27
444.3
11
13
34.1
300.
0.2840
0.988
9,974
170.15
27.57
36.43
447.9
11
29
34.8
310.
0.2745
0.990
10.340
171.35
27.95
36.76
454.9
11
61
36.2
320.
0.2656
0.991
10.710
172.52
28.35
37.13
461.7
11
93
37.6
330.
0.2572
0.992
11.083
173.67
28.79
37.53
468.4
12
24
39.1
340.
0.2494
0.993
11.460
174.80
29.24
37.96
474.8
12
55
40.6
350.
0.2421
0.994
11.842
175.91
29.72
38.41
481.1
12
85
42.1
360.
0.2352
0.994
12.229
176.99
30.22
38.88
487.2
13
15
43.7
370.
0.2287
0.995
12.620
178.07
30.73
39.37
493.2
13
45
45.3
380.
0.2225
0.996
13.016
179.12
31.26
39.88
499.1
13
74
46.9
390.
0.2167
0.996
13.417
180.16
31.80
40.40
504.9
14
03
48.6
400.
0.2112
0.997
13.824
181.19
32.35
40.93
510.5
14
32
50.3
410.
0.2059
0.997
14.236
182.21
32.91
41.48
516.1
52.0
420.
0.2009
0.998
14.654
183.22
33.48
42.03
521.6
53.8
430.
0.1962
0.998
15.077
184.21
34.05
42.59
526.9
55.5
440.
0.1917
0.998
15.505
185.20
34.62
43.15
532.3
57.3
450.
0.1873
0.999
15.940
186.17
35.20
43.72
537.5
59.2
460.
0.1832
0.999
16.380
187.14
35.78
44.29
542.7
61.0
470.
0.1793
0.999
16.825
188.10
36.36
44.85
547.8
62.9
480.
0.1755
0.999
17.277
189.05
36.94
45.42
552.8
64.7
490.
0.1719
1.000
17.734
189.99
37.51
45.99
557.8
66.6
500.
0.1684
1.000
18.197
190.93
38.08
46.55
562.8
68.5
520.
0.1619
1.000
19.139
192.78
39.22
47.67
572.5
72.4
540.
0.1558
1.001
20.103
194.60
40.33
48.78
582.1
76.3
560.
0.1502
1.001
21.090
196.39
41.42
49.85
591.5
80.2
580.
0.1450
1.001
22.097
198.16
42.49
50.91
600.7
84.1
600.
0.1402
1.001
23.126
199.90
43.52
51.94
609.9
88.0
METHANE
ISOBAR AT
P = 0.750 MPa
T
P
Z
H
S
Cv
Cp w
n
A
K
mol •dm"-'
kJ/mol
J/(mDl-K) J/(mol-K) J/Cmol-K) m-s"^
/iPa-s
mW/(m
95.
27.818
0.034
-5.496
70.20
34.01
53.68 1504.5
181.05
206.7
100.
27.396
0.033
-5.225
72.97
34.10
54.56 1452.4
158.64
200.4
105.
26.965
0.032
-4.951
75.65
33.88
55.18 1402.9
139.73
193.8
110.
26.523
0.031
-4.674
78.23
33.51
55.73 1353.8
123.77
187.0
115.
26.069
0.030
-4.394
80.72
33.09
56.28 1304.4
110.28
180.0
332
METHANE ISOBAR AT P = 0.750 MPa (continued)
H
K
120.
125.
130.
135.
140.
143.082
143.082
145.
150.
155.
-3
mol • dm
25.599
25.112
24.604
24.072
23.511
23.145
0.7363
0.7216
0.6855
0.6539
0.029
0.029
0.028
0.028
0.027
0.027
0.856
0.862
0.877
0.890
kJ/mol J/(nol-K) J/(nol-K) J/(inol-K) m-s-^
•4.111
■3.824
•3.534
•3.239
•2.937
83.13
85.47
87.74
89.97
92.17
-2.747 93.51
4.241 142.35
4.321 142.90
4.527 144.30
4.727 145.61
W r; A
/iPa-s mW/(m-K)
32.66 56.90 1253.9 98.81 172.9
32.25 57.64 1202.1 88.99 165.7
31.87 58.54 1148.7 80.52 158.5
31.53 59.66 1093.4 73.11 151.2
31.23 61.06 1035.6 66.56 143.8
31.06 62.13 998.4 62.86 139.2
27.75 43.06 286.3 5.81 16.9
27.36 42.07 289.6 5.88 17.0
26.84 40.46 297.8 6.07 17.3
26.58 39.46 305.4 6.25 17.8
160,
165,
170,
175,
180,
0.6258 0.901
0.6006 0.910
0.5778 0.918
0.5569 0.926
0.5378 0.932
4.922 146.85 26.39 38.71 312.6 6.44 18.2
5.114 148.03 26.24 38.09 319.5 6.62 18.7
5.303 149.16 26.11 37.58 326.1 6.81 19.2
5.490 150.24 26.00 37.15 332.4 6.99 19.8
5.675 151.28 25.90 36.79 338.5 7.17 20.3
185,
190,
195,
200,
205,
210,
215,
220,
225,
230,
5201
937
5037
942
4885
947
4743
951
4609
955
4484
958
4366
961
4255
964
4149
966
4049
968
5.858 152.29 25.83 36.48 344.4 7.36 20.9
6.039 153.26 25.78 36.23 350.2 7.54 21.5
6.220 154.20 25.74 36.02 355.7 7.72 22.0
6.400 155.11 25.72 35.85 361.1 7.90 22.5
6.579 155.99 25.71 35.70 366.4 8.08 23.1
6.757 156.85 25.72 35.59 371.6 8.26 23.7
6.935 157.68 25.74 35.50 376.6 8.43 24.2
7.112 158.50 25.77 35.44 381.5 8.61 24.8
7.289 159.30 25.81 35.39 386.3 8.79 25.4
7.466 160.07 25.86 35.37 391.0 8.96 25.9
235,
240,
245.
250,
255,
260,
265,
270,
275,
280,
285,
290,
295,
300,
310,
0.3955 0.971
0.3865 0.973
0.3779 0.974
0.3697 0.976
0.3619 0.978
0.3544 0.979
0.3472 0.980
0.3404 0.981
0.3338 0.983
0.3275 0.984
0.3214 0.985
0.3156 0.986
0.3100 0.986
0.3045 0.987
0.2943 0.989
7.643 160.83 25.92 35.36 395.5 9.14 26.5
7.819 161.58 25.99 35.37 400.0 9.31 27.1
7.996 162.31 26.07 35.39 404.4 9.48 27.7
8.173 163.02 26.17 35.43 408.7 9.65 28.3
8.351 163.72 26.27 35.48 413.0 9.82 29.0
8.528 164.41 26.38 35.54 417.1 9.99 29.6
8.706 165.09 26.50 35.62 421.2 10.16 30.2
8.884 165.76 26.63 35.71 425.2 10.32 30.8
9.063 166.41 26.76 35.81 429.1 10.49 31.5
9.243 167.06 26.91 35.92 433.0 10.65 32.1
9.422 167.70 27.06 36.05 436.8 10.82 32.8
9.603 168.33 27.23 36.18 440.5 10.98 33.5
9.784 168.95 27.40 36.32 444.2 11.14 34.1
9.966 169.56 27.58 36.48 447.8 11.30 34.8
10.333 170.76 27.95 36.81 454.8 11.62 36.2
333
METHANE ISOBAR AT P = 0.750 MPa (continued)
K
H
W
P ^ " - -V -p
mol-dm"3 kJ/mol J/(nol-K) J/(mDl-K) J/(mol-K) m-s'^
r, X
/iPa-s mW/(m-K)
320.
0.2847
0.990
10.703
171.93
28.36
37.17
461.6
11
94
37.6
330.
0.2758
0.991
11.076
173.08
28.79
37.57
468.3
12
25
39.1
340.
0.2674
0.992
11.454
174.21
29.25
37.99
474.7
12
55
40.6
350.
0.2595
0.993
11.836
175.32
29.73
38.44
481.0
12
86
42.1
360.
0.2521
0.994
12.223
176.41
30.22
38.91
487.2
13
16
43.7
370.
0.2451
0.995
12.614
177.48
30.74
39.40
493.2
13
45
45.3
380.
0.2385
0.995
13.011
178.54
31.26
39.90
499.1
13
75
47.0
390.
0.2322
0.996
13.413
179.58
31.80
40.42
504.9
14
04
48.6
400.
0.2263
0.997
13.819
180.61
32.35
40.96
510.5
14
32
50.3
410.
0.2207
0.997
14.232
181.63
32.91
41.50
516.1
52.0
420.
0.2153
0.997
14.649
182.64
33.48
42.05
521.6
53.8
430.
0.2102
0.998
15.073
183.63
34.05
42.61
527.0
55.6
440.
0.2054
0.998
15.502
184.62
34.63
43.17
532.3
57.4
450.
0.2007
0.999
15.936
185.59
35.20
43.73
537.5
59.2
460.
0.1963
0.999
16.376
186.56
35.78
44.30
542.7
61.0
470.
0.1921
0.999
16.822
187.52
36.36
44.87
547.8
62.9
480.
0.1880
0.999
17.274
188.47
36.94
45.44
552.9
64.8
490.
0.1842
1.000
17.731
189.41
37.51
46.00
557.9
66.6
500.
0.1804
1.000
18.194
190.35
38.09
46.57
562.8
68.5
520.
0.1734
1.000
19.136
192.20
39.22
47.69
572.6
72.4
540.
0.1670
1.001
20.101
194.02
40.33
48.79
582.2
76.3
560.
0.1609
1.001
21.088
195.81
41.42
49.86
591.6
80.2
580.
0.1554
1.001
22.095
197.58
42.49
50.92
600.8
84.1
600.
0.1502
1.001
23.124
199.32
43.52
51.94
610.0
88.0
METHANE ISOBAR AT P = 0.800 MPa
H
K
mol • dm" ^
kJ/mol
J/Cmol-K) J/(nol-l
95.
27.820
036
-5.495
70.19
34.01
100.
27.399
035
-5.224
72.97
34.11
105.
26.968
034
-4.950
75.65
33.88
110.
26.526
033
-4.672
78.23
33.51
115.
26.072
032
-4.392
80.71
33.09
120.
25.602
031
-4.110
83.12
32.67
125.
25.116
031
-3.823
85.46
32.26
130.
24.609
030
-3.533
87.74
31.88
135.
24.077
030
-3.238
89.96
31.53
140.
23.516
029
-2.936
92.16
31.23
w
53.68 1504.9
54.55 1452.8
55.18 1403.3
55.72 1354.3
56.26 1304.9
56.88 1254.5
57.62 1202.8
58.52 1149.4
59.63 1094.1
61.03 1036.5
181.15 206.8
158.73 200.5
139.81 193.9
123.85 187.0
110.35 180.1
98.87
89.06
80.58
73.17
66.62
173.0
165.8
158.5
151.2
143.9
334
METHANE ISOBAR AT P = 0.800 MPa (continued)
T
P
Z
H
S
Cv
Cp
W
n
A
K
inol-dm'''
kJ/mol
J/(nol-K) J/(n»l-K) J/(mDl-K)
m-s"^
H?a.- s
mW/(m'
144.396
22.992
0.029
-2.664
94.07
31.00
62.59
983.3
61.41
137.3
144.396
0.7843
0.850
4.256
142.00
27.88
43.68
286.3
5.88
17.1
145.
0.7796
0.851
4.281
142.17
27.74
43.31
287.4
5.90
17.2
150.
0.7391
0.868
4.492
143.60
27.02
41.23
296.0
6.08
17.5
155.
0.7040
0.882
4.695
144.93
26.70
40.05
303.8
6.27
17.9
160.
0.6730
0.894
4.893
146.19
26.50
39.19
311.2
6.45
18.3
165.
0.6453
0.904
5.087
147.38
26.33
38.51
318.2
6.64
18.8
170.
0.6203
0.912
5.278
148.52
26.18
37.94
324.9
6.82
19.3
175.
0.5975
0.920
5.467
149.62
26.06
37.46
331.3
7.00
19.9
180.
0.5766
0.927
5.653
150.67
25.97
37.06
337.5
7.19
20.4
185.
0.5574
0.933
5.838
151.68
25.89
36.73
343.5
7.37
21.0
190.
0.5396
0.938
6.020
152.65
25.83
36.45
349.3
7.55
21.6
195.
0.5231
0.943
6.202
153.60
25.79
36.22
355.0
7.73
22.1
200.
0.5077
0.948
6.383
154.51
25.76
36.02
360.5
7.91
22.6
205.
0.4933
0.952
6.562
155.40
25.75
35.87
365.8
8.09
23.2
210.
0.4797
0.955
6.741
156.26
25.75
35.74
371.0
8.27
23.7
215.
0.4670
0.958
6.920
157.10
25.76
35.64
376.0
8.45
24.3
220.
0.4550
0.961
7.098
157.92
25.79
35.56
381.0
8.62
24.8
225.
0.4436
0.964
7.275
158.72
25.83
35.51
385.8
8.80
25.4
230.
0.4329
0.966
7.453
159.50
25.88
35.47
390.5
8.97
26.0
235.
0.4227
0.969
7.630
160.26
25.94
35.46
395.1
9.15
26.6
240.
0.4130
0.971
7.808
161.01
26.01
35.46
399.7
9.32
27.2
245.
0.4038
0.973
7.985
161.74
26.09
35.48
404.1
9.49
27.8
250.
0.3950
0.974
8.162
162.45
26.18
35.51
408.4
9.66
28.4
255.
0.3866
0.976
8.340
163.16
26.28
35.56
412.7
9.83
29.0
260.
0.3786
0.978
8.518
163.85
26.39
35.62
416.8
10.00
29.6
265.
0.3709
0.979
8.696
164.53
26.51
35.69
420.9
10.17
30.2
270.
0.3635
0.980
8.875
165.20
26.64
35.78
424.9
10.33
30.9
275.
0.3565
0.981
9.054
165.85
26.77
35.87
428.9
10.50
31.5
280.
0.3497
0.983
9.234
166.50
26.92
35.98
432.8
10.66
32.2
285.
0.3432
0.984
9.414
167.14
27.07
36.10
436.6
10.83
32.8
290.
0.3370
0.985
9.595
167.77
27.24
36.23
440.3
10.99
33.5
295.
0.3309
0.986
9.776
168.39
27.41
36.38
444.0
11.15
34.2
300.
0.3251
0.986
9.958
169.00
27.58
36.53
447.6
11.31
34.9
310.
0.3141
0.988
10.325
170.20
27.96
36.85
454.7
11.63
36.2
320.
0.3039
0.989
10.696
171.38
28.37
37.21
461.5
11.94
37.7
330.
0.2943
0.991
11.070
172.53
28.80
37.61
468.2
12.25
39.1
340.
0.2853
0.992
11.448
173.66
29.25
38.03
474.7
12.56
40.6
350.
0.2769
0.993
11.830
174.77
29.73
38.47
481.0
12.86
42.2
360.
0.2690
0.994
12.217
175.86
30.23
38.94
487.2
13.16
43.7
335
METHANE ISOBAR AT P = 0.800 MPa (continued)
K
H
W
P ^ " _ _^ _p
mol-dm'3 kJ/mol J/(nol-K) J/(iiol-K) J/(mol-K) m-s'^
ri A
/iPa-s mW/(m-K)
370.
0.2615
0.994
12.609
176.93
30.74
39.43
493.2
13,
.46
45.3
380.
0.2544
0.995
13.006
177.99
31.27
39.93
499.1
13,
,75
47.0
390.
0.2478
0.996
13.408
179.03
31.81
40.45
504.9
14,
,04
48.6
400.
0.2414
0.996
13.815
180.06
32.36
40.98
510.5
14,
,33
50.3
410.
0.2354
0.997
14.227
181.08
32.92
41.52
516.1
52.1
420.
0.2297
0.997
14.645
182.09
33.48
42.07
521.6
53.8
430.
0.2243
0.998
15.069
183.09
34.05
42.63
527.0
55.6
440.
0.2191
0.998
15.498
184.07
34.63
43.19
532.3
57.4
450.
0.2141
0.999
15.933
185.05
35.21
43.75
537.6
59.2
460.
0.2094
0.999
16.373
186.02
35.79
44.32
542.7
61.0
470.
0.2049
0.999
16.819
186.98
36.36
44.89
547.9
62.9
480.
0.2006
0.999
17.271
187.93
36.94
45.45
552.9
64.8
490.
0.1964
1.000
17.728
188.87
37.52
46.02
557.9
66.7
500.
0.1925
1.000
18.191
189.81
38.09
46.58
562.9
68.6
520.
0.1850
1.000
19.134
191.66
39.22
47.70
572.6
72.4
540.
0.1781
1.001
20.099
193.48
40.33
48.80
582.2
76.3
560.
0.1717
1.001
21.086
195.27
41.42
49.87
591.7
80.2
580.
0.1657
1.001
22.094
197.04
42.49
50.93
600.9
84.1
600.
0.1602
1.001
23.122
198.78
43.52
51.95
610.1
88.1
METHANE ISOBAR AT P = 0.850 MPa
K
H
mol • dm
-3
W
kJ/mol J/(nol-K) J/(nDl-K) J/(nol-K) m-s'^ /iPa-s mW/(m-K)
95.
27,
.822
0.039
-5,
.493
70,
.19
34,
.01
53
.67
1505,
.3
181
.24
206
.8
100.
27,
.401
0.037
-5,
.223
72,
.96
34,
.11
54
.55
1453,
.3
158
.82
200
.5
105.
26.
.971
0.036
-4,
.948
75,
.64
33,
.88
55
.17
1403,
.8
139
.89
193
.9
110.
26,
.529
0.035
-4,
.671
78,
.22
33
.52
55
.71
1354,
.8
123
.92
187
.1
115.
26,
.075
0.034
-4,
.391
80,
.71
33,
.10
56
.25
1305,
.4
110
.42
180
.1
120.
25,
,606
0.033
-4,
.109
83,
.11
32,
.67
56,
.87
1255,
.1
98,
.94
173,
.0
125.
25,
.119
0.033
-3,
.822
85
.45
32,
.26
57,
.61
1203,
.4
89,
.12
165,
.9
130.
24,
.613
0.032
-3,
.532
87,
.73
31,
.88
58
.50
1150,
.1
80
.63
158,
.6
135.
24,
,082
0.031
-3,
.237
89,
.95
31,
.53
59,
.61
1094,
.9
73,
.23
151,
.3
140.
23,
,522
0.031
-2,
.936
92,
.15
31,
.23
61,
.00
1037.
,4
66,
.68
144,
.0
145.
22,
.926
0.031
-2,
.626
94,
.32
30,
.97
62,
.78
977.
.0
60,
.80
136,
.5
145.651
22,
.844
0.031
-2,
.585
94,
.60
30.
,94
63,
,06
968.
,7
60,
.07
135,
,5
145.651
0,
.8324
0.843
4,
.270
141,
.67
28,
,01
44,
,30
286.
,3
5,
,94
17.
,4
150.
0,
.7941
0.858
4,
.456
142,
.93
27.
,23
42,
,10
294.
,0
6.
.10
17.
,7
155.
0,
.7552
0.873
4,
.663
144,
.28
26,
.84
40.
,68
302.
,1
6.
,29
18.
,0
336
METHANE ISOBAR AT P = 0.850 MPa (continued)
T
P
Z
H
S
Cv
Cp
W
»?
A
K
mol'dm"^
kJ/mol
J/(nol-K) J/(iid1-K) J/(rrDl-K)
m-s"^
/iPa- s
mW/(m-
160.
0.7211
0.886
4.864
145.56
26.60
39.70
309.7
6.47
18.5
165.
0.6907
0.897
5.060
146.77
26.42
38.94
316.8
6.65
18.9
170.
0.6633
0.907
5.253
147.92
26.26
38.31
323.7
6.84
19.4
175.
0.6385
0.915
5.444
149.02
26.13
37.78
330.2
7.02
20.0
180.
0.6159
0.922
5.631
150.08
26.03
37.35
336.5
7.20
20.5
185.
0.5950
0.929
5.817
151.10
25.94
36.98
342.6
7.38
21.1
190.
0.5758
0.934
6.001
152.08
25.88
36.67
348.5
7.56
21.7
195.
0.5580
0.940
6.184
153.03
25.83
36.42
354.2
7.74
22.2
200.
0.5413
0.944
6.366
153.95
25.80
36.21
359.8
7.92
22.7
205.
0.5258
0.948
6.546
154.84
25.78
36.03
365.1
8.10
23.2
210.
0.5113
0.952
6.726
155.71
25.78
35.89
370.4
8.28
23.8
215.
0.4976
0.956
6.905
156.55
25.79
35.78
375.5
8.46
24.3
220.
0.4847
0.959
7.084
157.37
25.82
35.69
380.5
8.63
24.9
225.
0.4725
0.962
7.262
158.17
25.85
35.62
385.3
8.81
25.5
230.
0.4610
0.964
7.440
158.95
25.90
35.58
390.1
8.98
26.0
235.
0.4500
0.967
7.618
159.72
25.96
35.56
394.7
9.16
26.6
240.
0.4397
0.969
7.796
160.47
26.03
35.55
399.3
9.33
27.2
245.
0.4298
0.971
7.973
161.20
26.11
35.56
403.7
9.50
27.8
250.
0.4204
0.973
8.151
161.92
26.20
35.59
408.1
9.67
28.4
255.
0.4114
0.974
8.329
162.63
26.29
35.63
412.4
9.84
29.0
260.
0.4028
0.976
8.508
163.32
26.40
35.69
416.6
10.01
29.7
265.
0.3946
0.978
8.686
164.00
26.52
35.76
420.7
10.18
30.3
270.
0.3868
0.979
8.865
164.67
26.65
35.84
424.7
10.34
30.9
275.
0.3792
0.980
9.045
165.33
26.78
35.94
428.7
10.51
31.6
280.
0.3720
0.982
9.225
165.97
26.93
36.04
432.6
10.67
32.2
285.
0.3650
0.983
9.405
166.61
27.08
36.16
436.4
10.84
32.9
290.
0.3584
0.984
9.586
167.24
27.24
36.29
440.1
11.00
33.5
295.
0.3519
0.985
9.768
167.86
27.41
36.43
443.8
11.16
34.2
300.
0.3457
0.986
9.951
168.48
27.59
36.57
447.5
11.32
34.9
310.
0.3340
0.987
10.318
169.68
27.97
36.90
454.6
11.64
36.3
320.
0.3231
0.989
10.689
170.86
28.37
37.26
461.4
11.95
37.7
330.
0.3129
0.990
11.063
172.01
28.81
37.64
468.1
12.26
39.2
340.
0.3033
0.991
11.442
173.14
29.26
38.06
474.6
12.57
40.7
350.
0.2944
0.992
11.824
174.25
29.74
38.50
480.9
12.87
42.2
360.
0.2859
0.993
12.212
175.34
30.23
38.97
487.1
13.17
43.8
370.
0.2779
0.994
12.604
176.42
30.74
39.45
493.2
13.47
45.4
380.
0.2704
0.995
13.001
177.48
31.27
39.96
499.1
13.76
47.0
390.
0.2633
0.996
13.403
178.52
31.81
40.47
504.9
14.05
48.7
400.
0.2566
0.996
13.810
179.55
32.36
41.00
510.5
14.34
50.4
410.
0.2502
0.997
14.223
180.57
32.92
41.54
516.1
52.1
337
METHANE ISOBAR AT P = 0.850 MPa (continued)
K
H
W
mol-dm"2 kJ/mol J/(nDl-K) J/(nol-K) J/(nol-K) m-s"^ /iPa-s mW/(iii-K)
420.
0.2441
0.997
14.641
181.58
33.49
42.09
521.6
53.8
430.
0.2383
0.998
15.065
182.58
34.06
42.64
527.0
55.6
440.
0.2328
0.998
15.494
183.56
34.63
43.20
532.3
57.4
450.
0.2275
0.998
15.929
184.54
35.21
43.77
537.6
59.2
460.
0.2225
0.999
16.369
185.51
35.79
44.33
542.8
61.1
470.
0.2177
0.999
16.816
186.47
36.37
44.90
547.9
62.9
480.
0.2131
0.999
17.268
187.42
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